• Title/Summary/Keyword: Thermal and dielectric properties

Search Result 427, Processing Time 0.026 seconds

Microstructure and Dielectric Properties of (Sr.Ca)$TiO_3$-based Ceramics Exhibiting nonlinear Characteristics (비선형 특성을 갖는 (Sr.Ca)$TiO_3$계 세라믹의 미세구조 및 유전특성)

  • 최운식;강재훈;김진사;김충혁;조춘남
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.07a
    • /
    • pp.406-409
    • /
    • 2001
  • In this paper, the microstructure and the dielectric properties of the Sr$_{1-x}$ Ca$_{x}$TiO$_3$(0$\leq$$\chi$$\leq$0.2) -based grain boundary layer ceramics were investigated. The specimens were sintered from 142$0^{\circ}C$ to 152$0^{\circ}C$ for 4hr. in $N_2$ gas. The 2nd phase formed by thermal diffusing from the surface lead to a very high apparent dielectric constant, $\varepsilon$$_{r}$>50000. The structural properties of the specimens were studied by X-ray diffraction and SEM, EDX. All specimens exhibited cubic structure. Increasing content of Ca, the peak intensity were decreased.ed.d.

  • PDF

Microstructures and Dielectric Properties of SrTiO$_3$-Based BL Capacitor with Content of Ca

  • 김충혁;최운식;이준웅
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.12 no.1
    • /
    • pp.35-43
    • /
    • 1999
  • Microstructures and dielectric properties of (Sr$\_$1-x/Ca$\_$x/) TiO$_3$-0.006Nb$_2$O$\_$5/ (0.05$\leq$x$\leq$0.2) boundary layer ceramics were investigated. The samples fired in a reducing atmosphere(N$_2$) were painted on the surface with CuO paste for the subsequent grain boundary diffusion, and then annealed at 1100$^{\circ}C$ for 2 hrs. The metal oxide of CuO infiltrated by thermal diffusion from surface of sample presents continuously in not grain but only grain boundary, and makes up thin boundary phase. The SEM photo, and EDAX revealed that CuO was penetrated rapidly into the bulk along the grain boundaries during the annealing. The average grain sizes is continuously increased as the content of substitutional Ca is increased from 5[mol%] to 15[mol%], but the average grain size of the sample with content of 20[mol%] Ca is slightly decreased. In the samples with content of 10∼15[mol%] Ca, excellent dielectric properties were obtained as follows; dielectric constant <25000, dielectric loss <0.3[%], and capacitance change rate as a function of temperature <${\pm}$10[%], respectively. All samples in this study exhibited dielectric relaxation with frequency as a functior of the temperature.

  • PDF

Investigations on Partial Discharge, Dielectric and Thermal Characteristics of Nano SiO2 Modified Sunflower Oil for Power Transformer Applications

  • Nagendran, S.;Chandrasekar, S.
    • Journal of Electrical Engineering and Technology
    • /
    • v.13 no.3
    • /
    • pp.1337-1345
    • /
    • 2018
  • The reliability of power transmission and distribution depends up on the consistency of insulation in the high voltage power transformer. In recent times, considering the drawbacks of conventional mineral oils such as poor biodegradability and poor fire safety level, several research works are being carried out on natural ester based nanofluids. Earlier research works show that sunflower oil has similar dielectric characteristics compared with mineral oil. BIOTEMP oil which is now commercially available in the market for transformers is based on sunflower oil. Addition of nanofillers in the base oil improves the dielectric characteristics of liquid insulation. Only few results are available in the literature about the insulation characteristics of nano modified natural esters. Hence understanding the influence of addition of nanofillers in the dielectric properties of sunflower oil and collecting the database is important. Considering these facts, present work contributes to investigate the important characteristics such as partial discharge, lightning impulse, breakdown strength, tandelta, volume resistivity, viscosity and thermal characteristics of $SiO_2$ nano modified sunflower oil with different wt% concentration of nano filler material varied from 0.01wt% to 0.1wt%. From the obtained results, nano modified sunflower oil shows better performance than virgin sunflower oil and hence it may be a suitable candidate for power transformer applications.

STRUCTURAL MORPHOLOGY AND DIELECTRIC PROPERTIES OF POLYANILINE-EMERALDINE BASE AND POLY METHYL METHACRYLATE THIN FILMS PREPARED BY SPIN COATING METHOD

  • Shekar, B. Chandar;Yeon, Ji;Rhee, Shi-Woo
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2003.07a
    • /
    • pp.1081-1084
    • /
    • 2003
  • Structural morphology, annealing behavior and dielectric properties of polyaniline-emeraldine base (Pani-EB) and poly methyl methacrylate (PMMA) thin films prepared by spin coating technique have been studied. MIM and MISM structures were used to investigate annealing and dielectric behavior. The XRD and AFM spectrum of as grown and annealed thin films indicates the amorphous nature. The observed amorphous phase, low loss, dielectric behavior and thermal stability even at high temperatures implies the feasibility of utilizing PMMA and Pani-EB thin films as gate dielectric insulator layer in organic thin film transistors which can find application in flat panel display.

  • PDF

Characteristics of AlN Dielectric Layer for Metal PCB as a Function of Nitrogen Partial Pressure Using RF-Magnetron Sputtering Method (RF-Magnetron Sputtering 방법을 이용해 질소분압비에 따른 금속 PCB용 AlN 절연막의 특성)

  • Kim, Hwa-Min;Park, Jeong-Sik;Kim, Dong-Young;Bae, Kang;Sohn, Sun-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.23 no.10
    • /
    • pp.759-762
    • /
    • 2010
  • In this investigation, the effects of $N_2/(Ar+N_2)$ gas partial pressure on the structural, electrical, and thermal properties of AlN dielectric layers prepared on aluminum substrates using RF-magnetron sputtering method were analyzed. Among the films, the AlN dielectric film deposited under $N_2/(Ar+N_2)$ gas partial pressure of 75% exhibit the highest AlN (002) preferred orientation, which was grain size of about 15.32 nm and very dense structure. We suggest the possibilities of it's application as a dielectric layer for metal PCB because the AlN films prepared at optimized gas partial pressure can improving the insulating property, the thermal conductivity, and thermal diffusivity of the films.

Synthesis and Characterization of Graphene Based Unsaturated Polyester Resin Composites

  • Swain, Sarojini
    • Transactions on Electrical and Electronic Materials
    • /
    • v.14 no.2
    • /
    • pp.53-58
    • /
    • 2013
  • Graphene-based polymer nanocomposites are very promising candidates for new high-performance materials that offer improved mechanical, barrier, thermal and electrical properties. Herein, an approach is presented to improve the mechanical, thermal and electrical properties of unsaturated polyester resin (UPR) by using graphene nano sheets (GNS). The extent of dispersion of GNS into the polymer matrix was also observed by using the scanning electron microscopy (SEM) which indicated homogeneous dispersion of GNS through the UPR matrix and strong interfacial adhesion between the GNS and UPR matrix were achieved in the UPR composite, which enhanced the mechanical properties. The tensile strength of the nanocomposites improved at a tune of 52% at a GNS concentration of 0.05%. Again the flexural strength also increased around 92% at a GNS concentration of 0.05%. Similarly the thermal properties and the electrical properties for the nanocomposites were also improved as evidenced from the differential scanning caloriemetry (DSC) and dielectric strength measurement.

Characteristics of transparent dielectric in PbO-B$_2$O$_3$-${SiO_2}-{Al_2}{O_3}$ system and investigation of reaction between dielectric and electrode(ITO) (투명 유전체 PbO-B$_2$O$_3$-${SiO_2}-{Al_2}{O_3}$의 물성 및 전극(ITO)과의 반응성 연구)

  • Lee, Jae-Yeol;Hong, Gyeong-Jun;Kim, Deok-Nam;Kim, Hyeong-Sun;Heo, Jeung-Su
    • Korean Journal of Materials Research
    • /
    • v.11 no.4
    • /
    • pp.305-311
    • /
    • 2001
  • $PbO-B_2O_3-SiO_2-Al_2O_3$, system was investigated for optical, thermal and electrical properties of transparent dielectric. We also studied the reaction between transparent dielectric and transparent electrode(Indium Tin Oxide, ITO) during firing. For the evaluation of properties, dielectrics were prepared under the conditions fired at 520~58$0^{\circ}C$ with 12$\mu\textrm{m}$ thickness. In the reaction between dielectrics and electrode(ITO), In ions diffused into dielectric layer, while Sn ion diffusion was not observed. The coefficient of thermal expansion, the dielectric constant, the glass transition temperature and the transmittance of the dielectric were greatly dependent on PbO content. The increase of the coefficient of thermal expansion and the dielectric constant were monitored by increasing PbO, while the glass transition temperature and the transmittance were decreased. With the increased $Al_2O_3/B_2O_3$ ratio, the coefficient of thermal expansion and the transmittance were decreased, while the dielectric constant was increased. The glass transition temperature did not change significantly.

  • PDF

Dielectric Characterization of Unsaturated Polyester Curing (불포화 폴리에스터의 경화에 따른 유전특성 연구)

  • 오경성;김홍경;김명덕;남재도
    • Polymer(Korea)
    • /
    • v.26 no.6
    • /
    • pp.728-736
    • /
    • 2002
  • The thermal and dielectric properties of unsaturated polyester resin system during cure were analyzed under Isothermal conditions. Both $varepsilon$′ and $varepsilon$" decreased and dipole relaxation was observed under isothermal conditions during cure. The ionic conductivity decreased linearly with the conversion according to the Kienle-Rate equation (ln($varepsilon$"$_{ionic}$we$_{0}$)=C$_{r}$$alpha$+C$_{0}$) up to $alpha$=0.15, after which it aparted from the relationship due to the entanglement of polymer chains. The effect of ionic conductivity was revealed to be larger than that of dipole motion during the whole cure through the electrical modulus analysis. Although dielectric motion was analyzed with Debye model, it was observed only at a narrow time region of middle stage of cure. In order to estimate the dielectric properties during the whole cure, the Havriliak-Negami model was considered and modified with the strong effect of ionic conductivity. The changes of $varepsilon$′ and $varepsilon$" were well estimated with this modified Havriliak-Negami model.

A Study on the Insulation Properties for Stator Form-wound Winding by Thermal Degradation Test (가속 열열화 시험에 의한 고정자 형권 코일의 절연특성에 관한 연구)

  • 채승훈;김상걸;오현석;신철기;왕종배;김기준;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.07a
    • /
    • pp.115-118
    • /
    • 2000
  • In case of developing new motor, many examinations was tested to decide a motor efficiency and reliability. To give reliability judgment, traction motor winding insulation was tested by electrical method after appling electrical, heat, mechanical, environmental stress. In this study, stator form-wound winding of traction motor in urban transit E.M.U was tested by accelerative thermal degradation test. Stator form-wound winding was tested on the accelerative degradation composed of heat, vibration, moisture, overvoltage and researched insulation resistance, dielectric loss, partial discharge for insulation degradation properties, evaluated withstand voltage. Degradation temperature was $230[^\circ{C}]$, $250[^\circ{C}]$, $270[^\circ{C}]$, for stator form-wound winding respectively. On the test results of accelerative thermal degradation, insulation properties were relied all temperature until 10 times and expected life was evaluated by the rule of reducing $10[^\circ{C}]$ life into halves. Expected life was 31.8 years. It is guaranteed insulation reliability because of exceeding 25 years life times as considering.

  • PDF

Effects of Alumina Powder on the Properties of Mica Sheet Impregnated with Silicone Rubber Resin (알루미나 분말의 첨가에 따른 실리콘고무수지 함침 마이카시트의 특성)

  • Park Hyo-Yul;Kang Dong-Pil;Ahn Myeong-Sang;Myung In-Hye
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.54 no.12
    • /
    • pp.561-566
    • /
    • 2005
  • This paper describes electrical resistivity, dielectric strength, thermal conductivity, thermal stability and tensile strength of mica sheet impregnated with silicone rubber resin or silicone rubber resin containing alumina powder. The mica sheet impregnated with silicone rubber resin had higher electrical resistivity, dielectric strength and tensile strength than those of virgin mica sheet. Electrical resistivity of mica sheet impregnated with silicone rubber resin containing alumina increased with increasing the amount of alumina. However, dielectric strength and tensile strength of mica sheet impregnated with silicone rubber resin containing alumina decreased with increasing the amount of alumina. The mica sheet impregnated with silicone rubber resin had lower thermal conductivity than that of virgin mica sheet. However, thermal conductivity of mica sheet impregnated with silicone rubber resin conatining alumina increased with increasing the amount of alumina. In the case of thermal stability, thermal degradation of virgin mica sheet and impregnated mica sheet with silicone rubber resin did not occur up to $1100^{\circ}C$ and $400^{\circ}C$, respectively.