• 제목/요약/키워드: Thermal Transformation

검색결과 389건 처리시간 0.029초

로켓 추진제의 익스트림-스케일 상면 두께 예측 (Predicting Extreme-Thickness of Phase Fronts in HMX- and Hydrocarbon-based Propellants)

  • 여재익
    • 한국항공우주학회지
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    • 제37권1호
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    • pp.82-88
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    • 2009
  • 정상파 시스템의 구조는 발열반응으로 상변화를 하는 물질의 연속방정식에 의해 타당성을 검증받는다. 1차원 연속체 충격 구조 분석에서의 이론적 배경을 기반으로, 상변화 현상과 관련된 파의 마이크로 두께를 산출하였다. 상변화를 하는 물질로써, n-heptane은 탄화수소 연료의 증발과 응축 분석에 사용하였고, HMX은 고체 로켓 연료의 용융과 응고 분석에 사용하였다. n-heptane의 증발-응축 면의 산출 두께는 $10^{-2}$ 마이크론 차수이고, 반면에 HMX의 용융-응고 면의 산출 두께는 1 마이크론 차수 이다. 소개된 상면 두께 산출 이론은 실험적으로 얻을 수 없는 방대한 범위의 에너지 물질까지 계산범위를 확장시킬 수 있다.

Identification of the Genes Involved in the Fruiting Body Production and Cordycepin Formation of Cordyceps militaris Fungus

  • Zheng, Zhuang-Li;Qiu, Xue-Hong;Han, Ri-Chou
    • Mycobiology
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    • 제43권1호
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    • pp.37-42
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    • 2015
  • A mutant library of Cordyceps militaris was constructed by improved Agrobacterium tumefaciens-mediated transformation and screened for degradation features. Six mutants with altered characters in in vitro and in vivo fruiting body production, and cordycepin formation were found to contain a single copy T-DNA. T-DNA flanking sequences of these mutants were identified by thermal asymmetric interlaced-PCR approach. ATP-dependent helicase, cytochrome oxidase subunit I and ubiquitin-like activating enzyme were involved in in vitro fruiting body production, serine/threonine phosphatase involved in in vivo fruiting body production, while glucose-methanol-choline oxidoreductase and telomerase reverse transcriptase involved in cordycepin formation. These genes were analyzed by bioinformatics methods, and their molecular function and biology process were speculated by Gene Ontology (GO) analysis. The results provided useful information for the control of culture degeneration in commercial production of C. militaris.

Ti산화물강의 HAZ인성 및 미세조직에 미치는 용접열 cycle의 영향 (Effect of weld thermal cycle on the HAZ toughness and microstructure of a Ti-oxide bearing steel)

  • 정홍철;한재광;방국수
    • Journal of Welding and Joining
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    • 제14권2호
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    • pp.46-56
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    • 1996
  • HAZ impact toughness of Ti-oxide steel was investigated and compared to that of a conventional Ti-nitride steel. Toughness variations of each steel with weld peak temperatures and cooling rates were interpreted with microstructural transformation characteristics. In contrast to Ti-nitride steel showing continuous decrease in HAZ toughness with peak temperature, Ti-oxide steel showed increase in HAZ toughness above $1400^{\circ}C$ peak temperature. The HAZ microstructure of the Ti-oxide steel is characterized by the formation of intragranular ferrite plate, which was found to start from Ti-oxide particles dispersed in the matrix of the steel. Large austenite grain size above $1400^{\circ}C$ promoted intragranular ferrite plate formation in Ti-oxide steel while little intragranular ferrite plate was formed in Ti-nitride steel because of dissolution of Ti-nitrides. Ti-oxides in the Ti-oxide steel usually contain MnS and have crystal structures of TiO and/or $Ti_2O_3$.

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ZTA에서 잔류응력이 파괴인성 증진에 미치는 영향 (Effects of the Residual Stress on Fracture Toughness in ZTA)

  • 이영민;유진
    • 한국세라믹학회지
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    • 제27권3호
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    • pp.329-336
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    • 1990
  • In this investigation, bar-shaped specimens which consisted of three layers are prepared to study the effects of residual compressive stress on the mechanical properties in ZTA. The outer layers contained Al2O3 and unstabilized ZrO2 and the central layer contained Al2O3 and stabilized ZrO2(with 5.10wt% Y2O3). When cooled from the sintering temperature, some of zirconia in the outer layers transformed to the monoclinic form while zirconia in the central layer was retained in the tetragonal form. The transformation which induces to dilatational expansion led to the estabilishmenet of compressive stress in the outer layers and balances tensile stress in the central layer. Decrease of outer layer thickness(for a fixed total thickness)increases residual compressive stress. Because of residual compressive stress in the outer layers, the fracture toughness of outer layers of 3-layers composite is 10.21 Mpam1/2, which is increased to 25% above in comparison with 1-layer specimens in ZTA. Also, the 3-layers composite is believed to exhibite greater fracture resistance in contact damage environment from thermal shock test.

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리튬-암모니아 $(Li(NH_3)_n)$ 용액을 이용한 열전기적 특성 실험 (Experimental Study of Thermo-electric material using Lithium-Ammonia$(Li(NH_3)_n)$ Solution)

  • 박한우;김지범;전준현
    • Korean Chemical Engineering Research
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    • 제49권2호
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    • pp.263-270
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    • 2011
  • 본 논문의 목적은 리튬-암모니아 솔루션$(Li(NH_3)_n)$의 실험을 통하여 암모니아물질의 임계점인 $-40^{\circ}C$ 근처에서의 열전특성을 분석하고 이를 증명하는 것이다. 실험 결과 0.58 MPM~1.87 MPM을 갖는 리튬-암모니아 솔루션 $(Li(NH_3)_n)$ 은 온도차$({\Delta}T=0{\sim}15^{\circ}C)$에서 전류가 전압에 비례하는 열전전력을 발생시킨다는 사실을 확인하였다. 본 논문은 열전 물질 개발에 새로운 방향을 제시할 것이다.

$Al_2O_3/SiC$ Hybrid-Composite에서 SiC에 질화물 코팅의 영향 (The Effect of Nitride Coating on SiC Platelet in $Al_2O_3/SiC$ Hybrid-Composite)

  • 이수영;임경호;전병세
    • 한국세라믹학회지
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    • 제34권4호
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    • pp.406-412
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    • 1997
  • Al2O3/SiC hybrid-composite has been fabricated by the conventional powder process. The addition of $\alpha$-Al2O3 as seed particles in the transformation of ${\gamma}$-Al2O3 to $\alpha$-Al2O3 provided a homogeneity of the microstructure. The grain growth of Al2O3 are significantly surpressed by the addition of nano-size SiC particles. Dislocation were produced due to the difference of thermal expansion coefficient between Al2O3 and SiC and piled up on SiC particles in Al2O3 matrix, resulting in transgranular fracture. The high fracture strength of the composite was contributed to the grain refinement and the transgranular fracture mode. The addition of SiC platelets to Al2O3/SiC nano-composite decreased the fracture strength, but increased the fracture toughness. Coated SiC platelets with nitrides such as BN and Si3N4 enhanced fracture toughness much more than non-coated SiC platelets by enhancing crack deflection.

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金屬熱處理를 위한 高溫面의 膜沸騰急冷却에 관한 硏究 (第1報, 炭素鋼 켄칭 過程의 冷却曲線과 過渡沸騰熱傳達) (A Study on the Film Boiling-Quenching Process of the Hot Surface for the Heat Treatment of Metals (1st Report, Cooling Curves and Transient Boiling Heat Transfer during the Quenching Process of Carbon Steel))

  • 윤석훈;홍영표;김경근;정대인
    • Journal of Advanced Marine Engineering and Technology
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    • 제15권3호
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    • pp.57-65
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    • 1991
  • The quenching of steels by water is one of the important problems in engineering for the applications of heat treatment or continuous casting process, but the fundamental researches by the theoretical approaches have not been satisfactorily improved yet. The very rapid cooling problems by the thermal conduction including the latent heat of phase transformation in steel and the transient boiling heat transfer of water on the surface of the steel covering from $850^{\circ}C$ to $20^{\circ}C$ are the key problems of heat treatment. The present quenching experiments are performed for the cylindrical specimens of carbon steel, S45C of diameters (12-30). Nonlinear transient heat conduction and transient boiling heat transfer problem of water on the surface of specimens is analyzed by the numerical method of inverse heat conduction problem. The conditions for the calculation are that the initial temperature of specimens is $820^{\circ}C$ and the cooling water in bath are $20^{\circ}C$,$40^{\circ}C$,$60^{\circ}C$,$80^{\circ}C$,$95^{\circ}C$ with no agitation.

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방전 드릴을 이용한 미세 홀 관통 공정의 전극 소모량 실시간 예측 (Real-Time Prediction of Electrode Wear for the Small Hole Pass-Through by EDM-drill)

  • 최용찬;허은영;김종민;이철수
    • 한국생산제조학회지
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    • 제22권2호
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    • pp.268-274
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    • 2013
  • Electric discharge machining drill (EDM-drill) is an efficient process for the fabrication of micro-diameter deep metal hole. As there is non-physical contact between tool (electrode) and workpiece, EDM-drill is widely used to machine the hard machining materials such as high strength steel, cemented carbide, titanium alloys. The electro-thermal energy forces the electrode to wear out together with the workpiece to be machined. The electrode wear occurs inside of a machining hole. and It causes hard to monitor the machining state, which leads the productivity and the quality to decrease. Thus, this study presents a methodology to estimated the electrode wear amount while two coefficients (scale factor and shape factor) of the logarithmic regression model are evaluated from the experiment result. To increase the accuracy of estimation model, the linear transformation method is adopted using the differences of initial electrode wear differences. The estimation model is verified through experiment. The experimental result shows that within minute error, the estimation model is able to predict accurately.

예혼합 및 대향류확산 화염에서 NO의 생성에 미치는 소반응의 역할 (Roles of Key Elementary Reaction for NO Formation in Premixed Flame and Counterflow Diffusion Flame)

  • 최낙정;윤석범
    • Journal of Advanced Marine Engineering and Technology
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    • 제22권1호
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    • pp.108-116
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    • 1998
  • In this paper it is investigated the roles of key elementary reactions for NO formation in methane-air one-dimensional premixed flame and counterflow diffusion flame, which were studied numerically by using NO kinetics and $C_{2}$ -chemistry complied by Miller and Bowman. The spatial distributions of the reaction rates of 9 main elementary reactions directly related to NO formation and destruction were calculated. Integration of the rates of all reactions in the NO formation across the flame yields the quantitative reaction path diagram, which shows clearly relative importance of each reaction path in NO formation and how it changes with the type and parameters of the flame. The results show that the thermal and Fenimore mechanisms are dominant respectively for learn and rich premixed flames, and the latter is dominant for diffusion flames. In addition, it was found that the HCN recycle route is important for diffusion flame, and that the routes of mutual transformation between NO and NO$^{2}$, and between NO and HNO do not contribute to the net NO formation.

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The Phase Transition and Thermochromic Characteristics of W/Mg-codoped Monoclinic VO2 Nanoparticle and Its Composite Film

  • Park, Heesun;Kim, Jongmin;Jung, Young Hee;Kim, Yeong Il
    • 대한화학회지
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    • 제61권2호
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    • pp.57-64
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    • 2017
  • Monoclinic $VO_2(M)$ nanoparticles codoped with 1.5 at. % W and 2.9 at. % Mg were synthesized by the hydrothermal treatment and post-thermal transformation method of $V_2O_5-H_2C_2O_4-H_2O$ with $Na_2WO_4$ and $Mg(NO_3)_2$. The composite thin film of the W/Mg-codoped $VO_2(M)$ with a commercial acrylic block copolymer was also prepared on PET substrate by wet-coating method. The reversible phase transition characteristics of the codoped $VO_2(M)$ nanoparticles and the composite film were investigated from DSC, resistivity and Vis-NIR transmittance measurements compared with the undoped and Wdoped $VO_2(M)$ samples. Mg-codoping into W-doped $VO_2(M)$ nanoparticles synergistically enhanced the transition characteristics by increasing the sharpness of transition while the transition temperature ($T_c$) lowered by W-doping was maintained. The codoped composite film showed the prominently enhanced NIR switching efficiency compared to only W-doped $VO_2(M)$ film with a lowered $T_c$.