• 한국전산구조공학회논문집
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• 제28권3호
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• pp.325-333
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• 2015

최근들어 철근콘크리트 슬래브와 벽의 연결부에 적용 가능한 열교차단장치에 대한 연구가 다수 수행되고 있다. 이에 본 연구에서는 열교차단장치가 적용된 슬래브의 균열 전 탄성거동, 균열 후 항복거동 및 극한강도까지 적용이 가능한 해석모델을 제안하고, 실험결과와의 비교를 통하여 제안 모델의 정확도를 검증하고자 하였다. 해석모델은 변형률 적합조건과 힘의 평형개념을 적용하였으며, 이 때 구성 재료의 응력-변형률 관계는 재료실험 결과를 적용하였다. 해석모델의 신뢰성 검증을 위해 모멘트-곡률 관계, 하중단계에 따른 중립축을 실험결과와 비교하였으며, 제안된 해석모델은 실험결과로 획득한 전체적인 휨거동 양상과 거의 일치함을 확인할 수 있었다.

• 폴리머
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• 제29권2호
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• pp.161-165
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• 2005

Octamethylcyclotetrasiloxane$(D_4)$과 1,3,5-trimethyl-1,3,5-triphenylcyclotrisiloxane$(D_3^{MePh})$을 1,1,3,3,-tetramethyl-1,3-divinylsiloxane(MVS)과 평형중합시켜 dimethylsiloxane과 methylphenylsiloxane block unit를 갖는 $\alpha,\omega-vinyl$ poly(dimethyl-methylphenyl)siloxane prepolymer(VPMPS)를 제조하였으며 또한 $D_4$와 1,3,5-trimethyl-1,3,5-trifluoropropylcyclotrisiloxane $(D_3^{M3,F3P})$을 1,1,3,3-tetramethyldisiloxane과 평형중합시켜 dimethylsiloxane과 methyltrifluoropropyl siloxane block unit를 갖는 $\alpha,\omega-hydrogen$ poly(dimethyl-methyltrifluoropropyl)siloxane prepolymer(HPDMFS)를 제조하였다. VPMPS, HPDMFS, 열전도 필터 및 촉매를 고속교반기에 가하고 $130^{\circ}C$에서 컴파운딩하여 저경도 poly(organosiloxane) rubber를 제조하였으며 이의 가교밀도는 $115^{\circ}C$에서 oscillation rheometer를 이용하여 측정하였다. 열전도성 충전제로 구상 알루미나를 Horsfield's packing model에 따라 평균입자경의 분포를 조절하여 제조한 composite TC-POXR-2의 열전도도가 1.13 W/mK, 그리고 TC-POXR-4가 1.19 W/mK였으며 이는 단일입자경을 갖는 충전제를 가하여 제조한 경우보다 높은 열전도성을 나타내었다.

• Elastomers and Composites
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• 제54권4호
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• pp.359-367
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• 2019

Poly(2-hydroxyethyl methacrylate) (PHEMA) hydrogels modified with various co-monomers, such as N-vinyl pyrrolidone (NVP), glycidyl methacrylate (GMA), and glycerol monomethacrylate (GMMA), were prepared to investigate the effect of adding a co-monomer on the water contents, surface wettability, and tensile modulus. These polymers were synthesized by thermal- and photo-polymerization in the presence of azobisisobutyronitrile (AIBN) and diphenyl(2,4,6-trimethylbenzoyl)-phosphineoxide (TPO) as the initiators. The characteristics of the hydrogels were analyzed via FTIR and UV/Vis spectroscopies, contact angle measurements, and tensile modulus measurements with UTM. Regarding the properties of water in the hydrogels, the ratio between free to bound water was investigated using differential scanning calorimetry (DSC). The effects of adding the co-monomers on the water content, surface wettability, and tensile modulus for soft contact lenses were also investigated. In the case of p(HEMA-co-NVP) hydrogels, the increase in the equilibrium water content (EWC) was primarily due to the increase in the bound water content. For p(HEMA-co-GMMA) hydrogels, an increase in free water content was the main reason for the increased EWC. In contrast, in the case of p(HEMA-co-GMA) hydrogels, a decrease in bound water content was observed to be the main factor that reduced the EWC. Photo-polymerized PHEMA hydrogels showed enhanced surface wettability and tensile modulus as compared to those produced via thermal polymerization.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1997년도 Proceedings of the 12th KACG Technical Meeting and the 4th Korea-Japan EMGS (Electronic Materials Growth Symposium)
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• pp.7-11
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• 1997

SiC/C functionally gradient material (FGMs) were formed on graphite substrates by hot-wall chemical vapor deposition (CVD) technique using the SiCl$_4$-C$_3$H8-H$_2$ chemistry. Thermochemical equilibrium calculations were carried out to investigate the deposition process. The effect of process variables on the deposition yield and the SiC/C ratio in deposited layers was studied in detail. Calculated results showed a reasonable agreement with the experiment in a qualitative sense. SiC/C FGMs with excellent mechanical and thermal properties could be successfully formed on graphite substrates by carefully controlling the compositions in the deposited layers.

• Smart Structures and Systems
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• 제8권3호
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• pp.275-302
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• 2011

This is a review paper on mathematical modeling of actively controlled piezo smart structures. Paper has four sections to discuss the techniques to: (i) write the equations of motion (ii) implement sensor-actuator design (iii) model real life environmental effects and, (iv) control structural vibrations. In section (i), methods of writing equations of motion using equilibrium relations, Hamilton's principle, finite element technique and modal testing are discussed. In section (ii), self-sensing actuators, extension-bending actuators, shear actuators and modal sensors/actuators are discussed. In section (iii), modeling of thermal, hygro and other non-linear effects is discussed. Finally in section (iv), various vibration control techniques and useful software are mentioned. This review has two objectives: (i) practicing engineers can pick the most suitable philosophy for their end application and, (ii) researchers can come to know how the field has evolved, how it can be extended to real life structures and what the potential gaps in the literature are.

• Bulletin of the Korean Chemical Society
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• 제33권10호
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• pp.3391-3396
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• 2012

Two-dimensional infrared (2D-IR) spectroscopy can probe the fast structural evolution of molecules under thermal equilibrium. Vibrational frequency fluctuation caused by structural evolution produced the time-dependent line shape change in 2D-IR spectrum. A variety of methods has been used to connect the evolution of 2D-IR spectrum with Frequency-Frequency Correlation Function (FFCF), which connects the experimental observables to a molecular level description. Here, a new method to extract FFCF from 2D-IR spectra is described. The experimental observable is the time-dependent frequency shift of maximum peak position in the slice spectrum of 2D-IR, which is taken along the excitation frequency axis. The direct relation between the 2D-IR peak shift and FFCF is proved analytically. Observing the 2D-IR peak shift does not need the full 2D-IR spectrum which covers 0-1 and 1-2 bands. Thus data collection time to determine FFCF can be reduced significantly, which helps the detection of transient species.

• 전자공학회논문지D
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• 제34D권8호
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• pp.15-25
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• 1997

The integration method of carier concentrations to redcue the discretization error of th box integratio method used in the discretization of the three-dimensional poisson's equation is presented. The carrier concentration is approximated in the closed form as an exponential function of the linearly varying potential in the element. The presented method is implemented in the three-dimensional poisson's equation solver running under the windows 95. The accuracy and the convergence chaacteristics of the three-dimensional poisson's equation solver are compared with those of DAVINCI for the PN junction diode and the n-MOSFET under the thermal equilibrium and the DC reverse bias. The potential distributions of the simulatied devices from the three-dimensional poisson's equation solver, compared with those of DAVINCI, has a relative error within 2.8%. The average number of iterations needed to obtain the solution of the PN junction diode and the n-MOSFET using the presented method are 11.47 and 11.16 while the those of DAVINCI are 21.73 and 23.0 respectively.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1991년도 한국자동제어학술회의논문집(국제학술편); KOEX, Seoul; 22-24 Oct. 1991
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• pp.1873-1878
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• 1991

An high-speed isothermal calorimeter which can trace the progress of a liquid phase reversible reaction was constructed using analog and digital computer. By means of a set point change of the calorimeter, the thermal energy capacity and the heat of reaction in reversible reaction mixture can be measured. The heat of reaction between 2-methyl furan and maleic anhydride and the heat capacities of the adduct were 61,200 J/mol and 2.38 J/ g K, respectively. Also reaction equilibrium constant and reaction rate constants can be estimated from the response curves of the calorimeter.

• 대한기계학회논문집
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• 제5권3호
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• pp.199-206
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• 1981

This paper presents a method of calculation of the stresses, the strains and the deflections due to welding in L shape and in T shape. Using step by step method of plasticity and establishing the equilibrium conditions in section, we calculated thermal stresses and strains during welding and in the final step of calculation we got the residual stresses, strains and the deflections due to welding. Also we measured the stresses and the strains with hole-drilling method and compared the results with the method of calculation presented in this paper. Because of its symmetry of section, the deflection due to welding in T shape is generally much less than that in L shape. The residual stresses are tensile in welded joints and HAZ, and compressive in base metal as butt welding of plates, but the compressive stresses in base metal decrease repidly as the points are away from welded joint except horizontal plates of T shape. The theoretical method of calculaiton presented in this paper coincides faily well with the experiment.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.588-590
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• 2008

The thermal signature of nucleation process is characterized by the induction time, the degree of supercooling, and the equilibrium temperature depression. The initiation of nucleation presents stochastic characteristics. The factors that affect nucleation are mechanical impact, ionic concentration, mineral surface characters, and pore size. Hydrate-bearing sediments behave mechanically like other cemented sediments. The data set has important implications for the calibration and interpretation of geophysical measurements and downhole logs collected in gas hydrate provinces, providing particular insight for the interpretation of P- and S-wave data and resistivity logs. In addition, laboratory formation history and ensuing pore-scale spatial distribution likely have a more pronounced effect on the macroscale mechanical properties of hydrate-bearing sediments