• Title/Summary/Keyword: Thermal Effect

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Effect of Foaming Agent Content on the Apparent Density and Compressive Strength of Lightweight Geopolymers (발포제 함량에 따른 경량 다공성 지오폴리머의 밀도와 강도 특성)

  • Lee, Sujeong;An, Eung-Mo;Cho, Young-Hoon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.363-370
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    • 2016
  • Lightweight geopolymers are more readily produced and give higher fire resistant performance than foam cement concrete. Lowering the density of solid geopolymers can be achieved by inducing chemical reactions that entrain gases to foam the geopolymer structure. This paper reports on the effects of adding different concentrations of aluminum powder on the properties of cellular structured geopolymers. The apparent density of lightweight geopolymers has a range from 0.7 to $1.2g/m^3$ with 0.025, 0.05 and 0.10 wt% of a foaming agent concentration, which corresponds to about 37~60 % of the apparent density, $1.96g/cm^3$, of solid geopolymers. The compressive strength of cellular structured geopolymers decreased to 6~18 % of the compressive strength, 45 MPa of solid geopolymers. The microstructure of geopolymers gel was equivalent for both solid and cellular structured geopolymers. The workability of geopolymers with polyprophylene fibers needs to be improved as in fiber-reinforced cement concrete. The lightweight geopolymers could be used as indoor wall tile or board due to fire resistance and incombustibility of geopolymers.

Electrochemical Characterization of Cobalt Oxide Xerogel Electrode for Supercapacitor (수퍼커패시터용 산화코발트 건조겔전극의 전기화학적 특성)

  • Kim Han-Joo;Shin Dal-Woo;Kim Yong-Chul;Kim Seong-Ho;Park Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.3 no.3
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    • pp.146-151
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    • 2000
  • So fine cobalt oxide xerogel powders were prepared by using a unique solution chemistry associated with the sol-gel process. The effect of thermal treatment on the crystalinity, particle structure, and corresponding electrochemical properties of the resulting xerogel remained amorphous as $Co(OH)_2$ up to $160^{\circ}C$ With an increase in the temperature above $200^{\circ}C$, both the surface area and pore volume decreased sharply, because the amorphous $Co(OH)_2$ decomposed to form CoO that was subsequently oxidized to form crystalline Co304. In addition, the changes in the crystallinity, and particle structure all had significant but coupled effects on the electrochemical properties of the xerogels. A maximum capacitance of 192F1g was obtained for an electrode prepared with the $CoO_x$ Xerogel calcined at$150^{\circ}C$, which was consistent with the maxima exhibited in both the surface area and pore volume. This capacitance was attributed solely to a surface redox mechanism.

THE EFFECT OF VARIOUS SURFACE TREATMENT METHODS ON THE OSSEOINTEGRATION (임플랜트의 표면처리 방법이 골유착에 미치는 영향에 관한 연구)

  • Choi Jeong-Won;Kim Kwang-Nam;Heo Seong-Joo;Chang Ik-Tae;Han Chong-Hyun;Baek Hong-Gu;Choi Yong-Chang;Wennerberg Ann
    • The Journal of Korean Academy of Prosthodontics
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    • v.39 no.1
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    • pp.71-83
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    • 2001
  • The purpose of this study was to compare the effects of various surface treatments by measuring removal torque on bone healing around titanium implants. 40 Screw-shaped cp titanium implants with length of 4mm, outer diameter of 3.75mm, and pitch-height of 0.5mm were used Group 1 was left as machined(control), Group 2 was blasted with $50{\mu}m\;Al_2O_3$, group 3 was blasted and etched in etching solution($NH_4OH : H_2O_2:H_2O= 1 : 1 : 5$) at $90^{\circ}C$ for 1 minute group 4 was blasted and oxidated under pure oxygen at $800^{\circ}C$. The implant surface roughness was analyzed with SEM and CLSM(Confocal Laser Scanning Microscope) and implants were placed in proximal tibial metaphysis of 10 New Zealand White rabbits. After 3 months of healing period, removal torque of each implant was measured to compare bone healing around implant. The results obtained were as follows 1. In SEM view, blasting increased the roughness of the surface, but etching of that rough surface decreased the roughness due to the removal of the tip of the peak. Oxidation also decreased the roughness due to formation of needle-like oxide grains on the implant surface. 2. The Sa value from CLSM was least in the machined group($0.47{\mu}m$), greatest in blasted group($1.25{\mu}m$), and the value decreased after etching($0.91{\mu}m$) and oxidation($0.94{\mu}m$). 3. The removal torque of etched group(24.5Ncm) was greater than that of machined group(16.7Ncm) (P<0.05), and was greatest in the oxidated group(40.3Ncm) and the blasted group(34.7Ncm).

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Design and Integrity Evaluation of High-temperature Piping Systems in the STELLA-2 Sodium Test Facility (STELLA-2 소듐 시험 시설 고온 배관 계통의 설계 및 건전성 평가)

  • Son, Seok-Kwon;Lee, Hyeong-Yeon;Ju, Yong-Sun;Eoh, JaeHyuk;Kim, Jong-Bum;Jeong, Ji-Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.9
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    • pp.775-782
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    • 2016
  • In this study, elevated temperature design and integrity evaluation have been conducted using two different piping design codes for the high-temperature piping systems of sodium integral effect test loop for safety simulation and assessment(STELLA-2) being developed by KAERI(Korea Atomic Energy Research Institute). The design code of ASME B31.1 for power piping and French nuclear grade piping design guideline, RCC-MRx RD-3600 were applied, and conservatism of those codes was quantified based on the piping integrity evaluation results. The piping system of Model DHRS, Model IHTS and PSLS are to be installed in STELLA-2. The integrity evaluation results for the three piping systems according to the two design codes showed that integrity of the piping system was confirmed. As a code comparison result, ASME B31.1 was shown to be more conservative for sustained loads while RD-3600 was more conservative for thermal loads compared to B31.1.

Environmentally-friendly Control Methods and Forecasting the Hatching Time Lycorma delicatula (Hemiptera: Fulgoridae) in Jeonnam Province (전남지역에서 꽃매미 부화시기 예측과 친환경 방제방법)

  • Choi, Duck-Soo;Kim, Do-Ik;Ko, Suk-Ju;Kang, Beom-Ryong;Park, Jong-Dae;Kim, Seon-Gon;Choi, Kyeong-Ju
    • Korean journal of applied entomology
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    • v.51 no.4
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    • pp.371-376
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    • 2012
  • This study was conducted to predict the hatching time of eggs of Lycorma delicatula, to select an effective environmentally-friendly agriculture material (EFAM) and to evaluate the attraction effect of brown sticky traps for controling of Lycorma delicatula nymph and adults. Eggs hatched 55.9, 26.8, 21.6 days after incubation at 15, 20, $25^{\circ}C$ with 14L:10D condition and the hatching rates of egg were 61.9, 57.8, 30.4%, respectively. At high temperature conditions, egg development periods were shorter and the hatching rate was lower. The relationship between temperature and developmental rate was expressed by the linear equation Y=0.0028X-0.0228, $R^2$=0.9561. The low temperature threshold of eggs was $8.14^{\circ}C$ and the thermal constant required to reach larva was 355.4 DD. According to this relationship, the mean estimated hatching date was $22^{nd}$ May. The effective EFAM was natural plant extract, sophora extract, derris extract to nymph and natural plant extract, pyrethrum extract, sophora extract to adult. Among three colors of sticky trap : brown, blue and yellow, the brown sticky trap was the most attractive to nymphs and adults of L. delicatula over a 2 weeks trial period. It suggested that the brown sticky trap could be a very useful and environment-friendly control method for nymphs and adults of L. delicatula.

Three Dimensional Implementation of Intelligent Transportation System Radio Frequency Module Packages with Pad Area Array (PAA(Pad Area Array)을 이용한 ITS RF 모듈의 3차원적 패키지 구현)

  • Jee, Yong;Park, Sung-Joo;Kim, Dong-Yong
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.38 no.1
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    • pp.13-22
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    • 2001
  • This paper presents three dimensional structure of RF packages and the improvement effect of its electrical characteristics when implementing RF transceivers. We divided RF modules into several subunits following each subunit function based on the partitioning algorithm which suggests a method of three dimension stacking interconnection, PAA(pad area array) interconnection and stacking of three dimensional RF package structures. 224MHz ITS(Intelligent Transportation System) RF module subdivided into subunits of functional blocks of a receiver(RX), a transmitter(TX), a phase locked loop(PLL) and power(PWR) unit, simultaneously meeting the requirements of impedance characteristic and system stability. Each sub­functional unit has its own frequency region of 224MHz, 21.4MHz, and 450KHz~DC. The signal gain of receiver and transmitter unit showed 18.9㏈, 23.9㏈. PLL and PWR modules also provided stable phase locking, constant voltages which agree with design specifications and maximize their characteristics. The RF module of three dimension stacking structure showed $48cm^3$, 76.9% reduction in volume and 4.8cm, 28.4% in net length, 41.8$^{\circ}C$, 37% in maximum operating temperature, respectively. We have found that three dimensional PAA package structure is able to produce high speed, high density, low power characteristics and to improve its functional characteristics by subdividing RF modules according to the subunit function and the operating frequency, and the features of physical volume, electrical characteristics, and thermal conditions compared to two dimensional RF circuit modules.

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Introduction of Dental X-ray Imaging with New Concept - intra Oral x-ray Tube (신개념 치과용 X-선 영상장치 소개 - 강내형 X-선 튜브)

  • Cho, Sung-Ho;Kim, Dong-Young;Baek, Kwang-Woo;Lee, Re-Na
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.48 no.4
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    • pp.94-101
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    • 2011
  • Various kinds of medical imaging devices have been studied to develop periapical radiography. However, there are some problems such as high x-ray exposure rate and pains for patients because of the problems caused by intra-oral sensor based radiography system. In this study, a new concept of periapical radiography, intra oral X-ray tube and detector system, is introduced to solve these problems. This system is made up of miniature X-ray tube based on subminiature thermal electron or cold electron, CMOS based detector, and a body including automatic position and system control devices. In order to confirm the possibility of proposed new concept to periapical radiography, miniature x-ray tube from XOFT corporation is used to develop new x-ray system, and the performance evaluation of this system is performed according to collimator. Also, dental images are compared after acquiring both images from existing system versus new concept of system. As a result, new concept of system showed excellent image. Thus, it is considered that new concept of system will have a significant effect on medical imaging technology.

A study on synthesis of $Li_{x}Mn_{2}O_{4}$ for asecondary battery with various $MnO_{2}$ structure (다양한 $MnO_{2}$ 구조에 따른 2차전지용 $Li_{x}Mn_{2}O_{4}$ 합성에 관한 연구)

  • 김익진;이영훈;이종호;이재한;장동환;이경희;고영신
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.4
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    • pp.600-608
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    • 1996
  • Specific structural properties of Li intercalation reaction into the spinel relatedmanganese dioxide, $Li_{x}Mn_{2}O_{4}(0.2{\leq}x{\leq}2.0)$, are investigated by X-ray diffractional and electrochemical studies of Li/1M $LiClO_{4}$-propylene carbonate solution/$Li_{x}Mn_{2}O_{4}$ cell. The effect of the chemical composition and the reaction temperature on electrochemical parameter of $Li_{x}Mn_{2}O_{4}$ are studied by the phenomena of phase-transition, analysis of crystal lattice, fine structure, and thermal analysis. Treatment of the spinel $Li_{x}Mn_{2}O_{4}$ with aqueous acid was found to result in conversiton of $Li_{x}Mn_{2}O_{4}$ to nearly pure $MnO_{2}$, as evidenced by a reduction in the lattice constant $a_{c}$ from 8.255 to $8.031\;{\AA}$. At a composition range of $0.2{\leq}x{\leq}0.6$ in $Li_{x}Mn_{2}O_{4}$ the reduction proceeded in a homogeneous phase, which was characterized by a constant voltage of 3.9~3.7 V together with a lattice constant of $8.255\;{\AA}$.

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Preparation of Ion Exchange Membranes for Fuel Cell Based on Crosslinked Poly(vinyl alcohol) with Poly(acrylic acid-co-maleic acid)

  • Kim, Dae-Sik;Park, Ho-Bum;Lee, Chang-Hyun;Lee, Young-Moo;Moon, Go-Young;Nam, Sang-Yong;Hwang, Ho-Sang;Yun, Tae-II;Rhim, Ji-Won
    • Macromolecular Research
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    • v.13 no.4
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    • pp.314-320
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    • 2005
  • Crosslinked poly(vinyl alcohol) (PVA) membranes were prepared at various crosslinking temperatures using poly(acrylic acid-co-maleic acid) (PAM) containing different PAM contents. The thermal properties of these PVA/PAM membranes prepared at various reaction temperatures were characterized using differential scanning calorimetry (DSC). The proton conductivity and methanol permeability of PVA/PAM membranes were then investigated as PAM content was varied from 3 to 13 wt%. It was found that the proton and methanol transport were dependent on PAM content in their function both as crosslinking agent and as donor of hydrophilic -COOH groups. Both these properties decreased monotonously with increasing PAM concentration. The proton conductivities of these PVA/PAM membranes were in the range from $10^{-3}\;to\;10^{-2}S/cm$ and the methanol permeabilities from $10^{-7}\;to\;10^{-6}cm^{2}/sec$. In addition, the effect of operating temperature up to $80^{\circ}C$ on ion conductivity was examined for three selected membranes: 7, 9 and 11 wt% PAM membranes. Ion conductivity increased with increasing operating temperature and showed and S/cm at $80^{\circ}C$, respectively. The effects of crosslinking and ionomer group concentration were also examined in terms of water content, ion exchange capacity (IEC), and fixed ion concentration. In addition, the number of water molecules per ionomer site was calculated using both water contents and IEC values. With overall consideration for all the properties measured in this study, $7{\sim}9\;wt%$ PAM membrane prepared at $140^{\circ}C$ exhibited the best performance. These characteristics of PVA/PAM membranes are desirable in applications related to the direct methanol fuel cell (DMFC).

Effect on Graphene Addition on Characteristics of Polypropylene Biocomposites Reinforced with Sulfuric Acid Treated Green Algae (황산처리된 녹조류 보강 폴리프로필렌 바이오복합재료에 대한 그래핀 첨가영향)

  • Jang, Young Hun;Han, Seong Ok;Kim, Hyung-Il;Sim, I Na
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.518-525
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    • 2013
  • To improve the mechanical properties of polypropylene (PP) biocomposites reinforced with sulfuric acidtreated green algae (SGA), SGA/graphite nanoplatelets (GNP)/PP biocomposites were prepared and their properties were evaluated depending on the particle size and content of GNP. The flexural and impact strength of SGA/GNP/PP biocomposites decreased with the addition of GNP, whereas the flexrual and storage moduli were greatly improved with increasing GNP loading. SGA/GNP/PP biocomposites reinforced with GNP5 showed generally better mechanical properties compared to that reinforced with GNP15 mainly due to the improved dispersion of the smaller GNP. SGA/GNP/PP biocomposites reinforced with GNP5 showed a lower resistance to the thermal expansion because the relatively uniform dispersion of smaller GNP was responsible for the effective heat transfer to the polymer matrix. As a result, SGA/GNP/PP biocomposite was acceptable for the general purpose application due to the improved flexural resistance, storage moduli, and damping characteristics.