• Composites Research
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• v.26 no.5
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• pp.309-314
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• 2013

Highly ablation resistant carbon nanotube (CNT)-phenolic composites were fabricated by the addition of low concentrations of CNT nanofiller. Tensile and compressive properties as well as ablative resistance were significantly improved by the addition of only 0.1 and 0.3 wt% of uniformly dispersed CNTs. An oxygen-kerosene-flame torch and a field emission scanning electron microscope (FE-SEM) were used to evaluate the ablative properties and microstructures of these CNT-phenolic composites. Thermal gravimetric analysis (TGA) revealed that the ablation rate was lower for the 0.3 wt% CNT-phenolic composites than for neat phenolic or the composite with 0.1 wt% CNT. Ablative mechanisms for all three materials were investigated using this TGA in conjunction with microstructural studies using a FE-SEM. The microstructural studies revealed that CNT acted as an ablation resistant phase at high temperatures, and that the uniformity of dispersion of the CNT played an important role in this resistance to ablation.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.237.2-237.2
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• 2016

A pure hafnium-carbide (HfC) coating layer was deposited onto carbon/carbon (C.C) composites using a vacuum plasma spray system. By adopting a SiC buffer layer, we successfully integrated C.C composites with a $100-{\mu}m-thick$ protective coating layer of HfC. Compared to the conventional chemical vapor deposition process, the HfC coating process by VPS showed increased growth rate, thickness, and hardness. The growth behavior and morphology of HfC coatings were investigated by FE-SEM, EDX, and XRD. From these results, it was shown that the addition of a SiC intermediate layer provided optimal surface conditions during the VPS procedure to enhance adhesion between C.C and HfC (without delamination). The thermal ablation test results shows that the HfC coating layer perfectly protected inner C.C layer from thermal ablation and oxidation. Consequently, we expect that this ultra-high temperature ceramic coating method, and the subsequent microstructure that it creates, can be widely applied to improve the thermal shock and oxidation resistance of materials under ultra-high temperature environments.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.30 no.2
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• pp.119-125
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• 2017

Ablative material in a rocket nozzle is exposed to high temperature combustion gas, thus undergoes complicated thermal/chemical change in terms of chemical destruction of surface and thermal decomposition of inner material. Therefore, method for conjugate analysis of thermal response inside carbon/phenolic material including rocket nozzle flow, surface chemical reaction and thermal decomposition is developed in this research. CFD is used to simulate flow field inside nozzle and conduction in the ablative material. A change in material density and a heat absorption caused by the thermal decomposition is considered in solid energy equation. And algebraic equation under boundary layer assumption is used to deduce reaction rate on the surface and resulting destruction of the surface. In order to test the developed method, small rocket nozzle is solved numerically. Although the ablation of nozzle throat is deduced to be higher than the experiment, shape change and temperature distribution inside material is well predicted. Error in temperature with experimental results in rapid heating region is found to be within 100 K.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.8
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• pp.597-604
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• 2013

A coupled thermomechanical analysis of composite structures in pyrolysis and ablation environments is performed. The pyrolysis and ablation models include the effects of mass loss, pore gas diffusion, endothermic reaction energy, surface recession, etc. The thermal and structural analysis interface is based upon a staggered coupling algorithm by using a commercial finite element code. The characteristics of the proposed method are investigated through numerical experiments with carbon/phenolic composites. The numerical studies are carried out to examine the surface recession rate by chemical and mechanical ablation. In addition, the effects of shrinkage or intumescence during the pyrolysis process are shown.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.536-542
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• 2017

A great deal of difficulty is encountered in the thermo-mechanical analyses of nozzle assembly for solid propellant rocket motors. The main issue in this paper is the modeling of the boundary conditions and the connections between the various components-gaps, relative movements of the components, contacts, friction, etc. This paper evaluated the complex phenomena of nozzle assembly during burning time with co-simulation which include fluid, thermal surface reaction/ablation and structural analysis. The validity of this approach was verified by comparison of analysis results with measured strains.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.1
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• pp.36-44
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• 2018

The thermal response of carbon/phenolic used in a solid rocket nozzle liner was analyzed. In this paper, the numerical analysis of the thermal response of carbon/phenolic consists of (1) the integration equation of the boundary layer to obtain the convective heat transfer coefficient of the combustion gas on the rocket nozzle wall and (2) 1-D finite difference method for heat conduction of carbon/phenolic to calculate the ablation, char, and temperature. The calculated result was compared with the result of a blast-tube-type test motor. It is found that the calculated result shows good agreement with the thermal response of the test motor, except at the vicinity of the throat insert.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.4
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• pp.36-43
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• 2018

A great deal of difficulty is encountered in the thermo-mechanical analyses of nozzle assemblies for solid propellant rocket motors. The main issue in this paper is the modeling of the boundary conditions and the connections between the various components-gaps, relative movements of the components, contacts, friction, etc. This paper evaluates the complex phenomena of nozzle assemblies during burning time with co-simulations that include fluid, thermal surface reaction/ablation, and structural analysis. The validity of this approach is verified via comparison of analysis results with measured strains.

• Journal of the Korean Society for Precision Engineering
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• v.29 no.5
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• pp.572-577
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• 2012

Recently porous polymer has widely been applied to packaging, heat isolation, and sound absorption in various fields from the electrics to the automobiles industry. A lot of micro porosities inside foamed polymer provide lower heat conduction and lighter weight than non-porous polymer, because they involve gas or air during foaming process. In this paper experimental approaches of the UV laser micro machining behavior for Expanded Polypropylene (EPP) foamed polymer materials, which have different expansion rates, were investigated. From these results, the ablation phenomena were finally observed that the ablation is depended upon stronger photo-chemical than photo-thermal effect. This study will also help us to understand interaction between UV laser beam and porous polymer.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.38 no.2
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• pp.200-205
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• 2010

Heat-resistance of W/$Y_2O_3$ as throat insert material was evaluated to develop rocket motor keeping thrust uniformly under condition of high-temperature, high-pressure and long-burn time. Test was conducted with varying burn time, and test results were compared with CIT. Test showed that ablation rate was decreased according as burn time was increased, and that ablation rate of W/$Y_2O_3$ was about 55 % of CIT. Macro/micro structures of throat insert did not show a peculiar phenomenon by increased burn time. In addition, the vacuum heat treatment is effective for the prevention of crack in throat insert.

• Korean Journal of Materials Research
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• v.30 no.5
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• pp.262-266
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• 2020

In this paper, we investigated the effect of the passivation stack with Al₂O₃, hydrogenated silicon nitride (SiN_x:H) stack and Al₂O₃, silicon oxynitride (SiON_x) stack in the n type bifacial solar cell on monocrystalline silicon. SiNx:H and SiON_x films were deposited by plasma enhanced chemical vapor deposition on the Al₂O₃ thin film deposited by thermal atomic layer deposition. We focus on passivation properties of the two stack structure after laser ablation process in order to improve bifaciality of the cell. Our results showed SiN_x:H with Al₂O₃ stack is 10 mV higher in implied open circuit voltage and 60 ㎲ higher in minority carrier lifetime than SiON_x with Al₂O₃ stack at Ni silicide formation temperature for 1.8% open area ratio. This can be explained by hydrogen passivation at the Al₂O₃/Si interface and Al₂O₃ layer of laser damaged area during annealing.