• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.570-573
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• 2002

Pb(Zr0.52Ti0.48)O3 (PZT) thin films were deposited on the Pt/Ti bottom electrode by rf magnetron sputtering method from target containing 5%, 25% and 50% Pb excess for applying ferroelectric random access memory (FRAM). PZT films were deposited at $300^{\circ}C$ and then they were crystallized by rapid thermal annealing (RTA) at $700^{\circ}C$. After RTA treatment, our results showed that all PZT films indicated perovskite polycrystalline structure with preferred orientation (110) and no pyrochlore phase was observed by X-ray diffraction (XRD) and by Scanning electron microscopy (SEM). A well-fabricated PZT film of excess Pb 25% capacitor showed a leakage current density in the order of $2.63{\times}10^{-7}A/cm^2$ at 100kV/cm, a remanent polarization of $3.385{\mu}C/cm^2$ and a coercive field of 41.32 kV/cm. The results showed that Pb excess of target affects to electrical properties of PZT thin film.

• Transactions on Electrical and Electronic Materials
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• 제6권4호
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• pp.169-172
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• 2005

[ $Y_2O_3:Eu$ ] powder was synthesized using a solution-combustion method by dissolving $(CH_3CO_2)_3Y$ and $(CH_3CO_2)_3$ Eu in methyl-alcohol solution. Results from X-ray diffractometery (XRD), thermogravimetry (TG)-differential thermal analysis (DTA) show that $Y_2O_3:Eu$ crystallizes completely when the dry powder is sintered at $500^{\circ}C$. The investigated optical properties were the photoluminescence emission spectra, the excitation spectra and luminescence decay curve. Europium (Eu) concentration had no observable effect on the optical spectrum which depended on the emission intensity. The mean lifetime of synthesized phosphors was $2.3\~2.6 ms$.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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• pp.352-357
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• 1999

The Cu sheets were selected for the substrate of the superconductor films. Pure Cu sheets with the thickness of 50${\mu}$m were fabricated using hot and cold rolling. The Cu sheets were heat treated to induce the biaxial texturing. The z-axis and x-y plane texturing of Cu sheets heat treated at different conditions were analyzed using XRD and a best heat treatment condition for the texturing was selected. ZrO$_2$ film was dip coated on Cu sheets heat treated at the best condition to prevent possible reaction between Cu sheets and YBCO superconductors, to reduce possible cracking due to thermal expansion mismatch and to decrease the lattice mismatch for biaxial texturing. The texturing of the oxide buffer layers were also studied.

• 한국세라믹학회지
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• 제16권2호
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• pp.83-88
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• 1979

The Anorthite is useful compound for some ceramic industries but it is difficult to produce Anorthite because of its high melting point (1553$^{\circ}C$) and narrow firing range. On this study, glass frit was added to Anorthite batch composition to widen firing range and lower melting point. After mixing a glass frit $(Na_2O-CaO-6SiO_2)$ with Anorthite, it was melted and quenched. Ratio of Anorthite vs. glass frit was 9 : 1, 8.5 : 1.5, 8 : 2, 7.5 : 2.5, 7 : 3. In those batch composition added amount of $No_2O$ were between 1.3wt.% and 3.9wt.%. To find the thermal change of the quenched, D.T.A. was surveyed. The quenched were fired at various vitrification temperature and detected by X-Raydiffraction analysis. With addition of glass frit, firing range and vitrification temperature of Anorthite was 100~15$0^{\circ}C$ and 1050~115$0^{\circ}C$ respectively. Optimum amount of glass frit was 20wt.% for the upper mentioned.

• Carbon letters
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• 제15권3호
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• pp.198-202
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• 2014

Amorphous agglomerates of carbon nanospheres (CNS) with a diameter range of 10-50 nm were synthesized using the solution combustion method. High-resolution transmission electron microscopy (HRTEM) revealed a densely packed high surface area of $SP^2$-hybridized carbon; however, there were no crystalline structural components, as can be seen from the scanning electron microscopy, HRTEM, X-ray diffraction, Raman spectroscopy, and thermal gravimetric analyses. Electrochemical and thermo catalytic decomposition study results show that the material can be used as a potential electrode candidate for the fabrication of energy storage devices and also for the production of free hydrogen if such devices are used in a fluidized bed reactor loaded with the as-prepared CNS as the catalyst bed.

• Transactions on Electrical and Electronic Materials
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• 제12권3호
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• pp.119-122
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• 2011

A series of mesoporous silicalites was synthesized using different compositions of tetraethylorthosilicate and methyltriethoxysilane (MTES) as the silica source. Cetyltrimethylammonium bromide was used as the organic template. Their detailed pore structures were investigated by transmission electron microscopy, X-ray diffraction, and N2 adsorption method. The thermal properties of these silicalites were studied by thermogravimetric analysis. The increased amount of MTES destroyed mesoporous channels and reduced pore sizes from 3.4 nm to 2.8 nm in calcined silicalites. The calcined silicalite transformed completely into an amorphous state at 30% MTES loading. Methyl pending groups of MTES hindered the structural ordering of ≡Si-O- frameworks, resulting in an amorphous structure. This was caused by the insufficient formation of supramolecular assembly with the organic template. No capillary condensation step was found in MS 7/3 silicalite. The other capillary condensation steps shifted toward the lower relative pressure with increasing MTES content, indicating the reduction of pore sizes.

• 한국분말재료학회지
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• 제12권3호
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• pp.214-219
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• 2005

In order to investigate the formation of AlN, mechanical alloying was carried out in $N_2$ and $NH_3$ atmosphere. Differential thermal analysis (DTA), x-ray diffraction (XRD) and chemical analysis were carried out to examine the formation behavior of aluminum nitrides. No diffraction pattern of AlN was observed in XRD analysis of the as-milled powders in $NH_3\;or\;N_2$ atmosphere. However, DTA and chemical analysis indicated that the precursors for AlN were formed in the Al powders milled in $NH_3$ atmosphere. The AlN precursors transformed to AlN after heat treatment at and above $600^{\circ}C$. It was considered that the reaction between Al and $NH_3$ was possible by the formation of fresh Al surface during mechanical alloying of Al powders.

• International Journal of Automotive Technology
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• 제8권1호
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• pp.9-18
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• 2007

Phase separation and low cetane number are the main barriers to the large-scale use of ethanol-diesel blend fuel on small diesel engines. In this paper, an additive package is designed on the basis of the blended fuel properties to overcome these limitations. The experiments show that the solubility of ethanol in diesel is evidently increased by adding $1{\sim}2%$ (in volume) of the additive package and the flammability of ethanol-diesel blend fuel with the additive has reached the neat diesel level under the cold start conditions. Effects of the ethanol content in diesel on fuel economy, combustion characteristics, and emission characteristics are also investigated with the ethanol blend ratios of 10%, 20% and 30%. The increase in ethanol content shows that the specific fuel consumption and the brake thermal efficiency are both gradually increased compared to neat diesel. The soot concentrations of the three blended fuels are all greatly lower than that of neat diesel. $NO_x$ emission is increased with an increase in the engine load and is reduced with the increase in the ethanol blend ratio under a high load.

• 한국자동차공학회논문집
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• 제20권2호
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• pp.110-115
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• 2012

This study describes the characteristics of combustion and exhaust emission in the special engine applying a fuel reactivity controlled compression ignition (RCCI) concept with two different energizing type (solenoid and piezoelectric) injectors for diesel injection. A diesel-gasoline mixed dual-fuel reactivity controlled compression ignition concept is demonstrated as a promising method to achieve high thermal efficiency and low emission in internal combustion engines for transportation vehicles. For investigating the combustion characteristics of RCCI, engine experiments were performed in a light-duty diesel engine over a range of injection timing and mixing rate of gasoline in mass. It was investigated that by increasing the nozzle hole diameter, increasing the combustion pressure and the net indicated mean effective pressure. $NO_x$ and soot can be reduced by advancing start of injection in 84 mixing rate of gasoline in mass. The resulting operation showed that light duty engine could achieve 48 percent net indicated efficiency and 191[g/kW-hr] net indicated specific fuel consumption with lower levels of nitrogen oxides and soot.

• 에너지공학
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• 제17권4호
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• pp.198-203
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• 2008

The objective of the research was to study the effects of Miller cycle in a modified using diesel engine. The engine was dedicated to natural gas usage by modifying pistons, fuel system and ignition systems. The engine was installed on a dynamometer and attached with various sensors and controllers. Intake valve timing, engine speed, load, injection timing and ignition timing are main parameters. The results of engine performances and emissions are present in form of graphs. Miller Cycle without supercharging can increase brake thermal efficiency and reduce brake specific fuel consumption. The injection timing must be synchronous with valve timing, speed and load to control the performances, emissions and knock margin. Throughout these tested speeds, original camshaft is recommended to obtain high volumetric efficiency. Retard ignition timing can reduce $NO_x$ emissions while maintaining high efficiency.