• 제목/요약/키워드: Theory of viscosity

검색결과 136건 처리시간 0.038초

Viscometric Studies of Molecular Interactions in Binary Mixtures of Formamide with Alkanol at 298.15 and 308.15 K

  • Gahlyan, Suman;Verma, Sweety;Rani, Manju;Maken, Sanjeev
    • Korean Chemical Engineering Research
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    • 제55권4호
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    • pp.520-529
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    • 2017
  • Viscosity data were measured at 298.15 K and 308.15 K for formamide + 1-propanol, 2-propanol, 1-butanol, 2-methyl-1-propanol or 2-methyl-2-propanol mixtures. For an equimolar mixture, deviation in viscosity follows the sequence: 2-methyl-2-propanol >2-methyl-1-propanol>1-butanol>2-propanol>1-propanol. The viscosity data were further analyzed in terms of graph theory. Free energy of activation was also calculated from experimental viscosity data along with previously reported excess volume data. The deviation in viscosity and free energy of activation were fitted to Redlich-Kister polynomial equation. The viscosity data were also correlated by correlations like Grunberg-Nissan, Tamura-Kurata, HindMcLaughlin-Ubbelohde, and Katti-Chaudhari relation. Various adjustable parameters, $G_{12}$, $T_{12}$, $H_{12}$, and $W_{vis}/RT$, of various correlations were used to predict viscosity deviation of binary mixtures. Positive value of $G_{12}$ indicates strong interaction in the studied systems. Grunberg-Nissan relation has lowest deviation among the four correlations for formamide + 1-propanol or 2-propanol mixtures; and for mixtures of formamide with 1-butanol or 2-methyl-1-propanol, TamuraKurata has lowest deviation. Grunberg-Nissan gives lowest deviation for formamide + 2-methyl-2-propanol mixtures.

시간종속적 하중이 작용하는 구조물의 동특성 (Dynamic behavior of a supporting structure subjected to a force of time dependent frequency)

  • 정태진;박영조
    • 오토저널
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    • 제8권4호
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    • pp.66-72
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    • 1986
  • Numerical analysis has been made on the dynamic behavior of a supporting structure subjected to a force of time dependent frequency. The effect of solid viscosity is studied when the frequency of external force passes through the first critical frequency of the simple beam for four times. Within the Euler-Bernoulli beam theory, the solutions are obtained by using finite Fourier and Laplace transformation methods with respect to space and time variables. The result shows that the maximum value of the dynamic deflection is considerably affected by the value of the solid viscosity as well as the frequency difference The maximum dynamic deflection is found to occur in the frequency lower limit C of 0.85-0.985 in the presence of the solid viscosity.

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낙구식 점도계를 이용한 점탄성유체의 유동에 관한 연구 (A Study on the Flow Behavior of the Viscoelastic Fluids in the Falling Ball Viscometer)

  • 전찬열
    • 한국안전학회지
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    • 제3권1호
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    • pp.15-19
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    • 1988
  • The falling ball viscometer has been widely used for measuring the viscosity of the Newtonian fluids because of its simple theory and low cost. The use of the falling ball viscometer for measuring the non-Newtonian viscosity has been of interest to rheologists for some years. The analysis of the experimental results in a falling ball viscometer rest on Stokes law which yields the terminal velocity for a sphere moving through an infinite medium of fluids. An attempt to use the falling ball viscometer to measure the non-Newtonian viscosity in the intermediate shear rate ranEe was sucessfully accomplished by combining the direct experimental obserbations with a simple analytical model for the average shear-stress and shear rate at, the surface of a sphere. In the experiments with highly viscoelastic polyacrylamide solutions the terminal velocity was observed to be dependent on the time interval between the dropping of successive balls. The time-dependent phenomenon was used to determine characteristic diffusion times of the concentrated solutions of polyacrylamide.

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Ultrasonically enhancing flowability of cement grout for reinforcing rock joint in deep underground

  • Junho Moon;Inkook Yoon;Minjin Kim;Junsu Lee;Younguk Kim
    • Geomechanics and Engineering
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    • 제33권2호
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    • pp.211-219
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    • 2023
  • This study analyzes the changes in the physical properties of grout by irradiating it with ultrasonic energy and assesses the injectability of the grout into deep rock fractures. The materials used in the research are OPC (Ordinary Portland Cement) and MC (Micro Cement), and are irradiated depending on the water/cement ratio. After irradiating the grout with ultrasonic energy, viscosity, compressive strength, and particle size are analyzed, and the results of the particle size analysis were applied to Nick Barton's theory to evaluate the injectability of the grout into deep rock fractures under those conditions. It was found that the viscosity of the grout decreased after ultrasonic wave irradiation, and the rate of viscosity reduction tended to decrease as the water/cement ratio increased. Additionally, an increase in compressive strength and a decrease in particle size were observed, indicating that the grout irradiated with ultrasonic energy was more effective for injection into rock fractures.

와점성 변화가 회전곡면으로 이루어진 마이크로 슬롯 유동장에 미치는 영향 (Effects of Vortex Viscosity Variation on the Flowfields in a Micro-slot between Rotating Surfaces of Revolution)

  • 최근우;김윤제
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집B
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    • pp.591-596
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    • 2001
  • Micron-size mechanical devices are becoming more prevalent, both in commercial applications and in scientific inquiry. Within the last decade, a dramatic increase in research activities has taken place, mostly due to the rapidly expanding growth of applications in areas of MEMS(Micro-Electro-Mechanical Systems), bioengineering, chemical systems, and advanced energy systems. In this study, we have described the effects of vortex viscosity variation on the flowfields in a micro-slot between rotating surfaces of revolution using a micropolar fluid theory. In order to solve this problem, we have used boundary layer equations and applied non-zero values of the microrotation vector on the wall. The results are compared with the corresponding flow problems for Newtonian fluid. Results show that the coefficient $\delta$ controls the main part of velocity ${\upsilon}_x$ and the coefficient M controls the main part of microrotation component ${\Omega}_{\theta}$.

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초고강도강판의 마찰특성에 관한 연구 (Study on the Friction Characteristics of Advanced High Strength Steel Sheet)

  • 김남진;김상헌;정경환;박성호;금영탁
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2009년도 추계학술대회 논문집
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    • pp.250-253
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    • 2009
  • In this study, the friction test was performed to find friction characteristics of advanced high strength steel (AHSS) sheets and the multiple regression method was employed to obtain friction models. The friction coefficients associated with the lubricant viscosity, drawing speed, and blank holding pressure are measured. Differently from GA steel sheets, the effects of the lubricant viscosity and pulling speed are a little, which are explained by a theory of adhesion and wear as well as a deformation of friction surface. In addition, the effects of friction parameters are numerically represented by friction regression models.

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Seepage characteristics of the leaching solution during in situ leaching of uranium

  • Sheng Zeng ;Jiayin Song ;Bing Sun;Fulin Wang ;Wenhao Ye;Yuan Shen;Hao Li
    • Nuclear Engineering and Technology
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    • 제55권2호
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    • pp.566-574
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    • 2023
  • Investigating the seepage characteristics of the leaching solution in the ore-bearing layer during the in situ leaching process can be useful for designing the process parameters for the uranium mining well. We prepared leaching solutions of four different viscosities and conducted experiments using a self-developed multifunctional uranium ore seepage test device. The effects of different viscosities of leaching solutions on the seepage characteristics of uranium-bearing sandstones were examined using seepage mechanics, physicochemical seepage theory, and dissolution erosion mechanism. Results indicated that while the seepage characteristics of various viscosities of leaching solutions were the same in rock samples with similar internal pore architectures, there were regular differences between the saturated and the unsaturated stages. In addition, the time required for the specimen to reach saturation varied with the viscosity of the leaching solution. The higher the viscosity of the solution, the slower the seepage flow from the unsaturated stage to the saturated stage. Furthermore, during the saturation stage, the seepage pressure of a leaching solution with a high viscosity was greater than that of a leaching solution with a low viscosity. However, the permeability coefficient of the high viscosity leaching solution was less than that of a low viscosity leaching solution.

점도 변화와 폐색 현상을 고려한 그라우트재의 침투 특성 (Effect of Viscosity and Clogging on Grout Penetration Characteristics)

  • 김종선;최용기;박종호;우상백;이인모
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2006년도 춘계 학술발표회 논문집
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    • pp.414-423
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    • 2006
  • Many construction projects adopt grouting technology to prevent the leakage of groundwater or to improve the shear strength of the ground. Recognition as a feasible field procedure dates back to 1925, Since then, developments and field use have increased rapidly. According to improvement of grout materials, theoretical study on grout penetration characteristics is demanded. Fluid of grout always tends to flow from higher hydraulic potential to lower and the motion of grout is also a function of formation permeability. Viscosity of grout is changed by chemical action while grout moves through pores. Due to the increment of viscosity, permeability is decreased. Permeability is also reduced by grout particle deposits to the soil aggregates. In this thesis, characteristics of new cement grout material that is developed recently is studied: injectable volume of new grout material is tested in two different sizes of sands, and the method to calculate injectable volume of grout is suggested with consideration of change in viscosity and clogging phenomena. The calculated values are compared with injection test results. Viscosity of new grout material is found to be an exponential function of time. And lumped parameter $\theta$ of new grout material to be used for assessing deposition characteristics is estimated by comparing deposit theory with injection test results considering different soil types and different injection pressure.

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Impact of viscoelastic foundation on bending behavior of FG plate subjected to hygro-thermo-mechanical loads

  • Ismail M. Mudhaffar;Abdelbaki Chikh;Abdelouahed Tounsi;Mohammed A. Al-Osta;Mesfer M. Al-Zahrani;Salah U. Al-Dulaijan
    • Structural Engineering and Mechanics
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    • 제86권2호
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    • pp.167-180
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    • 2023
  • This work applies a four-known quasi-3D shear deformation theory to investigate the bending behavior of a functionally graded plate resting on a viscoelastic foundation and subjected to hygro-thermo-mechanical loading. The theory utilizes a hyperbolic shape function to predict the transverse shear stress, and the transverse stretching effect of the plate is considered. The principle of virtual displacement is applied to obtain the governing differential equations, and the Navier method, which comprises an exponential term, is used to obtain the solution. Novel to the current study, the impact of the viscoelastic foundation model, which includes a time-dependent viscosity parameter in addition to Winkler's and Pasternak parameters, is carefully investigated. Numerical examples are presented to validate the theory. A parametric study is conducted to study the effect of the damping coefficient, the linear and nonlinear loadings, the power-law index, and the plate width-tothickness ratio on the plate bending response. The results show that the presence of the viscoelastic foundation causes an 18% decrease in the plate deflection and about a 10% increase in transverse shear stresses under both linear and nonlinear loading conditions. Additionally, nonlinear loading causes a one-and-a-half times increase in horizontal stresses and a nearly two-times increase in normal transverse stresses compared to linear loading. Based on the article's findings, it can be concluded that the viscosity effect plays a significant role in the bending response of plates in hygrothermal environments. Hence it shall be considered in the design.

극초음속 희박유동 해석을 위한 축대칭 다화학종 GH 방정식의 개발 (EVELOPMENT OF AXISYMMETRIC MULTI-SPECIES GH EQUATION FOR HYPERSONIC RAREFIED FLOW ANALYSES)

  • 안재완;김종암
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 학술대회
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    • pp.84-91
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    • 2008
  • Generalized hydrodynamic (GH) theory for multi-species gas and the computational models are developed for the numerical simulation of hypersonic rarefied gas flow on the basis of Eu's GH theory. The rotational non-equilibrium effect of diatomic molecules is taken into account by introducing excess normal stress associated with the bulk viscosity. The numerical model for the diatomic GH theory is developed and tested. Moreover, with the experience of developing the dia-tomic GH computational model, the GH theory is extended to a multi-species gas including 5 species; O$_2$, N$_2$, NO, O, N. The multi-species GH model includes diffusion relation due to the molecular collision and thermal phenomena. Two kinds of GH models are developed for an axisymmetric flow solver. By compar-ing the computed results of diatomic and multi-species GH theories with those of the Navier-Stokes equations and the DSMC results, the accuracy and physical consistency of the GH computational models are examined.

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