• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2001.11a
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• pp.37-37
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• 2001

TiN coatings were applied for VarIOUS application fields, because of a good wear-resistance and a high hardness. Typically, TiN thin films show the hardness of 25GPa and friction coefficient of 0.6. However, in many field, one is looking for a more improved tool which has low friction coefficient and high wear resistance. The main motivation of this study is to characterize the influence of copper dopant content on TiN thin films. Ti-Cu-N thin films were deposited onto D2 steel substrates by PVD processing with various magnetron current densities (Cu contents). In this work, we synthesized titanium nitride films similar with reported typical titanium nitride films and synthesized Ti-Cu-N thin films with the addition of elemental copper which is measured improved hardness more than pure TiN films with copper content variables. This films has preferred oriented films of (111) direction. In addition, It was found that there is a strong correlation between content of various metal and film characteristics such as preferred orientation, grain size, hardness and friction coefficient and so, in future study, improved mechanical properties of TiN films can be controlled by change in target current density. The Ti-Cu-N film will show apparent hardness improvement and mechanical properties enhancement, when doping element is added onto TiN thin films. Film structure, chemical composition, mechanical properties were investigated by means of X-ray diffraction(XRD), scanning electron microscopy(SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy(EDS), wear resistance tester and nanohardness tester.

• Journal of Technologic Dentistry
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• v.23 no.2
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• pp.49-59
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• 2002

The photopolymerization efficiency and surface hardness of composite resin containing 1,2-phenylpropanedione (PD) and diacetyl (DA) as photoinitiators were studied by IR and Vickers hardness and the results were compared with that of camphorquinone (CQ). Relative photopolymerization efficiency of the photoinitiators increased in the order of DA < CQ < PD. Vickers hardness of composite resin containing the photoinitiators increased in the order of CQ < PD < DA. Thus, PD is a new visible light photoinitiator for dental composite resin with higher photopolymerization efficiency and surface hardness than that of CQ. Mechanical properties such as Vickers hardness, diametral tensile strength, and flexural strength of the experimental resin composite prepared by addition of the photosensitizer into a resin of bis-GMA improved with increasing the photosensitizer content and irradiation time. The resin composite of bis-GMA containing DA or PD shows better mechanical properties than that of CQ.

• Journal of the Korean Society for Heat Treatment
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• v.19 no.1
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• pp.3-9
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• 2006

The phase changes, nitride precipitation and hardness variations of 14%Cr-6.7Ni-0.65Mo-0.26Nb-0.05V-0.03C super martensitic stainless steel were investigated after nitrogen permeation heat treatment at a temperature range between $1050^{\circ}C$ and $1150^{\circ}C$. The nitrogen-permeated surface layer was transformed into austenite. The rectangular type NbN, NbCrN precipitates and fine round type precipitate were coexisted in the surface austenite layer, while the interior region that was free from nitrogen permeation kept the martensitic phase. The hardness of surface austenite showed 280 Hv, while the interior region of martensite phase represented 340 Hv. When tempering the nitrogen-permeated steel at $450^{\circ}C$, a maximum hardness of 433 Hv was appeared, probably this is attributed to the secondary hardening effect of the precipitates. The nitrogen concentration decreased gradually with increasing depth below the surface after showing a maximum of 0.3% at the outmost surface. The strong affinity between nitrogen and Cr enabled the substitutional element Cr to move from interiors to the surface when nitrogen diffuse form surface to the interior. Corrosion resistance of nitrogen permeated steel was superior to that of solution-anneaed steel in the solution of 1N $H_2SO_4$.

• Tribology and Lubricants
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• v.35 no.4
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• pp.237-243
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• 2019

Through this study, we investigate the effects of ultrasonic nanocrystal surface modification (UNSM) technology on the fatigue life of needle roller bearings. The fatigue life of untreated and UNSM-treated needle roller bearings is evaluated using a roller fatigue tester at various contact stress levels under oil-lubricated conditions. We can ascertain that the fatigue life of an UNSM-treated needle roller bearing was extended by approximately 34.3% in comparison with an untreated one, where the effectiveness of UNSM technology diminishes with increasing contact stress. The surface roughness and surface hardness of needle roller bearings before and after being treated by UNSM technology are compared and discussed to understand the role of UNSM technology in improving the fatigue life of needle roller bearings. In addition, a fractograph of the damaged bearings is observed using a scanning electron microscopy to shed light on the fracture mechanisms of bearings under different contact stress levels. We can therefore conclude that the application of UNSM technology to the needle roller bearings improves the fatigue life by reducing the friction coefficient and increasing the wear resistance; this may be attributed to a reduction in surface roughness from 0.5 to $0.149{\mu}m$ and an increase in surface hardness from 58 to 62 HRc.

• Journal of the Korean institute of surface engineering
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• v.38 no.4
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• pp.156-162
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• 2005

Nickel-iron nanocrystalline alloys with different compositions and grain sizes were fabricated by electro-plating for MEMS devices. The iron content of the deposits was changed by varying the nickel/iron ion ratio in the electrolyte. X-ray diffraction (XRD) analysis was applied for measuring the strength of the texture and grain size of the deposits. The nickel/iron atom ratio of the deposits was analyzed by EDS. The hardness of the alloys was evaluated by Vickers hardness indenter. The internal stress of the deposits was measured by Thin Film Stress Measurement using Stoney's formula. Surface morphology and roughness were investigated by Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM). The results of this study revealed that at a grain size of approximately $17\~24$nm the hardness, internal stress and roughness depend strongly on the iron content. With increasing the iron content, the hardness and internal stress of the deposits increased. An excellent correlation between the increase in the internal stress and the loss of (200) texture was found.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.11a
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• pp.87-88
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• 2020

The purpose of this study is to explore the possibility of estimating optimum surface finish time of the fresh concrete placed at the job site by applying a surface hardness test meter(Durometer). Tests are carried out by measuring and comparing the Penetration resistance test and hardness test by Durometer. Penetration resistance tester and improved Durometer are similar, but the higher the temperature, the higher the setting time, and the higher the correlation was shown. When the hardness value of the improved Durometer is about 50 HD, it is found that the initial and 80 HD represent the end. It is expected that this will be useful in determining the finish time of the surface at the actual site.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.11a
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• pp.169-170
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• 2020

The purpose of this study is to explore the possibility of estimating optimum surface finish time of the fresh concrete placed at the job site by applying a surface hardness test meter(Durometer). Tests are carried out by measuring and comparing the Penetration resistance test and hardness test by Durometer. Penetration resistance tester and improved Durometer are similar, but the higher the temperature, the higher the setting time, and the higher the correlation was shown. When the hardness value of the improved Durometer is about 50 HD, it is found that the initial and 80 HD represent the end. It is expected that this will be useful in determining the finish time of the surface at the actual site.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2012.05a
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• pp.179-180
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• 2012

Back ferrule is a circular ring shaped metallic object which is used for fastening, joining or reinforcement during the tube fitting as well as to prevent leakage. Therefore, during tube fitting the leading edge of the back ferrule should be sufficiently hard enough to prevent leakage. In our research, we concentrated the improvement of two major factors. Firstly, to improve the surface hardness of the back ferrule made by AISI 316 Stainless Steel. Secondly, the enhancement of corrosion resistance of back ferrule after plasma treatment. Initially, the corrosion resistance and hardness of the back ferrule (both commercial and without treated) was not good enough for tube fitting but after applying plasma treatment with suitable conditions on ferrule, we improved the corrosion resistance and hardness of the back ferrule dramatically.

• Journal of Welding and Joining
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• v.14 no.4
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• pp.53-61
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• 1996

It was attempted to improve the wear resistance of Al alloy under the load condition by making a formation of the thicker surface hardening alloy layers. The thicker surface hardening alloy layers were formed on 6061 Al alloys overlayed by MIG and TIG welding process with Cu powders feeding. The characteristics of hardening and wear resistance have been investigated in relation to the microstructures of alloyed layers, with a selection of optimum alloying conditions for formation of overlaying layer. The results obtained were summarized as follows With increasing feeding rate of Cu powders by MIG welding, the hardness and specific wear of the overlay weld alloys were increased. It is considered that these high hardness and specific wear of overlay weld alloys were due to the formation of Θ($Al_2Cu$) phases. With increasing feeding rate of Cu powders by TIG welding, the hardness and specific wear of the overlay weld alloys were increased in feeding rates 12 and 18g/min. However, the hardness and specific wear were decreased in the powder feeding rate 38g/min. It is considered that considered that decrease of hardness and specific wear in the powder feeding rate 38g/min due to formation of ${\gamma}$($Al_4Cu_9$) phases.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.2
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• pp.427-432
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• 1995

Surface heat treatment using a laser beam or an electron beam is studied through numerical analyses and experiments. For the surface heat treatment process, a theoretical model is developed to predict the effects of laser beam power, travel speed and properties of a workpiece on the depth and width of the heat affected zone(HAZ). The shape of HAZ and the hardness of heat-treated surface are experimentally obtained using an electron beam. Three materials(SS41, S45C and S55C) are selected as workpiece materials. The hardness of HAZ is increased up to 3 times for materials of a low carbon content. The results of the numerical analysis are compared with those of experiments. The comparison shows that the numerical model predicts larger depths and widths.