• 제목/요약/키워드: The law of diffusion

검색결과 231건 처리시간 0.026초

방사와 투과를 이용한 층류확산화염내 매연입자의 온도 및 농도 측정 (Soot Temperature and Concentration Measurement Using Emission/Transmission Tomography in Laminar Diffusion Flame)

  • 송상종;박성호;김상수
    • 대한기계학회논문집
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    • 제17권10호
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    • pp.2563-2573
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    • 1993
  • The measurements of monochromatic line-of-sight flame emission and light transmission in the same path having small spatial resolution were performed in an axisymmetric laminar propane $C_{3}H_{8}$ diffusion flame. The light wavelengthes of 632 nm, 800nm, 900nm were used. From these measurements, local point soot radiances (by Kirchhoff's law) and absorption coefficients were reconstructed by tomography. Thus local point soot temperatures and concentrations were obtained. The reconstructed soot temperatures and concentrations of local points have no differences between the case of visible range (632 nm) and the case of infrared range (800 nm and 900 nm). In these ranges, the scattering coefficient is much lower than the absorption coefficient. Soot mean temperature over the path also matches well with local soot temperature in outer region of the flame. Temperature measurement by thermocouple with different bead diameters $(222{\mu}m and 308{\mu}m)$ was carried in the same flame. Rapid insertion technique was used and radiation effect was considered. Radiation correction in the sooting region was carried out and the corrected result was in good agreement with the local soot temperature.

종이내 수분확산(제1보)-종이의 방습성 평가를 위한 수증기의 정류상 확산 실험- (Molecular Diffusion of Water in Paper( I )-Steady-State Diffusion Experiment for the Evaluation of Water Vapor-proof Properties of Paper-)

  • 윤성훈;전양;오세균;서영범
    • 펄프종이기술
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    • 제30권1호
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    • pp.59-70
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    • 1998
  • A steady-state molecular diffusion experiment was conducted to evaluate the water vapor proof properties of paper Handsheets prepared from unbleached Itraft pulps(UKP) and old newspapers(ONP) and four different types of polymer-laminated white duplex board were tested under appropriate standard conditions. The diffusivity was determined on the basis of the Fickean first law. Results obtained from this study can be summarized as follows ; 1. The diffusivity data for handsheets showed about $10^{-5}cm^2/min$. whereas polymer-laminated paperboards had remarkably improved water-vapor resistance with about $10^3 to 10^4$ times lower diffusivity : 2. Sheet basis weight, wet-swelling and sizing degree had little influence on the diffusivity of paper; 3 Linear relationship existed between sheet density and diffusivity, and, 4. Highly sfgnificant linear relationship could be observed between diffusivity and Darcy s gas permeability. Results indicate that diffusivity, an intrinsic property of paper, can provide a valuable information for precise evaluation and improved quality control of water-vapor proof properties of paper.

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Corrosion initiation time models in RC coastal structures based on reliability approach

  • Djeddi, Lamine;Amirat, Abdelaziz
    • Advances in concrete construction
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    • 제9권2호
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    • pp.149-159
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    • 2020
  • The present work proposes new engineering models for determining corrosion initiation time in concrete reinforcing steels in marine environment. The models are based on Fick's second law that is commonly used for chloride diffusion. The latter is based on deterministic analyses involving the most influencing parameters such as distance of the concrete structure from the seaside, depth of steel concrete cover, ambient temperature, relative humidity and the water-cement ratio. However, a realistic corrosion initiation time cannot be estimated because of the uncertainties associated to the different parameters of the models. Therefore a reliability approach using FORM/SORM method has been applied to develop the proposed engineering models integrating a limit state function and a reliability index β. As a result, the corrosion initiation time is expressed by new exponential engineering models where the uncertainties are associated to the model parameters. The main emerging result is a realistic decision tool for corrosion planning inspection.

Oxidation Kinetics of Silicon by Inductively Coupled Oxygen Plasma

  • Choi, Yong-Woo;Ahn, Jin-Hyung;Kim, Sung-Chul;Ahn, Byung-Tae
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2000년도 제1회 학술대회 논문집
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    • pp.63-64
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    • 2000
  • The low-temperature Si oxidation kinetics by inductively coupled oxygen plasma has been studied. Linear rate constants had negative values when the oxide growth rate was described by linear-parabolic growth law. The analysis of transverse-optical mode frequencies and etch rates indicated that the density of surface oxide was lower than that of bulk oxide. The oxidation kinetics could be explained qualitatively by assuming a surface layer with larger diffusion coefficient and a bulk layer with smaller diffusion coefficient.

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The application of model equations to Non-Fickian diffusion observed in Fluoropolymers

  • Lee, Sangwha
    • 한국막학회:학술대회논문집
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    • 한국막학회 1996년도 춘계 총회 및 학술발표회
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    • pp.34-35
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    • 1996
  • The diffusional behavior of many non-solvents in glassy or semicrystalline polymers cannot be adequately described by a concentration-dependent form of Fick's law, especially when mass transfer is coupled with structural changes. Many mathematical models have been devised to interprete non-Fickian diffusion dominated by relaxation kinetics. In formulation of non-Fickian diffusion mathematics, therefore, the most important factor to consider is how relaxation effects can influence the governing constitutive equation and boundary conditions. That is, relaxation parameters can be accommodated by variable boundary conditions or a modified continuity equation, or both, depending on specific systems and conditions (Frish, 1980). Accoring to Astarita and Nicolais (1983), the model equations can be broadly categorized as continuous or discontinuous. Continuous model equations encompass phenomena where the structural change takes place gradually over the whole volume of the polymer sample (Crank, 1953; Long and Richman, 1961; Berens and Hopfenberg, 1978). On the other hand, discontinuous model equations deal with the phenomena where the morphological change appears to be abrupt (Li, 1984). Four mathematical models with different relaxation parameters were applied to fit the anomalous sorption data observed in fluoropolymers (PVDF, ECTFE). The fitted result for PVDF-benzene sorption data is shown in Fig. 1.

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메모리소자를 위한 Ti1-xAlxN 방지막의 산화 거동 (Oxidation Behavior of Ti1-xAlxN Barrier Layer for Memory Devices)

  • 박상식
    • 한국재료학회지
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    • 제12권9호
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    • pp.718-723
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    • 2002
  • $Ti_{1-x}$ $Al_{ x}$N thin films as barrier layer for memory devices application were deposited by reactive magnetron sputtering. The crystallinity, micro-structure, oxidation resistance and oxidation mechanism of films were investigated as a function of Al content. Lattice parameter and grain size of thin films were decreased with increasing the Al content Oxidation of the film with higher Al content is slow and then, total oxide thickness is thinner than that of lower Al content film. Oxide layer formed on the surface is AlTiNO layer. Oxidation of $Ti_{1-x}$ /$Al_{x}$ N barrier layer is diffusion limited process and thickness of oxide layer with oxidation time increased with a parabolic law. The activation energy of oxygen diffusion, Ea and diffusion coefficient, D of $Ti_{0.74}$ /X$0.74_{0.26}$N film is 2.1eV and $10^{-16}$ ~$10^{-15}$ $\textrm{cm}^2$/s, respectively. $_Ti{1-x}$ /$Al_{x}$ XN barrier layer showed good oxidation resistance.

란탄족 원소와 Ferritic-Martensitic 강의 반응 거동 (Interaction Behavior between Lanthanide Element and Ferritic-Martensitic Steel)

  • 김준환;백종혁;이병운;이찬복;윤영수
    • 대한금속재료학회지
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    • 제48권8호
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    • pp.691-698
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    • 2010
  • A study has been carried out to evaluate the interaction behavior between a lanthanide element and clad material in order to analyze the effect of the lanthanide element on the fuel cladding chemical interaction (FCCI). A diffusion couple test between Misch metal (70Ce-30La) and ferritic-martensitic steel (Gr.92) was performed at $660^{\circ}C$, followed by a microstructural analysis of the coupled sample. The results showed that Ce in the Misch metal, rather than La, reacted with the ferritic-martensitic steel (FMS) to form an interaction layer that penetrated the clad thickness. Fe diffused outside the clad interface to form an $Fe_2Ce$ compound, leaving a depletion of Fe caused by excess diffusion as well as by the formation of Cr-rich precipitation inside the interaction layer. The rate of growth followed the cubic rate law, which indicated that Fe depletion was caused by the diffusion of Fe and that the associated Cr-rich phase formation controlled the whole diffusion process.

국제기술이전계약상(國際技術移轉契約上)의 부공정조항(不公正條項)에 관한 연구(硏究) (Unfair Contractual Clauses for the Transfer of Technology)

  • 서정두
    • 무역상무연구
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    • 제12권
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    • pp.107-132
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    • 1999
  • The technology transfer agreements, which transfer technology from industrialized countries to developing countries, are subjected to control and restrictions in many developing countries in order to protect national interests. The licensors endeavour, therefore, to ensure that their activities fit satisfactorily into the technological policies and plans of the host countries, and contribute to the development of national scientific and technological potential, including the establishment and improvement in host countries of their capacity to innovate. Secondly, the licensors adopt in the course of their business activities practices which permit the rapid diffusion of technologies with due regard to the protection of industrial and intellectual property rights. Thirdly, the licensors endeavour to grant licenses for the use of industrial property rights or to otherwise transfer technology on reasonable terms and conditions.

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주요 정보통신기반시설의 평가컨설팅 방법론에 대한 연구 (A Study on the Evaluation Consulting Methodology of Important Information Communication Base Facility)

  • 이영로;조재완
    • 디지털융복합연구
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    • 제5권1호
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    • pp.55-68
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    • 2007
  • It soaks but 2001 July information communication base step law enforcement and the Enforcement Ordinance are published to follow, in order to support the establishment of evaluation and protective measure in order the vulnerability analysis against the facility of the agency which manages an important information communication base hour opinion to designate information protection specialty enterprise. As information protection specialty enterprise being revealed evacuation laboratory back 12 enterprises from information communication department become designation as the consulting enterprise and they do an enterprise activity actively. It follows in diffusion of the IT and information reconciliation level the other side where our country belongs in the world-wide first group, the research against the disfunction plan of preparation comparison the fact that law it is come negligently all actuality. The network as it will give management coat fatal effect even at obstacle occurrence hour of instant for of case and IT facility of the cyber transactions which leads, in the future there to be to corporate management, there is a possibility the stable civil official of information Facilities for communications very seeing in the portion which is important. Present condition and important propulsion contents of information communication base step law enforcement after, against a vulnerability analysis of information protection relation field and evaluation consulting methodological application situation to sleep it researches from the dissertation which it sees consequently and it does.

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경찰의 총기·장구 사용과 국민의 인권보호에 대한 실태연구 (The survey on the use of firearms & equipment in police and the protection of citizens' rights)

  • 정정일
    • 융합보안논문지
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    • 제16권3_2호
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    • pp.43-54
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    • 2016
  • 우리나라 경찰은 지난 반세기동안 국내 외적인 시련을 극복하면서 질서유지자로서의 임무를 훌륭히 수행해 왔으나 최근 경찰을 둘러싼 환경은 국제화와 개방화, 민주화와 지방화, 산업화와 정보화가 급속히 전개되면서 치안수요의 폭발적 증가를 가져오고 있다. 또한 범죄유형이 날로 흉폭화 조직화 광역화 되는 추세여서 경찰 대응의 한계점과 더불어 장구 무기사용의 필요성이 대두되고 있는 실정이다. 하지만 장구와 무기 허용은 국민의 귀중한 생명을 위협할 수 있다는 선행과제로 인해 엄격하게 적용되어야 한다. 이에 본 연구에서는 기존에 경찰관들에게 지급된 장구 무기의 사용이 우리의 현실에 있어 실효성과 효과성이 있는지를 살펴보고, 일선 경찰관들의 법 집행력이 어느 범위여야 적정하고, 국민의 인권을 보호하는 경찰로서 신뢰를 받을 수 있는지를 조사하고 경찰 집행력 행사와 국민의 인권보호에 대해 방안을 제시하고자 한다.