• Title/Summary/Keyword: The heavy metal

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Selective Analysis of Heavy Metal Ions Using Protein-based Biosensor (단백질 바이오센서를 이용한 중금속 이온의 선택적 측정)

  • 김균영;김지현;유영제
    • KSBB Journal
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    • v.16 no.6
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    • pp.609-613
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    • 2001
  • New protein-based biosensors using fluorescence for the detection heavy metal ions were developed. The detection range of heavy metal ions was between 10$\^$-3/ mM - 1 mM using casein and albumin as a transducer of biosensor, respectively. Casein showed better results for detecting heavy metal ions than albumin. Simple assay method was developed for the selective analysis of the two heavy metal ions by the fluorescence at wavelength of excitation and emission. This method was successfully applied to determining the concentrations Of Co$\^$2+/ and Fe$\^$3+/.

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Adsorption of Hg(I), Pb(II), and U(VI) ions using from Fruits of Schizandra Chinensis (오미자를 이용한 Hg(I), Pb(II), U(VI) 이온들의 흡착)

  • Kim, Kwan-Chun;Kim, Joon-Tae
    • Journal of environmental and Sanitary engineering
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    • v.22 no.1 s.63
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    • pp.29-35
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    • 2007
  • This study was examined adsorption ability of heavy metal Hg(I), Pb(II), and U(Vl) ion use of fruit from schizandra chinensis, The fruits of schizandra chinensis sample used breaking into fragments $50{\sim}100$ mesh. The sample solution was mixed fruits of schizandra chinensis and heavy metal ion. Each heavy metal ion of into solution was quantum analysis with ICP-AES. As the result, each condition of maxium adsorption ability of heavy metal ion was high in the range of pH 5-7, adsorption time was about 15 minutes, and the optimum temperature was $100^{\circ}C$. The heavy metal ion was increased adsorption in order of increasing concentration and in ethanol solution better than in aqueous solution.

A Study On Heavy Metal Contamination in the Different Size Fractions of Deposited Road Particles(DRPs) (노면퇴적물의 입자 크기에 따른 중금속 오염에 관한 연구)

  • Kim, Boo-Gil;Lee, Byung-Cheol
    • Journal of Environmental Science International
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    • v.15 no.12
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    • pp.1171-1175
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    • 2006
  • Deposited road particles (DRPs) were analysed for heavy metal concentrations at four different roads in a city, Korea. The samples were collected using a roadway surface vacuum cleaning vehicle which was commonly used in collecting roadway surface particles. Six particle size ranges were analyzed separately for twelve heavy metal elements (Cd, Cr, Pb, Ni, Al, As, Co, Cu, Fe, Mn, Zn and Hg). At all sampling sites, the high concentration of the heavy metals occurred in the <74um particle size range, which conventional roadway cleaning vehicles do not remove efficiently. The Pb concentration significantly increased with decreasing particle size of DRPs, and other toxic heavy metals (Cd, Cr and Ni) also showed similar results. The heavy metal concentrations in the smaller size fraction of DRPs is important because they are contaminants that are preferentially transported by road runoff during rainfall.

Removal of Heavy Metals by Sawdust Adsorption: Equilibrium and Kinetic Studies

  • Lim, Ji-Hyun;Kang, Hee-Man;Kim, Lee-Hyung;Ko, Seok-Oh
    • Environmental Engineering Research
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    • v.13 no.2
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    • pp.79-84
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    • 2008
  • Adsorption of heavy metals by sawdust was investigated to evaluate the effectiveness of using sawdust to remove heavy metals from aqueous solutions. Kinetic and isotherm studies were carried out by considering the effects of initial concentration and pH. The adsorption isotherms of heavy metals fitted the Langmuir or Freundlich model reasonably well. The adsorption capacity of metal was in the order $Pb^{2+}$ > $Cu^{2+}$ > $Zn^{2+}$. A high concentration of co-existing ions such as $Ca^{2+}$ and $Mg^{2+}$ depressed the adsorption of heavy metal. Adsorption data showed that metal adsorption on sawdust follows a pseudo-second-order reaction. Kinetic studies also indicated that both surface adsorption and intraparticle diffusion were involved in metal adsorption on sawdust. Column studies prove that sawdust could be effective biosorbent for the removal of heavy metals from aqueous phase.

Studies on the Heavy Metal Contents in Cultivated Medicinal Plants and their Correlations with Soils (수종 재배 약용식물과 토양중 중금속 함량에 관한 연구)

  • Yoo, Seung-Jo;Song, Kyung-Sik
    • Korean Journal of Pharmacognosy
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    • v.22 no.1
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    • pp.33-35
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    • 1991
  • Heavy metals may cause trouble(s) in human body. For consideration of the safety of crude drugs cultivated in Korea, we selected some medicinal plants and soils from cultivated site and estimated their heavy metal contents by inductively coupled argon plasma spectrometry (ICAP). Among heavy metals tested, the highest level of Cu and Zn were shown in plants cultivated in Kyung Ki; the highest level of Fe in those in Youngnam and the highest level of Mg and Mn in those in Youngdong. The heavy metal content s were as low as to be permeasible at least for the medicinal plants we selected. There were no significant correlations between heavy metal contents of soils and cultivated medicinal plants.

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Influence of Heavy Metal on Riparian Vegetation in Downstream Areas of Disused Metal Mines (폐금속광산지역의 하천퇴적물에서 중금속이 식물에 미치는 영향에 관한 연구)

  • Ahn, Tae Woong;Lee, Joung An;Oh, Jong Min
    • Journal of Environmental Impact Assessment
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    • v.18 no.4
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    • pp.209-218
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    • 2009
  • The purpose of this study was to accumulation of the heavy metals by riparian vegetation throughout analysis of the heavy metal concentration in riparian vegetation, water, and sediment near mine drainage. According to analyzing concentration of the heavy metals in riparian vegetation, water, and sediment the heavy metal was indicated at the leaf significantly. Compared with the concentration of sediment soil, the maximum concentration of the As, Cd, CN, Pb, Zn was higher 2.6, 2.6, 25, non-detect, and 15 times in leaf. Also those concentration have 9.6, 16.6, 25, 1.6, and 25 times in root. As the results, the author can know the sediment has a very relative to vegetation in mine drainage. because, the increasing of concentration of heavy metal in sediment gives the more accumulative concentration of heavy metal in vegetation. Compared with the concentration of conta minated site and non-contaminated site. As, Cd, CN, Pb, Zn the maximum concentration in sediment soil was higher 5.7, 258.1, 10.9, 370.0, and 298.3 times respectively. In case of vegetation, the maximum concentration of the As, Cd, CN, Pb, Zn was higher 5.6, 62.3, 5.0, non-detect, and 30.6 times in leaf. Also those concentration have 8.5, 63.3, 2.6, 60.7, and 62.1 times in root. In this study, the author can surmise that there indicated a lot of adsorption with the heavy metal concentration in contaminated mine drainage.

Source Identification of Heavy Metal Contamination at an Industrial Complex Established Using Construction Wastes (건설폐기물을 성토재로 사용한 산업단지에서의 중금속 오염 원인 규명)

  • JOO, Gwonho;KIM, Kibeum;NAM, Kyoungphile;JUNG, Jae-Woong;Moon, Seheum;CHOI, Yongju
    • Journal of Soil and Groundwater Environment
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    • v.23 no.1
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    • pp.54-62
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    • 2018
  • This paper is aimed at source tracking of soil heavy metal contamination at a site established by reusing construction wastes. The soil heavy metal concentration at the study site peaked at a depth range of 5-10 m. Column studies were conducted to investigate the possibility of the contamination scenario of infiltration of stormwater carrying heavy metals of ground origin followed by selective heavy metal accumulation at the 5-10 m depth range. Almost all amount of lead, zinc, cadmium, and nickel introduced to the columns each packed with 0-5 m or 5-10 m field soil were accumulated in the column. The very poor heavy metal mobility in spite of the weak association of the heavy metals with the soil (characterized by a sequential extraction procedure) can be attributed to the high pH (10-11) of the construction wastes. From the results, the heavy metal contamination of the subsurface soil by an external heavy metal source was determined to be very unlikely at the study site. The column study applied in the current study is expected to be a useful methodology to present direct evidence of the contaminant source tracking at soil contamination sites.

Study for Phytostabilization using Soil Amendment and Aster koraiensis Nakai in Heavy Metal Contaminated Soil of Abandoned Metal Mine

  • Jung, Mun-Ho;Lee, Sang-Hwan;Ji, Won-Hyun;Park, Mi-Jeong;Jung, Kang-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.5
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    • pp.627-634
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    • 2016
  • The objectives of this study were to select optimal soil amendments through analysis of heavy metal availability in soil and uptake to Aster koraiensis Nakai for forest rehabilitation of heavy metal contaminated soil of abandoned metal mine. A. koraiensis was cultivated for 6 months at contaminated soil with several soil treatments (bottom ash 1 and 2%, fly ash 1 and 2%, waste lime+oyster 1 and 2%, Acid mine drainage sludge (AMDS) 10 and 20%, compost 3.4%, non-contaminated natural forest soil, and control). The analysis results of heavy metal concentrations in the soil by Mehlich-3 mehthod, growth and heavy metal concentrations of A. koraiensis showed that waste oyster+lime 1% and compost were more effective than the other amendments for phytostabilization. However, it is needed comprehensive review of factors such as on-site condition, slope covering to reduce soil erosion and vegetation introduction from surround forest for revegetation to apply forest rehabilitation.

Heavy Metal Absorption Properties of Sulfonated Polyethylene Terephthalate (Sulfonated Polyethylene Terephthalate의 중금속 흡착능)

  • Kang, Young-Goo;Kim, Dong-Hyun
    • Journal of the Korean Society of Safety
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    • v.18 no.4
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    • pp.92-97
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    • 2003
  • The purpose of this study is heavy metal absorption of recycled PET(poly ethylene terephatalate) NWF(non woven faric). The results of test are summarized as follows; Heavy metal abworption rates in Ni ions were higher then Zn and Cu ions, whereas heavy metal absorption rates by sulfonation times were not different. The heavy metal absorption times have a higher tendency from 60 min to 120 min. There were significant negative correlations among the amount used CSA(Chloro Sulfuric Acid) and the amount of absorption Zn(r = -0.33784, p < 0.05), Cu(r = -0.61177, p < 0.01) ions, whereas correlations between heavy metal absorption rates and sulfonation times were not significant. There were significant positive correlations among the amount of absorption Zn ions and the amount of absorption Ni(r = 96475, p < 0.014), Cu(r = 0.51614, p < 0.01) ions, likewise the positive correlations between the amount of absorption N ions and the amount of absorption Cu(r = 0.54766) ions were significant(p < 0.01).

Solidification of Heavy Metal Ions Using Magnesia-phosphate Cement (인산염 마그네시아 시멘트에 의한 중금속 이온 고정화)

  • Choi, Hun;Kang, Hyun-Ju;Song, Myung-Shin;Jung, Eui-Dam;Kim, Ju-Seng
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.20-25
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    • 2011
  • Since 1980's, many mines have been closed and abandoned due to the exhaustion of deposits and declining prices of international mineral resources. Because of the lack of post management for these abandoned mines, Farm land and rivers were contaminated with heavy metal ions and sludge. We studied on the solidification/stabilization of heavy metal ions, chromium ions and lead ions, using magnesia-phosphate cement. Magnesia binders were used calcined-magnesia and dead-burned magnesia. Test specimens were prepared by mixing magnesia binder with chromium ions and lead ions and activators. We analyzed the hydrates by reaction between magnesiaphosphate cement and each heavy metal ions by XRD and SEM-EDAX, and analyzed the content of heavy metal ions in the eruption water from the specimens for the solidification and stabilization of heavy metal ions by ICP. The results was shown that calcined magnesia binder is effective in stabilization for chromium ions and dead-burned magnesia binder is effective in stabilization for lead ions.