• Title/Summary/Keyword: The crystalline properties

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A Study On the Structure and Mechanical Properties of PP filament at Different Spinning speed and Draw ratio (방사속도 및 연신비 변화에 따른 Polypropylene filament의 구조와 물성에 관한 연구)

  • Lee, Eun-Woo;Cho, Kyu-Min;Cho, In-Sul
    • Journal of the Korean Society of Industry Convergence
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    • v.2 no.1
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    • pp.27-33
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    • 1999
  • Effects of spinning speed and draw ratio on structure and mechanical properties of PP filament. A The crystalline structure and mechanical properties of uniaxially deformed polypropylene filament has been examined by XRD, birefringence, UTM and density method. Uniaxially deformed PP filament was prepared of various spinning speeds (300, 600, 900m/min.) and draw ratio(x2, x3, x4). From the results of these studies, it found the following facts. Firstly, it was found that the crystallinity and crystallite size (110plane) of the samples were increased with increasing of spinning speed and draw ratio, especially, it was rapidly increased between as spun yarn and 2 times draw ratio. Secondly, birefringence value was increased with increasing of spinning speed and draw ratio. The mechanical properties of initial modulus, tensile strength were increased with increasing of spinning speed and draw ratio also, but the degree of elongation decreased as spinning speed and draw ratio.

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Design Sensitivity in Quasi-One-Dimensional Silicon-Based Photonic Crystalline Waveguides

  • Kinoshita, Takeshi;Shimizu, Akira;Iida, Yukio;Omura, Yasuhisa
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.3 no.1
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    • pp.55-61
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    • 2003
  • This paper describes how the optical properties of a quasi-one-dimensional photonic crystalline waveguide having a periodic air cavity are influenced by various structural parameters; the electromagnetic fields are simulated using the finite-difference time-domain method. The simulations considered four design parameters: cavity size, defect size, lattice constant, and number of cavity. The parameter sensitivity of the photonic bandgap property of the waveguide having air cavities is examined. A couple of significant design guidelines are obtained. We show that the quasi-one-dimensional photonic crystalline waveguide has significant unrealized potential.

Lattice strain effects on superconductivity in $La_{2-x}Sr_{x}CuO_{4}$ single-crystalline films grown by IR-LPE technique

  • Tanaka, I.;Islam, A.T.M.N.;Wataudhi, S.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.4
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    • pp.172-175
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    • 2003
  • We have investigated effects of the lattice mismatch between the LPE films and the substrates. We have grown $La_{2-x}Sr_{x}CuO_{4}$(x=0.1 to 0.15) single crystalline films on single crystalline substrates having different lattice parameter ratio c/a e.g., $La_{2-x}Sr_{x}Cu_{1-y}Zn_{y}O_{4},\;La_{2-x}Ba_{x}CuO_{4},\; LaSrAlO_{4}\;and\;La_{2-x}Sr_{x}Cu_{1-y}Al_{y}O_{4}$ etc., using the IR-LPE technique. The superconducting properties of the grown films were found to vary significantly depending on the lattice mismatch with different substrates.

Addition of Various Cellulosic Components to Bacterial Nanocellulose: A Comparison of Surface Qualities and Crystalline Properties

  • Bang, Won Yeong;Kim, Dong Hyun;Kang, Mi Dan;Yang, Jungwoo;Huh, Taelin;Lim, Young Woon;Jung, Young Hoon
    • Journal of Microbiology and Biotechnology
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    • v.31 no.10
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    • pp.1366-1372
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    • 2021
  • Bacterial nanocellulose (BNC) is a biocompatible material with a lot of potential. To make BNC commercially feasible, improvements in its production and surface qualities must be made. Here, we investigated the in situ fermentation and generation of BNC by addition of different cellulosic substrates such as Avicel and carboxymethylcellulose (CMC) and using Komagataeibacter sp. SFCB22-18. The addition of cellulosic substrates improved BNC production by a maximum of about 5 times and slightly modified its structural properties. The morphological and structural properties of BNC were investigated by using Fourier transform-infrared spectroscopy (FT-IR), scanning electron microscopy and X-ray diffraction. Furthermore, a type-A cellulose-binding protein derived from Clostridium thermocellum, CtCBD3, was used in a novel biological analytic approach to measure the surface crystallinity of the BNC. Because Avicel and CMC may adhere to microfibrils during BNC synthesis or crystallization, cellulose-binding protein could be a useful tool for identifying the crystalline properties of BNC with high sensitivity.

Research of Thermal Properties for Liquid Crystalline Epoxy Composites with Tin Oxide Filler (산화주석을 함유한 열경화성 액정 에폭시의 열적 특성에 관한 연구)

  • Hyun, Ha Nuel;Cho, Seung Hyun
    • Composites Research
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    • v.33 no.1
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    • pp.25-29
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    • 2020
  • A liquid crystalline thermosetting-epoxy-based composite was fabricated using diglycidyl ether of 4,4'-biphenol, tin(IV) oxide as a filler, and sulfanilamide as a curing agent. To investigate the thermal behavior, Thermogravimetric Analysis and Laser Flash Apparatus were performed using 3.0-7.0 wt% Tin(IV) oxide. The result showed that the activation energy and thermal conductivity were proportional to the amount of added filler.

Characteristics of Zns:Mn Thin Film Electroluminescences Prepared by a Repeated Deposition of Hot Wall Method (Hot Wall 법의 반복 증착에 의해 제작한 ZnS:Mn 박막 엘렉트로루미네센스의 특성)

  • 이상태
    • Journal of the Korean Institute of Navigation
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    • v.25 no.4
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    • pp.435-442
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    • 2001
  • A new technique to grow a manganese-doped zinc-sulfide(ZnS:Mn) has been proposed using the repeated deposition of the Hot Wall method. The optical characteristics and crystallinity for the ZnS and ZnS:Mn thin films deposited on a quartz glass substrate by the method were investigated. Also, The ZnS:Mn thin film elcetroluminescent devices were fabricated by the method to study luminescence characteristics. All films showed (111)-oriented cubic structure. By the repeated deposition, the deposition rates were decreased, and the optical characteristics and crystalline properties were improved, which clarifies that the method is effective to deposit the thin films with good crystallinity Futhermore, the crystallinity was more improved by the doping of Mn. Only one peak emission at around 585nm originating from Mn luminescent center is observed In the photoluminescent and electroluminescent spectra of ZnS:Mn films and the luminance of the ZnS:Mn-based thin film electroluminescent devices was obtained below 60cd/$m^2$ . The optical and crystalline properties, luminescence characteristics are discussed in terms of the effects of the repeated deposition and Mn-doping.

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Microstructure and Mechanical Properties of TiC-Co/Al Composites Prepared by Reaction-Bonded Sintering (반응결합 소결에 의한 TiC-Co/Al 복합체의 미세구조 및 기계적 특성)

  • 한인섭;남기웅;정윤중
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.257-269
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    • 1995
  • The TiC-Co/Al reaction-sintered products were prepared by the infiltration of various Co/Al metal mixture into the preform, and their microstructure, phases, and mechanical properties were investigated. With increasing the atomic ratio of Co/Al, tiC grain shape was changed from spherical to platelet particles, and the grain size increased. The crystalline phases found in the liquid matrix formed by the infiltration of Co/Al metal mixture were determined to be Al5Co2 and AlCo by EDS and XRD, and the two crystalline phases were located dominantly between TiC grains, when the Co/Al atomic ratio was lower than an unity. There was a tendency that the density, bending strength and fracture toughness increase with Co/Al atomic ratio until the infiltrated metal was 100% Co. The maximum value was achieved by the composition containing 100% Co infiltrated metal. The Vickers hardness decreased as Co/Al atomic ratio increased.

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Fabrication of Quasi-crystal Strengthened Aluminum Composites by Mechanical Milling Process (기계적 밀링 공정을 이용한 준결정 강화 알루미늄 복합재료의 제조)

  • Jang Woo Kil;Shin Kwang Seon
    • Journal of Powder Materials
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    • v.12 no.3
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    • pp.208-213
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    • 2005
  • Aluminum matrix composites strengthened by the quasi-crystalline (QC) phase were developed in the present study. The icosahedral $Al_{65}Cu_{20}Fe_{15}$ phase was produced by gravity casting and subsequent heat treatment. The mechanical milling process was utilized in order to produce the Al/QC composite powders. The microstructures of the composite powders were examined by optical microscopy (OM) and scanning electron microscopy (SEM). The composite powders were subsequently canned, degassed and extruded in order to produce the bulk composite extrusions with various volume fractions of QC. The microstructure and mechanical properties of the extrusions were examined by OM, SEM, Vickers hardness tests and compression tests. It was found that the microstructures of the Al/QC composites were uniform and the mechanical properties could be significantly improved by the addition of the QC phase.

Synthesis and Properties of Ca8Gd2(PO4)6O2 Nano-Crystalline Structures

  • Bharat, L. Krishna;Yu, Jae Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.286.1-286.1
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    • 2013
  • Nowadays, the glare towards the light-emitting diode (LED) lighting source has much attention due to its eco-friendly nature, reduced energy consumption, and low CO2 emission. LEDs can show versatile colors by changing the composition ratio of semiconductors. Phosphors re-emit light by absorbing light from LED, which is the key factor for emission. The endeavor to make replica of natural white light is increasing day by day. Industrially, blue LED chip crowned with a yellow phosphor coated lens gives low quality white light. Newly, many researchers are introducing modern approaches, adding red phosphor to the yellow phosphor to increase the quality of white light. Here, we synthesized structurally and chemically stable europium doped oxyapatite Ca8Gd2(PO4)6O2 nano-crystalline structures by a hydrothermal method. The ultrafine structures were formed due to the effect of ethylenediaminetetraacetic acid, which is confirmed by the transmission electron microscope images. The structural properties were analyzed using the X-ray diffraction patterns.

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Electronic Structures and Noncollinear Magnetic Properties of Structurally Disordered Fe

  • Park, Jin-Ho;Min, B.I.
    • Journal of Magnetics
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    • v.15 no.1
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    • pp.1-6
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    • 2010
  • The magnetic properties of amorphous Fe were investigated by examining the electronic structures of structurally disordered Fe systems generated from crystalline bcc and fcc Fe using a Monte-Carlo simulation. As a rst principles band method, the real space spin-polarized tight-binding linearized-mun-tin-orbital recursion method was used in the local spin density approximation. Compared to the crystalline system, the electronic structures of the disordered systems were characterized by a broadened band width, smoothened local density of states, and reduced local magnetic moment. The magnetic structures depend on the short range configurations. The antiferromagnetic structure is the most stable for a bcc-based disordered system, whereas the noncollinear spin spiral structure is more stable for a fcc-based system.