• 한국세라믹학회지
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• 제24권1호
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• pp.56-62
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• 1987

Tetragonal phase PZT ceramics with a tetragonality of c/a=1.027 to 1.041 were sintered at 1275$^{\circ}C$ for one hour. And the directionality of domain arrangement, microstructure, dielectric and aging properties were investigated. With increasing tetragonality, the directionality of domain arrangement of 180$^{\circ}$-domain on the surface is smaller than that in the internal part of specimens. Dielectric constants after poling are increased due to the increased internal energy or decreased due to the microcracks created by poling.

• 한국전기전자재료학회논문지
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• 제33권6호
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• pp.483-489
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• 2020

BaTiO₃ powder was synthesized by a solid-state reaction using BaCO₃ and TiO₂. Different calcination temperatures (800℃, 850℃, 900℃, and 950℃) were set to investigate their effects on the properties of BaTiO₃ powder. The synthesized BaTiO₃ phase was confirmed to be a single phase by XRD, and the tetragonality (c/a) and crystallite size were calculated. Thereafter, each calcinated BaTiO₃ was sintered at five different sintering temperatures (1,100℃, 1,150℃, 1,200℃, 1,250℃, and 1,300℃), and the tetragonality, density, porosity, dielectric constant, and grain size were measured. As the calcination temperature increased, the tetragonality and crystallite size also increased, to 1.008 and 66 nm, respectively, at 950℃. Moreover, most pellets showed increased density, dielectric constant, and tetragonality as the sintering temperature increased up to 1,250℃; the same parameters slightly decreased at 1,300℃. It is noteworthy that the tetragonality of BaTiO₃ at 1,250℃ exhibits a very high c/a value of 1.0084. In addition, the grain size and dielectric constant measured near the Curie temperature increased as the sintering temperature increased.

• 한국세라믹학회지
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• 제29권9호
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• pp.675-680
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• 1992

The purpose of this investigation was to study the stability of perovskite structure, the variation of electrical properties and a microstructure with varing amount of PbTiO3 additive in PZN-PT-BT system. The results are as follows: 1. The pyrochlore phase was reduced as the amount of PbTiO3 additive was increased and completely eliminated at 0.15PT in PZN-PT-BT system. 2. The aging rate was increased in proportion to tetragonality because the internal stress was increased in proportion to tetragonality. 3. On increasing the amount of PbTiO3 additive, the Curie temperature was increased in proportion to tetragonality. 4. As the amount of PT in the composition increase, the variation of dielectric constant was sharpened and the diffuseness of the transition decreased.

• 한국전기전자재료학회논문지
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• 제16권10호
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• pp.892-896
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• 2003

In this study, microstructure and piezoelectric properties of PSN-PZT ceramics modified with BiFeO$_3$ were investigated as a function of PNW substitution. With the increase of PNW substitution, tetragonality, Curie temperature and mechanical quality factor were decreased but grain size and electromechanical coupling factor(kp) was gradually increased. At 4 mol[%] PNW substitution, maximum kp of 0.567 was obtained.

• 한국전기전자재료학회논문지
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• 제14권1호
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• pp.20-25
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• 2001

To develop the piezoelectric actuator, the structural, dielectric and piezoelectric properties and electric fieldinduced strain of the ceramics(Pb$\_$1-2/Ba$\_$x/)[Mg$\_$1/2/W$\_$1/2/)$\_$0.03/-Ni$\_$1/3/Nb$\_$2/3/)$\_$0.12/-(Zr$\_$0.5/Ti$\_$0.5/)$\_$0.85/]O$_3$(x=0, 0.01, 0.03, 0.05, 0.07, 0.1) were investigated with the substitution of Ba. The tetragonality of crystal structure and grain size decreased by the substitution of Ba. Curie temperature decreased due to the decrease of the tetragonality, and dielectric constants increased with the substitution of Ba. The coercive field, remnant polarization and electromechanical coupling factor also decreased, whereas the piezoelectric constatns d$\_$33/ and d$\_$31/ were showed the highest value of 430 and 209(x10$\^$-12/C/N), respectively, because of the increase of dielectric constant. The strain induced by 60Hz AC electric field had the maximum value of 204x10$\^$-6/Δℓ/ℓ at the substitution of Ba 3mol%. As the applied electric field approaches to the coercive field, the piezoelectric element is depolarized and the electric field induced strain revealed non-linearity.

• 한국결정성장학회지
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• 제13권4호
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• pp.162-167
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• 2003

광페롤용 안정화 지르코니아 소결체의 특성을 평가하기 위하여, A, B와 C사의 원료를 이용하여 1350, 1400 및 $1450^{\circ}C$로 소결하여 시편을 제작하였다. 각각의 열처리 온도에 따른 결정화도, 미세구조 및 기계적 특성을 조사하였다. X-선 회절 분석법과 전계방사 주사형 전자현미경을 이용하여 소결된 시편의 결정화도와 미세구조를 분석하였으며, 만능재료 시험기와 비이커스 경도계를 이용하여 꺽임 강도와 비이커스 경도를 측정하였다 실용적인 측면에서 볼 때, 비교적 저온인 $1350^{\circ}C$로 소결한 시편 B의 경우가 tetragonality도 높고 좋은 기계적인 강도를 나타냈다.

• 한국세라믹학회지
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• 제25권4호
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• pp.335-340
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• 1988

The change in microstructure and the electrical properties of Pb(In1/2Nb1/2)O3-PbTiO3 Ceramics caused by V2O5 addition were studied. The results are ; 1. interability was increased because the mass transport through the second phase formed by V2O5 addition increased. 2. ith addition of V2O5, tetragonality and Curie temperature increased. The maximum value of kp was observed when 0.5wt% of V2O5 was added. 3. he second phase formed by V2O5 accelerated the grain growth, and existed in grain boundary. Electrical properties were changed by corelations between tetragonality and the amount of second phase.

• 한국세라믹학회지
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• 제46권2호
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• pp.137-145
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• 2009

A remarkable improvement of the productivity in barium titanate by slurry spray pyrolysis process was realized by supplying solid source slurry into the rector. The produced barium titanate powders showed uniform powder properties, and reproducibility with higher tetragonality in the range of 80$\sim$200 nm, case by case. The secondary calcination experiments of the as-prepared powders by spray pyrolysis revealed that the powders as-prepared over 700$^{\circ}C$ showed perfectly different behavior with the lower temperature's ones and the solid state reaction’s case. The result was discussed in terms of the reaction mechanism based on the activation energy analysis.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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• pp.280-283
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• 2002

In this study, the effects of $Nb_{2}O_{5}$ addition on microstructure and piezoelectric characteristics of PNW-PMN-PZT ceramics were investigated. As $Nb_{2}O_{5}$ addition amount is increased, grain size is gradully decreased. At 0.3wt%$Nb_{2}O_{5}$ addition composition ceramics, maximum density, tetragonality and piezoelectric characteristics were obtained.

• 센서학회지
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• 제7권1호
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• pp.51-60
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• 1998

초전형 적외선센서를 제조하기 위하여 La가 첨가된 $PbTiO_{3}$(PLT)박편을 소결온도, La첨가량 및 소결시의 분위기분말의 양과 같은 제조조건을 달리하면서 제조하여 이에 따른 시편의 구조적 특성을 X-선 회절기, 전자현미경 및 상대밀도의 측정을 통하여, 유전특성을 유전상수와 큐리온도 등의 측정을 통하여 조사하였다. La 첨가랑이 증가함에 따라 정방성비 c/a는 감소하였으며, 상대밀도 및 입자의 크기는 증가하였다. 이는 La 첨가량이 증가함에 따라 전하중성을 유지하기 위한 Pb공공의 증가에 기인하는 것으로 판단된다. 소결시 분위기분말의 증가는 La 첨가에 따른 효과에 비해 미미하지만 정방성비를 미세하게나마 증가시켜 PbO의 휘발을 감소시키는 것으로 나타났다. La 첨가량에 따른 정방성비의 감소로 상온에서의 유전상수는 증가하였으며 큐리온도는 감소하였다.