• Journal of the Korean Geosynthetics Society
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• v.19 no.2
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• pp.23-33
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• 2020

This study determines the basic properties and acid rock drainage generation capacity of Pohang tertiary mudstone through laboratory experiments. According to X-ray fluorescence (XRF) analysis results, the mudstone of this area mostly comprised of SiO₂ with a proportion of approximately 60%, followed in order by Al₂O₃ and Fe₂O₃. As such, it is clear that there is an abundance of aluminosilicates with a high probability of generating acid rock drainage. The XRD analysis showed that the mudstone contains pyrite (FeS₂), it is highly likely to generate acid rock drainage, and inductively coupled plasma atomic emission spectroscopy (ICP-AES) analysis results showed that the mudstone samples contained a high amount of Fe²⁺ ions. As a result of anion analysis measured by ion chromatography (IC), all mudstone samples were measured to have high SO^2-₄ concentrations. According to elemental analysis, the total sulfur (S) content was high, which in turn indicates a high risk of acid rock drainage generation reflected by a maximum potential acidity (MPA) higher than 1%. All in all, although there were slight deviations between the tertiary mudstone samples, overall, the samples exhibited high acid rock drainage generation capacities.

• Proceedings of the Korean Geotechical Society Conference
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• 2010.03a
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• pp.699-704
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• 2010

Tertiary unconsolidated mudstones spread throughout the eastern coast of Pohang area. Recently, the demand for high quality filling materials is increasing due to harbors and large-scale residential land development. But the features of the reclaimed land using soft mudstones have not been made clear yet. Unconsolidated rocks are diversely considered according to a different method of the applied geotechnical investigation. This study is examined that the applicability of mudstone as a harbor reclamation material through the laboratory test and pilot test. Expecially, it must be considered that the environmental characteristics of mudstone as a reclaimed materials.

• Journal of the Korean Geosynthetics Society
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• v.20 no.3
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• pp.1-10
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• 2021

The purpose of this study is to present the possibility a utilization of the tertiary mudstone in Pohang as road subsoil material through pilot experiments on the road embankment structure. This mudstone is an unconsolidated rock that is distributed in the soft rock sedimentary layer, the tertiary layer of the Cenozoic, and causes physical problems such as slaking, swelling, and reduced shear strength and chemical problem like acid drainage. In order to solve various complex problems, an laboratory mixing test was conducted, and the optimal mixing conditions of the tertiary mudstone (90%), composite slag (steel making 70%, blast furnace 30%), and neutralization and coating agent treatment were derived. In order to prove its utilization, a real-scale road embankment structure was constructed and tests were conducted for each section. The pre-processing section is stable due to the design of optimal mixing conditions, while in post-processing section, natural weathering proceeded rapidly, and structural problems were concerned. Since the effect of neutralizing and coating agents was confirmed in temporary-staking section, the neutralizing and coating agents can be applied during the temporary storage period.

• The Journal of Engineering Geology
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• v.13 no.2
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• pp.227-238
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• 2003

Understanding of a creep behavior in rocks under a constant load, due to visco-elastic properties of rock, is an essential element to predict a long term ground deformation. In order to clarify the creep characteristics of the mudstone in Duho formation at Pohang basin, deposited during Tertiary, a series of laboratory tests including physical properties, unconfined compressive strength and uniaxial creep tests, was performed. The mudstone showed a higher creep potential due to 26% of clay minerals such as illite and chlorite. The unconfined compressive strength of the rock was $462{\;}kg/\textrm{cm}^2$ in average, and four creep tests were performed under constant stress of 40 to 70 % of the strength. The creep constants in the empirical and theoretical equations were deduced from the time-strain curves obtained from the tests. Among the several equations, the empirical equation proposed by Griggs and theoretical equation of Burger’s model are appreciated as the best one to express the creep behavior of the mudstone. Instantaneous elastic strain was linearly increased with stress level but strain velocity during the first creep is decreased with a similar pattern by time lapse regardless the stress level.

• Proceedings of the Korean Geotechical Society Conference
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• 2002.11b
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• pp.3-17
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• 2002

Tertiary Pohang basin distributed in south weatern part of the korean peninsula, is composed of Chunbuk formation as the basal conglomerate, Hakjon formation, Duho formation and intrusive basalt which is 15 Ma by absolute age data. The basement of the basin is represented by Cretaceous sedimentary rocks, Hakjon welded tuff and Chilpo welded tuff and rhyolite. The fault systems at the basement of the Pohang basin are consist of NNE direction fault, WNW to EW trend fault. NNE fault is not only strike-slip fault but also normal fault. n fault has sinistral strike-slip sene and the EW fault is strike-slip and normal fault. In the Tertiary basin, the fault system is represented by nm strike-slip fault, EW normal fault and NNE thrust fault. By these fault relationships and geometries, it is interpreted that NNE sinistral strike-slip fault and nomal fault have acted at Creceous times. At Tertiary tines, NNE dextralstrike-slip fault and EW normal fault has created. Progressively Tertiary Pohang basin was influenced by the trenspression to make thrust fault and fold, namely as inversion tectonics.

• Journal of the Mineralogical Society of Korea
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• v.20 no.3
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• pp.223-229
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• 2007

The mechanism of hydrothermally synthesizing Na-A zeolite from siliceous mudstone at a $Na_2O/SiO_2$ ratio of 0.6, a $SiO_2/Al_2O_3$ 2.0 and a $H_2O/Na_2O$ 119 has been observed by IR, DTA, XRD and SEM. This mudstone is a tertiary periodic sedimentary rock and widely spreads around the Pohang area. In the early hydrothermal synthesis at $80^{\circ}C$ in an autoclave, sodium silicate and sodium aluminate were found to be preferentially reacted to generate Na-A type zeolite. Gibbsite and bayerite were also formed due to the presence of extra aluminum oxide in the feedstock. As reaction time in-creased up to 50 h, residual sodium aluminatewas reacted with siliceous mudstone, causing the Na-A zeolite crystal to grow and the hydroxylsodalite to generate. Therefore, in the $14{\sim}50\;h$ synthetic time, Na-A zeolite and hydroxylsodalite were formed. Also, if reaction time passed over 50 h, a part of the Na-A zeolite was finally redissolved and reacted with hydroxylsodalite to synthesize Na-P zeolite, generating porous surface of Na-A zeolite and disappearing hydroxylsodalite.

• Journal of the Korean Geotechnical Society
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• v.26 no.7
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• pp.25-36
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• 2010

Tertiary unconsolidated mudstones spread throughout the eastern coast area. The demand for high quality filling materials in these areas is increasing due to harbors and large-scale residential land development. Rock produced in-situ or near site has been used as road subbase construction or reclamation materials for economical reason, but it is hard to decide appropriateness of quality specification because of its characteristics. The test results showed that unconsolidated rocks are diversely considered according to a different method of the applied geotechnical investigation. Therefore, the site of tertiary unconsolidated mudstones, the classification of rock and evaluation of rock properties that must be evaluated by objective criteria and apply a different set of criteria are needed. In addition, the environmental impact must be considered due to acid mine drainage.

• Proceedings of the Korean Geotechical Society Conference
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• 2005.10a
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• pp.285-289
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• 2005

The Cenozoic Era consists of two period , the Tertiary and the Quaternary Period. Weak rock types may include areas containing: 1) poorly cemented or uncemented sediments, 2) highly weathered rock, or 3) fault lines. Especially this paper deal with poorly cemented or uncemented sedimentary rocks in slope. Mechanical weathering is caused by physical processes such as absorption and release of water, and changes in temperature and stress at or near the exposed rock surface. It results in the opening of discontinuities, the formation of new discontinuities by rock fracture, the opening of grain boundaries, and the fracture or cleavage of individual mineral grains. Decomposition causes some silicate minerals such as feldspars to change to clay minerals. There was a strong negative correlation between water absorption and important engineering properties such as strength and durability.

• Journal of the Mineralogical Society of Korea
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• v.13 no.4
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• pp.171-185
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• 2000

Siliceous mudstones are embedded on a large scale in the Tertiary formations of Pohang area. Some useful zeolites such as NsP, (Na, TMA)P, analcime and hydroxysodalite were synthesized from the siliceous mudstones by treating with the variety of solution, i.e ., NaOH, NaOH+NaCl, NaOH, NaOH+$NaAlO_2$and NaOH+TMAOH at the low-temperature hydrothermal system ranging 60~12$0^{\circ}C$. Major precursor of zeolites is found as opal-CT in the zeolite-forming reaction. Smectite, which is included in considerable amounts in the mudstone, appears to play a major role of Al-source in the zeolite synthesis. In comparison, chalcedonic quartz and mica are rather insoluble in alkaline solution, and thus, these are observed as major impurities in the reaction products. An addition of $NaAlO_2$to NaOH solution is effective for eliminating these impurities in the reaction procedure, through these are partly dissolved when elevating the reaction temperature, concentration, and time. Phase change from NaP to hydroxysodalite takes place at the NaOH concentrations of 3.0~4.0 M, and the reaction is not sensitive to the temperature shift. NaP is more stable at lower NaOH concentration and higher activity of $Na_{+}$ whereas analcime is sensitive to the temperature change and stable at higher than $100^{\circ}C$ and 2.0~4.0 M in NaOH concentration. For the pure NaP synthesis without any other products, the treatment of mudstones with 1:1 solution of NaOH and $NaAlO _2$ turns out to be quite effective. NaP was successfully synthesized together with analcime at $100^{\circ}C$ as well as lower concentrations of NaOH+NaCl solution. In addition, the organic type, (Na, TMA)P was formed together with smectite in the 1:1 solution of NaOH and TMAOH.

• Journal of the Korean Geotechnical Society
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• v.26 no.1
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• pp.63-73
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• 2010

The supply of high quality filling materials for pavement base course or reclamation is getting harder. So, there is an attempt to use soft mudstones as an earth filling material in Pohang area. But the engineering properties of the soil deposit placed with soft mudstones have not been clearly evaluated yet. We investigated the water absorption and softening, the slaking behavior and the geological mechanism in order to obtain an effective way of estimating the magnitude of land subsidence and the reduction of soil strength. The applicability of soft mudstones is examined by a variety of laboratory tests and pilot-scale field tests. In addition, it is necessary to consider the environmental characteristics of soft mudstones as a reclaiming material, Consequently, the results from the current study can be used to prevent any construction defects due to the careless use of soft mudstones for the pavement base course or reclamation.