• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.58-58
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• 2003

최근 전자재료분야 중 고집적 소자를 다루는 분야에서는 산화규소 유전박막의 두께가 얇아짐에 따라 상부전극과 하부기판 사이에서 발생하는 누설전류가 큰 문제가 되었다. 따라서 이를 극복하기 위해 고유전상수를 가진 두꺼운 유전박막을 사용하기 시작하였는데, 그 중 대표적 인 것이 하프늄옥사이드(HfO2)와 알루미나(A12O3)이다. HfO2의 장점은 큰 유전상수를 갖는다는 것이고, A1203의 장점은 열적 안정성 이 뛰어나며, 높은 bandgap에너지를 갖는 것인데, 이 둘의 장점을 살려서 보다 편리한 방법으로 박막을 증착한 것이 바로 HfAlO이다.

• Progress in Superconductivity and Cryogenics
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• v.8 no.2
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• pp.37-42
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• 2006

A research on several characteristics such as volume breakdown and surface discharge of insulators for a termination of power transmission class HTS cable was performed. We investigated the surface discharge of glass fiber reinforced plastic (GFRP) under air, cryogenic nitrogen gas and nitrogen gas media. The breakdown characteristics of these media were studied. Experimental results revealed that flashover voltage greatly depends on pressure, temperature, the kinds of insulating media and voltages, but it is slightly affected by shape and material of electrode. The breakdown voltage of liquid nitrogen, cryogenic nitrogen gas and nitrogen gas deeply depends on the shape and dimension of electrode, kinds of voltages and pressure. Moreover, the breakdown voltage of cryogenic nitrogen gas and flashover voltage of GFRP in the cryogenic nitrogen gas is also influenced by temperature and vapour-mist density of the gas.

• Journal of the Korean Ceramic Society
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• v.46 no.2
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• pp.175-180
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• 2009

Multilayer ceramic capacitors (MLCCs) have continually been made smaller in size and larger in capacity in resent years. However, the end termination electrode is still thick in many MLCCs. In this study, we used small grain glass frit to embody thin film and highly densification in the end termination by improve sintering driving force with well-dispersion and rising surface energy. Pastes were fabricated using size changed glass frit, such as 0.1 ${\mu}m$, 0.5 ${\mu}m$, 1.0 ${\mu}m$, 4.0 ${\mu}m$. Fabricated pastes were applied 05A475KQ5 chip and fired various sintering temperatures to analyze sintering behavior of pastes. Consequently, small glass frit used pastes have many merits than larger, such as well-dispersion, improve cornercoverage and surface roughness, possibility of low temperature sintering. However, we confirmed that small glass frit used pastes have narrow sintering window by rapid completion of sintering densification.

• Journal of Environmental Science International
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• v.17 no.1
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• pp.37-44
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• 2008

The electro-chemical decolorization of Rhodamine B (RhB) in water has been carried out by electro Fenton-like process. The effect of distance, material and shape of electrode, NaCl concentration, current, electric power, $H_2O_2$ and pH have been studied. The results obtained that decrease of RhB concentration of Fe(+)-Fe(-) electrode system was higher than that of other electrode system. The decrease of RhB concentration was not affected electrode distance and shape. Decolorization of electro Fenton-like reaction, which was added $H_2O_2$ onto the electrolysis using electrode was higher than electrolysis. Addition of NaCl decreased the electric consumption. The lower pH is, the faster initial reaction rate and reaction termination time observed.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2006.05a
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• pp.54-58
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• 2006

This paper deals with primary consideration in down-conductor system and earth-termination system design of apartments. For down-conductor system, steelworks within reinforced concrete apartment structures have the electrical continuity, however, lashing is not suitable for lightning-current-carrying connections. So this paper suggest that the additional dedicated conductors should be installed and they are should be lashed to the reinforcement steel. Also this paper suggested the foundation earth electrode and global earth system as the earth-termination system of the apartments. But perfect bonding system is essential in lightning protection system to avoid life hazard and to protect electronic equipments.

• Journal of the Korean Society of Safety
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• v.11 no.3
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• pp.126-136
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• 1996

Synthesis of perfluoromethanesulfonyl fluoride(PFMSF) which is a valuable precursor of perfluoro-chemicals such as surface modifier and fine chemicals was studied by electrochemical fluorination (ECF). In order to determine the termination of preelectrolysis, it was carried to monitor the variation of current during preelectrolysis by means of constant cell voltage operation. In a batch cell, chronopotentiometric electrolysis and various chemical analysis such as GC, GC/MS and If were used to understand the potential change of electrode and synthesis and control of hazardous gases products. Termination of preelectrolysis was determinated by measurement the current and/or detection of $F_2$ gas generation. And during the preelectrolysis, an amount of generated $OF_2$ was shown that a lot of moisture was absorbed from air when a cell was filled with anhydrous hydrogen fluoride( AHF ). Above 4V cell voltage, $F_2$ gas was generated and acted on any form of fluorinating agents. In the ECF of MSC (methane sulfonyl chloride) by constant current operation, the potential of anode was intimately relation with generation of $SO_2F_2$. Exchange of Cl to F was dominatly occured in a initial stage. There were various gaseous products including PFMSF as main product and $C_4$ compounds.

• Advances in nano research
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• v.15 no.1
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• pp.1-13
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• 2023

Ti₃C₂T_x MXene, a 2D material, is known to exhibit unique characteristics that are strongly dependent on surface termination groups. Here, we developed a novel annealing approach with Ca as a reducing agent to simultaneously remove F and O groups from the surface of multilayered MXene powder. Unlike H₂ annealing that removes F effectively but has difficulty in removing O, annealing with Ca effectively removed both O and F. X-ray photoelectron spectroscopy (XPS) and energy dispersive X-ray spectroscopy revealed that the proposed approach effectively removed F and O from the MXene powder. The results of O/N analyses showed that the O concentration decreased by 57.5% (from 2.66 to 1.13 wt%). In addition, XPS fitting showed that the volume fraction of metal oxides (TiO₂ and Al₂O₃) decreased, while surface termination groups (-O and -OH) were enhanced, which could increase the hydrophilic and adsorption properties of the MXene. These findings suggest that when F and O are removed from the MXene powder, the interlayer spacing of its lattice structure increases. The proposed treatment also resulted in an increase in the specific surface area (from 5.17 to 10.98 m²/g), with an increase in oxidation resistance temperature in air from ~436 to ~667 ℃. The benefits of this novel technology were verified by demonstrating the significantly improved cyclic charge-discharge characteristics of a lithium-ion battery with a Ca-treated MXene electrode.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.10a
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• pp.604-607
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• 2005

In the electro-discharge machining the machining performance is closely related to the characteristics of discharge which can be identified from electrical behavior in gap between workpiece and electrode. Therefore, the accurate prediction of electrical behavior in electro-discharge machining (EDM) is useful to process control and optimization. However, any simulation model fur prediction of electrical behavior in EDM process has never been reported until now. In this study, a simulation model is developed to analyze the electrical behavior of electro-discharge plasma which significantly influences electrical behavior in EDM process. For the purpose of this the fundamentals of electro-discharge mechanism such as inception, propagation, formation of plasma channel and termination are investigated to accurately predict the cycle of discharge plasma in EDM. As a result, a mathematical model of electro-discharge plasma is constructed with considering the fundamentals of electro-discharge plasma. Consequently, it is demonstrated that the developed model can predict the electrical behavior of plasma such as electron density in various conditions.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.105-105
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• 2012

We have developed a photoemission-assisted plasma-enhanced chemical vapor deposition (PAPE-CVD) [1,2], in which photoelectrons emitting from the substrate surface irradiated with UV light ($h{\nu}$=7.2 eV) from a Xe excimer lamp are utilized as a trigger for generating DC discharge plasma as depicted in Fig. 1. As a result, photoemission-assisted plasma can appear just above the substrate surface with a limited interval between the substrate and the electrode (~10 mm), enabling us to suppress effectively the unintended deposition of soot on the chamber walls, to increase the deposition rate, and to decrease drastically the electric power consumption. In case of the deposition of DLC gate insulator films for the top-gate graphene channel FET, plasma discharge power is reduced down to as low as 0.01W, giving rise to decrease significantly the plasma-induced damage on the graphene channel [3]. In addition, DLC thickness can be precisely controlled in an atomic scale and dielectric constant is also changed from low ${\kappa}$ for the passivation layer to high ${\kappa}$ for the gate insulator. On the other hand, negative electron affinity (NEA) of a hydrogen-terminated diamond surface is attractive and of practical importance for PAPECVD, because the diamond surface under PAPE-CVD with H2-diluted (about 1%) CH4 gas is exposed to a lot of hydrogen radicals and therefore can perform as a high-efficiency electron emitter due to NEA. In fact, we observed a large change of discharge current between with and without hydrogen termination. It is noted that photoelectrons are emitted from the SiO2 (350 nm)/Si interface with 7.2-eV UV light, making it possible to grow few-layer graphene on the thick SiO2 surface with no transition layer of amorphous carbon by means of PAPE-CVD without any metal catalyst.