• Elastomers and Composites
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• v.47 no.3
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• pp.238-245
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• 2012

Graphene oxide was synthesized from natural graphite, and its surface was modified using diisocyanatodicyclohexylmethane( $H_{12}MDI$). Isocyanate-graphene sheet(i-RGO) was obtained by reduction of surface modified GO. To select nanofiller having good dispersion with polyurethane, GO, i-RGO, natural graphite and thermal reduced graphite were analyzed, and then i-RGO was selected as a suitable nanofiller. PU/i-RGO nanocomposite was synthesized with various i-RGO contents to estimate effect of reinforcement on nanocomposite. Thermal stability, hardness, contact angle were increased with i-RGO contents due to i-RGO characteristic and crosslink bridge effect. But, tensile strength and elongation were decreased at i-RGO contents more than the 4 wt%. This phenomenon was interpreted by the excess formation of crosslink bridge.

• Composites Research
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• v.25 no.3
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• pp.76-81
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• 2012

Atmospheric pressure plasma treatment on carbon nanotube (CNT) surfaces was performed to modify reinforcement effect and interfacial adhesion of carbon fiber reinforced CNT-phenolic composites. The surface changes occurring on CNT treated with plasma were analyzed by using Fourier transform infrared spectroscope (FT-IR). The significant improvement of wettability on CNT was confirmed by static contact angle test after plasma treatment. Such plasma treatment resulted in a decrease in the advancing contact angle from $118^{\circ}$ to $60^{\circ}$. The interfacial adhesion between carbon fiber and CNT-phenolic composites increased by plasma treatment based on apparent modulus test results during quasi-static tensile strength. Furthermore, the proposed database offers valuable knowledge for evaluating interfacial shear strength (IFSS).

• Journal of the Korea Concrete Institute
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• v.14 no.4
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• pp.549-555
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• 2002

Tensile strength of CFRP (Carbon Fiber Reinforced Polymer) is approximately 10 times higher than that of the steel reinforcement, but the design strength of CFRP is normally limited by unpredictable bond failure between RC and CFRP. Many researches concerned with bond behavior between RC and CFRP have been carried out to prevent the bond failure of RC beam strengthened by CFRP, but the national design code for design bond strength of CFRP has not been constructed. In this study, three beam specimens strengthened by CFRP under the parameters of bonded length were tested to derive the design bond strength of CFRP for the RC flexural members. Each bonded length was calculated based on the bond strength of JCI and CFRP manufacturing company. Also, another two beam specimens strengthened by CFRP were tested to inspect the construction environment effects such as mixing error of epoxy resin, and the amount of epoxy primer. From the test results, it is concluded that the maximum design bond strength of CFRP to RC flexural member is considered to be $\tau$a =8 kgf/㎠.

• Journal of the Korea Concrete Institute
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• v.14 no.4
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• pp.467-473
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• 2002

The purpose of this study is to investigate the inelastic behavior and ductility capacity of reinforced concrete frame subjected to cyclic lateral load and to provide result for developing improved seismic design criteria. A computer program named RCAHEST(Reinforced Concrete Analysis in Higher Evaluation System Technology) for the analysis of reinforced concrete structures was used. Material nonlinearity is taken into account by comprising tensile, compressive and shear models of cracked concrete and a model of reinforcing steel. The smeared crack approach is incorporated. The strength increase of concrete due to the lateral confining reinforcement has been taken into account to model the confined concrete. In boundary plane at which each member with different thickness is connected local discontinuous deformation due to the abrupt change in their stiffness can be taken into account by introducing interface element. The effect of number of load reversals with the same displacement amplitude has been also taken into account to model the reinforcing steel. The proposed numerical method for the inelastic behavior and ductility capacity of reinforced concrete frame subjected to cyclic lateral load is verified by comparison with reliable experimental results.

• Journal of the Korea Concrete Institute
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• v.23 no.6
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• pp.731-740
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• 2011

Provisions for the redistribution of negative moments in KCI 2007 and ACI 318-08 use a method for continuous flexural members subjected to uniformly-distributed gravity load. Moment redistributions and plastic rotations in beams of reinforced concrete moment frames subjected to lateral load differ from those in continuous flexural members due to gravity load. In the present study, a quantitative relationship between the moment redistribution and plastic rotation is established for beams subjected to both lateral and gravity loads. Based on the relationship, a design method for the redistribution of negative moments is proposed based on a plastic rotation capacity. The percentage change in negative moments in the beam was defined as a function of the tensile strain of re-bars at the section of maximum negative moment, which is determined by a section analysis at an ultimate state using KCI 2007 and ACI 318-08. Span, reinforcement ratio, cracked section stiffness, and strain-hardening behavior substantially affected the moment redistribution. Design guidelines and examples for the redistribution of the factored negative moments determined by elastic theory for beams under lateral load are presented.

• Elastomers and Composites
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• v.55 no.1
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• pp.26-39
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• 2020

The physical properties of silica-filled SBR compounds (WSBR) prepared using silica-SBR wet masterbatches (WMB) were systematically investigated to understand the effect of the surface treatment of silica on the reinforcement performance of SBR. Treatment of silica with bis(triethoxysilylpropyl)tetrasulfide (TESPT) in the liquid phase, followed by mixing with an SBR solution and recovery by water stripping, easily produced silica-SBR WMB. However, insufficient surface treatment in terms of the amount and stability of the incorporated TESPT led to considerable silica loss and inevitable TESPT elution. Pretreatment of silica in the gas phase with TESPT and another organic material that enabled the formation of organic networks among the silica particles on the surface provided hydrophobated silica, which could be used to produce silica-SBR WMB, in high yields of above 99%. The amount and type of organic material incorporated into silica greatly influenced the cure characteristics, processability, and tensile and dynamic properties of the WSBR compounds. The TESPT and organic material stably incorporated into silica increased their viscosity, while the organic networks dispersed on the silica surface were highly beneficial for reducing their rolling resistance. Excessive dosing of TESTP induced low viscosity and a high modulus. The presence of connection bonds formed by the reaction of glycidyloxy groups with amine groups on the silica surface resulted in physical entanglement of the rubber chains with the bonds in the WSBR compounds, leading to low rolling resistance without sacrificing the mechanical properties. Mixing of the hydrophobated silica with a rubber solution in the liquid phase improved the silica dispersion of WSBR compounds, as confirmed by their low Payne effect, and preservation of the low modulus enhanced the degree of entanglement.

• Journal of the Earthquake Engineering Society of Korea
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• v.10 no.3 s.49
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• pp.113-123
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• 2006

An experimental investigation on the behavior of reinforced concrete coupling beams is presented. The test variables are the span-to-depth ratio, the ratio of flexural reinforcements and the ratio of shear rebars. The distribution of arch action and truss action which compose the mechanism of shear resistance is discussed. The increase of plastic deformation after yielding transforms the shear transfer by arch action into by truss action. This study proposes the deformation model for reinforced concrete coupling beams considering the bond slip of flexural reinforcement. The strain distribution model of shear reinforcements and flexural reinforcements based on test results is presented. The yielding of flexural reinforcements determines yielding states and the ultimate states of reinforced concrete coupling beam are defined as the ultimate compressive strain of struts and the degradation of compressive strength due to principal tensile strain of struts. The flexural-shear failure mechanism determines the ultimate state of RC coupling beams. It is expected that this model can be applied to displacement-based design methods.

• Smart Structures and Systems
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• v.17 no.1
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• pp.91-105
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• 2016

One of the most commonly used techniques to strengthen steel reinforced concrete structures is the application of externally bonded patches in the form of carbon fiber reinforced polymers (CFRP) or recently, textile reinforced cements (TRC). These external patches undertake the tensile stress of bending constraining concrete cracking. Development of full-field inspection methodologies for fracture monitoring are important since the reinforcing layers are not transparent, hindering visual observation of the material condition underneath. In the present study acoustic emission (AE) and digital image correlation (DIC) are applied during four-point bending tests of large beams to follow the damage accumulation. AE helps to determine the onset of fracture as well as the different damage mechanisms through the registered shifts in AE rate, location of active sources and change in waveform parameters. The effect of wave propagation distance, which in large components and in-situ can well mask the original information as emitted by the fracture incidents is also discussed. Simultaneously, crucial information is supplied by DIC concerning the moments of stress release of the patches due to debonding, benchmarking the trends monitored by AE. From the point of view of mechanics, conclusions on the reinforcing contribution of the different repair methodologies are also drawn.

• Nuclear Engineering and Technology
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• v.47 no.6
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• pp.756-765
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• 2015

Background: Fibers have been used in cement mixture to improve its toughness, ductility, and tensile strength, and to enhance the cracking and deformation characteristics of concrete structural members. The addition of fibers into conventional reinforced concrete can enhance the structural and functional performances of safety-related concrete structures in nuclear power plants. Methods: The effects of steel and polyamide fibers on the shear resisting capacity of a prestressed concrete containment vessel (PCCV) were investigated in this study. For a comparative evaluation between the shear performances of structural walls constructed with conventional concrete, steel fiber reinforced concrete, and polyamide fiber reinforced concrete, cyclic tests for wall specimens were conducted and hysteretic models were derived. Results: The shear resisting capacity of a PCCV constructed with fiber reinforced concrete can be improved considerably. When steel fiber reinforced concrete contains hooked steel fibers in a volume fraction of 1.0%, the maximum lateral displacement of a PCCV can be improved by > 50%, in comparison with that of a conventional PCCV. When polyamide fiber reinforced concrete contains polyamide fibers in a volume fraction of 1.5%, the maximum lateral displacement of a PCCV can be enhanced by ~40%. In particular, the energy dissipation capacity in a fiber reinforced PCCV can be enhanced by > 200%. Conclusion: The addition of fibers into conventional concrete increases the ductility and energy dissipation of wall structures significantly. Fibers can be effectively used to improve the structural performance of a PCCV subjected to strong ground motions. Steel fibers are more effective in enhancing the shear performance of a PCCV than polyamide fibers.

• Elastomers and Composites
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• v.45 no.1
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• pp.32-39
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• 2010

The mechanical properties of PTFE 100%, PTFT 90% + carbon black 10%, PTFE 85% + glass fiber 15%, PTFE 80% + glass fiber 15% + molybdenum disulfide ($MoS_2$) 5%, PTFE 75% + glass fiber 25%, and PTFE 75% + carbon black 18% + graphite 7% composites were investigated in this study. The differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were used to examine the heat of fusion(${\Delta}H_f$) and thermal stability of the composites. Also, the wear surface and wear volume of PTFE lip seal were examined using the durability test. Wear surface was observed using scanning electron microscope (SEM). It was found that the hardness, wear resistance and durability were enhanced by adding glass fiber and molybdenum disulfide into pure PTFE, but tensile strength and elongation were decreased. According to the experimental results, the composite (PTFE + 15% glass fiber + 5% molybdenum disulfide) showed the best properties for applying to oil-seal among six types of PTFE composites.