• 제목/요약/키워드: Temperature transition

검색결과 2,880건 처리시간 0.027초

Investigation of Spin Reorientation in Ga Substituted Y-type Hexaferrite based on Mössbauer Spectroscopy

  • Lim, Jung Tae;Kim, Jeonghun;Kim, Chul Sung
    • Journal of the Korean Physical Society
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    • 제73권11호
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    • pp.1708-1711
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    • 2018
  • The polycrystalline sample of $Ba_2Co_{1.5}Mg_{0.5}Fe_{11.88}Ga_{0.12}O_{22}$ Y-type hexaferrite, doped with Ga-cation, was prepared by using the solid-state reaction method. The crystalline structure of sample was investigated by x-ray diffractometer (XRD), and the magnetic properties of sample were measured by vibrating sample magnetometer (VSM), and $M{\ddot{o}}ssbauer$ spectrometer. The crystal structure of prepared sample was determined to be rhombohedral with space group R-3m. From the temperature dependence of the magnetization curves under 100 Oe between 4.2 and 740 K, two temperature-dependent magnetic transitions occurred in the $Ba_2Co_{1.5}Mg_{0.5}Fe_{11.88}Ga_{0.12}O_{22}$ sample. $M{\ddot{o}}ssbauer$ spectra of the sample were analyzed at various temperatures ranging from 4.2 to 620 K, and the $Ba_2Co_{1.5}Mg_{0.5}Fe_{11.88}Ga_{0.12}O_{22}$ sample showed abrupt changes in $H_{hf}$ and $E_Q$ at 200 K, indicating the spin transition effect. We have also determined the magnetic transition temperature $T_C$, in addition to the temperature dependent magnetization and ZVC measurements.

Phase Transition of Confined Gold Nanoparticles: Replica Exchange Molecular Dynamics Study

  • Kim, Hyun-Sik;Li, Feng-Yin;Jang, Soon-Min
    • Bulletin of the Korean Chemical Society
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    • 제33권3호
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    • pp.929-932
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    • 2012
  • The classical molecular dynamics simulation was used to study the phase transition of gold nanoparticles under confinement using Sutton-Chen (SC) potential. Metal gold nanoparticles with different number of atoms are subject to replica exchange molecular dynamics simulation for this purpose. The simulation showing the solidto-liquid melting temperature largely remains unaffected by confinement, while the confinement induces characteristic pre-melting at very low temperature depending on atom number in nanoparticles.

GAS PERMEATION THROUGH GLASSY POLYMER MEMBRANES WITH HIGH GLASS-TRANSITION TEMPERATURE

  • Kumazawa, Hidehiro
    • 한국막학회:학술대회논문집
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    • 한국막학회 1993년도 추계 총회 및 학술발표회
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    • pp.13-20
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    • 1993
  • The sorption equilibria and permeation rates for carbon dioxide in such glassy polymer membranes with high glass-transition temperature as polyimide, polyetherimide, polysulfone and polyethersulfone membranes, were measured. The sorption isotherms for these systems can be described well by the dual-mode sorption model, whereas the pressure dependences of the mean permeability coefficients are simulated better by a modified dual-mode mobility model than the conventional dual-mode mobility model in which the Henry's law and Langmuir populations execute four kinds of diffusive movement.

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Cell thickness dependence of liquid crystal parameters

  • Sood, Nitin;Khosla, Samriti;Singh, Darshan;Bawa, S.S.
    • Journal of Information Display
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    • 제13권1호
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    • pp.31-36
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    • 2012
  • Ferroelectric liquid crystal parameters, spontaneous polarization, and transition temperature were studied as a function of cell thickness. These parameters were found to increase with increasing cell thickness, but an exception was observed for the transition temperature in the case of a thin cell. A simple Landau model is presented to interpret the theoretical and experimental observations. The anomalous behavior is attributed to the electroclinic effect and is explained using the Landau model.

비스페놀-A를 기반으로 제작한 에폭시 복합체의 온도 변화에 따른 유전특성 (Dielectric Properties of Bisphenol-A Based Epoxy Resin Composite with Varying Temperature)

  • 이호식
    • 한국응용과학기술학회지
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    • 제34권1호
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    • pp.25-32
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    • 2017
  • 주파수 (30 ~ 300k Hz)와 온도 범위 ($20{\sim}160^{\circ}C$)가 경화 조건에 따른 에폭시 수지의 전기적 특성 (유전율 및 유전손실)에 미치는 영향을 조사하였다. 유리전이온도(Tg) 이하에서는 주파수와 상관없이 각각 3가지의 시편에서 유전분산 현상이 나타나지 않으며, 유리전이온도(Tg) 이상에서 유전분산 현상이 나타났다.

$(Pb, La)TiO_3$ 세라믹스의 소결 거동 및 유전.초전 특성 (Sintering Behavior, Dielectric and Pyroelectric Properties of $(Pb, La)TiO_3$ Ceramics)

  • 최동구;최시경
    • 한국세라믹학회지
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    • 제31권8호
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    • pp.841-848
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    • 1994
  • The sintering behavior of La-modified PbTiO3 ceramics was investigated in order to improve the poor sinterability of PbTiO3. Addition of La improved the sinterability. It was confirmed that this improvement was due to the decrease in tetragonality ratio c/a of crystal lattice. The variations of dielectric constant and pyroelectric coefficient were measured with temperature. It was observed that with the increase of La content, Curie temperature decreased and dielectric constant at room temperature increased. La-modified PbTiO3 ceramics had smaller pyroelectric figure of merits than those of pyroelectric materials in use. The effects of grain size on dielectric and pyroelectric properties were also investigated. The change of grain size had effect on maximum dielectric constant and pyroelectric coefficient, but is had little effect on pyroelectric figure of merit at room temperature. The closer examination near ferro-paraelectric phase transition temperature revealed that the behavior of phase transition approached a more relaxor character with the increase of La content and the decrease of grain size.

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편광 현미경을 이용한 Sodium Niobate 단결정의 분역 구조 관찰 (In Situ Observation of Domain Structure of $NaNbO_3$ Using Polarizing Microscope)

  • 정선태
    • 한국세라믹학회지
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    • 제34권12호
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    • pp.1235-1239
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    • 1997
  • Sodium niobate single crystals were grown by high temperature solution growth with Na2O/B2O3 flux. The phase transitions and domain structures of sodium niobate were observed using transmission polarizing microscope from room temperature to $650^{\circ}C$. There was imperfect extinction region within as-grown crystals and this area could be removed by heat treatment. The area existed within crystal till 3$65^{\circ}C$, in which temperature the space group of sodium niobate is changed from Pbma to Pmnm. The phase transition from Pbma to Pmnm happened abruptly with changing domain structure. At 48$0^{\circ}C$, 52$0^{\circ}C$ and 572$^{\circ}C$, the colors and walls of domains were changed. All domains disappeared and the space group of sodium niobate was changed from P4/mbm to Pm3m at 64$0^{\circ}C$. When sodium niobate changed from high temperature phase to low temperature phase, the memory effect of domain structure was not observed.

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Standardization of Critical Temperature Measurement based on IEC International Standard

  • Lee, Kyu-Won;Kim, Kyu-Tae
    • 한국초전도ㆍ저온공학회논문지
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    • 제5권1호
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    • pp.123-127
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    • 2003
  • For disseminating a ney IEC international standard of critical trmperature of NbTi,Nb$_3$Sn and Bi-2223 Composite Suterconductors, we develpted a measuring system and studied standardization of test method. The measuring system consisted of cryogenic reservoir, base plate, thermometer, voltmeter and current source. Various specimens of the Nbti, Nb$_3$Sn and Bi-2223 composite superconductors were tested using this system for measuring their critical temperatures. After measuring the resistance-temperature relation, the data were compensated with thermoelectric voltages for NbTi Nb$_3$Sn specimens. NbTi specimens showed 9.2 K ~ 9.5 K of transition temperature and Nb$_3$Sn specimen showed about 18 K. Bi-2223 specimens showed 104 K ~ 107 K of transition temperature.