• Title/Summary/Keyword: Temperature of aggregate

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Characterization of a Cell Aggregation Factor from Aspergillus sp.LAM 94-142 (Aspergillus sp. LAM 94-142가 생산하는 세포응집물질의 특성)

  • 이동희;함동수
    • Microbiology and Biotechnology Letters
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    • v.23 no.5
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    • pp.506-512
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    • 1995
  • A cell aggregation factor produced by Aspergillus sp. LAM 94-142 was purified and partially characterized. The factor was purified about 15 folds from culture broth by IRA 420 and IRC 120 treatment, 1% NaCl added acetone precipitation, and Sepharose 4B column chromatography with overall yield of 48%. It was heteropolysaccharide consisted of mannose, arabinose, and glucose with a molar ratio, 31:17:2, and its molecular weight was estimated to be about 900,000 daltons by Sepharodse 4B gel filtration method. The optimum pH and temperature was 8 and 40$\circ$C, respectively. The factor was stable in pH range of 3-9 and at 100$\circ$C for 90 min. The cell aggregation activity of the factor was inhibited by the addition of Hg$^{2+}$, Fe$^{2+}$, Cu$^{2+}$, and some polypeptides such as milk casein or hemoglobin. The factor aggregated Bacillus subtilis, B. macerans, B. turingiensis, E. coli, Peudomonas aeruginosa, P. fluorescens, P. malophilia, and weakly aggregated Staphylococcus sp., Sarcina lutea, P. putida and Cryptococcus neoformnans, but it didn't aggregate various strains of Candida sp. and Saccharomyces sp.

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Analysis of Influential Factors on Compressive Strength of Concrete Specimens Obtained from a Drilled Shaft Construction Site (현장타설말뚝 콘크리트 공시체 압축강도 데이터 분석을 통한 강도 영향인자 분석)

  • Lee, Kicheol;Chung, Moonkyung;Kim, So Yeun;Kim, Dongwook
    • Journal of the Korean Geotechnical Society
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    • v.31 no.10
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    • pp.37-47
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    • 2015
  • Recently, the quality of drilled shafts concrete has been improved significantly due to the improved concrete performance, upgraded concrete materials, and better management of on-site constructions. Despite the development, current conventional quality management on concrete constructions is still used without any criticism. In this study, compressive strength test results of more than 200 concrete specimens after 7 and 28 days of curing were collected from one site at Songdo area of Incheon. The concrete specimens were prepared from the concrete with aggregate maximum dimensions of 25 mm, target compressive strength of 40 MPa, and slump of 180 mm. Influential factors including concrete temperature, air temperature, amount of slump, amount of air, amount of salinity on concrete specimen were also examined. The database was established from collected information and statistical analyses were performed. Analyzed results confirm that "the difference between concrete temperature and air temperature" has the largest impact on the compressive strengths of specimens at the durations of 7 and 28 days.

Characterization of artificial aggregates fabricated with direct sintering method (직화소성법으로 제조된 인공골재의 특성 분석)

  • Kim, Kang-Duk;Kang, Seun-Ggu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.1
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    • pp.34-40
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    • 2011
  • The bulk density, water absorption and microstructure of the artificial aggregates were controlled as a function of sintering temperature (1100 and $1200^{\circ}C$) and time (10~60 min) in the fabrication process of the artificial aggregates by the direct sintering process using dredged soil, the inorganic wastes. Also, the physical properties of the artificial aggregates fabricated according to the different sintering methods such as the direct sintering method used in this study and the increasing temperature sintering method used in the previous report, were compared and analysed. The bulk density of aggregates sintered at $1200^{\circ}C$ by the direct sintering method showed below 1.0, and the thickness of a shell and the pore size of the black core were increased with sintering temperature. Also, in the same sintering temperature, the area of black core was decreased, the thickness of shell was increased and the water absorption was decreased with sintering time. The black core of artificial aggregates of bulk density below 1.0 had the similar microstructure, regardless of sintering methods. In contrast, the shell of aggregates fabricated by the increasing temperature sintering method showed more dense microstructure than that by direct sintering method, hence the water absorption of aggregate sintered using direct sintering was relatively high. Thus, the direct sintering method is suitable for fabrication of artificial aggregates in ceramic carriers or absorbents applications.

A Study of Heat Storage System with Phase Change Material - Inward Melting and Solidification in a Horizontal Cylinder - (상변화물질을 이용한 잠열축열조에 관한 기초 연구 - 수평원관내에서의 내향용융 및 응고열전달 실험 -)

  • Kim, I.G.;Cho, N.C.;Kim, J.G.;Lee, C.M.;Yim, C.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.1 no.4
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    • pp.319-329
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    • 1989
  • Heat transfer phenomena during inward melting and solidification process of the phase change material were studied expertimentally. The phase change medium was 99% pure n-docosane paraffin ($C_{22}H_{46}$). The solid-liquid interface motion during phase change was recorded photographically. Measurements were made on the temperature, the solid-liquid interface, the melted or frozen mass and the various energy components stored or extracted from the cylinder wall. For melting, the experimental results reaffirmed the dominant role played by the conduction at an early stage, by the natural convection at longer time. For solidification, natural convection effects in the superheated liquid were modest and were confined to short freezing time. Although the latent energy is the largest contributor to the total stored or extracted energy, the aggregate sensible energies can make a significant contribution, especially at large cylinder wall superheating or subcooling, large initial phase change material subcooling or superheating.

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Synthesis and Characterization of Di and Triblock Copolymers Containing a Naphthalene Unit for Polymer Electrolyte Membranes (고분자전해질 막을 위한 나프탈렌 단위를 포함하는 디 및 트리 블록공중합체의 합성 및 특성분석)

  • KIM, AERHAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.6
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    • pp.660-669
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    • 2016
  • A fluorinated-sulfonated, hydrophobic-hydrophilic copolymer was planed subsequently synthesized using typical nucleophilic substitution polycondensation reaction. A novel AB and ABA (or BAB) block copolymers were synthesized using sBCPSBP (sulfonated 4,4'-bis[4-chlorophenyl)sulfonyl]-1,1'-biphenyl), DHN (1,5-dihydroxynaphthalene), DFBP (decafluorobiphenyl) and HFIP (4,4'-hexafluoroisopropylidenediphenol). All block copolymers were easily cast and made into clear films. The structure and synthesized copolymers and corresponding membranes were analyzed using GPC (gel permeation chromatography), $^1H$-NMR ($^1H$ nuclear magnetic resonance) and FT-IR (Fourier transform infrared). TGA (Thermogravimetric analysis) and DSC (differential scanning calorimetry) analysis showed that the prepared membranes were thermally stable, so that elevated temperature fuel cell operation would be possible. Hydrophobic/hydrophilic phase separation and clear ionic aggregate block morpology was confirmed in both triblock and diblock copolymer in AFM (atomic force microscopy), which may be highly related to their proton transport ability. A sulfonated BAB triblock copolymer membrane with an ion-exchange capacity (IEC) of 0.6 meq/g has a maximum ion conductivity of 40.3 mS/cm at $90^{\circ}C$ and 100% relative humidity.

Temperature Sensitivity Analysis of TDR Moisture Content Sensor for Road Pavement (도로하부 함수비 계측을 위한 TDR 방식 함수비 센서 온도 민감도 분석)

  • Cho, Myunghwan;Lee, Yoonhan;Kim, Nakseok;Jee, Keehwan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.1
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    • pp.329-336
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    • 2013
  • The infrastructure of flexible pavement is composed of aggregate subbase, anti-frost layer, and subgrade. In particular, the subgrade performance is affected by climates such as frost action and precipitation. The method of TDR(Time Domain Reflectometry) sensors to measure moisture contents in subgrade layer has been used in the research. Due to the TDR method using dielectric permitivity of soil and water, the sensors can be affected by the low subgrade temperatures. The air temperatures frequently drops below $-20^{\circ}C$ in the winter in Korea. As a result, it is necessary to estimate the accuracy of the TDR moisture sensors in the range of below zero temperatures. In this study, the subgrade temperatures of lower than $-2^{\circ}C$ were extended to evaluate temperature sensitivity of the TDR moisture sensors. The test results revealed that the moisture contents around the sensors were reduced while those of the upper part of specimen showed a tendency to increase as the specimen surface temperature drops below zero under the volumetric moisture contents(VMC) of 20% and 30%. However, the impact of temperature on the function of the sensor at lower water contents was found to be negligible if any.

A Study for Controlling Early-age Temperature Rise of the Concrete Pavement by Shadow Tent in Hot Weather Construction (차광막를 이용한 하절기 콘크리트포장의 초기온도 관리 방안연구)

  • Joh, Young-Oh;Kim, Hyung-Bae;Suh, Young-Chan;Ann, Sung-Soon
    • International Journal of Highway Engineering
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    • v.6 no.4 s.22
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    • pp.75-89
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    • 2004
  • Long term performance of concrete pavement significantly depends on the given construction and environmental condition. It means that random cracks and extreme crack width due to inappropriate quality control at the early age might lead to decreasing the pavement service life. The temperature and moisture during the construction, cement and aggregate types, curing condition are major components to affect the quality of the concrete pavement at the early age. First of all, the high temperature differential, that is made by increasing air temperature and the heat of cement hydration, is known as the major contributor to severe cracks. In this study, tent covering was used for controlling temperature of the concrete slab. The field measurement data indicates that the effect of the tent covering is very significant to decrease possibilities of random crack occurrence and curling stress and enhance the long-term concrete strength. HIPERPAV(High PERformance PAVing software), a program predicting the strength and stress of an earty-age concrete pavement (72 hour after placement), is used for simulating the effects of tent covering. The HIPERPAVE results showed that the section with the tent covering has higher reliability than the section without the tent covering by 22.5%. In details, reliability is increased 72.5% (without the tent covering) to 95% (with the tent covering).

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Facile Low-temperature Chemical Synthesis and Characterization of a Manganese Oxide/multi-walled Carbon Nanotube Composite for Supercapacitor Applications

  • Jang, Kihun;Lee, Sung-Won;Yu, Seongil;Salunkhe, Rahul R.;Chung, Ildoo;Choi, Sungmin;Ahn, Heejoon
    • Bulletin of the Korean Chemical Society
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    • v.35 no.10
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    • pp.2974-2978
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    • 2014
  • $Mn_3O_4$/multi-walled carbon nanotube (MWCNT) composites are prepared by chemically synthesizing $Mn_3O_4$ nanoparticles on a MWCNT film at room temperature. Structural and morphological characterization has been carried out using X-ray diffraction (XRD) and scanning and transmission electron microscopies (SEM and TEM). These reveal that polycrystalline $Mn_3O_4$ nanoparticles, with sizes of about 10-20 nm, aggregate to form larger nanoparticles (50-200 nm), and the $Mn_3O_4$ nanoparticles are attached inhomogeneously on MWCNTs. The electrochemical behavior of the composites is analyzed by cyclic voltammetry experiment. The $Mn_3O_4$/MWCNT composite exhibits a specific capacitance of $257Fg^{-1}$ at a scan rate of $5mVs^{-1}$, which is about 3.5 times higher than that of the pure $Mn_3O_4$. Cycle-life tests show that the specific capacitance of the $Mn_3O_4$/MWCNT composite is stable up to 1000 cycles with about 85% capacitance retention, which is better than the pure $Mn_3O_4$ electrode. The improved supercapacitive performance of the $Mn_3O_4$/MWCNT composite electrode can be attributed to the synergistic effects of the $Mn_3O_4$ nanoparticles and the MWCNTs, which arises not only from the combination of pseudocapacitance from $Mn_3O_4$ nanoparticles and electric double layer capacitance from the MWCNTs but also from the increased surface area, pore volume and conducting property of the MWCNT network.

Freezing and Bearing Capacity Characteristics of Road Foundations under Temperature Condition (온도조건에 의한 도로하부 지반의 동결 및 지지력 특성)

  • Shin, Eun-Chul;Kim, Sung-Hwan;Park, Jeong-Jun
    • Journal of the Korean Geotechnical Society
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    • v.28 no.3
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    • pp.5-14
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    • 2012
  • In the current design codes for anti-freezing layer, the thickness of anti-freezing layer is calculated by freezing depth against the temperature condition. Therefore, they have a tendency of over-design and uniform thickness without the considerations of thermal stability, bearing capacity and frost susceptibility of materials. So, it is essential for studying the appropriateness and bearing capacity of road foundation materials as well as their seasonal and mechanical properties to take an appropriate and reasonable design of the road structure system. In this paper, the freezing and bearing capacity characteristics of typical road foundation materials were evaluated in the large scale laboratory test. LFWD (light falling weight deflectometer) was used to determine the change of elastic modulus ($E_{LFWD}$) caused by to the frost heave and thaw. Furthermore, the influence of crushed natural aggregate on the freezing of the subgrade soil was studied to verify the function and effectiveness of the anti-freezing layer.

Freezing and Deflection Characteristics of Flexible Pavement Structure Using Frost Model Test (동상모형실험을 통한 아스팔트 포장체의 동결 및 처짐 특성)

  • Shin, Eun-Chul;Hwang, Soon-Gab;Park, Jeong-Jun
    • Journal of the Korean Geosynthetics Society
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    • v.11 no.3
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    • pp.27-35
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    • 2012
  • In this paper, the frost heaving and thawing characteristics of flexible pavement structure were evaluated in the large scale freezer which have a specification of temperature range $-20^{\circ}C{\sim}10^{\circ}C$ and $3.2m(L){\times}3.2m(B){\times}2.4m(H)$ in size. The insulated steel box with the size of $0.9m(L){\times}0.9m(B){\times}0.9m(H)$ was used to simulate actual pavement road structure. The variation of temperature, frost heave amount and frost heave pressure were measured through the instrument of TDS-602 data logger. LFWD (light falling weight deflectometer) was used to determine the change of deflection due to the frost heaving and thawing. Furthermore, the influence of aggregate layer to the freezing of the subgrade soil was studied to verify the function and effectiveness of the anti-freezing layer.