• Journal of the Korean Applied Science and Technology
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• v.31 no.3
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• pp.408-415
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• 2014

In order to prepare high-quality activated carbons (ACs), coal tar pitch (CTP), and mixtures of CTP and petroleum pitch (PP) were activated with KOH. The ACs prepared by activation of CTP in the range of $700{\sim}1000^{\circ}C$ for 1~5 h had very porous textures with large specific surface areas of $2470{\sim}3081m^2/g$. The optimal activation conditions of CTP were determined as CTP/KOH ratio of 1:4, activation temperature of $900^{\circ}C$, and activation time of 3 h. The obtained AC showed the highest micro-pore volume, and pretty high specific surface area and meso-pore volume. The micro-pore volumes and specific areas of activated mixtures of CTP and PP were similar to each other but the meso-pore volume could be increased. In order to change the degree of crystallinity of precursors before KOH activation process, the CTPs were carbonized in the range of $500{\sim}900^{\circ}C$. As the carbonization temperature increased, the specific surface area and pore volume of the activated ACs with the same activation conditions for CTP decreased dramatically. It was demonstrated that the increased pore size distribution of AC electrodes in the range of 1 to 2 nm plays an important role in the performance of electric double-layer capacitor.

• Journal of Ginseng Research
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• v.19 no.3
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• pp.249-253
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• 1995

In the browning reaction of Korean ginseng, it appears that enzymatic and non-enzymatic browning reaction occurred in the initial stage of heating fresh ginseng at low temperature, and then non-enzymatic browning reaction followed in the drying period after heating. Activation energy of the browning reaction for red ginseng was about 9.0 kcal/mol. Browning reaction of red ginseng was accede- rated with an increase in steaming time, and a great extent of browning reaction occurred between 60-90 min of steaming at 10$0^{\circ}C$. Browning pigments of red ginseng were mostly water soluble subset.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.7
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• pp.1205-1212
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• 2000

The effect of temperature on the sources of organic acids and sludge when phosphorus was biologically released was evaluated in this study. The sludge used in this study was obtained from sequencing batch reactor processing the swine wastewater. Temperature is one of the most important parameters influencing the phosphorus release. As a result, the rate of phosphorus released was increased as the temperatures were increased from 5 to $30^{\circ}C$ regardless of the sources of organic acids used. Under anaerobic conditions, as acetate, propionate, glucose, and domestic wastewater were used as the sources of organic acids, the corresponding activation energy($E_a$) values were 49.83, 55.82, 54.61, and 45.44 KJ/mol, respectively. Temperature coefficient($\theta$) values were 1.0676, 1.0826, 1.0748, and 1.0698, respectively. Therefore, the rate of phosphorus released was increased as temperature was increased, whereas, the effect, of the sources of organic acids and temperature on the activation energy and temperature coefficient values were minimal. When the sludge previously adapted to acetate as external organic source was used, the activation energy and temperature coefficient values were 44.94 KJ/mol and 1.0570 respectively. The effect of temperature was minimal. These values obtained from the sludge previously adapted to acetate were smaller than those from the sludge not previously adapted to the same organic acid. This suggest that the sludge previously adapted to acetate was less dependent on temperature than that not adapted to the acetate.

• Applied Chemistry for Engineering
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• v.31 no.6
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• pp.639-645
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• 2020

Among the components of redox flow battery (RFB), the electrode serves as a diffusion layer of an electrolyte and a path for electrons and also is a major component that directly affects the RFB performance. In this paper, chloric/sulfuric mixed acidwas used as a supporting electrolyte in RFB system with Fe2+/Fe3+ and V2+/V3+ as redox couple. The optimum electrode and activation temperature were suggested by comparing the capacity, coulombic efficiency and energy efficiency according to the electrode type and activation temperature. In the RFB single cell evaluation using 5 types of carbon electrodes used in the experiments, all of them showed close to the theoretical capacity to retain the reliability of the evaluation results. GFD4EA showed relatively excellent energy efficiency and charge/discharge capacity. In order to investigate the electrochemical performance according to the activation temperature, GFD4EA electrode was activated by heat treatment at different temperatures of 400, 450, 500, 600 and 700 ℃ under an air atmosphere. Changes in physical properties before and after the activation were observed using electrode mass retention, scanning electron microscope (SEM), XPS analysis, and electrochemical performance was compared by conducting RFB single evaluation using electrodes activated at each temperature given above.

• Journal of the Semiconductor & Display Technology
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• v.3 no.1
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• pp.35-39
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• 2004

Statistical design of experiments was successfully employed to investigate the effect of alternating magnetic field on activation of polycrystalline Si (p-Si) doped as n-type using $\textrm{PH}_3$, by full factorial design of three factors with two levels. In this design, the input variables are graphite size, alternating current, and activation time. The output parameter, sheet resistance, is analyzed in terms of the primary effects and multi-factor interactions. Notably, the three-factor interaction is calculated to be a dominant interaction. The interaction between graphite size and activation time and the main effect of current are important effects compared to the other variables and relevant interactions. Alternating magnetic flux activation is proved a significantly beneficial processing technique.

• Polymer(Korea)
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• v.27 no.3
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• pp.176-182
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• 2003

The fluorine-containing epoxy resin, 2-trifluorotoluene diglycidylether (FER) was prepared by reaction of 2-chloro-${\alpha}$,${\alpha}$,${\alpha}$-trifluorotoluene with glycerol diglycidylether in the presence of pyridine catalyst. Curing behavior of FER/DDM system was investigated using dynamic and isothermal DSC. Cure activation energy (Ea) was determined by Flynn-Wall-Ozawa's equation. The rheological properties of FER/DDM system were studied under isothermal condition using a rheometer. Cross-linking activation energy (Ec) was determined from the Arrhenius equation based on gel time and curing temperature. As a result, the chemical structure of FER was confirmed by FT-IR, $\^$13/C NMR, and $\^$19/F NMR spectroscopy. The cure activation energy of FER/DDM system was 55.4 kJ/mol and conversion and conversion rate were increased with the curing temperature. The cross-linking activation energy of FER/DDM system was 41.6 kJ/mol and gel time was decreased with the curing temperature.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.3 no.2
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• pp.67-72
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• 2004

Electro-Rheological(ER) fluids consist of suspensions of fine polarizable particles In a dielectric oil, which upon application of an external electric field control take on the characteristics of the Bingham solid. In this study, the temperature dependence of the viscosity was Investigated for an ER fluid consisting of 35 weight % of zeolite particles in hydraulic oil 46cSt. Thermal activation analysis was performed by changing the ER fluid's temperature from $-10^{\circ}C$ to $50^{\circ}C$. According to the analysis, the activation energy for flow of the ER fluid was 79.6 kJ/mole without applying electric field. On the other hand, with the electric field of 2kV/mm, the linearity between viscosity and temperature was not existed By changing the temperatures the viscosity (or shear stress) versus shear rates were measured. In this experiment shear rates were increased from 0 to $200s^{-1}$ in 2 minutes. Generally, the hydraulic oil 46cSt will be operated at the temperature of about $40^{\circ}C$, thus, the ER fluid's electric field dependence of viscosity was examined at this temperature. Also, an influence of adding the dispersant(Carbopl 940) on ER effect was discussed.

• KCI Concrete Journal
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• v.13 no.1
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• pp.3-9
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• 2001

This research concerns the effect of kaolin as material of cement admixture. which has the advantage of low price and high adaptability. Kaolin, a kind of soil, is well known as a raw material of pottery. which is widely scat-tered on the earth (especially in Korea). This research shows the method and process for activating kaolin to have the properties of a cement admixture through experiment. In the experiments, kaolin is baked in high temperature and then cooled suddenly to be activated. The temperature zone and time span, on which kaolin is activated are examined. The research looks over the effect of the activated kaolin based on several criteria regarding to chemical and physical characteristic of general admixtures. The results of this research are as follows; kaolin start activation at the temperature above 50$0^{\circ}C$ and make ends of activation at the temperature below 95$0^{\circ}C$ and there was little effect by the change of duration. It is concluded that compressive strength can be increased by putting activated kaolin in the concrete and the activated kaolin is good for water resistance and anti-chemical , and that it is effective for protecting the leakage of hazardous article like Cl- and for protecting damage by an organic salt like acid. The activated kaolin of proper temperature and time is effective in compressive strength, salt resistance and acid resistance. The adaptability of activated kaolin as a cement admixture was shown through this research.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2003.05a
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• pp.300-305
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• 2003

Reduced activation ferritic (JLF-1) steel is leading candidates for blanket/first-wall structures of the D-T fusion reactor. In fusion application, structural materials will suffer effects of repeated changes of temperature. Therefore, the data base of tensile strength and fracture toughness at operated temperature $400^{\circ}C$ are very important. Fracture toughness ($J_{IC}$) and tensile tests were carried out at room temperature and elevated temperature ($400^{\circ}C$). Fracture toughness tests were performed with two type size to investigate the relationship between the constraint effect of a size and the fracture toughness resistance curve. As the results, the tensile strength and the fracture toughness values of the JLF-1 steel are slightly decreased with increasing temperature. The fracture resistance curve increased with increasing plane size and decreased with increasing thickness. The fracture toughness values of JLF-1 steel at room temperature and at $400^{\circ}C$ shows an excellent fracture toughness ($J_{IC}$) of about $530kJ/m^2\;and\;340kJ/m^2$, respectively.

• Fire Science and Engineering
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• v.33 no.1
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• pp.7-14
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• 2019

While wood pellets are often used as a fuel in thermoelectric power plants and firewood boilers, there is a risk of ignition temperature when strong wood pellets, which have a high calorific value, for prolonged periods of time. In this research study, the minimum auto ignition temperature and the ignition limitation temperature according to the change in flow rate depending on the size of the test vessel were calculated, and based on these temperatures, the apparent activation energy was calculated to predict the combustive properties of the material. The apparent activation energy was calculated to be 190.224 kJ/mol. The thicker the sample is storage in the vessel, the longer the ignition induction time was due to the increased difficulty in heat being transferred from the surface of the vessel to the middle section area of the vessel. For vessel of the same size, the higher the flow rate, the lower the auto ignition temperature was. It was also confirmed that increases in the size of the test vessel lowered the auto ignition temperature and increased the ignition induction time.