• 대한기계학회논문집A
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• 제31권11호
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• pp.1069-1076
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• 2007

This paper presents the road simulator control technology for reproducing the road input signal to implement the real road data. The simulator consists of the hydraulic pump, servo valve, hydraulic actuator and its control equipment. The QFT(Quantitative Feedback Theory) is utilized to control the simulator effectively. The control system illustrates a tracking performance of the closed-loop controller with low order transfer function G(s) and pre-filter F(s) for a parametric uncertain model. A force controller is designed to communicate the control signal between simulator and digital controller. Tracking specification is satisfied with upper and lower bound tolerances on the steep response of the system to the reference signal. The efficacy of the QFT force controller is verified through the numerical simulation, in which combined dynamics and actuation of the hydraulic servo system are tested. The simulation results show that the proposed control technique works well under uncertain hydraulic plant system. The conventional software (Labview) is used to make up for the real controller in the real-time basis, and the experimental works show that the proposed algorithm works well for a single road simulator.

• Bulletin of the Korean Chemical Society
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• 제34권11호
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• pp.3211-3217
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• 2013

Density functional theory (DFT) and time-dependent DFT (TD-DFT) calculations have been employed to investigate the molecular structures and absorption spectra of three D-${\pi}$-A-type organic dyes (C1-1, D5 and TH208) containing identical ${\pi}$-spacers and electron acceptors, but different aromatic amine electron-donating groups (tetrahydroquinoline, triphenylamine and phenothiazine). The coplanar geometries indicate that the strong conjugation is formed in the dyes. The electronic structures suggest that the intramolecular charge transfer from the donor to the acceptor occurs, and the electron-donating ability of tetrahydroquinoline is stronger than those of triphenylamine and phenothiazine. The computed orbital energy levels of these dyes confirm that the electrons could be injected from the excited dyes to the semiconductor conduction band and the oxidized dyes could be reduced effectively by electrolyte. The TD-DFT results show that the CAM-B3LYP/6-31+G(d, p) is suitable for calculating the absorption spectra. The first absorption band for these dyes is assigned to the HOMO${\rightarrow}$LUMO and HOMO-1${\rightarrow}$LUMO transitions.

• Bulletin of the Korean Chemical Society
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• 제32권7호
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• pp.2358-2368
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• 2011

Density functional theory (DFT) and time-dependent density functional theory (TDDFT) calculations, employing the B3LYP method and the LANL2DZ, 6-31G$^*$(LANL2DZ for Tc), 6-31G$^*$(cc-pVDZ-pp for Tc) and DGDZVP basis sets, have been performed to investigate the electronic structures and absorption spectra of the technetium-99m-labeled methylenediphosphonate ($^{99m}Tc$-MDP) complex of the simplest diphosphonate ligand. The bonding situations and natural bond orbital compositions were studied by the Mulliken population analysis (MPA) and natural bond orbital (NBO) analysis. The results indicate that the ${\sigma}$ and ${\pi}$ contributions to the Tc-O bonds are strongly polarized towards the oxygen atoms and the ionic contribution to the Tc-O bonding is larger than the covalent contribution. The electronic transitions investigated by TDDFT calculations and molecular orbital analyses show that the origin of all absorption bands is ascribed to the ligand-to-metal charge transfer (LMCT) character. The solvent effect on the electronic structures and absorption spectra has also been studied by performing DFT and TDDFT calculations at the B3LYP/6-31G$^*$(cc-pVDZ-pp for Tc) level with the integral equation formalism polarized continuum model (IEFPCM) in different media. It is found that the absorption spectra display blue shift in different extents with the increase of solvent polarity.

• 청정기술
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• 제14권4호
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• pp.281-286
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• 2008

Polyacrylamide (PAA) 수용액의 유변학적 특성이 $CO_2$의 흡수속도에 미치는 영향을 고찰하기 위해 $25^{\circ}C$, 1기압에서 평판조의 흡수기(교반조의 임펠러 크기 0.05 m, 교반속도 50 rpm)를 사용하여 PAA 수용액에 $CO_2$의 흡수실험을 행하였다. 제시한 Deborah수와 $CO_2$의 물질전달계수와의 상관관계식으로부터 물질전달계수를 구하여 triethanolamine을 첨가한 PAA수용액에서 $CO_2$의 화학흡수속도의 산출에 사용하였다. PAA수용액에서 $CO_2$의 흡수속도는 동일점도의 기준에서 뉴튼액체에서의 값보다 감소하였다.

• 한국군사과학기술학회지
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• 제13권5호
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• pp.725-733
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• 2010

A simulator is proposed in this paper for predicting the RF signal level after propagating over sea and land surfaces. Various sea and land types and transmit/receive antenna patterns, as well as the locus of the transmit antenna, are considered for this simulator. At first, microwave reflection characteristics of various sea surfaces have been computed, based on an empirical formula which is developed in this study for the relation between the sea surface roughness and wind speed. Then, microwave reflections from land surfaces such as forests, agricultural areas, and bare surfaces, are computed using the first-order vector radiative transfer theory. Finally, the signal paths over sea and land surfaces are found using the ray tracing technique and the digital elevation model, and the signal level received by a receiving antenna is computed by the using the reflection coefficients of sea and land surfaces and the signal paths.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.933-940
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• 2012

Recently, it has been shown that quantum coherence appears in energy transfers of various photosynthetic lightharvesting complexes at from cryogenic to even room temperatures. Because the photosynthetic systems are inherently complex, these findings have subsequently interested many researchers in the field of both experiment and theory. From the theoretical part, simplified dynamics or semiclassical approaches have been widely used. In these approaches, the quantum-classical Liouville equation (QCLE) is the fundamental starting point. Toward the semiclassical scheme, approximations are needed to simplify the equations of motion of various degrees of freedom. Here, we have adopted the Poisson bracket mapping equation (PBME) as an approximate form of QCLE and applied it to find the time evolution of the excitation in a photosynthetic complex from marine algae. The benefit of using PBME is its similarity to conventional Hamiltonian dynamics. Through this, we confirmed the coherent population transfer behaviors in short time domain as previously reported with a more accurate but more time-consuming iterative linearized density matrix approach. However, we find that the site populations do not behave according to the Boltzmann law in the long time limit. We also test the effect of adding spurious high frequency vibrations to the spectral density of the bath, and find that their existence does not alter the dynamics to any significant extent as long as the associated reorganization energy is changed not too drastically. This suggests that adopting classical trajectory based ensembles in semiclassical simulations should not influence the coherence dynamics in any practical manner, even though the classical trajectories often yield spurious high frequency vibrational features in the spectral density.

• 기술혁신학회지
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• 제10권2호
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• pp.284-309
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• 2007

본 연구는 2002년부터 5년간 운영된 권역별 공공기술이전컨소시엄의 실증분석을 통하여 기술이전컨소시엄의 유효성과 주요 특성요인을 살펴보고자 한다. 유효성 검정은 기술이전프로세스를 토대로 하여 개발된 기술이전효율성지수가 컨소시엄의 운영기간 동안 변화한 정도로 판단하였고, 특성요인의 탐색은 기술이전 메커니즘 연구의 핵심변수인 가입동기, 촉진요인, 장애요인 및 극복과제를 사용하여 이루어졌다. 그 결과, 기술이전컨소시엄에 참여한 대학 또는 정부연구기관의 기술 이전효율성지수가 참여하지 않은 기관에 비하여 더욱 큰 증가를 보였으며, 조사된 특성요인들도 컨소시엄의 직접참여자 그룹과 간접참여자 그룹간에 인식 차가 거의 없는 것으로 판명되었다. 본 연구는 기술이전컨소시엄이 새로운 기술이전 메커니즘으로서의 유의미성과 공통적 특성을 갖는지를 탐색해 보았다는 것에 그 의의가 있다.

• Journal of Electrochemical Science and Technology
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• 제6권4호
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• pp.121-130
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• 2015

The micro emulsion method has been successfully used for preparing perovskite LaCoO₃ with uniform, fine-shaped nanoparticles showing high activity as electro catalysts in oxygen reduction reactions (ORRs). They are, therefore, promising candidates for the air-cathode in metal-air rechargeable batteries. Since the activity of a catalyst is highly dependent on its specific surface area, nanoparticles of the perovskite catalyst are desirable for catalyzing both oxygen reduction and evolution reactions. Herein, LaCoO₃ powder was also prepared by sol-gel method for comparison, with a broad particle distribution and high agglomeration. The electro catalytic properties of LaCoO₃ and LaCoO₃-carbon Super P mixture layers toward the ORR were studied comparatively using the rotating disk electrode technique in 0.1 M KOH electrolyte to elucidate the effect of carbon Super P. Koutecky-Levich theory was applied to acquire the overall electron transfer number (n) during the ORR, calculated to be ~3.74 for the LaCoO₃-Super P mixture, quite close to the theoretical value (4.0), and ~2.7 for carbon-free LaCoO₃. A synergistic effect toward the ORR is observed when carbon is present in the LaCoO₃ layer. Carbon is assumed to be more than an additive, enhancing the electronic conductivity of the oxide catalyst. It is suggested that ORRs, catalyzed by the LaCoO₃-Super P mixture, are dominated by a 2+2-electron transfer pathway to form the final, hydroxyl ion product.

• 기술혁신학회지
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• 제11권4호
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• pp.532-562
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• 2008

최근 국가연구개발사업의 성과관리 측면에서 논의되고 있는 이슈 가운데 하나가 공동연구개발을 통해 발생된 지적재산권의 관리에 관한 것으로, 현행 법제에 따르면 국가공동연구개발 특허는 주관연구기관과 참여기업이 투자지분에 따라 공동으로 소유하도록 하고 있는 바, 과연 이것이 법리상으로나 실제상 바람직한가에 대하여 많은 논의들이 일어나고 있다. 국가공동연구개발 특허는 공공자산 및 공유특허로서의 속성상 여러 관련법령에 의하여 복합적으로 규율되는 구조를 띠고 있으며, 그 권리의 행사에 있어서도 일정한 제약이 따르는 등 일반특허와는 다른 특성을 갖는다. 이 글은 국가공동연구개발 과정에서 발생된 특허의 귀속 및 활용에 관한 규율법리를 체계적으로 검토하고, 이를 바탕으로 현행 제도의 발전적 개선방안을 모색함을 목적으로 하고 있다. 이에 따라 본 연구에서는 국가공동연구개발 특허의 의의와 법적 규율체계를 살펴보고, 공동발명 특허권의 귀속 및 활용에 관한 법적 지배원리를 규명한 다음, 현행 제도의 문제점과 개선방안에 대하여 살펴보았다.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1996년도 Proceedings of the Korea Automatic Control Conference, 11th (KACC); Pohang, Korea; 24-26 Oct. 1996
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• pp.56-59
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• 1996

Worst-case state estimation will be proposed in this paper. By using the worst-case disturbance and worst-case state estimation, we can obtain right/left constrained coprime factors. If constrained coprime factors are used in designing a controller, the infinity-norm of closed-loop transfer matrix can be smaller than any constant .gamma.(> .gamma.$_{opt}$) without matrix dilation optimization. The derivation of left/right constrained coprime factors is achieved by doubly coprime factorization for the plant constrained by the infinity norm. And the parameterization of stabilizing controllers gives us easily understanding for H$_{\infty}$ control theory.ry.