• Title/Summary/Keyword: Technical Stability

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Production of Lipase-catalyzed Structured Lipid from Olive Oil with Omega-3 Polyunsaturated Fatty Acids

  • Kahveci, Derya;Can, Ash;Ozcelik, Beraat
    • Food Science and Biotechnology
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    • v.18 no.1
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    • pp.79-83
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    • 2009
  • Acidolysis of olive oil with omega-3 (n-3) polyunsaturated fatty acids (PUFAs) was carried out to produce a structured lipid. Novozym $435^{(R)}$ from Candida antarctica was used as the biocatalyst. Response surface methodology (RSM) was used to determine optimum conditions for lipase-catalyzed enrichment of olive oil. Three factors, 5 levels, central composite design was used. The effects of incubation time, temperature, and substrate mole ratio on incorporation ratio (n-3 fatty acids/total fatty acids, %) were investigated. From the evaluation of response surface graphs, the optimal conditions for incorporation of long chain n-3 PUFAs into olive oil were $40-60^{\circ}C$ for temperature, 30-45 hr for reaction time, and 3:1-5:1 (n-3 fatty acids/olive oil) for substrate mole ratio. Experiments conducted under optimized conditions predicted by the model equation obtained from RSM yielded structured lipids with 50.8% n-3 PUFAs. This value agreed well with that predicted by the model. Oxidative stability tests showed that the product was more susceptible to oxidation than unmodified olive oil. Antioxidant addition improved the oxidative stability of the product.

Determination and Characterization of Thermostable Esterolytic Activity from a Novel Thermophilic Bacterium Anoxybacillus gonensis A4

  • Faiz, Ozlem;Colak, Ahmet;Saglam, Nagihan;Canakci, Sabriye;Belduz, Ali Osman
    • BMB Reports
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    • v.40 no.4
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    • pp.588-594
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    • 2007
  • A novel hot spring thermophile, Anoxybacillus gonensis A4 (A. gonensis A4) was investigated in terms of capability of tributyrin degradation and characterization of its thermostable esterase activity by the hydrolysis of p-nitrophenyl butyrate (PNPB). It was observed that A. gonensis A4 has an esterase with a molecular weight of 62 kDa. The extracellular crude preparation was characterized in terms of substrate specificity, pH and temperature optima and stability, kinetic parameters and inhibition/activation behaviour towards some chemicals and metal ions. Tributyrin agar assay showed that A. gonensis A4 secreted an esterase and $V_{max}$ and $K_m$ values of its activity were found to be 800 U/L and 176.5 ${\mu}M$, respectively in the presence of PNPB substrate. The optimum temperature and pH, for A. gonensis A4 esterase was $60-80^{\circ}C$ and 5.5, respectively. Although the enzyme activity was not significantly changed by incubating crude extract solution at $30-70^{\circ}C$ for 1 h, the enzyme activity was fully lost at $80^{\circ}C$ for same incubation period. The pH-stability profile showed that original crude esterase activity increased nearly 2-fold at pH 6.0. The effect of some chemicals on crude esterase activity indicated that A. gonensis A4 produce an esterase having serine residue in active site and -SH groups were essential for its activity.

Study on the Mechanical Properties of Polyketone Fiber according to Coating Process for Technical Textile (산업용 폴리케톤 섬유의 코팅 가공에 따른 기계적 물성에 관한 연구)

  • Kim, Sang Yong;Jeon, Jae Woo;Kwak, Dong Sub;Lee, Won;Lee, Deuk Jin;Whang, Sun Dong;Do, Sung Jun
    • Textile Coloration and Finishing
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    • v.27 no.4
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    • pp.334-339
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    • 2015
  • Polyketone fiber, a newly developed high strength fiber, has a tenacity and modulus similar to the paramid fiber, and can be used for reinforcing mechanical rubber goods(MRG), such as tires, hoses, and technical textiles. In addition, aliphatic polyketone, which has excellent strength, modulus, chemical stability and reasonable price, is being developed only in South Korea. It will be expected for replacement of super fiber such as aramids and increasing the technical textile market share. This paper surveys the mechanical properties of polyketone fiber yarn for technical textiles. For this purpose, two kinds of yarns are prepared, mechanical properties of coated and uncoated polyketone yarns such as tensile strength, elongation and modulus were examined before and after weather resistance test(temperature $60^{\circ}C$, humidity 60%, amount of power $0.67w/m^2$). The differences of mechanical properties between uncoated and coated yarns for high functional technical textiles and composite materials are estimated through this study.

Peel Stength of the Acrylic Copolymer and Pressure Sensitive Adhesives (아크릴계 점착제의 박리강도와 점착부여제)

  • 김현중
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.79-88
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    • 1999
  • The stability and performance (peel strength) of the acrylic copolymer and various modified rosin systems were investigated. The peel strength was measured over a wide range of scaling rates, and the influence of the viscoelasticity of the PSA(pressure sensitive adhesive) was considered. In the case of miscible systems, the peak of peel strength (PSA performance) over wide peel rates was changed and modified systematically with increasing glass transition temperature of the blends. The peak of the peel strength for blended systems shifts toward the lower rate side as glass transition temperature ($T_g$) of the blend increased. The influence of esterification of the rosin on performance and stability against deterioration was greatly modified by blending with rosin of glycerol ester and rosin pentaerythritol ester. The failure mode of the blend varies with the combination with acrylic copolymer and modified rosin, and cohesive failure was found at a lower peel rate while interfacial failure was found at a high peel rate. A few systems where a single Tg could be measured, despite the fact that two phases were observed microscopically, were detected.

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Modeling of rain-wind induced vibrations

  • Peil, Udo;Nahrath, Niklas
    • Wind and Structures
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    • v.6 no.1
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    • pp.41-52
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    • 2003
  • Rain-wind induced vibrations of cables are a challenging problem in the design of cable-stayed bridges. The precise excitation mechanism of the complex interaction between structure, wind and rain is still unknown. A theoretical model that is able to accurately simulate the observed phenomena is not available. This paper presents a mathematical model describing rain-wind induced vibrations as movement-induced vibrations using the quasi-steady strip theory. Both, the vibrations of the cable and the movement of the water rivulet on the cable surface can be described by the model including all geometrical and physical nonlinearities. The analysis using the stability and bifurcation theory shows that the model is capable of simulating the basic phenomena of the vibrations, such as dependence of wind velocity and cable damping. The results agree well with field data and wind tunnel tests. An extensive experimental study is currently performed to calibrate the parameters of the model.

Numerical investigation on dynamic characteristics of sandwich plates under periodic and thermal loads

  • Mouayed H.Z., Al-Toki;Wael Najm, Abdullah;RidhaA., Ahmed;Nadhim M., Faleh;Raad M., Fenjan
    • Steel and Composite Structures
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    • v.45 no.6
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    • pp.831-837
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    • 2022
  • Numerical investigation on dynamic characteristics of sandwich plates under periodic and thermal loads has been presented by assuming that the plate has three layers which are a foam core and two skins. The foam core made of Aluminum has porosities with uniform and graded dispersions. The sandwich plate has been supposed to be affected by periodical compressive loads. Also, temperature variation causes uniform thermal load. The formulation has been established based upon a higher-order plate theory and Ritz method has been used to solve the equations of motion. The stability boundaries have also been obtained performing Bolotin's method. It will be indicated that stability boundaries of the sandwich plate depend on periodical load parameters, porosities, skin thickness and temperature.

A Case of Design and Field Construction on the Removable Post-tensioned Soil Nailing System (제거식 포스트텐션 쏘일네일의 설계 및 시공사례)

  • Park, Si-Sam;Park, Joo-Suck;Kim, Eung-Soo;Yoon, Myung-June;Park, Ji-Woong;Kim, Hong-Taek
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09a
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    • pp.1081-1086
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    • 2010
  • The general soil nailing support system may result in excessive deformations particularly in an excavation zone of the existing weak subsoils. Pretensioning the soil nails then, could play important roles to reduce deformations mainly in part of the nailed-soil excavation system as well as to improve local stability. Morever, soil nails are installed underneath roads, underground structures, and subway structures, thereby resulting in difficulties in nail remval after completion of temporary soil nailed walls. Hence, to date, in order to solve the technical difficulties and avoid legal issues related to the construction of soil nails underneath the surrounding areas and structures, the removable soil nailing system has been developed and used. But, Therefore, a new soil nailing technique called Removable Post-tensioned Soil Nailing(RPTN) system has been developed in the current study. In this study, an investigation of the RPTN system has been conducted by carrying out field measurement. Hence, the RPTN system can reduce ground displacement and enhance stability of the soil nailed walls.

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Camber calculation of prestressed concrete I-Girder considering geometric nonlinearity

  • Atmaca, Barbaros;Ates, Sevket
    • Computers and Concrete
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    • v.19 no.1
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    • pp.1-6
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    • 2017
  • Prestressed concrete I-girders are subject to different load types at their construction stages. At the time of strand release, i.e., detensioning, prestressed concrete girders are under the effect of dead and prestressing loads. At this stage, the camber, total net upward deflection, of prestressed girder is summation of the upward deflection due to the prestressing force and the downward deflection due to dead loads. For the calculation of the upward deflection, it is generally considered that prestressed concrete I-girder behaves linear-elastic. However, the field measurements on total net upward deflection of prestressed I-girder after detensioning show contradictory results. In this paper, camber calculations with the linear-elastic beam and elastic-stability theories are presented. One of a typical precast I-girder with 120 cm height and 31.5 m effective span length is selected as a case study. 3D finite element model (FEM) of the girder is developed by SAP2000 software, and the deflections of girder are obtained from linear and nonlinear-static analyses. Only geometric nonlinearity is taken into account. The material test and field measurement of this study are performed at prestressing girder plant. The results of the linear-elastic beam and elastic-stability theories are compared with FEM results and field measurements. It is seen that the camber predicted by elastic-stability theory gives acceptable results than the linear-elastic beam theory while strand releasing.

Fuzzy Applications in a Multi-Machine Power System Stabilizer

  • Sambariya, D.K.;Gupta, Rajeev
    • Journal of Electrical Engineering and Technology
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    • v.5 no.3
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    • pp.503-510
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    • 2010
  • This paper proposes the use of fuzzy applications to a 4-machine and 10-bus system to check stability in open conditions. Fuzzy controllers and the excitation of a synchronous generator are added. Power system stabilizers (PSSs) are added to the excitation system to enhance damping during low frequency oscillations. A fuzzy logic power system stabilizer (PSS) for stability enhancement of a multi-machine power system is also presented. To attain stability enhancement, speed deviation ($\Delta\omega$) and acceleration ($\Delta\varpi$) of the Kota Thermal synchronous generator rotor are taken as inputs to the fuzzy logic controller. These variables have significant effects on the damping of generator shaft mechanical oscillations. The stabilizing signals are computed using fuzzy membership functions that are dependent on these variables. The performance of the fuzzy logic PSS is compared with the open power system, after which the simulations are tested under different operating conditions and changes in reference voltage. The simulation results are quite encouraging and satisfactory. Similarly, the system is tested for the different defuzzification methods, and based on the results, the centroid method elicits the best possible system response.

Study on the Thermal Fastness of Fluorescent Whitening Agents (제지용 형광증백제의 열 견뢰도에 대한 연구)

  • Kim, Chul-Hwan;Lee, Ji-Young;Kim, Beong-Ho;Choi, Jae-Sung;Lim, Gi-Baek;Kim, Da-Mi
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.1
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    • pp.10-15
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    • 2012
  • Fluorescent whitening agents (FWAs) are used extensively in the paper industry to improve the optical properties. FWAs are neither photochemically nor thermally stable, and thereby the papers containing FWAs can be damaged by external heat. We observed that the CIE whiteness, ISO brightness and fluorescence index of the commercial papers decreased with the thermal treatment and thought that the thermal fastness of FWAs was the main factor affecting the thermal stability of the papers. Thus, the model papers treated with three types of FWAs were manufactured respectively and the thermal stability of FWAs was identified by determining ${\Delta}$ CIE whiteness and ${\Delta}$ fluorescence index.