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Comparison of Fuel-NOx Formation Characteristics in Conventional Air and Oxyfuel Combustion Conditions (일반 공기 및 순산소 연소 조건에서 Fuel-NOx 생성 특성의 비교)

  • Woo, Mino;Park, Kweon Ha;Choi, Byung Chul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.5
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    • pp.481-488
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    • 2013
  • Nitric oxide ($NO_x$) formation characteristics in non-premixed diffusion flames of methane fuels have been investigated experimentally and numerically by adding 10% ammonia to the fuel stream, according to the variation of the oxygen ratio in the oxidizer with oxygen/carbon dioxide and oxygen/nitrogen mixtures. In an experiment of coflow jet flames, in the case of an oxidizer with oxygen/carbon dioxide, the $NO_x$ emission increased slightly as the oxygen ratio increased. On the other hand, in case of an oxygen/nitrogen oxidizer, the $NO_x$ emission was the maximum at an oxygen ratio of 0.7, and it exhibited non-monotonic behavior according to the oxygen ratio. Consequently, the $NO_x$ emission in the condition of oxyfuel combustion was overestimated as compared to that in the condition of conventional air combustion. To elucidate the characteristics of $NO_x$ formation for various oxidizer compositions, 1D and 2D numerical simulations have been conducted by adopting one kinetic mechanism. The result of 2D simulation for an oxidizer with oxygen/nitrogen well predicted the trend of experimentally measured $NO_x$ emissions.

Morphological Correlation and Chronology of Lower Terrace Formations of Southeastern Coast of Korea (한국 남동해안 저위단구 퇴적층의 지형대비 및 형성시기 고찰)

  • Choi, Weon-Hack;Kim, Ju-Yong
    • Proceedings of the Korean Quaternary Association Conference
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    • 2005.10a
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    • pp.48-54
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    • 2005
  • Terrace morphology is so conspicuous in the south eastern coastal areas. Coastal terraces can be divided into 5 main surfaces, including beach and coastal alluvial plain(AP, $4{\sim}5m$), Low Terrace(LT, 8 $^{\sim}$ 25m), Middle Terrace(MT, 36 $^{\sim}$ 55m), High Terrace(HT, 63 $^{\sim}$ 86m) and upper High Terrace(uHT, above 90m). Among them Lower Terrace Formation is distributed between 8m and 20m in altitude. Both Tephra deposited of LT2 formation and OSL datings of sand layers in LT 2 and LT 3 Formations support the age of the LT 2 formation is MIS 5d or 5e, most probably 5e. The age of LT 3 is interpreted MIS 5a, based on tephra production in organic mud layers and OSL dating of sand deposits just above the beach pebbles of the LT 3. Particularly the transgression, possibly equivalent to the well-known Monastirrian episode in the Mediterranean Sea.

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Security and Safety Assessment of the Small-scale Offshore CO2 Storage Demonstration Project in the Pohang Basin (포항분지 해상 중소규모 CO2 지중저장 실증연구 안전성 평가)

  • Kwon, Yi Kyun;Chang, Chandong;Shinn, Youngjae
    • The Journal of Engineering Geology
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    • v.28 no.2
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    • pp.217-246
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    • 2018
  • During the selection and characterization of target formations in the Small-scale Offshore $CO_2$ Storage Demonstration Project in the Pohang Basin, we have carefully investigated the possibility of induced earthquakes and leakage of $CO_2$ during the injection, and have designed the storage processes to minimize these effects. However, people in Pohang city have a great concern on $CO_2$-injection-intrigued seismicity, since they have greatly suffered from the 5.4 magnitude earthquake on Nov. 15, 2017. The research team of the project performed an extensive self-investigation on the safety issues, especially on the possible $CO_2$ leakage from the target formation and induced earthquakes. The target formation is 10 km apart from the epicenter of the Pohang earthquake and the depth is also quite shallow, only 750 to 800 m from the sea bottom. The project performed a pilot injection in the target formation from Jan. 12 to Mar. 12, 2017, which implies that there are no direct correlation of the Pohang earthquake on Nov. 15, 2017. In addition, the $CO_2$ injection of the storage project does not fracture rock formations, instead, the supercritical $CO_2$ fluid replaces formation water in the pore space gradually. The self-investigation results show that there is almost no chance for the injection to induce significant earthquakes unless injection lasts for a very long time to build a very high pore pressure, which can be easily monitored. The amount of injected $CO_2$ in the project was around 100 metric-tonne that is irrelevant to the Pohang earthquake. The investigation result on long-term safety also shows that the induced earthquakes or the reactivation of existing faults can be prevented successfully when the injection pressure is controlled not to demage cap-rock formation nor exceed Coulomb stresses of existing faults. The project has been performing extensive studies on critical stress for fracturing neighboring formations, reactivation stress of existing faults, well-completion processes to minimize possible leakage, transport/leakage monitoring of injected $CO_2$, and operation procedures for ensuring the storage safety. These extensive studies showed that there will be little chance in $CO_2$ leakage that affects human life. In conclusion, the Small-scale Offshore $CO_2$ Storage Demonstration Project in the Pohang Basin would not cause any induced earthquakes nor signifiant $CO_2$ leakage that people can sense. The research team will give every effort to secure the safety of the storage site.

The Characteristics of NOx Formation in Stainless Mixed Acid Pickling Process and The Effect of Hydrogen Peroxide Addition on NOx Formation (스테인레스 혼산 산세 공정에서 NOx 생성 특성과 과산화수소첨가에 따른 영향)

  • Yoon, Jeyong;Yie, Jaeeui;Lee, Sujin;Lee, Younghwan;Huh, Jin;Park, Sungkook;Chun, Heedong
    • Clean Technology
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    • v.2 no.1
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    • pp.96-108
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    • 1996
  • $NO_x$ is mainly emitted from mixed acid pickling process in the stainless industry and its impact to the environment has been worried over. This study which may be considered as one of the development of clean technologies, differing from the traditional end pipe technology is about how to reduce $NO_x$ emission through the modification of corresponding process. This study consists of two parts. First, the influence of various reaction parameters in a acid pickling process on $NO_x$ emission was investigated. Second, the influence of hydrogen peroxide on $NO_x$ formation, which is known as inhibitor of $NO_x$ emission, was investigated. Major findings in this study are as follows. The important reaction parameters which have a great influence on $NO_x$ emission are the reaction temperature and the concentration of fluoric acid. The concentration of nitric acid, some of which results in $NO_x$ compound is not as important as the concentration of fluoric acid. Synthetic mixed acid of nitric acid and fluoric acid itself in absent of pickling plate contributed the $NO_x$ emission, however, its impact was negligible in terms of quantity. The addition of hydrogen peroxide to the acid pickling process significantly contributed to the reduction of $NO_x$ emission and successfully achieved 80% reduction of $NO_x$ emission at the condition of $9.51{\times}10^{-2}mole\;hydrogen\;peroxide/m^2$ pickling area. This result was compared to literature value from Avesta steel process, indicating a sixth of hydrogen peroxide addition of Avesta's in achieving a same amount of $NO_x$ reduction. The region of the economic hydrogen peroxide addition per unit area of plate to be pickled from the result of this study was established.

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Protective Effect of a Herbal Preparation (HemoHIM) on the Self-Renewal Tissues and Immune System against γ-Irradiation (방사선에 대한 생약복합조성물(HemoHIM)의 재생조직 및 면역계 방호 · 회복촉진 효과)

  • Jo, Sung-Kee;Park, Hae-Ran;Jung, Uhee;Oh, Heon;Kim, Sung-Ho;Yee, Sung-Tae
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.6
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    • pp.805-813
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    • 2005
  • In our previous study, a novel herb mixture (HIM-I) of Angelim gigas radix, Cnidium officinale rhizoma, and Paeonia japonica radix was developed to protect the intestinal and immune systems and promote its recovery against radiation damage. In this study, a new herbal preparation (HemoHIM) with the high immune modulating activity was developed from HIM-I. HIM-I was fractionated into ethanol fraction (HIM-I-E) and polysaccharide fraction (HIM-I-P). And HemoHIM was prepared by adding HIM-I-P to HIM-I. The protective activities against $\gamma$ -irradiation were compared among HemoHIM, HIM-I and the fractions. HemoHIM and HIM-I significantly decreased the radiation-induced DNA damage in vitro, and scavenged hydroxyl radicals in a dose-dependent manner. HemoHIM showed similar activity to HIM-I. In vitro proliferation assay with mouse lymphocytes and bone marrow cells showed that HIM-I-P was remarkably higher than HIM-I and HIM-I-E in cell proliferating activity. HemoHIM showed higher activity than HIM-I and this might be associated with the higher polysaccharide content. The in vivo protective effects of HemoHIM and HIM-I were investigated in $\gamma$-irradiated mice. HemoHIM increased the surviving intestinal crypts to a similar extent compared with HIM-I. In contrast, HemoHIM appeared to be more effective than HIM-I in endogenous spleen colony formation assay. The recovery of white blood cells and lymphocytes in irradiated mice were significantly enhanced by the administration of HemoHIM. Also HemoHIM administration prolonged the survival of irradiated mice. These results showed that the novel herbal preparation, HemoHIM, effectively protected the self-renewal tissues and immune system, and promoted the survival of irradiated mice. Moreover, in comparison with HIM-I, HemoHIM maintained similar activity in the reduction of oxidative damage of self-renewal tissue but exhibited the higher activity in protection and proliferation of immune and hematopoietic cells. These results suggested that HemoHIM might be more effective than HIM-I in immune modulation as well as radioprotection.

Implementation of A Millimeter-Wave Multiflare-Angle Horn Antenna (밀리미터파 다중개구각 혼안테나 구현)

  • Oh, Kyung-Hyun;Kim, Ji-Hyung;Yang, Seung-Sik;Shin, Sang-Jin;Cho, Young-Ho;Lee, Byung-Ryul;Ahn, Bierng-Chearl
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.29 no.1
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    • pp.36-41
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    • 2018
  • This paper presents an implementation of a millimeter-wave(W band) multiflare-angle horn antenna. The proposed antenna is a multimode dual-polarized square horn having equal E- and H-plane beamwidths and consists of a multimode generating section, a four-square-waveguide exciter, orthomode transducers, and power combiners for the sum pattern formation. The antenna structure has been designed to allow for easy fabrication and the designed antenna has been fabricated to a precision of ${\pm}0.02mm$ by layer-by-layer machining and diffusion bonding. The input reflection coefficient and the radiation pattern of the fabricated antenna have been measured using a network analyzer and a far-field test facility. Measurements show that the proposed antenna has 17.7~18.3 dBi gain, $25.2{\sim}28.5^{\circ}$ beamwidth, and an input VSWR between 1.02~1.75, within ${\pm}0.5GHz$ from the center frequency.

Water Quality Characteristics Along Mid-western Coastal Area of Korea (한국 서해 중부 연안역의 수질환경 특성)

  • Lim, Dhong-Il;Kang, Mi-Ran;Jang, Pung-Guk;Kim, So-Young;Jung, Hoi-Soo;Kang, Yang-Soon;Kang, Young-Shil
    • Ocean and Polar Research
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    • v.30 no.4
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    • pp.379-399
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    • 2008
  • Spatial-temporal variations in physiochemical water qualities (temperature, salinity, DO, SPM, POC and nutrients) of surface and bottom waters were investigated along the mid-western coastal area (Taean Peninsula to Gomso Bay) of Korea. Spatial distribution patterns of temperature and salinity were mostly controlled by the physical mixing process of freshwater from Geum River and/or Gyunggi Bay with nearby coastal water. A strong tidal front is formed off Taean Peninsula during spring and summer. Seasonal variations in nutrient concentrations, lower in spring and summer and higher in fall and winter, are primarily regulated by magnitude of phytoplankton occurrence rather than freshwater loadings into the bay. Based on seasonal and spatial variability of physicochemical parameters, water quality of the study area can be divided into four water masses; Gyunggi Bay-influenced Water Mass (GBWM), Geum River-influenced Water Mass (GRWM), Yellow Sea Bottom Cold Water Mass (YSBCWM) and Cheonsu Bay Water Mass (CBWM). Water quality of the GBWM (Taean Peninsula coastal area), which has relatively low salinity and high concentrations of nutrients, is strongly controlled by the Gyunggi Bay coastal water, which is under influence of the Han River freshwater. In this water mass, the mixed layer is always developed by strong tidal mixing. As a result, a tidal front is formed along the offshore boundary of the mixed layer. Such tidal fronts probably play an important role in the distribution of phytoplankton communities, SPM and nutrients. The GRWM, with low salinity and high nutrients, especially during the flood summer season, is closely related to physiochemical properties of the Geum River. During the flood season, nutrient-enriched Geum River water mass extends up to 60 km away from the river mouth, potentially causing serious environmental problems such as eutrophication and unusual and/or noxious algal blooms. Offshore (<$30{\sim}40m$ in water depth) of the study area, YSBCWM coupled with a strong thermocline can be identified in spring-summer periods, exhibiting abundant nutrients in association with low temperature and limited biological activity. During spring and summer, a tidal front is formed in a transition zone between the coastal water mass and bottom cold water mass in the Yellow Sea, resulting in intensified upwelling and thereby supplying abundant nutrients to the GBWM and GRWM. Such cold bottom water mass and tidal front formation seems to play an important role in controlling water quality and further regulating physical ecosystem processes along mid-western Korean coastal area.

MethA Fibrosarcoma Cells Expressing Membrane-Bound Forms of IL-2 Enhance Antitumor Immunity

  • Sonn, Chung-Hee;Yoon, Hee-Ryung;Seong, In-Ock;Chang, Mi-Ra;Kim, Yong-Chan;Kang, Han-Chul;Suh, Seok-Cheol;Kim, Young-Sang
    • Journal of Microbiology and Biotechnology
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    • v.16 no.12
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    • pp.1919-1927
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    • 2006
  • Tumor cells genetically engineered to secrete cytokines are effective in tumor therapy, but various unexpected side effects are observed, which may result from the bulk activation of various bystander cells. In this study, we tested tumor vaccines expressing various membrane-bound forms of IL-2 (mbIL-2) on MethA fibrosarcoma cells to focus antitumor immune responses to CTL. Chimeric forms of IL-2 with whole CD4, deletion forms of CD4, and TNF were expressed on the tumor cell surface, respectively. Tumor clones expressing mbIL-2 or secretory form of IL-2 were able to support the cell growth of CTLL-2, an IL-2-dependent T cell line, and the proliferation of spleen cells from 2C TCR transgenic mice that are responsive to the $p2Ca/L^d$ MHC class I complex. Expression of mbIL-2 on tumor cells reduced the tumorigenicity of tumor cells, and the mice that once rejected the live IL-2/TNF tumor clone acquired systemic immunity against wild-type MethA cells. The IL-2/TNF clone was inferior to other clones in tumor formation, and superior in the stimulation of the CD8+ T cell population in vitro. These results suggest that the IL-2/TNF clone is the best tumor vaccine, and may stimulate CD8+ T cells by direct priming. Expression of IL-2/TNF on tumor cells may serve as an effective gene therapy method to ameliorate the side effects encountered in the recombinant cytokine therapy and the conventional cytokine gene therapy using the secretory form of IL-2.

A Study on Properties of High Blaine Cement for Shotcrete (숏크리트용 고분말도 시멘트의 특성)

  • Kim, Jae-Young;Kim, Teuk-Jun;Lee, Min-Suk;Ryoo, Dong-Woo
    • Journal of the Korea Concrete Institute
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    • v.22 no.5
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    • pp.633-640
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    • 2010
  • This study was performed to get basic information about properties of high blaine cement for shotcrete use. Particle size distribution, setting time and compressive strength test, analysis like as SEM, DSC thermal analysis, XRD was carried out to investigate principle properties of high blaine cement. Setting time of high blaine cement was shorter and compressive strength was higher than those of ordinary portland cement (OPC). Results of analysis showed early hydration products of high blaine cement is smaller and spread widely due to increased specific surface. From the SEM observation and analysis of DSC and XRD results, it was seen that the aluminates accelerators promoted calcium aluminium hydrates while the alkali free accelerators increased ettringite and monosulfates formation. Strength and setting time measurement of cement paste with aluminate accelerator is more effective than the alkali free accelerator in reducing the setting time and increasing early strength while alkali free accelerator is more effective in increasing the strength after 7 days.

A Comparative Analysis of Annual Surface Soil Erosion Before and After the River Improvement Project in the Geumgang Basin Using the RUSLE (RUSLE을 활용한 금강 수변지역의 하천정비사업 전·후의 연간 표토침식량 변화 비교분석)

  • Kim, Jeong-Cheol;Choi, Jong-Yun;Lee, Sunmin;Jung, Hyung-Sup
    • Korean Journal of Remote Sensing
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    • v.35 no.6_4
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    • pp.1351-1361
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    • 2019
  • In this study, the annual surface soil erosion amount of before (2007 year) and after (2015 year) the river improvement projects were calculated using RUSLE (Revised Universal Soil Loss Equation) in the Geumgang basin (Daecheong-Dam to Geumgang Estuary-Bank). After the results were classified into five classes, the results were compared and analyzed with the results of the change in the land cover. In order to generate each factor of RUSLE, various spatial information data, such as land cover maps for 2007 and 2015 years, national basic spatial information, soil map, and average annual precipitation data were utilized. The results of the analysis are as follows: 1) annual surface soil erosion in the study area increased the area of class 1 in 2015 years compared to 2007, 2) the area of class 2, 3 and 5 decreased, 3) the area of class 4 increased. It is believed that the average annual amount of surface soil erosion decreased in most areas due to the reduction of annual average precipitation, the formation of ecological parks, the expansion of artificial facilities, and the reduction of illegal farmland.