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Physical Properties According to the Covering Process and Heat Treatment Condition of the Thermoplastic Polyetherester Elastomeric Fibers (에스터계 열가소성 탄성 섬유의 커버링 공정 및 열처리 조건에 따른 물성 변화)

  • Kim, Jin Oh;Kim, Young Su;Park, Seong Woo
    • Textile Coloration and Finishing
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    • v.33 no.3
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    • pp.120-130
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    • 2021
  • The condition of covering process using thermoplastic polyetherester elastomeric fibers(TPEE) was established. Two types of core yarn(TPEE, Spandex) and one type of effect yarn(PET) were used as materials to confirm the change in physical properties of covering yarn under various covering conditions. In addition, the effects of the treatment temperature on the elongation at break of covering yarn after heat treatment was analyzed. Through this analysis, it was confirmed that the elastic recovery of TPEE which is used as the core yarn was increased with the draw ratio, but decreases when it exceeds 1:2.5. And the elongation at break of the covering yarn could be increased by increasing the twist per meter of it. Additionally, it was confirmed that the elastic recovery of TPEE which is used as a core yarn, could be increased by applying heat treatment.

A Study on the Dyeing and Physical Properties of Napping Knit Fabric using Latent Crimped Yarn (잠재권축사를 적용한 기모편성물의 염색 및 물성변화에 대한 연구)

  • Lee, Bum Hoon
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.182-190
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    • 2021
  • The purpose of this study is to provide the dyeing and physical characteristics of napped knit fabrics composed of latent crimped yarn. The K/S values, dyeing fastness, thickness, bulkiness, and shrinkage characteristics of three knit fabrics were investigated. The original knit fabric (SK) was composed of 1ply latent crimped yarn (75/36) in the ground and PET DTY (70/100) in the pile loop, in order of napped process the napped knit fabric (SN) was napped SK fabric. In order to compare of latent crimped yarn content, the last knit fabric (DN) was napped 2ply latent crimped yarn were included in the same structure of SK. Dyeability of three knit fabrics was similar but the shrinkage properties of DN fabric were significant different. The bulkiness shows a tendency to increase the bulkiness as increasing the dyeing temperature, and the bulkiness of the SN was higher because of the napping process and optimal content of latent crimped yarn.

A Study of Thermal-stability of Blue Dyes Depending on Dye Chromophore and Substituents (Blue dye의 Chromophore와 치환기에 따른 열안정성 특성 연구)

  • Kim, Tae Hyeon;Lee, Ju Hong;Kang, Eun Jin;Choi, Jae Hong
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.169-181
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    • 2021
  • Five dyes based on phthalocyanine, a dye on azo, and a dye on anhraquinone were prepared from corresponding starting material to investigate the effects of substituent on thermal-stability of dyes which is essentially required to apply to the color filters. Synthesized dyes were confirmed their chemical structure using by 1H-NMR, MASS and Elemental analysis. The thermal-stability was evaluated by the weight reductions measured by TGA analysis comparing to that of conventional C.I. Pigment Blue 15:6. The absorption maxima were measured by UV-VIS spectrophotometer then the effects of substituent on absorption maximum was also investigated.

A Study on the Preparation of 5(6)-Carboxyflurescein-supported Phospholipid Liposomes and Evaluation of Bacterial Sensing Ability (5(6)-Carboxyflurescein을 담지한 인지질 리포좀의 제조 및 박테리아 센싱 능력 평가에 대한 연구)

  • Han, Minho;Jeon, Jaewoo;Lee, Junyoung;Shin, Eunsuk;Kim, Woojin;Kim, Samsoo
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.338-347
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    • 2021
  • In the case of occlusive dressings currently used in dressings for burn treatment, it is impossible to confirm the replacement time, so replacement is delayed, resulting in additional infection. To solve this problem, liposomes capable of bacterial sensing were prepared using 5(6)-Carboxyfluorescein, Phosphatidylcholine, 1,2-Dipalmitoyl-sn-glycero-3-phosphocholine, Cholesterol, and 10,12-Tricosadiynoic acid. In this study, evaluation of changes in drug encapsulation rate in liposomes according to changes in three types of phosphatidylcholine phospholipids during liposome production, high-performance phosphatidylcholine phospholipids selected through vesicle size analysis, low and high temperature stability evaluation, bacterial sensitization ability evaluation, animals cell responses were assessed.

Study on the Preparation and Properties of 1-Step Twisted NylonYarns (1-Step 연사공정 적용 나일론 연사물의 제조 및 특성 연구)

  • Lee, Jun Young;Jeon, Jae Woo;Park, Dong Kyu;Seo, Young Ho;Im, Young Min;Oh, Tae Hwan
    • Textile Coloration and Finishing
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    • v.31 no.4
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    • pp.332-340
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    • 2019
  • Due to the change in lifestyle, new sensible materials for sportswear and outdoor are needed. This study is conducted in order to obtain the data for sensible materials through nylon twist process. 1-step nylon twisting machine was used to set the optimum twist process. DSC measurements of twisted nylon yarn showed crystallization temperatures around 170℃ and melting temperatures around 220℃. Nylon 40D/13F DTY and Nylon 50D/48F DTY showed optimal results at 160℃, 1,500 T/M(Turns per meter), and Nylon 70D/68F DTY at 160℃, 1,200 T/M(Turns per meter) after 1-step twist process. Also, Nylon 40D/13F DTY was confirmed to have inter-layer property deviation of ±5 percent.

Electrochemical Study for 1,3-Bisdicyanovinylindane

  • Kim, Hyungjoo;Rao, Boddu Ananda;Son, Young-A
    • Textile Coloration and Finishing
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    • v.25 no.2
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    • pp.89-93
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    • 2013
  • The electrochemical study has been enjoyed in many areas of chemistry. Through this approach using electrochemical measurement, empirical HOMO and LUMO values can be calculated by three methods such as absorption measurement, cyclicvoltammetry and computational calculations. In this study, 1,3-bisdicyanovinylindane was prepared and investigated toward its optical properties. The absorption intensities were changed depending on changes of pH. These absorption changes are induced by resonance form of 1,3-bisdicyanovinylindane. The electron delocalization in ${\pi}$ system is related to the resonance form. In according to this electron density distribution and HOMO/LUMO values of 1,3-bisdicyanovinylindane were simulated and calculated by Material Studio 4.3, absorption measurement and cyclicvoltammograms. The 1,3-bisdicyanovinylindane is one of the most attracted acceptor units in D-${\pi}$-A system. This attempt is useful to determine more detailed characteristics of the energy potentials.

Low Temperature Sintering and Dielectric Properties of $Bi_2(Zn_{1/3}Nb_{2/3})_2O_7$ with (ZBS, BZBS) glasses (붕규산염 유리 첨가에 따른 $Bi_2(Zn_{1/3}Nb_{2/3})_2O_7$의 저온 소결 및 유전 특성)

  • Kim, Kwan-Soo;Park, Jong-Guk;Yoon, Sang-Ok;Kim, Shin;Kim, Yun-Han;Kang, Suk-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.342-342
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    • 2008
  • The low temperature sintering and microwave dielectric properties of ceramic/glass composites which were composed of ceramics in the $Bi_2(Zn_{1/3}Nb_{2/3})_2O_7$ and zinc borosilicate glass/bismuth-zinc borosilicate glass were investigated with a view to applying the microwave dielectrics to low temperature co-fired ceramics. The $Bi_2(Zn_{1/3}Nb_{2/3})_2O_7$ addition of 5 wt% ZBS and BZBS glass ensured a successful sintering below $900^{\circ}C$. In addition, pyrochlore phase was observed in the all composition. $Bi_2(Zn_{1/3}Nb_{2/3})_2O_7$ with 5 wt% BZBS glasss demonstrated 70 as the dielectric constant ($\varepsilon_r$), 2,500 GHz as the Q$\times$f value, and -40 ppm/$^{\circ}C$ as TCF.

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A Study on Microwave Dielectric Properties of Low-temperature Sintered (1-x) $ZnNb_2$$O_6$-$xPb_5$$Nb_4$$O_{15}$ and Microstructure (저온소결형 (1-x)$ZnNb_2$$O_6$-$xPb_5$$Nb_4$$O_{15}$계 세라믹스의 유전특성과 미세구조에 관한 연구)

  • 김현학;김경용;김병호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.11
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    • pp.926-931
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    • 2000
  • The microwave dielectric properties and the microstructures as a mole fraction of (1-x)ZnNb$_2$O$_{6}$-xPb$_{5}$Nb$_4$O$_{15}$ ceramics with CuV$_2$O$_{6}$, Sb$_2$O$_3$ and glass(ZNPN ceramics) was investigated. 0.98ZN-0.02PN ceramics containing 1.5 wt% CuV$_2$O$_{6}$ 1.0 wt% Sb$_2$O$_3$ and 1.0 wt% glass had a dielectric constant($\varepsilon$$_{r}$) of 23, Qxf$_{o}$ value of 15000 and TCF(Temperature Coefficient of resonance Frequency) of -25 ppm/$^{\circ}C$ and it is possible to be co-fired with Ag electrode at 90$0^{\circ}C$. As sintered temperature increases over 90$0^{\circ}C$ the grain size of ZNPN ceramics was increasing for growth and it has poor co-fired properties with Ag electrode.e.ctrode.e.e.

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A Study on the Sulfonation of Persimmon Tannin (감타닌의 술폰화에 관한 연구)

  • Kwon, Seul Gi;Bae, Do Gyu
    • Textile Coloration and Finishing
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    • v.29 no.2
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    • pp.69-76
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    • 2017
  • To get the proper treatment conditions, sulfonation reactions of persimmon tannin with sodium sulfite and sulfuric acid were proceeded in various settings, respectively. Also, the property changes were investigated by carrying out the additional analysis: elementary analysis and instrumental analysis using FT-IR, DSC, and TGA. The degree of $-SO_3Na$ substitutions appeared 0.216 and 0.208 under the treatment time of 3 hours and 6 hours, respectively and the degree of $-SO_3H$ substitutions indicated 0.200 and 0.167 under 9 hours and 18 hours, respectively by elemental analysis. In terms of the FT-IR spectras, there was a peak based on the bonds of pyran ring and ether in relation to non-treated and sulphonated tannin at $1,102cm^{-1}$. No peak was shown in the sulfited tannin. An absorption peak which was due to the $C{\rightarrow}O$ of secondary -OH group became evident in nontreated and sulfited tannin at $1,092cm^{-1}$ and $1,090cm^{-1}$, respectively but the same result was not found in sulphonated tannin. The results of TGA analysis of the sulfonated persimmon tannin showed that the sulfonation of it improved thermal properties.

Nanostructure and Thermal Effects Dependent on the Film Thickness in Poly(3-hexylthiophene):Phenyl-C61-butyric Acid Methyl Ester(P3HT:PCBM) Films Fabricated by 1,2-Dichlorobenzene Solvent for Organic Photovoltaics (1,2-Dichlorobenzene Solvent를 이용한 고분자 유기태양전지에서 박막 두께에 따른 나노 구조와 열처리 효과)

  • Lee, Hyun Hwi;Kim, Hyo Jung
    • Textile Coloration and Finishing
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    • v.26 no.4
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    • pp.347-352
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    • 2014
  • Film thickness dependent nanostructure evolution by a post annealing was investigated in poly (3-hexylthiophene):phenyl-C61-butyric acid methyl ester(P3HT:PCBM) films for organic solar cells which were fabricated by dichlorobenzene(DCB) solvent. In case of a 70nm thin film, the thermal annealing process affected to slight increment of the P3HT crystals in the surface region. On the other hand, large number of small sized P3HT crystals near the surface region was formed in the 200nm thick film. The solar cell devices showed the 3% power conversion efficiency(PCE) in 1:0.65 and 1:1 ratio(by weight) of P3HT and PCBM in 70nm and 200nm thickness conditions, respectively. Despite to the similar PCE, the short circuit current Jsc was different in 70nm and 200nm devices, which was related to the different nanostructure of P3HT:PCBM after thermal annealing.