[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.5764/TCF.2013.25.2.89

Electrochemical Study for 1,3-Bisdicyanovinylindane

Kim, Hyungjoo (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University)
Rao, Boddu Ananda (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University)
Son, Young-A (Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University)

Publication Information

Textile Coloration and Finishing / v.25, no.2, 2013 , pp. 89-93 More about this Journal

Abstract

The electrochemical study has been enjoyed in many areas of chemistry. Through this approach using electrochemical measurement, empirical HOMO and LUMO values can be calculated by three methods such as absorption measurement, cyclicvoltammetry and computational calculations. In this study, 1,3-bisdicyanovinylindane was prepared and investigated toward its optical properties. The absorption intensities were changed depending on changes of pH. These absorption changes are induced by resonance form of 1,3-bisdicyanovinylindane. The electron delocalization in ${\pi}$ system is related to the resonance form. In according to this electron density distribution and HOMO/LUMO values of 1,3-bisdicyanovinylindane were simulated and calculated by Material Studio 4.3, absorption measurement and cyclicvoltammograms. The 1,3-bisdicyanovinylindane is one of the most attracted acceptor units in D- ${\pi}$ -A system. This attempt is useful to determine more detailed characteristics of the energy potentials.

Keywords

HOMO; LUMO; absorption; cyclicvoltammetry; 1,3-bisdicyanovinylindane; D- ${\pi}$ -A;

Citations & Related Records

Times Cited By KSCI : 3 (Citation Analysis)

Reference
Cited By KSCI

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