• Title/Summary/Keyword: Tailored-Properties

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Structural and Optical Properties of Sol-gel Derived MgxZn1-x Thin Films

  • Kim, In-Soo;Kim, Do-Yun;Choi, Se-Young
    • Korean Journal of Materials Research
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    • v.19 no.3
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    • pp.125-131
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    • 2009
  • In this report, the structural and optical properties of sol-gel derived $Mg_xZn_{1-x}O$ thin films upon changes in the composition and annealing temperature were investigated. The $Mg^{2+}$ content and the annealing temperature were varied in the range of $0{\leq}x{\leq}0.35$ and $400^{\circ}C{\leq}T{\leq}600^{\circ}C$, respectively. The films exhibited a hexagonal wurtzite structure of a polycrystalline nature. The optical transmittance exceeded 85% and the optical band gap of the film was tuned as high as 3.84 eV at a value of x = 0.35 (annealed at $400^{\circ}C$), which was evidently the maximum $Mg^{2+}$ content for the single-phase polycrystalline $Mg_xZn_{1-x}O$ thin films prepared in this experiment. The optical band gap and photoluminescence emission were tailored to the higher energy side while maintaining crystallinity without a significant change of the lattice constant.

Synthesis and Biocompatibility of PVA/NaCMC Hydrogels Crosslinked by Cyclic Freezing/thawing and Subsequent Gamma-ray Irradiation

  • Shin, Ji-Yeon;Jeong, Heeseok;Lee, Deuk Yong
    • Journal of Biomedical Engineering Research
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    • v.39 no.4
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    • pp.161-167
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    • 2018
  • Polyvinyl alcohol/sodium carboxymethyl cellulose (PVA/NaCMC) hydrogels were prepared by physical crosslinking (cyclic freezing/thawing) and gamma (${\gamma}$)-ray irradiation to evaluate the effect of NaCMC concentration (2~8 wt%) on the mechanical properties and the biocompatibility of the PVA/NaCMC hydrogels. The swelling rate of PVA/NaCMC hydrogels regardless of irradiation rose with increasing NaCMC content from 2 wt% to 8 wt%, while the gelation rate was the reverse. As the NaCMC content increased from 2 wt% to 6 wt%, the compressive strength of the hydrogels increased dramatically from $8.5{\pm}2.0kPa$ to $52.7{\pm}2.5kPa$ before irradiation and from $13.5{\pm}2.9kPa$ to $65.5{\pm}8.7kPa$ after irradiation. When 8 wt% NaCMC was added afterwards, the compressive strength decreased however. The irradiated PVA/NaCMC hydrogels containing 6 wt% NaCMC exhibited the tailored properties of the swelling rate of $118{\pm}3.7%$, the gelation rate of $71.4{\pm}1.3%$, the strength of $65.5{\pm}8.7kPa$, respectively, and no cytotoxicity was observed.

Influence of GaAs/AlGaAs Superlattice Layers on Optical Properties of InAs Quantum Dots (InAs 양자점의 광학적 성질에 미치는 초격자층의 영향)

  • Jeong Yonkil;Choi Hyonkwang;Park Yumi;Hwang Sukhyon;Yoon Jin-Joo;Lee Jewon;Leem Jae-Young;Jeon Minhyon
    • Korean Journal of Materials Research
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    • v.14 no.2
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    • pp.146-151
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    • 2004
  • We investigated the effects of high potential barriers on the optical characteristics of InAs quantum dots (QDs) by using photoluminescence (PL) and photoreflectance (PR) spectroscopy. A sample with regular InAs quantum dots on GaAs was grown by molecular beam epitaxy (MBE) as a reference. Another InAs QDs sample was embedded in single AlGaAs barriers. On the other hand, a sample with GaAs/AlGaAs superlattice barriers was adopted for comparison with a sample with a single AlGaAs layer. In results, we found that the emission wavelength of QDs was effectively tailored by using high potential barriers. Also, it was found that the optical properties of a sample with QDs embedded in GaAs/AlGaAs superlattices were better than those of a sample with QDs embedded in a single layer of AlGaAs barriers. We believe that GaAs/AlGaAs superlattice could effectively prevent the generation of defects.

Photoluminescence properties and energy transfer of $Dy^{3+}$ and $Tm^{3+}$ co-activated $CaZrO_3$ phosphor for white LEDs

  • Li, Yezhou;Wang, Yuhua
    • Journal of Information Display
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    • v.12 no.2
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    • pp.93-96
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    • 2011
  • Single-phased $CaZrO_3:Dy^{3+}$, $Tm^{3+}$ series have been successfully synthesized by solid-state reaction, and their luminescence properties were investigated. Under 355 nm excitation, $CaZrO_3:Dy^{3+}$ series showed characteristic emission of $Dy^{3+}$, which exhibited yellowish white color. By introducing $Tm^{3+}$ into the matrix, the emitted hue of the $Dy^{3+}$-doped sample could be easily tailored to white, and simultaneously, energy transfer from $Tm^{3+}$ to $Dy^{3+}$ was observed. The color coordinates of the optimum white-emitting sample were (0.321, 0.323), which were very close to the data of the National Television Standard Committee (0.33, 0.33). The co-activated phosphors presented good match to ultraviolet light-emitting diodes (LEDs), which revealed that they could be novel promising phosphors utilized in white LED application.

Microstructure and Mechanical Properties of SiC-BN Composites with Oxynitride Glass

  • Lee, Young-Il;Kim, Young-Wook
    • Journal of the Korean Ceramic Society
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    • v.40 no.3
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    • pp.229-233
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    • 2003
  • By using an oxynitride glass as a sintering additive, the effects of BN content on microstructure and mechanical properties of the hot-pressed and subsequently annealed SiC-BN composites were investigated. The microstructures developed were analyzed by image analysis. The morphology of SiC grains was strongly dependent on BN content in the starting composition. The aspect ratio of SiC decreases with increasing BN content and the average diameter of SiC shows a maximum at 5 wt% BN and decreases with increasing BN content in the starting powder. The fracture toughness increased with increasing BN content while the strength decreased with increasing BN content. The strength and fracture toughness of SiC or SiC-TiC composites were strongly dependent on the morphology of SiC grains, but the strength and fracture toughness of SiC-BN composites were strongly dependent on BN content rather than morphology of SiC grains. These results suggest that fracture toughness of SiC ceramics can be tailored by manipulating BN content in the starting composition. Typical fracture toughness and strength of SiC-10 wt% BN composites were 8 MPa$.$m$\^$1/2/ and 445 MPa, respectively.

Exact third-order static and free vibration analyses of functionally graded porous curved beam

  • Beg, Mirza S.;Khalid, Hasan M.;Yasin, Mohd Y.;Hadji, L.
    • Steel and Composite Structures
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    • v.39 no.1
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    • pp.1-20
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    • 2021
  • An exact solution based on refined third-order theory (TOT) has been presented for functionally graded porous curved beams having deep curvature. The displacement field of the refined TOT is derived by imposing the shear free conditions at the outer and inner surfaces of curved beams. The properties of the two phase composite are tailored according the power law rule and the effective properties are computed using Mori-Tanaka homogenization scheme. The equations of motion as well as consistent boundary conditions are derived using the Hamilton's principle. The curved beam stiffness coefficients (A, B, D) are obtained numerically using six-point Gauss integration scheme without compromising the accuracy due to deepness (1 + z/R) terms. The porosity has been modeled assuming symmetric (even) as well as asymmetric (uneven) distributions across the cross section of curved beam. The programming has been performed in MATLAB and is validated with the results available in the literature as well as 2D finite element model developed in ABAQUS. The effect of inclusion of 1 + z/R terms is studied for deflection, stresses and natural frequencies for FG curved beams of different radii of curvature. Results presented in this work will be useful for comparison of future studies.

A Study on the Formability of Engine Cradle applied to Hydroforming according to Material Properties (하이드로포밍을 적용한 Engine Cradle의 소재 특성에 따른 성형성 고찰)

  • 박재헌;최이천;김경기
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.05a
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    • pp.249-253
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    • 2003
  • In recent years, developments of light weight vehicle are one of the most important issues in automotive makers. New materials and new processes have been studied on the point of weight saving of chassis worldwide. Associated with materials, applications of high strength steel, aluminium, magnesium are being developed. On the point of new processes, tailored welded blank and hydroforming have been applied. In this paper, focusing to both material and process, we have applied hydroforming process to the engine cradle. In addition to that, three kinds of high strength steel have been applied to the development of light weight material for hydroforming. All the studies have been carried by FEM.

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Possible Strategies for Microstructure Control of Liquid-Phase-Sintered Silicon Carbide Ceramics

  • Chun, Yong-Seong;Kim, Young-Wook
    • Journal of the Korean Ceramic Society
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    • v.42 no.8 s.279
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    • pp.542-547
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    • 2005
  • Keys to the attainment of tailored properties in SiC ceramics are microstructure control and judicious selection of the sintering additives. In this study, three different strategies for controlling microstructure of liquid-phase-sintered SiC ceramics (LPS-SiC) have been suggested: control of the initial $\alpha-SiC$ content in the starting powder, a seeding technique, and a post-sintering heat treatment. The strategies suggested offer substantial flexibility for producing toughened SiC ceramics whereby grain size, grain size distribution, and aspect ratio can be effectively controlled. The present results suggest that the proposed strategies are suitable for the manufacture of toughened SiC ceramics with improved toughness.

Polymer concrete filled circular steel beams subjected to pure bending

  • Oyawa, Walter O.;Sugiura, Kunitomo;Watanabe, Eiichi
    • Steel and Composite Structures
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    • v.4 no.4
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    • pp.265-280
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    • 2004
  • In view of the mounting cost of rehabilitating deteriorating infrastructure, further compounded by intensified environmental concerns, it is now obvious that the evolvement and application of advanced composite structural materials to complement conventional construction materials is a necessity for sustainable construction. This study seeks alternative fill materials (polymer-based) to the much-limited cement concrete used in concrete-filled steel tubular structures. Polymers have been successfully used in other industries and are known to be much lighter, possess high tensile strength, durable and resistant to aggressive environments. Findings of this study relating to elasto-plastic characteristics of polymer concrete filled steel composite beams subjected to uniform bending highlight the enormous increase in stiffness, strength and ductility of the composite beams, over the empty steel tube. Moreover, polymer based materials were noted to present a wide array of properties that could be tailored to meet specific design requirements e.g., ductility based design or strength based design. Analytical formulations for design are also considered.

Communication Delay Properties in Performance Model of Profibus Token Passing Protocol (Profibus 토큰 패싱 프로토콜 성능 모델에서의 전송 지연 특성)

  • Lee, Kyung-Chang;Kim, Hyun-Hee;Lee, Seok
    • Journal of Institute of Control, Robotics and Systems
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    • v.9 no.12
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    • pp.1055-1064
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    • 2003
  • In many automated systems, such as manufacturing systems and process plants, a fieldbus is a very important component for the exchange of various and sometimes crucial information. Some of the information has a tendency to rapidly lose its value as time elapses after its creation. Such information or data is called real-time data that includes sensor values and control commands. In order to deliver these data in time, the fieldbus network should be tailored to have short delay with respect to the individual time limit of various data. Fine-tuning the network for a given traffic requires the knowledge on the relationship between the protocol parameters such as timer values and the performance measure such as network delay. This paper presents a mathematical performance model to calculate communication delays of the Profibus-FMS network when the timer value and the traffic characteristics are given.