• 제목/요약/키워드: TVOC (Total Volatile Organic Compounds)

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목재 펠릿 난로와 보일러 사용에 의한 대기오염물질과 블랙카본의 배출 특성 (Emission Characteristics of Air Pollutants and Black Carbon from Wood-pellet Stove and Boiler)

  • 박성규;유근정;김대근;김동영;장영기;전의찬
    • 한국기후변화학회지
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    • 제6권1호
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    • pp.41-47
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    • 2015
  • This study was carried out simulating domestic utilization conditions of a wood pellet stove and a wood pellet boiler in order to determine emission factors (EFs) of macro-pollutants, i.e., carbon monoxide, nitrogen oxides, sulfur oxides, ammonia, particulate matters (total suspended particulate, $PM_{10}$, $PM_{2.5}$, black carbon) and trace pollutants (i.e., ten different volatile organic compounds). The composite pollutants EFs for the pellet stove were: for TSP 4.58 g/kg, for $PM_{10}$ 3.35 g/kg, for $PM_{2.5}$ 2.48 g/kg, CO 119.23 g/kg, NO 14.40 g/kg, $SO_2$ 0.17 g/kg, TVOC 37.73 g/kg, $NH_3$ 0.02 g/kg and emissions were similar to the pellet boiler appliance: for TSP 4.73 g/kg, for $PM_{10}$ 3.41 g/kg, for $PM_{2.5}$ 2.63 g/kg, CO 161.51 g/kg, NO 13.67 g/kg, $SO_2$ 0.19 g/kg, TVOC 45.22 g/kg, $NH_3$ 0.02 g/kg.

화목 난로와 보일러 사용에 의한 대기오염물질과 블랙카본의 배출 특성 (Emission Characteristics of Air Pollutants and Black Carbon from Wood Stove and Boiler)

  • 박성규;최상진;김대근;김동영;장영기;전의찬
    • 한국기후변화학회지
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    • 제6권1호
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    • pp.49-54
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    • 2015
  • Manually fed firewood burning appliances, i.e., stove and boiler, were tested in order to determine emission factors (EFs) of macro-pollutants, i.e., carbon monoxide, nitrogen oxides, sulfur oxides, ammonia, particulate matters (total suspended particulate, $PM_{10}$, $PM_{2.5}$, black carbon) and trace pollutants (i.e., ten different volatile organic compounds). The composite pollutants EFs for the wood stove were: for TSP 15.45 g/kg, for $PM_{10}$ 6.53 g/kg, $PM_{2.5}$ 4.16 g/kg, CO 175.49 g/kg, NO 1.58 g/kg, $SO_2$ 0.15 g/kg, TVOC 48.02 g/kg, $NH_3$ 0.02 g/kg and emissions were similar to the wood boiler appliance: for TSP 12.23 g/kg, for $PM_{10}$ 5.84 g/kg, $PM_{2.5}$ 3.66 g/kg, CO 146.74 g/kg, NO 1.42 g/kg, $SO_2$ 0.15 g/kg, TVOC 47.78 g/kg, $NH_3$ 0.01 g/kg.

Evaluation of Physical, Mechanical Properties and Pollutant Emissions of Wood-Magnesium Laminated Board (WML Board) for Interior Finishing Materials

  • PARK, Hee-Jun;JO, Seok-Un
    • Journal of the Korean Wood Science and Technology
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    • 제48권1호
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    • pp.86-94
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    • 2020
  • This study serves as basic research for the development of a new wood-based building finishing material that improved the weakness of inorganic materials such as gypsum board and magnesium board widely used as interior finishing materials and brought out the strength of the wood. The results of evaluating the physical and mechanical properties and the environmental effect related to hazardous substance discharge having manufactured a wood-magnesium laminated composite are as follows. The thermal conductivity and thermal resistance of WML board was improved by about 28~109 percent over magnesium board due to the low thermal conductivity of wood. The adhesive strength of WML board showed a similar result to that of plywood as it exceeds 0.7N/㎟, the adhesive standard of wood veneer which is presented by KS F 3101. Bending strength and screw holding strength were more improved by manufacturing WML board than magnesium board. The WML board manufactured in this study satisfied the criteria for emissions of hazardous substances prescribed in the Indoor Air Quality Control Act, and confirmed the possibility of development as a new wood-based composite material that can replace existing inorganic materials.

전국 일부 학교 건축물 내의 실내 공기 및 인식도 조사 (The Assessment and Recognition on Indoor Air Quality at Schools in Korea)

  • 손종렬;윤승욱;김종혁;이용식;최한영;김영성;손부순;양원호;김민회
    • 환경위생공학
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    • 제20권3호
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    • pp.1-9
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    • 2005
  • Recently, indoor air quality (IAQ) in workplace, residential environments and schools has been concerned of people, scientists and related the public, and has recognized the healthy effectsrelated to IAQ, specially in schools in Korea. Therefore, objectives of this study in this study were to measure and compare the perception of TAQ of selected air pollutants in Seoul from April to September 2004. Measurement place measured 2 schools of Seoul and local 9 schools (by Kyonggi Province, Chungchong-bukdo Chungchong-namdo, Chollado-bukdo, Cholla-namdo, Kyongsang-bukdo, Kyongsang-namdo, Kwangju, schoolin Pusan each 1 place). Temperature, humidity, illumination, carbon monoxide, carbon dioxide, TBC (total bacteria count), noise, PM10, TVOC(total volatile organic compounds), HCHO (formaldehyde) were measured simultaneously. Also, we Performed a questionnaire survey of 250 students and 50 teachers about their awareness for the importance of IAQ in their schools. Among this article, we handled noise, carbon monoxide, carbon dioxide, TBC, TVOC, HCHO, PM 10 in our conclusion. Major results were as follows ; Carbon monoxide (CO) was lower than indoor air standard of Korea. Carbon dioxide $(CO_2)$ appeared that 4 schools among our sample target school exceeded in normal standard. 4 schools were almost similar with normal standard. TBC appeared that 7 schools among 11 schools were higher than standard. Noise measured school's mean value passed exceeded standard. And school which passed over standard appeared to 7 schools among 11 schools. HCHO was exceeded 4 schools by standard that excess and certainly interrelation between school's establishment year and facilities of construction was detected. PM10 was exposed all schools by fitness in standard. TVOC appeared that 9 schools among 11 measurement school was exceeded health effect standard of Japan.

조선소 용접작업 중 오존 및 TVOCs의 노출평가와 사용 호흡보호구의 적합성 (Exposure to Ozone and TVOCs during Shipyard Welding and the Adequacy of RPE)

  • 한돈희;김동환
    • 한국산업보건학회지
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    • 제28권2호
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    • pp.200-210
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    • 2018
  • Objectives: The purpose of this study is to assess the exposure to ozone and total volatile organic compounds(TVOCs) generated during welding work at a shipyard and recommend respiratory protective equipment(RPE) adequate against these hazards. Method: Ozone was collected for about 30 minutes at two-minutes intervals using a direct reading instrument, specifically an ozone analyzer(Serinus 10, Ecotech, Australia). TVOCs were collected for about 30 minutes at three-minute intervals using a portable GC (Alpha 115, Synspec BV, the Netherlands), and were determined simultaneously by area sampling at the welding plume closest to the welder's breathing zone. The total measurements were 162 for ozone($CO_2$ welding 47, TIG 60, stick 55), and 136 for TVOCs($CO_2$ 65, TIG 50, stick 21). Based on these measurements, a literature survey was conducted to assess the adequacy of RPE. Results: Relative to Korean OEL, measurements above STEL 0.2 ppm were 23.4% for $CO_2$, 63.3% for TIG and 14.5% for stick welding. There were significant differences(p=<0.0001) among welding types. Compared with ACGIH peak exposure of 0.4 ppm for ozone, which is not applied in Korea, $CO_2$ welding exceeded it by 10.6%, TIG by 40.0% and stick by 7.3%. Although it was not feasible to compare them directly since there are no Korean OEL, TVOCs had very high levels similar to the concentrations before moving into a new apartment and about 10-20 times the indoor air quality recommendations for some individual measurements. Conclusions: As ozone removal RPE has been recommended in welding environments for a long time(Lunau, 1967), this fact was demonstrated based on the results of the on-site work environment measurements(ozone and TVOCs). In conclusion, for all welding at a shipyard, gas/vapor and particulate combination RPE are recommended. If this is not possible, it should at least be present for TIG welding.

소형챔버를 이용한 건축자재 오염물질 방출시험방법 평가 (Evaluation of sampling and analytical method for emission experiment of pollutants in building materials using small chamber)

  • 이석조;장성기;김미현;이홍석;임준호;장미;서수연
    • 분석과학
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    • 제18권4호
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    • pp.344-354
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    • 2005
  • 최근 들어 실내공기질 악화의 주 오염원인 건축자재에 대한 관심이 고조되면서 건축자재 오염물질 방출시험 자료 구축이 중요하게 됨에 따라, 신뢰성 있는 자료 확보를 위해 건축자재 방출시험 정도 관리에 대한 필요성이 대두되었다. 이에 본 연구는 건축자재 방출시험 성능에 대한 정도관리를 위해 총 휘발성 유기화합물과 포름알데히드에 대하여 기기분석 재현성, 회수율, 검출한계, 중복 및 반복채취 재현성, 파과용량 평가 등을 실시하였다. 기기분석 및 시료채취에 대한 재현성은 20~30% 이내의 양호한 결과를 보였으며, 회수율은 80% 이상으로 나타났으며, 파과 역시 일어나지 않아 소형챔버법에 의한 성능은 전반적으로 만족할 만한 수준을 보였다. 따라서, 소형챔버를 이용한 건축자재 오염물질 방출시험방법은 신뢰성있는 자료를 제공해 줄 수 있을 것으로 판단된다.

Application of Field and Laboratory Emission Cell (FLEC) to Determine Formaldehyde and VOCs Emissions from Wood-Based Composites

  • Kim, Sumin;Kim, Jin-A;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • 제35권5호
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    • pp.24-37
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    • 2007
  • The Korean Ministry of Environment started controlling indoor air quality (IAQ) in 2004 through the introduction of a law regulating the use of pollutant emitting building materials. The use of materials with formaldehyde emission levels above $1.25 mg/m^2{\cdot}h$ (JIS A 1901, small chamber method) has been prohibited. This level is equivalent to the $E_2$ grade ($>5.0mg/{\ell}$) of the desiccator method (JIS A 1460). However, the $20{\ell}$ small chamber method requires a 7-day test time to obtain the formaldehyde and volatile organic compound (VOC) emission results from solid building interior materials. As a approach to significantly reduce the test time, the field and laboratory emission cell (FLEC) has been proposed in Europe with a total test time less than one hour. This paper assesses the reproducibility of testing formaldehyde and TVOC emissions from wood-based composites such as medium density fiberboard (MDF), laminate flooring, and engineered flooring using three methods: desiccator, perforator and FLEC. According to the desiccator and perforator standards, the formaldehyde emission level of each flooring was ${\le}E_1$ grade. The formaldehyde emission of MDF was $3.48 mg/{\ell}$ by the desiccator method and 8.57 g/100 g by the perforator method. To determine the formaldehyde emission, the peak areas of each wood-based composite were calculated from aldehyde chromatograms obtained using the FLEC method. Formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde and benzaldehyde were detected as aldehyde compounds. The experimental results indicated that MDF emitted chloroform, benzene, trichloroethylene, toluene, ethylbenzene, m,p-xy-lene, styrene, and o-xylene. MDF emitted significantly greater amounts of VOCs than the floorings did.

Hazard Levels of Cooking Fumes in Republic of Korea Schools

  • Lee, Iu-Jin;Lee, Sang-Gil;Choi, Bo-Hwa;Seo, Hoe-Kyeong;Choi, Ji-Hyung
    • Safety and Health at Work
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    • 제13권2호
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    • pp.227-234
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    • 2022
  • Background and Purpose: In 2021, lung cancer in school food workers was first recognized as an occupational cancer. The classification of the carcinogenicity of cooking fumes by International Agency for Research on Cancer (IARC) was based on Chinese epidemiological data. This study aimed to determine the hazard levels of school cooking fumes in Korea. Materials and Methods: Based on public school cafeterias in one area, 25 locations were selected for the survey according to the number per school type, ventilation states, and environmental pre-assessments of cafeterias. Two inside cooking areas using a heat source and one outside cooking area were selected as control measurement points. Measurements of CO, CO2, polycyclic aromatic hydrocarbons (PAHs), and total volatile organic compounds (TVOCs), including benzene, formaldehyde, and particulate matter (PM10, PM2.5, PM1, respectively), were taken. The concentrations and patterns of each substance in the kitchens were compared with the outdoor air quality. Result: Known carcinogens, such as the concentrations of PAHs, formaldehyde, TVOC (benzene), and particulate matter in school cooking fumes, were all detected at similar or slightly higher levels than those found outside. Additionally, substances were detected at relatively low concentrations compared to the Chinese cooking fumes reported in the literature. However, the short-term exposure to high concentrations of CO (or composite exposure with CO2) and PM2.5 in this study were shown. Conclusion: The school cooking fumes in South Korea was a relatively less harmful than Chinese cooking fumes, however short-term, high exposure of toxic substances can cause a critical health effect.

변성 비닐계 접착제를 이용한 파티클보드의 포름알데히드/VOCs 방산특성 (The Formaldehyde/VOCs Emission of Particleboard with Cross-linked Vinyl Resin)

  • 김기욱;이세나;백봉산;이병호;김현중;최윤미;장성욱
    • 접착 및 계면
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    • 제9권1호
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    • pp.28-34
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    • 2008
  • 요소 수지와 변성 비닐계 수지의 혼합비에 따라 200 : 0, 180 : 20, 140 : 60, 100 : 100 으로 파티클보드를 제작하였다. 제조된 파티클보드는 변성 비닐계 수지의 비율이 증가수록 함수율과 밀도가 약간 감소하였다. 기계적 특성은 휨강도의 경우 변성 비닐계 수지 첨가로 인해 파티클보드의 전체적인 휨강도는 증가하였으나 박리강도는 약간 감소하였다. VOC Analyzer를 이용하여 방산실험을 한 결과 실험 종료 후, 4 VOCs의 값이 $294{\mu}g/L$, $1435{\mu}g/L$, $1272{\mu}g/L$ 정도로 저감되었다. 또한 FLEC을 이용하여 TVOC, 5 VOCs, 포름알데히드의 방산 실험 결과 요소수지만으로 만들어진 파티클보드의 방산값이 각각 $1.392mg/m^2h$, $0.0259mg/m^2h$, $0.179mg/m^2h$ 정도를 나타내었다. 요소수지와 변성 비닐계 수지의 혼합비를 동일하게 하여 제조된 파티클보드로부터 방산된 경우 $0.235mg/m^2h$, $0.0033mg/m^2h$, $0.105mg/m^2h$ 로 저감되었다.

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지하에 위치한 방사선종양학과에서의 실내공기 질 평가 (Evaluation of Indoor Air Quality in a Department of Radiation Oncology Located Underground)

  • 김원택;신용철;강동묵;기용간;김동원;권병현
    • Radiation Oncology Journal
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    • 제23권4호
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    • pp.243-252
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    • 2005
  • 목적: 지하에 위치한 방사선치료 관련시설 내의 실내공기 질은 근무자뿐만 아니라 장기간 치료받는 환자들의 건강에도 중요하다. 저자들은 근무자들의 빌딩증후군 증상유무의 확인과 함께 실내공기 질과 관련된 여러 인자들을 측정, 분석하여 그 원인을 찾고 해결책을 제시하고자 하였다. 대상 및 방법: 근무자들을 대상으로 자각증상 및 근무환경 인식과 관련된 설문조사를 하였고, 예비조사를 바탕으로 실내공기 질과 관련된 항목들(온 습도, 미세먼지, 이산화탄소, 일산화탄소, 포름알데히드, 총휘발성유기화합물, 라돈)에 대해 근무자들이 주로 머무르는 지역들을 중심으로 일정기간 측정하였다. 아울러 환기(공조) 시스템의 효율 및 주변 환경에 대한 평가를 동시에 진행하였으며, 실외공기와의 비교평가를 위해 1층(실외)에서도 같은 항목들을 측정하였고, 측정 자료들은 국내외 환경관련 기관들의 권고 수치를 기준으로 각각 평가하였다. 결과: 설문조사에서 근무자들은 악취, 습도, 먼지 등에 대해 불만족을 보였으며, 근골격계 증상, 신경계 증상, 점막 자극 증상 등을 주로 호소하였다. 대부분의 실내공기 질 관련 항목들은 기준치를 넘지 않았으나 총휘발성유기화합물 수치가 기존 미국 사무실 측정 수치에 비해 $3{\sim}4$배 높게 나왔다. 환기 횟수나 환기량에서는 문제가 없었으나 실외공기 유입구와 실내공기 배출구의 위치 문제로 인해 오염된 공기의 유입 가능성이 있었다. 총휘발성유기화합물을 배출할 수 있는 현상액과 같은 화학물질의 관리에 주의가 필요했으며, 오염된 공기의 재유입 문제를 해결하기 위해 환기 시스템의 위치조정이 시급한 상황이었다. 결론: 저자들은 실내공기 질에 대한 평가에서 일부 화학물질 및 부적절한 환기 시스템으로 인해 근무자들이 주관적인 증상을 호소할 수 있음을 확인하였다. 지하 공간에서 장시간 거주하는 근무자들의 근무여건 개선과 함께 면역저하를 동반한 환자들의 건강관리를 위해 실내공기 질에 대한 평가는 반드시 필요하며, 그 자료를 바탕으로 향후 방사선종양학과의 설계나 기존 시설의 환경개선 등에 적극적으로 이용해야 하겠다.