• Title/Summary/Keyword: TSMA

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Mechanical Properties of Recycled Coarse Aggregate concrete using Two-Stage Mixing Approach (TSMA 방법을 이용한 순환 굵은골재 콘크리트의 기계적 성능)

  • Kwon, Seung Jun;Lim, Hee Seob;Lee, Han Seung;Lim, Myung Kwan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.4
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    • pp.60-67
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    • 2018
  • As the lack of specific aggregation intensifies, the development of alternative resources is urgent. Construction waste is increasing every year, but recycled aggregate is used as a low value added material. Various studies are currently underway at the national level. In this paper, the mechanical performance of the concrete according to the concrete mixing method and the replacement amount of the circulating coarse aggregate was compared and evaluated. Concrete mixing method was normal mixing approach(NMA) method, two-stage mixing approach1 (TSMA1) method, two-stage mixing approach2 (TSMA2) method. Fresh concrete was tested for air content, slump test, and unit volume weight. Compressive strength and flexural strength were tested in hardened concrete. According to the TSMA method, the mechanical performance difference of concrete is shown, and the strength is decreased according to the circulating coarse aggregate replacement amount.

Evaluation on Long-term Mechanical Performance and Durability of Recycled Coarse Aggregate Concrete Produced by Two-stage Mixing Approach (2단계 배합방법으로 제조된 순환굵은골재 콘크리트의 장기재령 역학적 성능 및 내구성 평가)

  • Seong-Uk, Heo;Jeong Jin, Son;Chul-Woo, Chung;Young Chan, Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.475-481
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    • 2022
  • Recycled aggregates show high water absorption rate compared to natural aggregates due to microcrack developed during production process and adhered cement pastes at the surface of recycled aggregates. This leads to the deterioration of mechanical properties and slow work flow. Currently it is getting hard to satisfy high demand for natural aggregates. Utilizing recycled aggregate more widely may be a substitutable countermeasure for the shortage of natural resources. In this study, two-stage mixing approach(TSMA) suggested by Tam et al. is used to produce recycled aggregate concrete(RAC) with 100 % replacement of coarse natural aggregate and tests for compressive strength, elastic modulus, and chloride ion diffusion coefficient are conducted to find out the effect of TSMA compared to normal mixing method. According to experimental result compressive strength and elastic modulus of RAC with TSMA was superior to those of RAC with normal mixing irrespective of water-cement ratio, and in some cases mechanical properties of RAC with TSMA approached to those of natural aggregate concrete(NAC). However, chloride ion diffusion coefficient of RAC was higher than that of NAC. This illustrates that TSMA is not an appropriate method in reducing chloride ion diffusion coefficient, resulting in inconsequential contribution of TSMA to the durability of RAC.

Synthesis and Characterization of Crosslinked Polyacrylates Containing Cubane and Silyl Groups

  • Mahkam Mehrdad;Assadi Mohammad;Mohammadzadeh Rana
    • Macromolecular Research
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    • v.14 no.1
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    • pp.34-37
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    • 2006
  • Attaching the organosilyl groups to macromolecular chains of 2-hydroxyethyl methacrylate (HEMA) should lead to important modifications of polymer properties. t-$BuMe_{2}Si$ and cubane-l, 4-dicarboxylic acid (CDA) were covalently linked with 2-hydroxyethyl methacrylate (HEMA). The silyl-linked HEMA is abbreviated as TSMA, while cubane-l ,4-dicarboxylic acid (CDA) linked to two HEMA groups is the cross-linking agent (CA). Free radical cross-linking copolymerization of TSMA and HEMA with various ratios of CA as the cross-linking agent was carried out at 60-70$^{circ}C$. The compositions of the cross-linked, three-dimensional polymers were determined by FTIR spectroscopy. The glass transition temperature ($T_{g}$) of the network polymers was determined calorimetrically. The $T_{g}$ of the network polymer increased with increasing cross-linking degree.

Compatibility of POSS Composites with Silicone Monomers and Application to Contact Lenses Material

  • Lee, Min-Jae;Lee, Kyungmun;Sung, A-Young
    • Journal of the Korean Chemical Society
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    • v.64 no.6
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    • pp.354-359
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    • 2020
  • This research was conducted to analyze the compatibility of used monomers and produce the high functional contact lens material containing silicone monomers. Silicone monomer (Sil-OH), Trimethylsilylmethacrylate (TSMA) were used as additives for the basic combination of Polyhedral Oligomeric Silsesquioxane (POSS), methyl methacrylate (MMA) and methyl acrylate (MA). And also, the materials were copolymerized with ethylene glycol dimethacrylate (EGDMA) as the cross-linking agent, AIBN (thermal polymerization initiator) as the initiator. It is judged that the fabricated lenses of all combinations are optically excellent and thus used monomers have good compatibility. Measurement of the optical and physical characteristics of the manufactured hydrophilic lens material were varied in each case. Especially TSMA with POSS increases the oxygen permeability and Sil-OH with POSS increases the wettability by the addition of Sil-OH. These materials were considered to have compatibility each other, so it can be used in functional contact lens material.

Analysis of Physical Properties of Hydrogel Lenses Polymer Containing Styrene and PVP

  • Lee, Min-Jae;Sung, A-Young
    • Korean Journal of Materials Research
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    • v.29 no.7
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    • pp.399-407
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    • 2019
  • This research is carried out to analyze the effects of Styrene and PVP on the properties of silicone hydrogel lenses. Styrene group and PVP(Polyvinylpyrrolidone) are used as additives for a basic combination containing silicone monomer, TSMA(trimethylsilyl methacrylate) and DMA(n,n-dimethylacrylamide) added to the mix at ratios of 1~10 %. Silicone hydrogel lens is produced by cast-mold method. The polymerized lens sample is hydrated in a 0.9 % saline solution for 24 hours before its optical and physical characteristics are measured. Measurement of the physical characteristics of the produced material shows that the refractive index is 1.3682~1.4321, water content 77.11~45.73 %, visible light transmittance 95.14~88.20 %, and tensile strength 0.0652~0.3113 kgf. The results show a decrease of refractive index as the ratio of additives and water content decreases. The result of the stabilization test of polymerization show an increase of extractables along with increase of the ratio of additives, but the difference is not significant for all samples, so it can be judged that the stabilization of the polymer is maintained. Therefore, the additions of styrene and PVP should be taken into consideration for their effects on the physical properties of silicone hydrogel lens.

Sustainable self compacting acid and sulphate resistance RAC by two stage mixing approaches

  • Rajhans, Puja;Kisku, Nishikant;Nayak, Sanket;Panda, Sarat Kumar
    • Advances in concrete construction
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    • v.9 no.1
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    • pp.55-70
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    • 2020
  • In this research article, acid resistance, sulphate resistance and sorptivity of self compacted concrete (SCC) prepared from C&D waste have been discussed. To improve the above properties of self compacted recycled aggregate concrete (SCRAC) along with mechanical and durability properties, different two stage mixing approaches (TSMA and TSMAsfc) were followed. In the proposed two stage mixing approach (TSMAsfc), silica fume, a proportional amount of cement and a proportional amount of water were mixed in premix stage which fills the pores and cracks of recycled aggregate concrete (RAC). The concrete specimen prepared using above mixing approaches were immersed in 1% concentration of sulphuric acid (H2SO4) and magnesium sulphate (MgSO4) solution for 28, 90 and 180 days for evaluating the acid resistance of SCRAC. Experimental results concluded that the proposed two stage mixing approach (TSMAsfc) is most suitable for acid resistance and sulphate resistance in terms of weight loss and strength loss due to the elimination of pores and cracks in the interfacial transition zone (ITZ). In modified two stage mixing approach, the pores and cracks of recycled concrete aggregate (RCA) were filled up and make ITZs of SCRAC stronger. Microstructure analysis was carried out to justify the reason of improvement of ITZs by electron probe micro analyser (EPMA) analysis. X-ray mapping was also done to know the presence of strength contributing elements presents in the concrete sample. It was established that SCRAC with modified mixing approach have shown improved results in terms of acid resistance, sulphate resistance, sorptivity and mechanical properties.

A Method of Extending a Multiagent Framework with a Plan Generation Module (계획생성 모듈을 갖는 멀티에이전트 기반구조의 확장방법)

  • Lee, Gowang-Lo;Park, Sang-Kyu;Jang, Myong-Wuk;Min, Byung-Eui;Choi, Joong-Min
    • The Transactions of the Korea Information Processing Society
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    • v.4 no.9
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    • pp.2280-2288
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    • 1997
  • An agent is a software element that, by making use of knowledge and inference, performs tasks on behalf of the user. In general, an agent has the properties of autonomy, social ability, reactivity, and durability. Many researches on agents are more and more aiming at the multiagent systems since it is not sufficient to let a single agent do the whole things, especially in a real world where tasks require many diverse activities. However, the multiagent frameworks still have some limitations in the processing of user queries that are often ambiguous and goal-oriented. Also, a series of procedures or plans could not be generated from a single query directly. In order to give more intelligence to the multiagent framework, we propose a method of extending the framework with a plan generation module. The open agent architecture (OAA), which is a multiagent framework that we developed, is integrated with UCPOP, which is a AI planner. A travel schedule management agent (TSMA) system is implemented to explore the effects of the method. The extended system enables the user to only specify goal-oriented queries, and the plans and procedures to satisfy these goals are generated automatically. Also, this system provides a cooperative and knowledge-sharing environment that integrates several knowledge-based systems and planning systems that are distributed and used independently.

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