• Title/Summary/Keyword: TRITIUM

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Water Chemistry and Age Dating of Springwater in Cheju Island (제주도 용천수의 수질 화학적 특성과 연대 측정에 관한 연구)

  • Kim Jong-Hun;Ahn Jong-Sung
    • Journal of the Korean Chemical Society
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    • v.36 no.5
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    • pp.727-737
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    • 1992
  • The water chemical characteristics and age dating of springwater in Cheju island had been investigated. C_1, C_4, C_7, C_9 springwaters were not affected by seawater intrusion by TDS and electrical conductivity, relationship of Cl and tritium, Cl and HCO_3 ratio, and total hardness and pseudo hardness. In this case only C_7 springwater was evaluated tasty and healthy mineral springwater by Hahimoto's Mineral Balance Index. On the basis of the mean tritium content of rainfalls and springwater, the average residence time of it, were calculated. Considering the hydrogeologic and hydrochemical condition, completely mixed model seems to be very fit. It was obtained the result that C_9 group springwater (C_{10}, C_{12}, C_{14}) was 1.2 months, C_7 springwater was 5.6 months, and deep groundwater C_{17} was 4 years.

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Determination of carbon-14 and tritium in a PWR spent nuclear fuel (PWR 사용후핵연료 중 탄소-14 및 트리튬 정량)

  • Kim, Jung Suk;Park, Soon Dal;Lee, Chang Hun;Song, Byong Chul;Jee, Kwang Yong
    • Analytical Science and Technology
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    • v.18 no.4
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    • pp.298-308
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    • 2005
  • The methods for determining C-14 and tritium contents in the spent nuclear fuel sample were developed. The carbon-14($^{14}CO_2$) released during the dissolution of the spent fuel sample and $CaCO_3$ ($CO_2$ carrier) with 8 M $HNO_3$ at $90^{\circ}C$ was collected in trap containing 1.5 M NaOH. The volatile radioactive iodine evolved when the spent fuel was dissolved, was trapped on to Ag-silicagel (Ag-impregnated silicagel) adsorbent in column which is connected to two NaOH traps. The solutions which contain tritium as HTO after fuel dissolution were decontaminated by deionization with a mixture of cation and anion exchange resins and inorganic ionexchangers. The amount of C-14 in the trap solutions and the HTO concentration in the resulting deionization water were then determined by liquid scintillation counting.

Fabrication and Characterization of a Fiber-optic Radiation Sensor for Detection of Tritium (삼중수소 검출용 광섬유 방사선 센서의 제작 및 특성분석)

  • Jang, Kyoung-Won;Cho, Dong-Hyun;Yoo, Wook-Jae;Lee, Bong-Soo;Moon, Joo-Hyun;Park, Byung-Gi;Cho, Young-Ho;Kim, Sin
    • Korean Journal of Optics and Photonics
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    • v.20 no.4
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    • pp.201-206
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    • 2009
  • In this study, we have fabricated a fiber-optic radiation sensor for detection of tritium using inorganic scintillators and optical fibers. We have tested various kinds of inorganic scintillators such as $Gd_2O_2S$ : Tb, $Y_3Al_5O_{12}$ : Ce, and CsI : Tl to select the most effective sensor tip. In addition, we have measured the scintillating lights using a photomultiplier tube as a function of distance between sensor tips to the source with the different activities of hydride tritium. The final results are compared with those which are obtained using a surface activity monitor.

Design, setup and routine operation of a water treatment system for the monitoring of low activities of tritium in water

  • C.D.R. Azevedo ;A. Baeza ;E. Chauveau ;J.A. Corbacho ;J. Diaz;J. Domange;C. Marquet ;M. Martinez-Roig ;F. Piquemal ;C. Roldan;J. Vasco ;J.F.C.A. Veloso ;N. Yahlali
    • Nuclear Engineering and Technology
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    • v.55 no.7
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    • pp.2349-2355
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    • 2023
  • In the TRITIUM project, an on-site monitoring system is being developed to measure tritium (3H) levels in water near nuclear power plants. The quite low-energy betas emitted by 3H have a very short average path in water (5 ㎛ as shown by simulations for 18 keV electrons). This path would be further reduced by impurities present in the water, resulting in a significant reduction of the detection efficiency. Therefore, one of the essential requirements of the project is the elimination of these impurities through a filtration process and the removal of salts in solution. This paper describes a water treatment system developed for the project that meets the following requirements: the water produced should be of near-pure water quality according to ISO 3696 grade 3 standard (conductivity < 10 µS/cm); the system should operate autonomously and be remotely monitored.

Shield Material Consideration in the LAR Tokamak Reactor

  • Hong, B.G.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.314-314
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    • 2010
  • For the optimal design of a tokamak-type reactor, self-consistent determination of a radial build of reactor systems is important and the radial build has to be determined by considering the plasma physics and engineering constraints which inter-relate various reactor systems. In a low aspect ratio (LAR) tokamak reactor with a superconducting toroidal field (TF) coil, the shield should provide sufficient protection for the superconducting TF coil and the shield plays a key role in determining the size of a reactor. To determine the radial build of a reactor, neutronic effects such as tritium breeding in the blanket, nuclear heating, and radiation damage to toroidal field (TF) coil has to be included in the systems analysis. In this work, the outboard blanket only is considered where tritium self-sufficiency is possible by using an inboard neutron reflector instead of breeding blanket. The reflecting shield should provide not only protection for the superconducting TF coil but also improved neutron economy for the tritium breeding in outboard blanket. Tungsten carbide, metal hydride such as titanium hydride and zirconium hydride can be used for improved shielding performance and thus smaller shield thickness. With the use of advanced technology in the shield, conceptual design of a compact superconducting LAR reactor with aspect ratio of less than 2 will be presented as a viable power plant.

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Neutronic investigation of waste transmutation option without partitioning and transmutation in a fusion-fission hybrid system

  • Hong, Seong Hee;Kim, Myung Hyun
    • Nuclear Engineering and Technology
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    • v.50 no.7
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    • pp.1060-1067
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    • 2018
  • A feasibility of reusing option of spent nuclear fuel in a fusion-fission hybrid system without partitioning was checked as an alternative option of pyro-processing with critical reactor system. Neutronic study was performed with MCNP 6.1 for this option, direct reuse of spent PWR fuel (DRUP). Various options with DRUP fuel were compared with the reference design concept; transmutation purpose blanket with (U-TRU)Zr fuel loading connected with pyro-processing. Performance parameters to be compared are transmutation performance of transuranic (TRU) nuclides, required fusion power and tritium breeding ratio (TBR). When blanket part is loaded only with DRUP, initial $k_{eff}$ level becomes too low to maintain a practical subcritical system, increasing the required fusion power. In this case, production rate of TRU nuclides exceeds the incineration rate. Design optimization is done for combining DRUP fuel with (U-TRU)Zr fuel. Reactivity swing is reduced to about 2447 pcm through fissile breeding compared to (U-TRU)Zr fuel option. Therefore, a required fusion power is reduced and tritium breeding performance is improved. However, transmutation performance with TRU nuclides especially $^{241}Am$ is degraded because of softening effect of spectrum. It is known that partitioning and transmutation should be accompanied with fusion-fission hybrid system for the effective transmutation of TRU.

Evaluation of Effects on Tritium Measurement According to HTO Type Sample Preparation Conditions (HTO 형태 시료 조제 조건에 따른 삼중수소 계측에 미치는 영향 평가)

  • An, Eun-Mi;Kim, Jung-Hoon;Lee, Hong-Yeon;Han, Sang-Jun;Kim, Bo-Gil
    • Journal of radiological science and technology
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    • v.44 no.4
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    • pp.381-387
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    • 2021
  • In this study, for the measurement of 3H(tritium) radioactivity concentration, a study was conducted on whether the type of cocktail and the material of the vial had an effect on the measurement before liquid scintillation counter measurement on HTO-type samples that had undergone physical and chemical pretreatment. As a result of the study, the efficiency according to the type of cocktail was higher in Ultima Gold LLT than Ultima Flo-AP cocktail with polyethylene (1.49%), glass (5.10%), and teflon (6.58%), respectively. Regarding the effect according to the type of vial, the efficiency and SQP(E) of both Ultima Gold LLT and Ultima Flo-AP showed the highest values in the order of teflon, polyethylene, and glass.

Tritium Concentrations of Tritiated Water Vapor and Tritiated Hydrogen in the Atmosphere in Taejon (대전지역 대기중 수증기상태 (HTO) 및 가스상태 (HT) 삼중수소의 농도)

  • Kim, C.K.;Han, M.J.;Kim, K.H.
    • Journal of Radiation Protection and Research
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    • v.22 no.2
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    • pp.97-101
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    • 1997
  • During the period of March 1995 to December 1995, tritium concentrations of tritiated water vapor (HTO) and tritiated hydrogen (HT) in the atmosphere in Taejon were measured to evaluate present background levels of tritium in the atmosphere. Air samples were collected continuously for three weeks with a sampling system for tritium in the atmosphere and were analyzed by a liquid scintillation counting system. The range of the atmospheric HTO concentrations was 3.2-36 mBq $m^{-3}$ with a mean value of 16.2 mBq $m^{-3}$. The atmospheric HTO concentrations were the highest in summer and the lowest in winter. This trend was similar to the variation of atmospheric absolute humidity. The specific activities of tritium in atmospheric water vapor in Taejon ranged from 0.62 Bq $L^{-1}$ to 3.82 Bq $L^{-1}$ with a mean value of 2.04 Bq $L^{-1}$. The atmospheric HT concentrations were in the range of 35.7 mBq $m^{-3}$ to 48.9 mBq $m^{-3}$ with a mean value of 41.1 mBq $m^{-3}$.

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