• Title/Summary/Keyword: TRITIUM

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Three-dimensional groundwater water flow in an upland area-groundwater flow analysis by steady state three-dimensional model (홍적지대에 있어서의 지하수의 3차원적 유동-3차원 정상류모델에 의한 지하수 유동해석)

  • 배상근
    • Proceedings of the Korea Water Resources Association Conference
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    • 1987.07a
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    • pp.113-122
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    • 1987
  • A numerical simulation technique of three-dimensional finite difference model is developed to study the groundwater flow system in Dcjima, an upland area which faces Kasumigaura Lake. For general perspectives of the groundwater flow system, a steady state three-dimentional model is simulated. For the sedimentary mud formations which are found in the representative formation, three situations of hydraulic conductivity are considered, representing an isotropic condition and situations where the horizontal permeability is equal to 10 times and 100times of the vertical one. The finite difference grid used in the simulation has 60x50x30=90,000 nodes. A converged solution with a tolerance of 0.001 meter of hydraulic head is set. Having determined the flow net by using a steady state three-dimensional model. the results for the three cases of hydraulic conductivity are compared with the results of tracer methods (Bae and Kayane 1987) With the aid of four representative vertical cross-sections, groundwater flow systems in the study area are assumed. Water balances for the three cases indicate very good agreement between total recharge and discharge in each case Analyses of groundwater flow system based on the tritium concentrations and water quality measurements (Bae and Kayane 1987) are confirmed by the numerical simulation and the results obtained by these two methods appeared to be in close agreement.

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Oxidative Degradation of a Drug during the Course of Diffusion Across the Skin

  • Choi, Hoo-Kyun
    • Archives of Pharmacal Research
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    • v.20 no.6
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    • pp.637-642
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    • 1997
  • Degradation of a compound with a hydroxyl group during the course of its diffusion across the skin was investigated. Based on the experimental findings of ashortened retention time of a degradant peak from post-diffusion samples and from the ability to evaporate radioactivity from such samples, it seems that during diffusion the parent compound degrades into a more hydrophilic product which is then oxidized. A tritium label at the carbon with a hydroxyl group was released as a tritiated water. When the post-diffusion samples were left open to the air allowing evaporation of water, there was a corresponding decrease in radioactivity of such samples. There was a linear relationship between the time left open and the fraction of radioactivity lost. When such samples were fractionated by HPLC, and then had their radioactivities measured by scintillation counting, two peaks wre identified. The first peak, which may be attributable to tritiated water, was eluted at the same retention time as the solvent front. The second peak eluted at the retention time of the parent compound. When the evaporation/loss of radioactivity experiment was repeated using a $^{14}C$-labeled compound there was no significant loss of radioactivity, indicating that the earlier loss with $^{3}H$-labeled compound was related to the formation and loas sof tritiated water.

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AN INVESTIGATION INTO RADIATION LEVELS ASSOCIATED WITH DISMANTLING THE KOREA RESEARCH REACTOR

  • Choi, Geun-Sik;Kim, Hee-Reyoung;Han, Moon-Hee
    • Nuclear Engineering and Technology
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    • v.42 no.4
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    • pp.468-473
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    • 2010
  • We confirmed that the dismantling of two research reactors with thermal power of $2MW_{th}$ and $100kW_{th}$, respectively, reveals no significant difference between the radiation levels of the research reactor site and the surrounding environment far away from it, from the radiation level aspect. Radiation dose and radioactivity were measured at monitoring points around the research reactor site of the Korea Atomic Energy Research Institute (KAERI) in Seoul and comparison points 0.5 km to 3.3 km from the site. To grasp trends in the radiation levels during dismantling from the end of 2002 to the end of 2007, the gamma radiation dose rate, the accumulated dose, and the radioactivity of the strontium, tritium, and gamma isotopes were statistically treated and estimated. The averages of these items between the two groups, the research reactor site and comparison points, were assessed by applying a T-test with a significance level of 0.05. P-values found by using the T-test were from 0.12 to 0.83 where the values were much higher than the significance level. As a result, no difference was observed between the radiation levels at the research reactor site and at the comparison points by this T-test. This study showed that dismantling activity of the Korea Research Reactor of the Seoul site did not expose the public or the environment to harmful levels of radiation.

TOKAMAK REACTOR SYSTEM ANALYSIS CODE FOR THE CONCEPTUAL DEVELOPMENT OF DEMO REACTOR

  • Hong, Bong-Guen;Lee, Dong-Won;In, Sang-Ryul
    • Nuclear Engineering and Technology
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    • v.40 no.1
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    • pp.87-92
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    • 2008
  • Tokamak reactor system analysis code was developed at KAERI (Korea Atomic Energy Research Institute) and is used here for the conceptual development of a DEMO reactor. In the system analysis code, prospects of the development of plasma physics and the relevant technology are included in a simple mathematical model, i.e., the overall plant power balance equation and the plasma power balance equation. This system analysis code provides satisfactory results for developing the concept of a DEMO reactor and for identifying the necessary R&D areas, both in the physics and technology areas for the realization of the concept. With this system analysis code, the performance of a DEMO reactor with a limited extension of the plasma physics and technology adopted in the ITER design. The main requirements for the DEMO reactor were selected as: 1) demonstrate tritium self-sufficiency, 2) generate net electricity, and 3) achieve a steady-state operation. It was shown that to access an operational region for higher performance, the main restrictions are presented by the divertor heat load and the steady-state operation requirements.

Special monitoring results for determination of radionuclide composition of Russian NPP atmospheric releases

  • Vasyanovich, Maxim;Vasilyev, Aleksey;Ekidin, Aleksey;Kapustin, Ivan;Kryshev, Alexander
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.1176-1179
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    • 2019
  • Measurements of activity concentrations of radionuclides in atmospheric releases were performed in 2017-2018 at vent stacks of seven Russian nuclear power plants. The selected instruments and research methods, with detection limits significantly lower than the existing detection limit of Russian NPPs routine control, allowed to reliably determine up to 26 radionuclides. Analysis of experimental data allows to determine the list of radionuclides for calculation the effective dose rates to public and the permissible annual discharge levels for each Russian NPP. Radiocarbon is determined as major contributor for the dose from the atmospheric releases of LWGR reactors - up to 98% for EGP-6 and RBMK-1000 (Smolensk NPP) reactors. For PWR reactors (VVER) radionuclides contribution to the annual dose from atmospheric releases is more complicated, but, in general, dose is formed by tritium, $^{14}C$ and noble gases. The special monitoring results with ranking of measured radionuclides according to their contribution to the effective dose makes it possible to optimize the list of controlled radionuclides in airborne releases of Russian NPPs from 94 to 8-16 for different NPPs.

Minimum detectable activity of plastic scintillator for in-situ beta measurement system in ground water

  • Choi, Woo Nyun;Lee, UkJae;Bae, Jun Woo;Kim, Hee Reyoung
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.1169-1175
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    • 2019
  • The minimum detectable activity (MDA) value was derived according to the flow rate of the sample and degree of amplification of the device by sending the sample directly from the collection site to the detection part through a pump. This method can lead to reduction in time and cost compared to the existing measurement method that uses a pre-treatment process. In this study, experiments were conducted on $^3H$ and $^{90}Sr$, which are the major pure beta-emitting radionuclides, by setting the sample flow rate and the amplification gain as factors. The MDA values were derived according to the flow rates, considering that the flow rate can affect the MDA values. There were no change in the MDA under different flow rates of 0, 600, 800, and 1000 mL/min. Therefore, it was confirmed that the flow rate may not be considered when collecting samples for monitoring in actual field. As the degree of amplification of the amplifier increased, the time required to reach the target MDA decreased. When the amplification was quadrupled, the detection efficiency increased by approximately 23.4 times, and the time to reach the MDA decreased to approximately 1/550 times. This method offers the advantage of real-time on-site monitoring.

Hydrogen Isotope Separation by using Zeolitic lmidazolate Frameworks (ZIF-11) (ZIF-11을 이용한 수소 동위원소 분리)

  • Lee, Seulji;Oh, Hyunchul
    • Korean Journal of Materials Research
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    • v.30 no.12
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    • pp.655-659
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    • 2020
  • Hydrogen isotopes (i.e. deuterium and tritium) are supplied to the tokamak in the International Thermonuclear Experimental Reactor (ITER) fuel cycle. One important part of the ITER fuel cycle is the recycling of unused fuel back to the tokamak, as almost 99 % of fuel is unburned during fusion reaction. For this, cryogenic distillation has been used in the isotope separation system (ISS) of ITER, but this technique tends to be energy-intensive and to have low selectivity (typically below 1.5 at 24 K). Recently, efficient isotope separation by porous materials has been reported in the so-called quantum sieving process. Hence, in this study, hydrogen isotope adsorption behavior is studied using chemically stable ZIF-11. At low temperature (40 K ~ 70 K), the adsorption increases and the sorption hysteresis becomes stronger as the temperature increases to 70K. Molar ratio of deuterium to hydrogen based on the isotherms shows the highest (max. 14) ratio at 50 K, confirming the possibility of use as a potential isotope separation material.

Neutronic design of pulsed neutron facility (PNF) for PGNAA studies of biological samples

  • Oh, Kyuhak
    • Nuclear Engineering and Technology
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    • v.54 no.1
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    • pp.262-268
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    • 2022
  • This paper introduces a novel concept of the pulsed neutron facility (PNF) for maximizing the production of the thermal neutrons and its application to medical use based on prompt gamma neutron activation analysis (PGNAA) using Monte Carlo simulations. The PNF consists of a compact D-T neutron generator, a graphite pile, and a detection system using Cadmium telluride (CdTe) detector arrays. The configuration of fuel pins in the graphite monolith and the design and materials for the moderating layer were studied to optimize the thermal neutron yields. Biological samples - normal and cancerous breast tissues - including chlorine, a trace element, were used to investigate the sensitivity of the characteristic γ-rays by neutron-trace material interactions and the detector responses of multiple particles. Around 90 % of neutrons emitted from a deuterium-tritium (D-T) neutron generator thermalized as they passed through the graphite stockpile. The thermal neutrons captured the chlorines in the samples, then the characteristic γ-rays with specific energy levels of 6.12, 7.80 and 8.58 MeV were emitted. Since the concentration of chlorine in the cancerous tissue is twice that in the normal tissue, the count ratio of the characteristic g-rays of the cancerous tissue over the normal tissue is approximately 2.

Corrosion behavior and mechanism of CLAM and 316L steels in flowing Pb-17Li alloy under magnetic field

  • Xiao, Zunqi;Liu, Jing;Jiang, Zhizhong;Luo, Lin;Huang, Qunying
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.1962-1971
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    • 2022
  • The liquid lead-lithium (Pb-17Li) blanket has many applications in fusion reactors due to its good tritium breeding performance, high heat transfer efficiency and safety. The compatibility of liquid Pb-17Li alloy with the structural material of blanket under magnetic field is one of the concerns. In this study, corrosion experiments China low activation martensitic (CLAM) steel and 316L steel were carried out in a forced convection Pb-17Li loop under 1.0 T magnetic field at 480 ℃ for 1000 h. The corrosion results on 316L steel showed the characteristic with a superficial porous layer resulted from selective leaching of high-soluble alloy elements and subsequent phase transformation from austenitic matrix to ferritic phase. Then the porous layers were eroded by high-velocity jet fluid. The main corrosion mechanism of CLAM steel was selective dissolution-base corrosion attack on the microstructure boundary regions and exclusively on high residual stress areas. CLAM steel performed a better corrosion resistance than that of 316L steel. The high Ni dissolution rate and the erosion of corroded layers are the main causes for the severe corrosion of 316L steel.

Administrative dose control for occupationally-exposed workers in Korean nuclear power plants

  • Kong, Tae Young;Kim, Si Young;Jung, Yoonhee;Kim, Jeong Mi;Cho, Moonhyung
    • Nuclear Engineering and Technology
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    • v.53 no.1
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    • pp.351-356
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    • 2021
  • Korean nuclear power plants (NPPs) have various radiation protection programs to attain radiation exposure as low as reasonably achievable (ALARA). In terms of ALARA, this paper provides a comprehensive overview of administrative dose control for occupationally-exposed workers in Korean NPPs. In addition to dose limits, administrative dose constraints are implemented to resolve an inequity of radiation exposure in which some individuals in NPPs receive relatively higher doses than others. Occupational dose constraints in Korean NPPs are presented in this paper with the background of how those values were determined. For pressurized water reactors, 80% and 90% of the annual average limit for an effective dose, 20 mSv/y, are set as the primary and secondary dose constraints, respectively. Pressurized heavy water reactors (PHWRs) have also established the primary and secondary dose constraints corresponding to 70% and 80% of the effective dose limit, and additional constraints for tritium concentration are provided to control internal exposure in PHWRs. Follow-up measures for exceeding these administrative dose constraints are also introduced compared to exceeding the dose limits. Finally, analysis results of dose distributions show how the implementation of administrative dose constraints impacted the occupational dose distributions in Korean NPPs during the years 2009-2018.