• Title/Summary/Keyword: TOC removal

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Evaluation of Water Quality Change by Membrane Damage to Pretreatment Process on SDI in Wastewater Reuse (하수재이용에서 전처리 막 손상에 의한 수질변화가 SDI에 미치는 영향평가)

  • Lee, Min Soo;Seo, Dongjoo;Lee, Yong-Soo;Chung, Kun Yong
    • Membrane Journal
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    • v.32 no.4
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    • pp.253-263
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    • 2022
  • This study suggests a guideline for designing unit process of wastewater reuse in terms of a maintenance of the process based on critical parameters to draw a high quality performance of RO unit. Defining the parameters was done by applying membrane integrity test (MIT) in pretreatment process utilizing lab-scale MF. SDI is utilized for judging whether permeate is suitable to RO unit. However, result said TOC concentration matching with particle count analysis is better for judging the permeate condition. When membrane test pressure (Ptest) was measured to derive log removal value in PDT, virgin state of membrane fiber was used to measure dynamic contact angle utilizing surface tension of the membrane fiber. Actually, foulant affects to the state of membrane surface, and it decreases the Ptest value along with time elapsed. Consequently, LRVDIT is also affected by Ptest value. Thus, sensitivity of direct integrity test descends with result of Ptest value change, so Ptest value should be considered not the virgin state of the membrane but its current state. Overall, this study focuses on defining design parameters suitable to MF pretreatment for RO process in wastewater reuse by assessing its impact. Therefore, utilities can acknowledge that the membrane surface condition must be considered when users conduct the direct integrity test so that Ptest and other relative parameter used to calculate LRVDIT are adequately measured.

Comparison and Management of Water Purification Efficiency of Artificial Wetland according to Inflow Water Conditions: Focusing on the Gyeongancheon Basin (유입수 조건에 따른 인공습지 수질 정화효율 비교: 경안천 유역을 중심으로)

  • Seol Jun Lee;Beomjin Eun;Jong Hwan Kim;I Song Choi;Jong-Min Oh
    • Korean Journal of Ecology and Environment
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    • v.57 no.1
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    • pp.28-38
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    • 2024
  • In this study, in order to analyze the water purification efficiency according to the influent water conditions of artificial wetlands, the purification efficiency was compared at two points where sewage treatment water flows in and one point where good effluent flows in. As a result of reviewing the results of the analysis of influent and effluent and the removal efficiency, the T-N and T-P removal efficiency was calculated at 54.7% and 77.4%, respectively, for the two points where sewage treatment water was treated, the treatment efficiency of SS 90.8%, BOD 51.1%, TOC 30.6%, T-N 38.8%, T-P 55.3% was shown. As a result, the efficiency of removing pollutants in the artificial wetland was found to be proportional to the concentration of influent water, and in order to create an efficient artificial wetland, it is judged that thorough review and management at the design stage are necessary considering that the removal efficiency of high-concentration contaminated water was high.

A Study on Optimal Packing Volume of Media in Swirl Flow Biological Fluidized Bed (선회류 생물학적 유동상의 최적 메디아 충전량에 관한 연구)

  • Choi, Doo-Hyoung;Kim, Hwan-Gi
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.2
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    • pp.331-340
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    • 2000
  • The existing two-phase biological fluidized bed has some problems such as limit of oxygen transfer and blockade of fluidized distributor. In this study, three-phase swirl flow biological fluidized bed has designed to solve the problems and to investigate its running characteristics. TOC of influent synthetic wastewater was approximately $70mg/{\ell}$. HRT of reactor was 1.6 hours. Mean particle size of sand, as packing media, was 0.397mm and packing volume was varied from $200m{\ell}/{\ell}$ to $600m{\ell}/{\ell}$ by stages in the bed. The amount of biomass and effluent water quality was throughly investigated in the bed. Showing experiment results from the above conditions, it was possible to solve the problems of existing fluidized bed and to keep DO of $3mg/{\ell}$ or more. And it was also TOC removal rate of 91 to 94 %, MLVSS of 2,360 to $3,860mg/{\ell}$, MLVSS per g-media of 8.4 to 17.3 mg/g, F/M ratio of 0.59 to $1.04kg-TOC/kg-MLVSS{\cdot}day$, biofilm thickness of $35{\sim}71{\mu}m$ and sludge productivity of 1.03 to $2.35kg-SS/m^3{\cdot}day$. Optimal conditions in this experimental were as follows.; those were biofilm thickness of approximately $54{\mu}m$. MLVSS per g-media of 13 mg and media packing volume of 350 to $400m{\ell}/{\ell}$ when F/M ratio was low, treatment efficiency was high and sludge productivity was low. Showing the media with optics microscope in this optimal condition, attached microbes such as Epistylis sp. were observed. From SEM photographs, it showed that Coccus adhere to and grow on the media surface.

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Chemical/Electro-Chemical Method for Swine Wastewater Treatment (화학적/전기화학적 방법을 이용한 돈사폐수 처리)

  • Yoon, S.J.;Jo, W.S.;Kim, C.H.;Park, J.I.;Shin, J.S.;Ra, C.S.
    • Journal of Animal Science and Technology
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    • v.45 no.4
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    • pp.641-648
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    • 2003
  • In a batch mode treatment process, which electrolyzes the wastewater after derivation of N-P crystal formation and recovery, the characteristics of pollutant removal induced with the changes of loading rate and hydraulic retention time were studied. $MgCl_2$ was used as Mg source for the formation of struvite and the molar ratio of $MgCl_2$ to $PO_4^{3-}$ in influent was 1.3. When analyzing the average treatment efficiencies and removal characteristics obtained from four separate operations (Run I, II, III, IV), removal efficiencies of PO43- was not function of its loading rate. Under a condition of sufficient aeration and Mg source provided, over 88% of $PO_4^{3-}$ was eliminated by the formation of MAP without any pH adjustment, in spite of loading rate variation. An optimum-loading rate of NH4-N to achieve high removal efficiency was approximately $100g/m^3/d$. Below that loading rate, the removal of NH4-N was proportional to the loading rate into the system, and hence stable and high removal efficiency, over 90%, was achieved. However, when the loading rate increased over that rate, removal efficiency began to drop and fluctuate. Removal efficiency of TOCs was dependant upon the hydraulic retention time ($r^2$=0.97), not upon the loading rate. Stable and high color removal (94%) was obtained with 2 days of HRT in electrolysis reactor.

Pollutant Removal and Characteristic of Floc by Alum Coagulation (응집 현상에 따른 오염물질 제거 및 입자 형태 특성: Alum을 사용한 경우)

  • Moon, Byung-Hyun;Kim, Seung-Hyun;Lee, Hyang-In
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.7
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    • pp.1263-1271
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    • 2000
  • This study investigated the floc structure and removal of turbidity and organic matter by alum coagulation. Results of this study indicated that sweep floc and charge neutralization area were shifted to more acidic region than that in the Amirtharajah's diagram. This was caused by organic matter present in the raw water. Removal regions of turbidity and organic matter were generally overlapped. However, organic matters was removed better at lower pH than turbidity. Floc structure was characterized by measuring fractal dimension and volume diameter using AIA and SALLS. SALLS method was found to be more reliable than AIA method. Floes in sweep floc region had larger size and fractal dimension than flocs in charge neutralization region. As pollutant removal increased, larger fractal dimension and size of floc were measured.

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Investigation on the products generated by the ozonation of Microcystis sp. (Microcystis sp.의 오존접촉특성 및 부산물 생성에 관한 연구)

  • Kim, Young-Ung;Son, Hee-Jong;Yu, Myung-Ho;Lee, Chun-Sik;Kim, Seong-Yun
    • Journal of Korean Society on Water Environment
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    • v.16 no.4
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    • pp.479-490
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    • 2000
  • This study investigated the removal characteristics, Microcystin decomposition and generation of by-products when aqueous Microcystis sp. is oxidized by ozone. The concentration of Microcystin (MC) in aqueous solution has been found by HPLC analysis to decrease continuously by ozonation after the initial, abrupt increase. The kinetic constant of the decomposition of MC-RR and -LR were 0.0596 and 0.0243, respectively. This means that removal efficiency of MC-RR by its oxidative decomposition is preferable compared with that of MC-LR. On the other hand, it has been found that the decomposition product, TOC, exhibits the continuous decrease in the concentration by further ozonation, while DOC and UV-254 increase temporarily until 10 minutes before the decrease. Furthermore, the GC/MSD analysis has revealed that the ozonation of Microcystis sp. for 100minutes affords five kinds of aldehydes, six kinds of alcohols, and trans-1, 2-dimethyl-cyclopropane.

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Livestock Wastewater Treatment by a Constructed Wetland (인공습지를 이용한 축산폐수의 처리)

  • Park, Jae-hong;Choi, Eui-so;Cho, Il-hyoung
    • Journal of Korean Society on Water Environment
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    • v.20 no.2
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    • pp.157-162
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    • 2004
  • Constructed wetlands are considered as an important tool for wastewater treatment, wastewater management and flooding control. In addition, one of the most promising technologies for application in many countries seems to be constructed wetlands, due to their properties such as utilization of natural processes, simple construction, operation and maintenance, process stability, cost effectiveness, etc. This study considered possibility of treatment of livestock wastewater using a constructed wetland. The removal efficiencies of $COD_{cr}$, TOC, TN, TP, SS, and color were 97.6%, 96.6%, 97.0%, 96.7%, 99.0%, and 85.6%, respectively. In particular, SS was completely removed. However, $Cl^{-}$ concentration of the constructed wetland effluent was higher than that in influent. In conclusion, constructed wetlands could be applied to livestock wastewater treatment if $Cl^{-}$ would be properly treated. Further, it needs time for stabilization to reduce the pollutants which were accumulated in soil.

Mass Cultivation of Botryococcus braunii for the Advanced Treatment of Swine Wastewater and Lipid Production in a Photobioreactor (축산폐수의 고도처리 및 지질생산을 위한 Botryococcus branuii의 대량배양)

  • 이석준;김성빈;김희식;권기석;윤병대;오희목
    • Microbiology and Biotechnology Letters
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    • v.27 no.2
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    • pp.166-171
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    • 1999
  • This study was conducted to investigate the removal rate of nitrogen and phosphorus, and lipid production from a swine wastewater by Botryococcus braunii UTEX 572 in an outdoor photobioreactor. B. braunii successfully predominated in competition with bacteria and other algae, especially Oscillatoria, which were grown spontaneously in a secondary-treated swine wastewater, under the conditions of incubation temperature at $25^{\circ}C$ and increased inoculum amount at 287mg/l. There was a significant relationship between dry weight of B. braunii and absorbance of culture solution at 680mn(r2=0.967), suggesting that the latter is as good as the former commonly used for the measurement of algal biomass which is considerably time-consuming. The removal rates of COD, TOC, total nitrogen, and total phosphorus from the swine wastewater were 33.2$\pm$2.6% and 32.8$\pm$3.2, respectively, which showing no different between them. These results suggested that the mass cultivation of B. braunii in an outdoor photobioreactor could be used for the advanced treatment of swine wastewater and lipid production.

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Radiation Treatment of Terephthalic Acid and Ethylene Glycol by using Gamma-rays (감마선을 이용한 테레프탈산과 에틸렌글리콜의 방사선처리)

  • Lee, Sun-Mi;Jo, Hun-Je;Kim, Jeong-Gyu;Jung, Jinho
    • Journal of Korean Society on Water Environment
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    • v.20 no.5
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    • pp.452-456
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    • 2004
  • Gamma-rays effectively decomposed TPA and EG, thus removal of $1.0{\times}10^{-3}$ M pollutants was near 65 and 95%, respectively, at an absorbed dose of 10 kGy. However, TOC removal in the radiation treatment was less than 5% due to a low transformation of both TPA and EG to $CO_2$. For TPA, gamma-ray treatment largely reduced biodegradability($BOD_5/COD$) by degrading TPA to non-biodegradable organic acids. This implies that the change of biodegradability should be considered when the radiation treatment is combined with conventional biological techniques. A weight-loss wastewater containing TPA and EG was also purified by gamma-ray treatment. Extraordinarily, biodegradability of the wastewater was increased at a low dose of 1 kGy. Though underlying mechanism was not clearly identified, this result stresses the effect of wastewater composition and absorbed dose on the biodegradability change.

Synthesis of N-doped Titania using Ammonium Hydroxide and Photocatalytic Degradation of Humic Acid (암모니아수를 이용한 N-doped TiO2 제조 및 부식산의 광촉매 분해)

  • Cho, A-Young;Nam, Yun-Seon;Rhee, Dong-Seok
    • Journal of Industrial Technology
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    • v.32 no.A
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    • pp.95-102
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    • 2012
  • To advance luminance efficiency of Titania at visible range, N-doped $TiO_2$ was prepared by using ammonium hydroxide as a source of nitrogen. The photoactivities of the synthesized $TiO_2$ were evaluated on the basis of degradation of humic acid in aqueous solutions with different light sources, UV-C, UV-A and fluorescent lamp. As a result, at UV-C is high efficiency $UV_{254}$ decrease and TOC removal. In this study, the best synthetic conditions of N-doped $TiO_2$ were 5.0 M of ammonium hydroxide concentration and calcination temperature of $550^{\circ}C$. The degradation rate of humic acid as an evaluation of photoactivities of the catalysts were conducted with pH variation, decrease rate of molecular absorption, removal rate of total organic carbon and fluorescece evolution for humic acid solution. XRD and SEM were applied for analysis of surface analysis of the catalysts.

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