• Korean Chemical Engineering Research
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• v.48 no.2
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• pp.259-267
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• 2010

The catalytic wet oxidations of the wastewater containing azo dye Reactive Black 5(RB5) with heterogeneous catalyst of CuO have been carried out to investigate the effects of temperature($190{\sim}230^{\circ}C$) and catalyst concentration(0.00~0.20 g/l) on the removals of colour and total organic carbon TOC. The wastewater colour was measured with spectrophotometer, and the oxidation rate was estimated with TOC. About 90% of colour was removed during 120 min in thermal degradation of the RB5 wastewater at $230^{\circ}C$, while TOC was not removed at all. As increasing reaction temperature and catalyst concentration, the removal rates of colour and TOC increased in the catalytic wet oxidations of RB5 wastewater. The effects of catalyst were already considerable even at 0.01 g CuO/l, while the removal rates of colour and TOC increased negligibly with increasing the catalyst concentration above 0.05 g CuO/l. The initial destruction rates of the wastewater colour have shown the first-order kinetics with respect to the wastewater colour. TOC changes during catalytic wet oxidations have been well described with the global model, in which the easily degradable TOC was distinguished from non-degradable TOC of the wastewater. The impacts of reaction temperature on the destruction rate of the wastewater colour and TOC could be described with Arrhenius relationship. Activation energies of the colour removal reaction in thermal degradation, wet oxidation, and catalytic wet oxidation(0.20 g CuO/l) of the RB5 wastewater were 108.4, 78.3 and 74.1 kJ/mol, respectively. The selectivity of wastewater TOC into the non-degradable intermediates relative to the end products in the catalytic wet oxidations of RB5 wastewater was higher compared to that in phenol wet oxidations.

• Journal of the Korean GEO-environmental Society
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• v.18 no.4
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• pp.23-29
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• 2017

As the Enforcement Ordinance of Environmental Policy Act was revised in 2013, Total Organic Carbon (TOC) was added as an indicative parameter for organic matter in Water and Aquatic Ecosystem Environmental Criteria. Under these imminent circumstances, a regulatory standard is needed to achieve the proposed TOC limitation control water quality from the STP (Sewage Treatment Plant). In this study, a electrolysis utilizing the electrochemical reaction was investigated in lab-scale experiments for the treatment of TOC in sewage effluent. TOC reduction by a electrolysis was investigated response surface methodology using the Box-Begnken methods were applied to the experimental results. A central composite design was used to investigate the effects of the independent variables of electrode space ($x_1$), current density ($x_2$) and electrolyte concentration ($x_3$) on the dependent variables removal efficiency of TOC (y). The optimal conditions for electrolysis were determined: electrode space, current density and electrolyte concentration were 50 mm, $10.3mA/cm^2$ and 0.1M, respectively. Statistical results showed the order of significance of the independent variables to be electrode space > current density > electrolyte concentration.

• Journal of Korean Society on Water Environment
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• v.33 no.2
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• pp.203-210
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• 2017

This study was performed to verify the replacement of COD to TOC, which is more accurate and reliable in analysis, as the water quality pollution index and to investigate the characteristics of water quality and the correlations for organic matter, suspended solids and nutrient materials during 2012 to 2015. The oxidation rates were compared by calculating the values of BOD-C/TOC & COD-C/TOC. The average value of TOC was 3.4(1.1 ~ 8.0) mg/L at 14 sites during the period. The ratios of BOD-C/TOC and COD-C/TOC, that mean the resolvability amounts among all carbon materials, were 28.8% and 62.7%, respectively. The correlation coefficient of TOC to COD at all sites was 0.718 (p<0.01), the highest value in comparing all items. The correlation coefficient of TOC to COD at Gwangju stream was 0.753 (p<0.01), the highest compare to the values at other rivers. The correlation coefficient of TOC to COD was 0.757 (p<0.01) at all sites in the range of TP-III ($0.1{\leq}TP$) and the value was 0.762 (p<0.01) in the range of TN-II ($2.0{\leq}TN$<3.0). As a result, TOC could be used as a water pollution index of organic matter instead of COD.

• Korean Journal of Food Science and Technology
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• v.20 no.4
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• pp.563-568
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• 1988

Relative effectiveness of antioxidants with their synergists was investigated by measuring AOM stability of palm oil and beef tallow during heating. TBHQ added at a concentration of 0.02% gave the highest AOM stability to palm oil among the antioxidants tested at the equivalent concentration. Beef tallow with added TBHQ showed a higher AOM stability than those with α-tocopherol$({\alpha}-toc)$ and a mixture of BHA and BHT, but showed a lower AOM stability than those with {$\delta}-rich$ tocopherol$({\delta}-toc)$ and mixed tocopherol(m-toc). Addition of ${\alpha}-toc$ to palm oil and beef tallow increased the AOM stability less than a mixture of BHA and BHT. Palm oil and beef tallow with added ${\delta}-toc$ and m-toc showed higher AOM stabilities than that with ${\alpha}-toc$, and there was no significant difference in AOM stability noted between ${\delta}-toc$ and m-toc. The synergistic effects of citric acid to ${\alpha}-toc\;and\;{\delta}-toc$ and of ascorbyl palmitate to ${\delta}-toc$ was noted higher in beef tallow than in palm oil, while that of ascorbyl palmitate to ${\alpha}-toc$ was higher in palm oil than in beef tallow.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.27 no.1
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• pp.103-108
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• 2004

Companies adopted a program called Six Sigma, in order to make fundamental changes in the way the company operated to fulfill customers' expectations. Six Sigma reduces the occurrence of defects. This approach derives the overall process of selection the right projects based on their potential to improve performance metrics and selection and training the right people to get the business results. However, in the course of Six Sigma process steps, companies are in the face of problems. This study is to solve the problems using TOC(Theory of Constrains). TOC is methodology for solving key problem in system which is called Constraints. Nowadays, its application is going to be wide and its concept is being implemented. In this paper, it is showed possibility of application TOC to Six Sigma.

• Journal of Korean Society for Quality Management
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• v.32 no.2
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• pp.154-167
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• 2004

The TOC/DBR and Six Sigma are the most attention-getting concepts for managing manufacturing companies in Korea. Using the ideas and methods of the TOC/DBR, companies can achieve a large reduction of work-in-process and finished-good inventories, significant improvement in scheduling performance, and substantial earnings increase. The Six Sigma approach derives the overall process of selecting the right projects based on their potential to improve performance metrics and selecting/training the right people to get the business results. These two concepts have different backgrounds and different viewpoints for production systems. So, if the two concepts collaborate each other, the synergy effects to innovate production systems can be expected. This paper proposes a new approach to implement the TOC/DBR concepts in production systems. This approach uses some concepts of Six Sigma which stresses educations, project approaches (step by step procedure using a Roadmap), and improvement philosophy.

• Journal of the Korea Safety Management & Science
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• v.7 no.3
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• pp.121-135
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• 2005

The TOC and Six Sigma are the most attention-getting concepts for managing manufacturing companies. Using the ideas and methods of the TOC, companies can achieve a large reduction of work-in-process and finished good inventories, significant improvement in scheduling performance, and substantial earnings increase. The six sigma approach derives the overall process of selecting the right project based on their potential to improve performance metrics and selecting and training the right people to get the business results. These two concepts have different backgrounds and different viewpoints for production systems. so, if the two concepts integrate each other, the synergy effects to innovate production systems can be expected. The purpose of this paper suggest that integration strategy between Six Sigma and TOC for profit maximization.

• Journal of the Korea Safety Management & Science
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• v.19 no.4
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• pp.291-299
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• 2017

Recently, many business and government organizations have benefitted by executing projects using TOC-CCPM(Theory of Constraints-Critical Chain Project Management). In parallel, Earned Value Management(EVM) metrics have also become popular. Many organizations like US government requires that all large projects measure and report project progress status using EVM. Thus, project management in business fields such as plant construction, IT development, ship building need to integrate TOC-CCPM and EVM in oder to keep and reduce the delivery date of projects for improvement of customer satisfaction and enlargement of business opportunity. This paper proposes the scheme and case of developing the Synchro-EVM system which TOC-CCPM and EVM are connected.

• Korean Journal of Ecology and Environment
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• v.40 no.2
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• pp.193-200
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• 2007

The objective of this study was to estimate uncertainty of online TOC analyzer in water quality monitoring system. A procedure for the estimation of measurement uncertainty of total organic compounds (TOC) based on the ISO approach is presented. It is based on a mathematical model that involves 4 input parameters (standardization, sensitivity, solute effect and representativeness). In this study, a major problem in estimating the uncertainty of online TOC analyzer was the solute effect. It was strongly depends on organic materials. So homogeneity of the sample is the most important consideration. Modified concentration and combined standard uncertainty was $4.71{\pm}0.36$ mg $L^{-1}$ by model modified in this study.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.3
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• pp.2321-2327
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• 2015

Three coagulants, alum sulfate(alum), poly aluminum chloride(PAC) and poly aluminum silicate chloride (PASC), were used to remove low to high turbidity and TOC in surface and ground blended water. Laboratory experiments and pilot plant experiments were carried out to evaluate the optimal coagulant and its dosage. To determine the optimized coagulant and its dosage, the turbidity, TOC and pH were measured. The experimental results showed the best removal performance using PASC. The optimal dosage of PASC between 3-20 NTU was found to be 15 mg/L in the jar test. In the pilot test, a 15 mg/L PASC dosage was applied and resulted in the efficient removal of turbidity and TOC between 3.6-27 NTU. The removal efficiency of PASC increased with increasing turbidity and TOC.