• Journal of the Korean GEO-environmental Society
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• v.11 no.2
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• pp.33-42
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• 2010

The main objective of this study was to offer informations about the current conditions of stream sediments and to evaluate biochemical methane potentials of stream sediments from the urban streams in Busan city using conventional BMP tests. First we select total 5 urban streams and collect sediment samples. Then, COD, proximate analysis, volatile solid, organic carbon content and elemental analysis were conducted to determine characteristics of the sediments. Results show that COD, volatile solid and organic carbon content are determined in the range of $15.20{\sim}75.07mg\;g^{-1}$, 2.34~11.54% and 1.28~34.21%, respectively. Also, several biochemical methane potential tests were performed in a laboratory. As a result, pH values of the reactors generally increased and then stabilized at 7.11~7.35. In addition, C/N ratio, ultimate methane and carbon dioxide yield (mL/g VS) and biodegradability (%) were determined to 1.05~10.27, 10.1~179.4, 10.3~34.4 and 4.0~30.1, respectively. For the determination of the correlations between ultimate methane yield and ultimate carbon dioxide yield, C/N ratio, COD, volatile solid and organic carbon content, a linear model was fitted to the data using a least-squares algorithm. As a result, except for COD ($r^2=0.7586$) and volatile solid ($r^2=0.7876$), Linear model was well fitted to each data with good values of the correlation coefficient ($r^2=0.9795{\sim}0.9858$). Finally, we propose empirical equations, which contain C/N ratio or TOC, for the prediction of ultimate methane yield for the urban streams in Busan city.

• Korean Journal of Ecology and Environment
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• v.55 no.2
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• pp.99-110
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• 2022

We investigated physicochemical properties and isotopic compositions of organic matter (δ¹³C_TOC and δ ¹⁵N_TN) in the old fish farming (OFF) site after the cessation of aquaculture farming. Based on this approach, our objective is to determine the organic matter origin and their relative contributions preserved at sediments of fish farming. Temporal and spatial distribution of particulate and sinking organic matter(OFF sites: 2.0 to 3.3 mg L^-1 for particulate matter concentration, 18.8 to 246.6 g m^-2 day^-1 for sinking organic matter rate, control sites: 2.0 to 3.5 mg L^-1 for particulate matter concentration, 25.5 to 129.4 g m^-2 day^-1 for sinking organic matter rate) between both sites showed significant difference along seasonal precipitations. In contrast to variations of δ¹³C_TOC and δ¹⁵N_TN values at water columns, these isotopic compositions (OFF sites: -21.5‰ to -20.4‰ for δ¹³ C_TOC, 6.0‰ to 7.6‰ for δ¹⁵N_TN, control sites: -21.6‰ to -21.0‰ for δ¹³C_TOC, 6.6‰ to 8.0‰ for δ¹⁵N_TN) investigated at sediments have distinctive isotopic patterns(p<0.05) for seawater-derived nitrogen sources, indicating the increased input of aquaculture-derived sources (e.g., fish fecal). With respect to past fish farming activities, representative sources(e.g., fish fecal and algae) between both sites showed significant difference (p<0.05), confirming predominant contribution (55.9±4.6%) of fish fecal within OFF sites. Thus, our results may determine specific controlling factor for sustainable use of fish farming sites by estimating the discriminative contributions of organic matter between both sites.

• Journal of environmental and Sanitary engineering
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• v.20 no.3 s.57
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• pp.36-43
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• 2005

Prior to the study of the sewage treatment methods, water quality for Gwangju sewage of fluent was investigated from January to December, 2004 for sewage water reuse. Monthly mean values of BOD, SS, turbidity, total phosphorus and color were 4.1 mg/L, 2.9 mg/L, 0.8 NTU, 1.3 mg/L, and 27 unit, respectively. Jar-test was performed to investigate the removal efficiency of pollutants under the coagulation conditions of fast mixing for 5 min, slow mixing for 15 min and precipitation for 1hr. Here, alum and polyaluminium chloride (PAC) were used as coagulants to reduce color, turbidity, total phosphorus (TP) and total organic carbon (TOC) in sewage effluents. The results showed that PAC gave better efficiency in removing turbidity and dissolved phosphorus than alum. It was also found from the relative molecular weight (RMW) distribution analysis that organic matter over 1,000 Dalton (Da) was easily removed by coagulation and subsequently MF treatment, while it was not effective for less than 500 Da. Based on tis result, Natural organic matter (NOM) with lower molecular weight (< 500 Da) may cause harmful disinfectant by-product (DBP) after chlorine treatment. Thus, activated carbon adsorption seems to be required for the complete removal of DBP in the hybrid system.

• Journal of Marine Life Science
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• v.8 no.2
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• pp.121-127
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• 2023

The study was performed in order to understand the association between organic matter content in the sediments and the distribution of macrobenthos in the intertidal zone of the Muan bay. The sediment samples obtained from 21 sampling sites in August 2019 were analyzed for sediment composition and organic matter content (Ignition loss; IL and Total organic carbon; TOC). Further the macro benthos was sorted and enumerated. The sediments of inner area of bay has coarser composition where mouth part of bay, the sediments were predominantly silty. The highest organic matter content (both of IL and TOC) was measured at station 10 located near the Mokpo area while the lowest values was measured at station 20 adjacent to the north side of the bay. The 4 most abundant species accounted for more than 10% of all specimens were Assiminea sp., Musculista senhousia, Cerithideopsilla cingulate and Heteromastus filiformis. The maximum number of species and density were observed at station 10. Cluster analysis and non-metric multidimensional scaling (MDS) allow identification of four benthic assemblages based on species abundance. The correlation analysis revealed that there was a significant difference (p<0.05) in the density with TOC. Based on the analysis; it was found that the distribution of macrobenthos varied with the differences in sediment composition and organic matter content.

• Journal of Environmental Science International
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• v.12 no.8
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• pp.847-852
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• 2003

It was examined carefully that the bacterial die-off between Chlorella vulgaris and E. coli. W3110 was tested through adding TOC (total organic carbon) with the lab-scaled continuous river water flow system (CRWFS). Artificial synthetic wastewater was applied at two levels of organic carbon concentration; 1,335 mg/l in treatment type 1 and 267 mg/l in type 2. In both types, the population densities of Chlorella vulgaris were similar in a maximum 8.25 ${\times}$ 10$\^$6/ cells/ml (type 1) and 6.925 ${\times}$ 10$\^$6/ cells/ml (type 2). The maximum densities of E. coli. W3110 were 2.0 ${\times}$ 10$\^$8/ colony forming unit (CFU)/ml in type 1 and 3.9 ${\times}$ 10$\^$8/ CFU/ml in type 2. The densities increased for 11 days in type 1 and 4 days in type 2, then decreased rapidly till the 35th day, then slightly increased again. This trend was prominent in type 2. It implied that a wider range of nutrients was required in the growth of heterotrophic bacteria in type 2 than in type 1. We could not expect successful bacterial die-off if the wastewater retention time was not furnished sufficiently.

• Journal of Environmental Impact Assessment
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• v.22 no.2
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• pp.171-181
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• 2013

In this study, we report the water quality characteristics of pollutants for 4 major tributaries in the Yeongsan and Sumjin river basins using statistical analysis, such as regression equation and factor analysis. The flow rate and water qualtiy data collected from 4 sampling sites(Hwangryoung A, Jiseok A, Chooryeong A, Osu A) in the Yeonsan and Sumjin river basin during the past 3 years were analyzed for 11 parameters(flow rate, dissolved oxgen, pH, water temperature, electric conductivity, biochemical oxygen demand, chemical oxygen deman, total organic carbon, total nitorgen, total phosphorus, suspended solid). The results showed that the concentrations of BOD, COD, TOC, T-N, T-P in Hwangryoung A(HW) and Jiseok A(JS) of the Yeongsan river basin were decreased as the flow rate was increased. This means that rather than nonpoint soources, point sources affect water quality. In the cases of Chooryeong A(CR) and Osu A(OS) in the Sumjin river basin, howerever, nonpoint sources than point sources are an important factor that affects the water quality. Also, the factor analysis technique was employed to analyze principal component influencing on water quality. The results revealed that the first principal component in HW was correlated with EC, DO, T-N, water temperature. This "nitrogen influx according to seasonal pattern" factor may be interpreted. In JS, the first principal component was correlated with BOD, COD, TOC and is likely to represent "organic matter" processes. In CR and OS, BOD, COD, TOC, SS and T-P were significantly correlated and is considered as representing "Organic matter and adsorption of phosphorus on sediments influx". This study is expected to contribute to the effective pollution control/management of the surfac waters in the study sites.

• Journal of the Korean Society of Marine Environment & Safety
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• v.18 no.1
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• pp.1-13
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• 2012

We measured various geochemical parameters, including the grain size, loss on ignition(LOI), total organic carbon(TOC), total nitrogen(TN), total sulfur(TS) and metallic elements, in surface sediment collected from 19 stations in Gamak Bay in April 2010 in order to understand the sedimentary types, the origin of organic matters, and the distribution patterns of alkali(Li, Na, K, Rb) and alkaline earth(Be, Mg, Ca, Sr, Ba) elements. The surface sediments were mainly composed of mud. The concentrations of Chlorophyll-a, TOC, TN, TS and LOI in sediment were the highest at the cultivation areas of fish and shellfish in the northern and southern parts of the bay. The redox potential(or oxidation-reduction potential) showed the positive value in the middle part of the bay, indicating that the surface sediment is under oxidized condition. The organic materials in sediment at almost all of stations were characterized by the autochthonous origin. Based on the overall distributions of metallic elements, it appears that the concentrations of alkali and alkaline earth elements except Ba in sediment are mainly influenced by the dilution effect of quartz. The concentrations of Sr and Ba are also dependent on the secondary factors such as the effect of calcium carbonate and the redox potential.

• Environmental Engineering Research
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• v.15 no.2
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• pp.63-70
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• 2010

In this study, the response surface method and experimental design were applied as an alternative to conventional methods for the optimization of coagulation tests. A central composite design, with 4 axial points, 4 factorial points and 5 replicates at the center point were used to build a model for predicting and optimizing the coagulation process. Mathematical model equations were derived by computer simulation programming with a least squares method using the Minitab 15 software. In these equations, the removal efficiencies of turbidity and total organic carbon (TOC) were expressed as second-order functions of two factors, such as alum dose and coagulation pH. Statistical checks (ANOVA table, $R^2$ and $R^2_{adj}$ value, model lack of fit test, and p value) indicated that the model was adequate for representing the experimental data. The p values showed that the quadratic effects of alum dose and coagulation pH were highly significant. In other words, these two factors had an important impact on the turbidity and TOC of treated water. To gain a better understanding of the two variables for optimal coagulation performance, the model was presented as both 3-D response surface and 2-D contour graphs. As a compromise for the simultaneously removal of maximum amounts of 92.5% turbidity and 39.5% TOC, the optimum conditions were found with 44 mg/L alum at pH 7.6. The predicted response from the model showed close agreement with the experimental data ($R^2$ values of 90.63% and 91.43% for turbidity removal and TOC removal, respectively), which demonstrates the effectiveness of this approach in achieving good predictions, while minimizing the number of experiments required.

• Korean Journal of Ecology and Environment
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• v.43 no.2
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• pp.338-344
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• 2010

The automatic water quality monitoring system (AWQMS) have been installed to immediately response to any pollution incident. It also make it possible to conduct the task efficiently regarding water quality control. The purpose of this study is to enhance reliability by securing accuracy of automatic water quality data through quality assessment (QA) for temperature, pH, dissolved oxygen (DO), electric conductivity (EC), total organic carbon (TOC). The result of comparison between manual and automatic data, relative accuracy of general items (temperature, pH, EC, DO) and TOC were mostly satisfied with guideline (i.e. less than 20%). On the other hand, relative accuracy of DO between sampling site and housing site was somewhat against the guideline. The contamination by attaching algae and microorganism in the pipeline is considered as main cause. After backwashing the pipeline, DO concentration was increased up to 53%. Therefore, pipeline management is recognizable as important thing to secure reliability of water quality data.

• Korean Journal of Ecology and Environment
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• v.48 no.1
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• pp.12-25
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• 2015

The tributaries of Daechung Lake play an important role in controlling eutrophication in the lake, which is used for agricultural purposes and as potable water. However, water quality properties were not extensively studied in the tributaries of Daechung Lake. The objectives of this study are to investigate spatial and temporal properties of water quality and to characterize streams which could threaten water quality of Daechung Lake. For this study, water samples were weekly or monthly collected from February 2014 to October 2014 in 9 streams. Water quality parameters analyzed in this study include biochemical oxygen demand (BOD), chemical oxygen demand (COD), total organic carbon (TOC), total nitrogen and phosphorus (TN and TP), suspended solids (SS), and chlorophyll a. Based on temporal distribution and principal component analysis, BOD, COD, TOC, SS, and TP were controlled by not only river discharge that increased during summer due to heavy rain fall, but also due to anthropogenic input (e.g., bridge construction and/or agricultural activity). Dilution is also one of the factors explaining TN and conductivity, both of which decreased with increased discharge. Generally, concentrations of contaminants (BOD, COD, TOC, TN and TP) in the tributaries were higher than those of Daechung Lake. However, pollution load indicated that only the main channel of Geum River and Sook Stream may largely influence lake waters, attributed mostly to their large volumes. This implies that the main channel and Sook Stream are the major influences on the water quality of Daechung Lake.