• Title/Summary/Keyword: TOC(total organic carbon)

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Seasonal changes in soil acidity and related properties in ginseng artificial bed soils under a plastic shade

  • You, Jiangfeng;Liu, Xing;Zhang, Bo;Xie, Zhongkai;Hou, Zhiguang;Yang, Zhenming
    • Journal of Ginseng Research
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    • v.39 no.1
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    • pp.81-88
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    • 2015
  • Background: In Changbai Mountains, Panax ginseng (ginseng) was cultivated in a mixture of the humus and albic horizons of albic luvisol in a raised garden with plastic shade. This study aimed to evaluate the impact of ginseng planting on soil characteristics. Methods: The mixed-bed soils were seasonally collected at intervals of 0-5 cm, 5-10 cm, and 10-15 cm for different-aged ginsengs. Soil physico-chemical characteristics were studied using general methods. Aluminum was extracted from the soil solids with $NH_4Cl $(exchangeable Al) and Na-pyrophosphate (organic Al) and was measured with an atomic absorption spectrophotometer. Results: A remarkable decrease in the pH, concentrations of exchangeable calcium, $NH_4^+$, total organic carbon (TOC), and organic Al, as well as a pronounced increase in the bulk density were observed in the different-aged ginseng soils from one spring to the next. The decrease in pH in the ginseng soils was positively correlated with the $NH_4^+$ (r=0.463, p<0.01), exchangeable calcium (r=0.325, p<0.01) and TOC (r= 0.292, p < 0.05) concentrations. The $NO_3^-$ showed remarkable surface accumulation (0-5 cm) in the summer and even more in the autumn but declined considerably the next spring. The exchangeable Al fluctuated from $0.10mg\;g^{-1}$ to $0.50mg\;g^{-1}$ for dry soils, which was positively correlated with the $NO_3^-$ (r=0.401, p < 0.01) and negatively correlated with the TOC (r=-0.329, p < 0.05). The Al saturation varied from 10% to 41% and was higher in the summer and autumn, especially in the 0-5 cmand 5-10 cm layers. Conclusion: Taken together, our study revealed a seasonal shift in soil characteristics in ginseng beds with plastic shade.

Methane Gas Emission from an Artificial Reservoir under Asian Monsoon Climate Conditions, with a Focus on the Ebullition Pathway (아시아 몬순 기후지역에 위치한 대형 인공호에서 기포형태로의 메탄 (CH4) 가스 배출량)

  • Kim, Kiyong;Jung, Sungmin;Choi, Youngsoon;Peiffer, Stefan;Knorr, Klaus-Holger;Kim, Bomchul
    • Korean Journal of Ecology and Environment
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    • v.51 no.2
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    • pp.160-167
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    • 2018
  • The role played by reservoirs in the biogeochemical cycles of elements is a subject of ongoing debate. Recent research has revealed that reservoirs emit significant levels of greenhouse gases. To assess the importance of reservoirs in monsoon climate areas as a source of methane gas into the atmosphere, we investigated variations in organic carbon (OC) input into the reservoir, oxic state changes, and finally the amount of methane emitted (focusing on the ebullition pathway) in Lake Soyang, which is the largest reservoir in South Korea. Total organic carbon (TOC) concentrations were higher during summer after two years of heavy rainfall. The sedimentation rates of particulate organic carbon (POC) and particulate organic nitrogen (PON) were higher in the epilimnion and hypolimnion than the metalimnioin, indicating that autochthonous and allochthonous carbon made separate contributions to the TOC. During stratification, oxygen depletion occurred in the hypolimnion due to the decomposition of organic matter. Under these conditions, $H_2S$ and $CH_4$ can be released from sediment. The methane emissions from the reservoir were much higher than from other natural lakes. However, the temporal and spatial variations of methane ebullition were huge, and were clearly dependent on many factors. Therefore, more research via a well-organized field campaign is needed to investigate methane emissions.

Real Time Water Quality Forecasting at Dalchun Using Nonlinear Stochastic Model (추계학적 비선형 모형을 이용한 달천의 실시간 수질예측)

  • Yeon, In-sung;Cho, Yong-jin;Kim, Geon-heung
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.6
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    • pp.738-748
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    • 2005
  • Considering pollution source is transferred by discharge, it is very important to analyze the correlation between discharge and water quality. And temperature also influent to the water quality. In this paper, it is used water quality data that was measured DO (Dissolved Oxygen), TOC (Total Organic Carbon), TN (Total Nitrogen), TP (Total Phosphorus) at Dalchun real time monitoring stations in Namhan river. These characteristics were analyzed with the water quality of rainy and nonrainy periods. Input data of the water quality forecasting models that they were constructed by neural network and neuro-fuzzy was chosen as the reasonable data, and water quality forecasting models were applied. LMNN (Levenberg-Marquardt Neural Network), MDNN (MoDular Neural Network), and ANFIS (Adaptive Neuro-Fuzzy Inference System) models have achieved the highest overall accuracy of TOC data. LMNN and MDNN model which are applied for DO, TN, TP forecasting shows better results than ANFIS. MDNN model shows the lowest estimation error when using daily time, which is qualitative data trained with quantitative data. If some data has periodical properties, it seems effective using qualitative data to forecast.

A Study on Formation Pattern of DBPs by Disinfection of Drinking Raw Water II (음용 원수의 염소소독에 의한 소독부산물 생성패턴에 관한 연구 II)

  • Lee, Kang Jin;Hong, Jee Eun;Pyo, Heesoo;Park, Song-Ja;Yoo, Je Kang;Lee, Dae Woon
    • Analytical Science and Technology
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    • v.17 no.1
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    • pp.69-81
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    • 2004
  • The formation pattern of DBPs (disinfection by-products) in raw water treated with hypochlorite, chlorine disinfectant was studied. TOC (total organic carbon), residual chlorine, turbidity and 14 DBPs in raw water from Han-river and Nakdong river during 1 ~ 14 days were determined. Total DBPs in Han river was 101.3 ng/mL (789.6 nM) after 7days and THMs (trihalomethanes) are the dominant portion of 68%. HAAs (haloacetic acids) and chloral hydrate were determined 19% and 10% respectively. In Nakdong river total DBPs was 98.4 ng/mL (678.6 nM) and dominant class was HAAs. (55.8 ng/mL, 57%) THMs(34%) and N-compounds like HANs (haloacetonitriles, 5%) and chloropicrin were increased. It may be explained that high concentration of NH4-N in Nakdong river react with chlorine produced chloramine and this formed different pattern of DBPs. As a result, total DBPs formation pattern depends on raw water and disinfectant and in generally the initial concentration of acidic HAAs was high and THMs was increased gradually.

Seven-Parameter Log Linear Model for Estimating Constituent Loads in Nakdong River (7변수 대수선형모형을 이용한 낙동강 오염부하량 추정)

  • Lee, A-Yeon;Choi, Dae-Gyu;Kim, Sang-Dan
    • Proceedings of the Korea Water Resources Association Conference
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    • 2010.05a
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    • pp.1400-1404
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    • 2010
  • In this study the flow duration curves and load duration curves for Nakdong river basin are analyzed. The TANK model is used as s hydrologic simulation model whose parameters are estimated from 8-days intervals flow data measured by Nakdong River Water Environment Laboratory. also in this study a Minimum Variance Unbiased Estimator(MVUE) is confirmed that it provides satisfactory load estimate. The Seven-Parameter Log Linear Model for estimating Total Organic Carbon(TOC) and Biochemical Oxygen Demand(BOD) loads in Nakdong river using a MVUE.

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Removal of Total Organic Carbon and Micropollutants in Tertiary Treated Sewage by Medium Pressure UV/H2O2 (중압 자외선과 과산화수소 공정을 이용한 하수 3차 처리수중 총유기탄소와 미량오염물질 제거)

  • Lee, Jai-Yeop;Kim, Ilho
    • Journal of Korean Society on Water Environment
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    • v.36 no.4
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    • pp.314-321
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    • 2020
  • This study evaluated the applicability of UV-AOP process using medium-pressure UV lamp and H2O2 to remove TOC and emerging micropollutants in the effluent from a sewage treatment plant. The UV lamp with higher output(1.6~8.0 kW) showed slightly higher amount of power in removing TOC of 1 mg/L(0.09 kWh/mg/L~0.11 kWh/mg/L), however it was found that there was no significant difference for each cases. In addition, under the condition that the H2O2 concentration is sufficient, as the power consumption of the UV lamp increases, the unit TOC removal concentration per unit H2O2 decomposition concentration also increases, resulting in effective removal of TOC. The removal rate of 7 new trace contaminants, such as antibiotics by the UV-AOP tested, was at least 89.4%, and the ability to remove the emerging micro pollutants in the process was very effective. But, it was judged that it could not be excluded that the probablity of transforming to oxidated by-product in the case of a low TOC removal efficiency. Depending on the operating conditions of the UV and H2O2 processes, a higher BOD concentration is found in the treated water than in the influent, and it is necessary to review the UV power and proper injection conditions of H2O2 to maintain the BOD concentration increase below a certain level.

Evaluation of Attainment Ratio on Water Quality Goal of the Mid-watershed Representative Station (중권역 대표지점의 목표수질 달성도 평가 - TOC를 중심으로 -)

  • Lee, Jaeho;Lee, Seunghyun;Lee, Soohyung;Lee, Jaekwan
    • Journal of Korean Society on Water Environment
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    • v.33 no.5
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    • pp.525-530
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    • 2017
  • The attainment ratios of the water quality goals of the 114 mid-watershed representative stations, examined during the period2011 to 2015, were evaluated in the study. Of the four major river basins, the attainment ratio on water quality goal of the Geum River basin turned out to be the lowest. As a result of formal evaluation of the attainment ratios of BOD, COD and TOC, it was found that the attainment ratio of COD was much lower than that of BOD and TOC (I a circumstance thought to be caused by the higher COD/BOD and COD/TOC ratios of the water quality of the river than those of the environmental water quality standard). As well, higher COD/BOD and COD/TOC of wastewater discharged from point and non-point sources (other than those of the environmental water quality standards) might possibly represent one of the reasons. We also compared attainment ratio between the main stream and tributaries, which indicated that the higher attainment ratio was present in the main stream. The attainment ratio is also documented as more significant in the winter season than the summer season, possibly due to the contribution of non-point pollutants swept in by rain during the summer season during documented periods of high precipitation. Thus, water quality management in summer season and improvement of water quality of the tributaries might be important as a means of increasing attainment ratio on water quality goal.

Estimating BOD, CDO and TOC Hydrologic Flux in Nakdong River Basin (낙동강 유역 BOD, COD 및 TOC의 수문학적 플럭스 추정)

  • Lee, A-Yeon;Park, Moo-Jong;Jo, Deok-Jun;Kim, Sang-Dan
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.9
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    • pp.830-839
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    • 2010
  • This study presents a constituent load estimating procedure that can be operated with the present Korean TMDL monitoring system. The modified TANK model is used as a daily river flow simulation model whose parameters are estimated from 8-day intervals flow data. Constituent loads are estimated with the 7-parameter log linear model whose parameters are estimated by the minimum variance unbiased estimator. Results from Nakdong river basin reveals that the proposed procedure provides satisfactory TOC and BOD load estimates. As an application, a representative load duration curve is derived for working out a way to represent the overall hydrologic flux of BOD, COD and TOC at Nakdong river basin. The present water quality can be checked stochastically by Load Duration Curve through this study and presented visually.

Characteristics of Surficial Sediment and Benthic Environments Based on Geochemical Data in Gwangyang Bay, Korea (지화학적 자료에 근거한 광양만 표층퇴적물의 특성과 저서환경)

  • 현상민;팽우현;이태희
    • Korean Journal of Environmental Biology
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    • v.22
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    • pp.93-102
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    • 2004
  • A total of 110 surface sediment were analyzed in order to understand the geochemical eharacteristics of the surface sediments and to evaluate the benthic environmental condition of Gwangyang Bay. The surface sedimentary distribution can be classified by five facies; mud (M), sandy mud (sM), sand (S), muddy sand (mS) and gravely sand mud ((g)sM). However, mud face is the predominant sedimentary feature of the Gwangyang Bay. The benthic environment based on total organic carbon/total nitrogen (C/N) and total organic carbon/total sulfur (C/S) ratios of organic matter showed that anoxic environment is prevailed in some parts of the study area because the C/S ratio of organic matter was higher than 2.8. The hydrogen sulfide (H$_2$S) content showed extreme variability from site to site. It varies from 307 ppm to 1 ppm (average, 92 ppm). The inter-relationship of redox-sensitive elements (Mn, V, Mo and Cr) showed a relatively strong positive relationship with high accumulation in the sediment at the inner sites of the Bay (left of Myo Island). High content of TOC and hydrogen sulfide, and a high accumulation rate of redox- sensitive element were predominant characteristics in the sediments at the inner sites of the Bay (left of Myo Island), suggesting that this area is in an oxygen deficient, and potentially polluted condition.

Distribution and Pollution Status of Organic Matter and Heavy Metals in Surface Sediment Around Goseong Bay, a Shellfish Farming Area, Korea (패류양식해역인 고성만 주변 표층 퇴적물의 유기물과 중금속 분포 및 오염현황)

  • Lee, Garam;Hwang, Dong-Woon;Hwang, Hyunjin;Park, Jung-Hyun;Kim, Hyung-Chul;Kwon, Jung-No
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.6
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    • pp.699-709
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    • 2017
  • We measured the grain size, total organic carbon (TOC), total nitrogen (TN), and heavy metals (As, Cd, Cr, Cu, Fe, Hg, Mn, Pb, and Zn) in order to understand the spatial distribution and pollution level of organic matter and metals in surface sediment around Goseong Bay, a shellfish farming area, Korea. The surface sediments were composed of finer sediments such as mud and clay. The concentration of TOC, TN, and heavy metals were much higher in the innermost bay than in the mouth and outside of bay. The spatial distribution of organic matter and heavy metals and C/N ratio (5-10) in sediment showed that the organic matter and heavy metals in sediment of the study region were significantly influenced by oceanic origin organic matter and anthropogenic sources, respectively. Based on the results of four assessment techniques (sediment quality guideline, geoaccumulation index, pollution load index, ecological risk index), the sediments around the Goseong Bay were a little polluted for heavy metals and the high metal concentrations in the northern region of bay could adverse impact on benthic organisms in sediment. Thus, the systematic management plan for the improvement of water and sediment environment and the concentrated monitoring of pollutants for sustainable aquaculture and seafood safety around Goseong Bay are necessary in the future.