• Journal of Ecology and Environment
• /
• v.43 no.1
• /
• pp.22-30
• /
• 2019

Background: Piton du Milieu (PdM) impounding reservoir is suspected to be eutrophic based on the elevated level of orthophosphate and nitrate. Water supplies from three adjacent rivers are primarily thought to contribute to the nutrient enrichment of the reservoir. It is also suspected that there is leaching of orthophosphate, nitrate and organic matter into the rivers during rainfall events and also as a result of anthropogenic activities within the catchment area. The aim of this study was to ascertain the impact of nutrient loading on the water quality of PdM water and on the population of freshwater microalgae in the reservoir. The enumeration and identification of algae from PdM were performed by differential interference contrast microscopy. Dissolved oxygen (DO) and pH were determined by electrometric methods, whereas nutrient levels, silica and total organic carbon (TOC) were determined by instrumentation techniques. Results: Annual mean orthophosphate, nitrate and total organic carbon input from the three feeders within the catchment area of PdM reached levels as high as 0.09 mg/L, 0.4 mg/L and 2.62 ppm respectively. Over a 12-month period, mean TOC concentration in the reservoir was 2.32 ppm while the mean algal cell count was 4601 cells/mL. The dominant algal species identified were Oscillatoria, Cyclotella, Navicula and Cosmarium. Conclusion: This study highlights the trophic state of the reservoir water and clearly points to the need for constant monitoring in order to avoid the occurrence of an impending harmful algal bloom.

• Korean Chemical Engineering Research
• /
• v.48 no.2
• /
• pp.259-267
• /
• 2010

The catalytic wet oxidations of the wastewater containing azo dye Reactive Black 5(RB5) with heterogeneous catalyst of CuO have been carried out to investigate the effects of temperature($190{\sim}230^{\circ}C$) and catalyst concentration(0.00~0.20 g/l) on the removals of colour and total organic carbon TOC. The wastewater colour was measured with spectrophotometer, and the oxidation rate was estimated with TOC. About 90% of colour was removed during 120 min in thermal degradation of the RB5 wastewater at $230^{\circ}C$, while TOC was not removed at all. As increasing reaction temperature and catalyst concentration, the removal rates of colour and TOC increased in the catalytic wet oxidations of RB5 wastewater. The effects of catalyst were already considerable even at 0.01 g CuO/l, while the removal rates of colour and TOC increased negligibly with increasing the catalyst concentration above 0.05 g CuO/l. The initial destruction rates of the wastewater colour have shown the first-order kinetics with respect to the wastewater colour. TOC changes during catalytic wet oxidations have been well described with the global model, in which the easily degradable TOC was distinguished from non-degradable TOC of the wastewater. The impacts of reaction temperature on the destruction rate of the wastewater colour and TOC could be described with Arrhenius relationship. Activation energies of the colour removal reaction in thermal degradation, wet oxidation, and catalytic wet oxidation(0.20 g CuO/l) of the RB5 wastewater were 108.4, 78.3 and 74.1 kJ/mol, respectively. The selectivity of wastewater TOC into the non-degradable intermediates relative to the end products in the catalytic wet oxidations of RB5 wastewater was higher compared to that in phenol wet oxidations.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.16 no.3
• /
• pp.2321-2327
• /
• 2015

Three coagulants, alum sulfate(alum), poly aluminum chloride(PAC) and poly aluminum silicate chloride (PASC), were used to remove low to high turbidity and TOC in surface and ground blended water. Laboratory experiments and pilot plant experiments were carried out to evaluate the optimal coagulant and its dosage. To determine the optimized coagulant and its dosage, the turbidity, TOC and pH were measured. The experimental results showed the best removal performance using PASC. The optimal dosage of PASC between 3-20 NTU was found to be 15 mg/L in the jar test. In the pilot test, a 15 mg/L PASC dosage was applied and resulted in the efficient removal of turbidity and TOC between 3.6-27 NTU. The removal efficiency of PASC increased with increasing turbidity and TOC.

• Environmental Engineering Research
• /
• v.21 no.1
• /
• pp.84-90
• /
• 2016

Regionally the lowest average concentration of TOC was observed with 0.66 mg/L in Nakdong river, while the highest concentration of TOC was observed with 0.91 mg/L in Yeongsan river. The average concentration of TOC for national water quality monitoring site showed that the lowest average concentration of TOC was 1.58 mg/L in Han river, while the highest concentration of TOC was 3.37 mg/L in Yeongsan river. Seasonally, the average concentration of TOC at six upstream sites showed 0.77 mg/L and 0.56 mg/L, 0.69 mg/L and 0.63 mg/L, 0.80 mg/L and 0.73 mg/L, and 1.21 mg/L and 0.68 mg/L between wet season and dry season in Han river, Nakdong river, Gem river and Yeongsan river, respectively. For the national water quality site, the average concentration of TOC between wet season and dry season was 1.70 mg/L and 1.45 mg/L in Han river, 2.01 mg/L and 1.75 mg/L in Nakdong river, 2.01 mg/L and 1.60 mg/L in Gem river, and 3.75 mg/L and 3.00 mg/L in Yeongsan river. The distribution of TOC in upstream and national water quality monitoring sites on four major rivers have been influenced by seasonal and regional characteristics in Korea.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2006.05a
• /
• pp.1032-1036
• /
• 2006

본 연구에서는 영산강 본류를 대표하는 나주지점을 대상으로 하여, 해당 지점에서 자동 측정되고 있는 수질 항목들 중에서 총유기탄소(TOC: Total Organic Carbon)의 시계열 자료에 대한 비선형 동역학적 거동을 파악하고자 하였다. 1994년 낙동강에서의 수질오염 사고 이후 4대강 유역에서 설치.운영되고 있는 수질자동 측정망의 TOC 자료를 일자료로 환산하여 사용하였으며, 시계열 자료에 비선형 동역학적(카오스적) 특성이 존재하는지를 알아보기에 앞서 자료의 전처리 과정으로써 3가지의 잡음제거 방법을 적용하였다. 잡음이 제거된 시계열 자료에 비선형 동역학적 거동의 파악을 위해 보편적으로 사용되고 있는 상관차원분석을 실시하였다. 또한 상관차원분석 결과 비선형 동역학적 거동을 나타내는 것으로 판별된 자료에 대하여 그 양상을 가시적으로 알아보기 위해 지체시간$(\tau)$을 적용하여 3차원 위상공간에 도시하였다. 본 연구의 결과, 나주지점에서 측정되고 있는 총유기탄소에 대해 비선형 잡음제거 방법을 적용한 자료가 비선형 동역학적 거동을 내재하고 있는 것으로 나타났으나, 이를 위상공간에 재건하였을 경우 이상한 끌개(strange attractor)의 뚜렷한 구조가 보이지 않았다. 그러나 상관차원분석 결과 잡음이 제거된 자료가 카오스적 특성을 보이므로, 자료의 단기예측을 위한 방법에 기초적인 정보를 제공할 수 있을 것으로 기대된다.

• Journal of Environmental Science International
• /
• v.16 no.1
• /
• pp.45-53
• /
• 2007

This study was carried out to investigate the variation of organic, nitrogen and phosphorus in $(AO)_2$ SBBR process according to the variation of operating cycle at the high TOC concentration. The operation time in anoxic (anaerobic) time to oxic time was 1:1. Three lab-scale SBBRS were fed with synthetic wastewater based on glucose as carbon source, The variation of total TOC removal was similar each other irrespective of operation time, however, the TOC concentrations in SBBRs showed a little difference according to the operating condition. In SBBR, complete nitrification was not occurred at all reactors, however, R3 showed a higher nitrification than R2. And in SBBR, the variation of operating time more affected at phosphorus removal than nitrogen removal. R2 which had the shortest time at the 1st aeration time showed the lowest phosphorus release and uptake efficacy.

• Journal of Korean Society on Water Environment
• /
• v.24 no.5
• /
• pp.611-617
• /
• 2008

It is necessary to analysis the data characteristics of discharge and water quality for efficient water resources management, aggressive alternatives to inundation by flood and various water pollution accidents, the basic information to manage water quality in lakes and to make environmental policy. Therefore, the present study applied Self-Organizing Map (SOM) showing excellent performance in classifying patterns with weights estimated by self-organization. The result revealed five patterns and TOC versus rainfall-storage data according to the respective patterns were depicted in two-dimensional plots. The visualization presented better understanding of data distribution pattern. The result in the present study might be expected to contribute to the modeling procedure for data prediction in the future.

• Journal of Korean Society for Atmospheric Environment
• /
• v.34 no.3
• /
• pp.457-468
• /
• 2018

To improve understanding of the physico-chemical characteristics of aerosols in the national park and comparing the air pollution between national park and the urban area nearby national park, the aerosol characterization study was conducted in Bukhansan National Park, Seoul, from July through September 2017. Semi-continuous measurements of $PM_{2.5}$ using PILS (Particle Into Liquid System) coupled with IC (Ion Chromatography) and TOC (Total Organic Carbon) analyzer allowed quantification of concentrations of major ionic species($Cl^-$, $SO_4{^{2-}}$, $NO_3{^-}$, $Na^+$, $NH_4{^+}$, $K^+$, $Mg{^{2+}}$ and $Ca{^{2+}}$) and water soluble organic carbon (WSOC) with 30-minute time resolution. The total mass concentration of $PM_{2.5}$ was measured by T640 (Teledyne) with 5-minute time resolution. The black carbon (BC) and ozone were measured with a minute time resolution. The timeline of aerosol chemical compositions reveals a strong influence from urban area (Seoul) at the site in Bukhansan National Park. Inorganic aerosol composition was observed to be dominated by ammoniated sulfate at most times with ranging from $0.1{\sim}32.6{\mu}g/m^3$ (6.5~76.1% of total mass of $PM_{2.5}$). The concentration of ammonium nitrate, a potential indicator of the presence of local source, ranged from below detection limits to $20{\mu}g/m^3$ and was observed to be highest during times of maximum local urban (Seoul) impact. The total mass of $PM_{2.5}$ in Bukhansan National Park was observed to be 10~23% lower than the total mass of $PM_{2.5}$ in urban area (Gireum-dong and Bulgwang-dong, Seoul). In general, ozone concentration in Bukhansan National Park was observed to be similar or higher than urban sites in Seoul, suggesting additional biogenic VOCs with $NO_x$ from vehicle emission were to be precursors for ozone formation in Bukhansan National Park.

• Proceedings of the Korean Nuclear Society Conference
• /
• 1996.11a
• /
• pp.127-132
• /
• 1996

Total organic carbon (TOC) derived from organics is one of tile possible contamination in the reactor water system and causes of pH change and high conductivity levels. Measurements of total dissolved oxidizable carbon were carried out and its contribution to conductivities at elevated temperature was studied by using tile thermodynamic equilibrium analysis in carbonic acid system. The calculated conductivities were in good agreement with tile levels observed for tile formation of carbonic acid from salicylic acid solution.

• Journal of Korean Society of Water and Wastewater
• /
• v.37 no.5
• /
• pp.281-288
• /
• 2023

This study was performed to evaluate the pollutants removal characteristics of two types of RBFs(Riverbank filtration, Riverbed filtration) intake facilities installed in Nakdong River and in Hwang River respectively. The capacity of each RBF is 45,000 m³/d for riverbank filtration intake facility and 3,500 m³/d for riverbed filtration intake facility. According to data collected in the riverbank filtration site, removal rate of each pollutant was about BOD(Biochemical Oxygen Demand) 52%, TOC(Total Organic Carbon) 57%, SS(Suspended Solids) 44%, Total coliforms 99% correspondingly. Furthermore, Microcystins(-LR,-YR,-RR) were not found in riverbank filtered water compared to surface water in Nakdong River. DOC(Dissolved Organic Carbon) and Humics which are precursors of disinfection byproduct were also reported to be removed about 59% for DOC, 65% for Humics. Based on data analysis in riverbed filtration site in Hwang River, removal rate of each contaminant reaches to BOD 33.3%, TOC 38.5%, SS 38.9%, DOC 22.2%, UV254 21.2%, Total coliforms 73.8% respectively. Additionally, microplastics were also inspected that there was no obvious removal rate in riverbed filtered water compared to surface water in Hwang River.