• Title/Summary/Keyword: TN/TP ratio

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The Characteristic of Point Source Loads for Nitrogen and Phosphorus to Gwangyang Bay, Korea (광양만으로 유입되는 질소, 인의 점원 오염부하 특성)

  • Kim Do-Hee;Cho Hyeon-Seo;Lee Young Sik
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.8 no.1
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    • pp.1-8
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    • 2005
  • We estimated the loadings of nitrogen and phosphorus flowing into Gwangyang Bay front river for monthly interval from April to December of 2003. We analyzed the concentrations of nitrogen and phosphorus in water and estimated the flowing rates of fresh water in 34 rivers. The amounts of water flowing into the Gwdngyang Bay from Sum-Jin River was 51-76% in the total inflow of the river. The river water over 96% of discharge was from Sumjin River, Dong River, Ju-Kyo River, Seo River and Shinkyum River. The flowing patterns of nitrogen and phosphorus into Gwangyang Bay were similar to the flowing of river. The nitrogen and phosphorus loadings into the Bay were higher in July and August than in dry seasons. In particular, the concentrations of phosphorus were high in Namshu River, Deukyang River and Kilho River sewage during in dry seasons. The range of DIN and TN loadings from Sumjim River were 46-66% and 36-64%, respectively. The loading of DIP and TP from Sumjim River were 2-55% and 12-67%, respectively. These results show that the most efficient control of N. p flow into Gwangyang Bay is to restrain the inflows of N, p from Namshu River, Deukyang River and Kilho River and to restrain the flows of N, p from Dong River, Ju-Kyo River and industrial plant. The DIN/DIP atom ratio in river water was about 18 in July and August, while the ratio was more higher in dry seasons than July and August of rainy seasons. The TN/TP atom ratio in river water was about 7 in rainy seasons, while the ratios were higher than 100 in the other months of dry seasons.

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Experimental study of Nutrient Removal by Endogeneous Nitrate Respiration (ENR) Mechanism in domestic wastewater (질산성질소의 내생탈질기작을 이용한 하수내 영양소 제거에 관한 실험적 연구)

  • Park, Myung-Gyun;Ahn, Won-Sik;Lee, Eui-Sin;Heo, Yong-Rok;Park, Chong-Bok
    • Clean Technology
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    • v.8 no.2
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    • pp.77-83
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    • 2002
  • The purpose of this study is to develop the efficient nutrient removal process and to verify operation and design parameters in domestic sewage. Endogenous nitrate respiration (ENR) was used for denitrification of nitrate in return sludge without additional organic carbon source. ENR reactor before the anaerobic tank enable to reduce nitrate below 3 mg/L and increase phosphate release at anaerobic reaction. Primary effluent during pilot scale plant were shown as TCOD/TP ratio of 40~60 and TCOD/TKN ratio of 5~7. Effluent concentrations were 10 to 12mg/L as TN and 1mg/L as TP respectively. In lab scale experiments endogenous denitrification rate of ENR reactor ranges from 0.042 to $0.057gNO_3-N/gMv.d.$ $SP_{rel}/SCOD_{rm}$ was shown as from 0.13 to 0.17 in anaerobic reaction. These kinetic parameters are expected to be available for BNR(Biological Nutrient Removal) plant design and ENR reaction is available for nutrient removal in low strength wastewater.

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Spatial and Temporal Variations of Environmental Factors and Phytoplankton Community in Andong Reservoir, Korea (안동호에서 환경요인과 식물플랑크톤의 시.공간적 변동)

  • Park, Jae-Chung;Park, Jung-Won;Kim, Jong-Dal;Shin, Jae-Ki
    • ALGAE
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    • v.20 no.4
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    • pp.333-343
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    • 2005
  • Spatial and temporal variations of environmental factors and phytoplankton community were investigated in the three stations of Andong Reservoir in 1997 and 2003. The changes of physico-chemical water quality and phytoplanktonic biomass were higher in 2003 than that of 1997, due to rainfall difference. The concentration of total nitrogen (TN) and total phosphorus (TP) in the reservoir decreased, but total nitrogen fell relatively more between them. TN/TP ratio decreased from 109 to 90 showing no change at the downstream but a big decrease at the midand upstream. Predominant phylum of phytoplankton in Andong Reservoir were six genus that composed to Anabaena, Aphanizomenon and Microcystis of Cyanophyceae, Cosmarium and Scenedesmus of Chlorophyceae and Synedra of Bacillariophyceae, respectively. Among the observed phytoplankton, diatom Synedra occured as the maximum amount of 3,400 cells mL$^{-1}$ even at the above 30°C. Green algae Scenedesmus observed along with Microcystis. It seemed to be compete with Microcystis during the high water temperature period. Although trophic state of Andong Reservoir was decreased, the standing crops of phytoplankton were increased. Moreover bluegreen algae, Aphanizomenon and Microcystis in the region of upstream to midstream and diatom, Synedra in the region of midstream to downstream were increased until to reach the algal bloom, respectively. It seemed necessary to attention the changes of blue-green algae Aphanizomenon, that has an ability of nitrogen fixation.

Analysis of Livestock Nonpoint Source Pollutant Load Ratio for Each Sub-watershed in Sancheong Watershed using HSPF Model (HSPF 모형을 이용한 산청 유역의 소유역별 축산비점오염부하량 비중 분석)

  • Kim, So Rae;Kim, Sang Min
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.1
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    • pp.39-50
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    • 2020
  • The objective of this study was to assess the livestock nonpoint source pollutant impact on water quality in Namgang dam watershed using the HSPF (Hydrological Simulation Program-Fortran) model. The input data for the HSPF model was established using the landcover, digital elevation, and watershed and river maps. In order to apply the pollutant load to the HSPF model, the delivery load of the livestock nonpoint source in the Namgang dam watershed was calculated and used as a point pollutant input data for the HSPF model. The hydrologic and water quality parameters of HSPF model were calibrated and validated using the observed runoff data from 2007 to 2015 at Sancheong station. The R2 (Determination Coefficient), RMSE (Root Mean Square Error), NSE (Nash-Sutcliffe efficiency coefficient), and RMAE (Relative Mean Absolute Error) were used to evaluate the model performance. The simulation results for annual mean runoff showed that R2 ranged 0.79~0.81, RMSE 1.91~2.73 mm/day, NSE 0.7~0.71 and RMAE 0.37~0.49 mm/day for daily runoff. The simulation results for annual mean BOD for RMSE ranged 0.99~1.13 mg/L and RMAE 0.49~0.55 mg/L, annual mean TN for RMSE ranged 1.65~1.72 mg/L and RMAE 0.55 mg/L, and annual mean TP for RMSE ranged 0.043~0.055 mg/L and RMAE 0.552~0.570 mg/L. As a result of livestock nonpoint pollutant loading simulation for each sub-watersehd using the HSPF model, the BOD ranged 16.6~163 kg/day, TN ranged 27.5~337 kg/day, TP ranged 1.22~14.1 kg/day.

Analysis of Water Quality Fluctuations in Upstream Namhan River Watershed Using Long-term Statistical Analysis (통계적 경향 분석을 통한 남한강 상류 수계 수질 변동 해석)

  • Byeon, Sang-Don;Noh, Yeon-Jung;Lim, Kyeong-Jae;Kim, Jong-Gun;Kim, Dong-Jin;Hong, Eun-Mi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.5
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    • pp.15-26
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    • 2020
  • There are fifteen non-point pollution management areas in Korea and three of them (Doam lake, Daegi district and Golji-cheon) are located in the upstream of the Namhan river watershed. Many efforts to reduce non-point sources (NPS) pollution have been conducted, however, water quality pollution in the watershed is still serious. To solve these problems, it is a priority to grasp water quality using statistical techniques. In this study, a trend analysis was conducted to evaluate the effect of NPS management in the watershed. The long-term trends from 1996 to 2018 of water quality properties were analyzed using data collected from the water environment information system. Seventeen monitoring stations were selected along the main stream in Namhan river basin. Monthly water quality properties (BOD, COD, TN, TP, TN/TP ratio, Conductivity, SS and Chlorophyll-a) were collected and analyzed by Mann-Kendall test and LOWESS. The results showed that the Conductivity tended to increase in all regions and was the highest level in Jijangcheon. Organic pollution such as BOD and COD tended to increase in the Jungseon area. SS did not show a large tendency, but it showed high concentration in the Doam watershed. In all regions, 40% of water quality properties showed a tendency to 'UP', 15% of water quality properties tended to 'DOWN', and 46% indicated no tendency. In order to determine the cause of this, additional research and measures for improvement are necessary. This study will be used for the establishment of water quality policy in the future.

Evaluation of the impact of sewage treatment plants in the Linked treatment through the sewage treatment computer simulation program (하수처리 전산모사 프로그램을 통한 연계처리시 하수처리장 영향 평가)

  • Kim, Sungji;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.22 no.4
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    • pp.321-327
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    • 2020
  • Recently The amount of wastewater and linked wastewater is being increased every year due to industrial development, population growth, and improvement in living standards. Linked wastewater shows the feature-low flow rate and high concentration. Therefore, it has been shown that it has a great impact on the operation of the sewage treatment plant and costs a lot for treating linked wastewater. In this study, a scenario with low increase of water quality when the total amount of the inflow of linked wastewater was entered into individual reactors is obtained. According to the result of modeling, The effluent water quality get the least increment once the water was introduced into the influent and anoxic tank. We generated the various scenarios Based on these results. scenarios are varying according to inflow from linked waste water's distribution ration. As a result of modeling through various scenarios, it was found that the increment of TN and TP were at the least when the inflow of linked water was distributed with ratio between sewage (80%) and oxygen-free tank (20%).

Effect of Coagulant addition on Nutrient Removal Efficiency in a Submerged Membrane Bioreactor (응집제의 첨가에 따른 Membrane bioreactor 의 고도처리 효율 연구)

  • Park, Jong-Bu
    • Journal of Korean Society on Water Environment
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    • v.27 no.2
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    • pp.235-241
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    • 2011
  • This study was performed to investigate the characteristics of nutrient removal of municipal wastewater in the submerged membrane bioreactor by addition of alum directly into aerobic tank. Membrane bioreactor consists of three reactors such as two intermittent anaerobic tanks and the aerobic tank with hollow fiber membrane. The removal efficiencies of $COD_{cr}$, BOD, SS, TN and TP on the membrane bioreactor were 94.0%, 99.1%, 99.9%, 66.9%, and 58.9%, respectively. In addition, The removal efficiencies of $COD_{cr}$, BOD, SS, TN and TP on the membrane bioreactor with alum addition were 93.4%, 99.0%, 99.9%, 63.2%, and 96.8%, respectively. There was little difference between them on the nutrient removal efficiencies except phophorus removal. The estimated sludge production, specific denitrification rate, specific nitrification rate and phosphorus removal content on the membrane bioreactor were 1.76 kgTSS/d, $0.055mgNO_3-N/mgVSS{\cdot}d$, $0.031mgNH_4-N/mgVSS{\cdot}d$, and 0.095 kgP/d, respectively. And The estimated sludge production, specific denitrification rate, specific nitrification rate and phosphorus removal content on the membrane bioreactor with alum addition were 2.90 kgTSS/d, $0.049mgNO_3-N/mgVSS{\cdot}d$, $0.030mgNH_4-N/mgVSS{\cdot}d$, and 0.160 kgP/d, respectively. The alum content added was 1.7 molAl/molP on an average. The increasing ratio of tran-membrane pressure on the membrane bioreactor was $0.0056kgf/cm^2{\cdot}compared$ to $0.0033kgf/cm^2{\cdot}d$ on the membrane bioreactor with alum addition. There was a slightly reduction effect on membrane fouling by alum addition.

Development of ensemble machine learning model considering the characteristics of input variables and the interpretation of model performance using explainable artificial intelligence (수질자료의 특성을 고려한 앙상블 머신러닝 모형 구축 및 설명가능한 인공지능을 이용한 모형결과 해석에 대한 연구)

  • Park, Jungsu
    • Journal of Korean Society of Water and Wastewater
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    • v.36 no.4
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    • pp.239-248
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    • 2022
  • The prediction of algal bloom is an important field of study in algal bloom management, and chlorophyll-a concentration(Chl-a) is commonly used to represent the status of algal bloom. In, recent years advanced machine learning algorithms are increasingly used for the prediction of algal bloom. In this study, XGBoost(XGB), an ensemble machine learning algorithm, was used to develop a model to predict Chl-a in a reservoir. The daily observation of water quality data and climate data was used for the training and testing of the model. In the first step of the study, the input variables were clustered into two groups(low and high value groups) based on the observed value of water temperature(TEMP), total organic carbon concentration(TOC), total nitrogen concentration(TN) and total phosphorus concentration(TP). For each of the four water quality items, two XGB models were developed using only the data in each clustered group(Model 1). The results were compared to the prediction of an XGB model developed by using the entire data before clustering(Model 2). The model performance was evaluated using three indices including root mean squared error-observation standard deviation ratio(RSR). The model performance was improved using Model 1 for TEMP, TN, TP as the RSR of each model was 0.503, 0.477 and 0.493, respectively, while the RSR of Model 2 was 0.521. On the other hand, Model 2 shows better performance than Model 1 for TOC, where the RSR was 0.532. Explainable artificial intelligence(XAI) is an ongoing field of research in machine learning study. Shapley value analysis, a novel XAI algorithm, was also used for the quantitative interpretation of the XGB model performance developed in this study.

Temporal Changes of Limiting Nutrients and Phytoplankton Growth Rate in Lake Paldang (팔당호 식물플랑크톤의 제한영양염과 성장률의 경시적 변화)

  • Choi, Kwang-Hyun;Kim, Ho-Sub;Han, Myung-Soo;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.36 no.2 s.103
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    • pp.139-149
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    • 2003
  • This study was conducted to determine limiting nutrients and the physiological characteristics of phytoplankton in response of nutrients in Lake Paldang from March 2002 to October 2002. A field research was conducted along with laboratory batch culture experiment to find the limiting nutrients and the growth kinetics. According the results of Chl. a TP relationship, TN/TP ratio, and nutrient addition bioassay, phosphorus appeared to be a major limiting nutrient in Lake Paldang and thus the lake productivity was greatly influenced by it. P limitation for the phytoplankton of Lake Paldang varied with season, and the possibility of limitation by nitrogen and silica also occurred. The degree of P limitation was greatest during spring when the concentration of dissolved phosphorus is relatively much lower than summer and autumn. The maximum growth rate (${\mu}_{max}$) and half saturation concentration ($K_u$) of Lake Paldang phytoplankton ranged from 0.8${\sim}$1.1$day^1$ and from 0.1${\sim}$O.8${\mu}M$, respectively. $K_u$ was highest during May ($0.8{\mu}M$) and the lowest during September ($0.1{\mu}M$). Such result may be induced by the phytoplankton cell quota that showed the lowest concentration ($0.13{\mu}gP/{\mu}gChl.$ a) during May. The growth kinetics showed that phytoplankton growth in Lake Paldang was faster during summer and autumn than spring, suggesting that the Potential of algal bloom is high after the summer monsoon season.

The Policy Review and Water Quality Characteristics of National Fishing Harbors and Designated Ports in East Coast of Korea (동해안 국가어항과 지정항만의 수질특성 및 정책적 고찰)

  • Lee, Dae-In;Kim, Gui-Young;Moon, Ju-Hoon;Eom, Ki-Hyuk
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.14 no.4
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    • pp.213-223
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    • 2011
  • The status and changes of water quality of national fishing harbors and designated ports in East Coast of Korea were analyzed to support establishment effective water environmental management. COD (Chemical Oxygen Demand) concentration was satisfied to designated water quality criteria in most areas, but TN (Total Nitrogen) and TP (Total Phosphorus) exceeded the criteria frequently. Also, peak concentration was summer in COD and SS (Suspended Solid), but winter in TP. Eutrophication index of Ganggu and Pohang (old) area were the highest. Pollution index by function of COD, TN, and TP of Ganggu, Pohang, Jumunjin, and Guryongpo was high with gradual increasing recently, on the contrary, that of Samcheok, Imwon, and Chuksan was decreased. Pollution index involving multi-indictors relation to organics and inorganics was necessary for water quality assessment. Designated water quality criteria needed to be improved because the criteria of Jukbyun and Chuksan was applied more strictly compared to the other regions although without difference of environmental characteristics. Furthermore, the criteria notified lately needed to be related to management pollutants from land-based sources. The continuous diagnosis and monitoring on sediment quality within the study area were necessary for prevention of water pollution and eco-friendly disposal of dredged sediment. Especially, monitoring of Designated Ports was implemented partially, however monitoring ratio of National Fishing Har-bors was 7% to whole part. Therefore, systematic and integrated environmental monitoring for ports and harbors with charge of national management was reestablished by strengthening and securing a legal basis.