• Title/Summary/Keyword: TN/TP ratio

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Analysis of Harmful Cyanobacteria Occurrence Characteristics and Effects of Environmental Factors (덕동호 유해남조류 출현 특성 및 환경요인 영향 분석)

  • Dong-Gyun Hong;Hae-Kyung Park;Yong-jin Kim
    • Journal of Korean Society on Water Environment
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    • v.39 no.1
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    • pp.20-29
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    • 2023
  • This study analyzed the relationship between harmful cyanobacterial abundance and environmental factors in order to figure out the causes of the recent increase of cyanobacteria in Lake Dukdong from 2019 to 2021. Lake Dukdong, which is used as a drinking water source for Gyeongju City, has an algae alert system in place. Lake Dukdong has maintained good water quality, but algae alert level 1 (over 1,000 cells/mL) has been issued in recent years. As a result of Pearson correlation analysis (from May to Oct.), the cell density of Microcystis and Aphanizomenon, which form part of the most harmful cyanobacteria genus, were significantly positively correlated with the water temperature and water storage volume. T-test was performed to compare the data from 2016-2018 and 2019-2021 (from May to Oct.). The average density of harmful cyanobacteria cells increased about six-fold from 54 to 344 cells/mL. There were significant differences in water temperature, pH, total nitrogen (TN), total phosphorus (TP), TN/TP ratio, water storage volume, and cyanobacterial cell density. Water temperature increased from 19.2 to 22.8 ℃. TP concentration increased from 0.017 to 0.028 mg/L. The main cause of the recent increase of harmful cyanobacteria in Lake Dukdong is thought to be the increase in water temperature, TP concentration, and water storage volume from 2019 and 2021, resulting in more favorable conditions for cyanobacterial growth.

Characteristics of chemical water quality and the empirical model analysis before and after the construction of Baekje Weir (금강수계 백제보 건설 전·후의 화학적 수질특성 및 경험적 모델 분석)

  • Kim, Yu-Jin;Lee, Sang-Jae;An, Kwang-Guk
    • Korean Journal of Environmental Biology
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    • v.37 no.1
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    • pp.48-59
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    • 2019
  • This study analyzed the water quality characteristics and developed empirical models prior to and after the construction of Baekje Weir, in the Geum River watershed between 2004-2017. The comparative evaluation of the surface water chemistry before and after the four major river projects on the weirs indicated that total phosphorus (TP), based on annual data, rapidly decrease after the construction of the weir while the total nitrogen(TN) decreased. Conversely, chlorophyll-a (CHL) concentration, which is a good indicator of primary productivity, increased after the construction of the weir together with an increase in specific conductivity. Simply put, the construction of the weir led to the decrease in concentrations of N and P due to the increased water residence time (WRT), whereas the CHL :TP ratio greatly increased in magnitude. The regression analysis of the empirical model indicated that CHL had no significant relation (r=0.068, p=0.6102, n=58) with TP before the weir construction, but had a relation with TP after the weir construction (r=0.286, p<0.05, n=56). Therefore, such conditions resulted in an increase in primary productivity on a given unit of phosphorus, resulting in frequent algal blooms. In contrast, seasonal suspended solids (SS) and TP increased during the monsoon period, compared to the pre-monsoon, thereby showing positive correlations (r>0.40, p<0.01, n=163) with precipitation. If the government consistently discharges water from the weir, the phosphorus concentration will be increased due to its reversion to a lotic waterbody from a lentic waterbody hereby reducing algal blooms in the future.

Effects of Nutrients and N/P Ratio Stoichiometry on Phytoplankton Growth in an Eutrophic Reservoir (부영양 저수지에서 식물플랑크톤 성장에 대한 제한영양염과 질소/인 비의 영향)

  • Kim, Ho-Sub;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.37 no.1 s.106
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    • pp.36-46
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    • 2004
  • We evaluated the effect of limiting nutrients and N/P ratio on the growth of phytoplankton in a small eutrophic reservoir from November 2002 to December 2003. Nutrient limitation was investigated seasonally using nutrient enrichment bioassay (NEB). DIN/DTP and TN/TP ratio (by weight) of the reservoir during the study period ranged 17${\sim}$187 and 13${\sim}$60, respectively. Most of nitrogen in the reservoir account for $NO_3$-N, but sharp increase of ammonia was evident during the spring season. Seasonal variation of dissolved inorganic phosphorus concentration was relatively small. DTP ranged 26.5${\sim}$10.1 ${\mu}g\;P\;L^{-1}$, and the highest and lowest concentration was observed in August and December, respectively. Chlorophyll a concentration ranged 28.8${\sim}$109.7 ${\mu}g\;L^{-1}$, and its temporal variation was similar to that of cell density of phytoplankton. Dominant phytoplankton species were Bacillariphyceae (Melosira varians) and Chlorophyceae (Dictyosphaerium puchellum) in Spring (March${\sim}$April). Cyanophyceae, such as Osillatoria spp., Microcystis spp., Aphanizomenon sp. dominated from May to the freezing time. TN/TP ratio ranged from 46 to 13 (Avg. 27${\pm}$6) from June to December when cyanobacteria (Microcystis spp.) dominated. p limitation for algal growth measured in all NEB experiments (17cases), while N limitation occurred in 8 out of 17 cases. The growth rates of phytoplankton slightly increased with decreasing of DIN/DTP ratio. Evident increase was observed in the N/P ratio of > 30, and it was sustained with DTP increase until 50 ${\mu}g\;P\;L^{-1}$. Under the same N/P mass ratio with the different N concentrations (0.07, 0.7and 3.5 mg N $L^{-1}$), Microcystis spp. showed the highest growth rate in the N/P ratio of< 1 with nitrogen concentration of 3.5 mg N $L^{-1}$). The responses of phytoplankton growth to phosphate addition were clearly greater with increase of N concentration. These results indicate that the higher nitrogen concentration in the water likely induce the stronger P-limitation on the phytoplankton growth, while nitrogen deficiency is not likely the case of nutrient limitation.

Road Runoff Treatment using Pilot Scale-NPS Treatment Plant Filling up Expended Polypropylene Media (발포고분자여재가 충전된 파일럿 규모의 비점오염물질 처리장치를 이용한 도로 강우유출수 처리)

  • Kim, Seogku;Oh, Hyecheol;Ahn, Jaehwan
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.10
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    • pp.711-718
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    • 2014
  • Investigated the processing characteristics of the pollutants and runoff due to storm events in the actual application of the road fields and a Non-Point Sources (NPS) pilot scale equipment. This phenomenon has occurred in the influent bypass the blockage occurs after 90 min the expended polymeric media was filled with filtered column. When entering a treatment tank SS 200 mg/L or more high concentration of effluent treatment efficiency was reduced from the reaction time 60 min. Influent concentration less then SS 180 mg/L was stable handling. The $COD_{Cr}/SS$ ratio were analyzed with 0.67, median value. Showed 92.1% and 82.3% respectively with an average removal rate of the SS and the $COD_{Cr}$. If the influent concentration of TP is the 0.5 mg/L or less, the quality of the treated water is 0.1 mg/L levels were expressed in a stable process. And when entering the 1.0 mg/L or more of the treated water, had a greater than average 0.2 mg/L. If the influent concentration of TN is 4~10 mg/L, the treatment water quality level was kept a 1.5~3.0 mg/L. The average removal efficiency of TP and TN respectively 73.9%, 50.4%.

Investigation of the Effect of Weirs Construction in the Han River on the Characteristics of Sediments (보 설치가 퇴적물 특성에 미치는 영향에 관한 연구)

  • Kang, Min Kyoung;Choi, In Young;Park, Ji Hyoung;Choi, Jung Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.9
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    • pp.597-603
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    • 2012
  • To investigate the effects of weir construction on sediment characteristics of river bed, we conducted sediments sampling on the 9 locations near the weir, Kangchun, Yuju and Ipo in Namhan-River. Physical and chemical characteristics of sediments were analyzed by measuring particle size distribution, water content, Ignition loss, COD (Chemical Oxyzen Demand), TOC (Total Organic Carbon), TP (Total Phosphorus), SRP (Soluble Reactive Phosphorus) and TN (Total Nitrogen). Particle classification of all three weir sediments showed sandy loam that was caused by the river bed dredging. Due to the presence of weir, Ignition loss, COD, TOC, TP, SRP and TN showed similar trend such as the concentrations of upward weir had higher than those of downward weir. For the case of SRP concentration and C/N ratio, however, there is not much difference in the sediment characteristics compared to the those of sediments before weir construction. Therefore, It can be predicted that there are little effects of weir construction on sediment characteristics. However, weir construction could influence water quality of the river by controlling the transport and the accumulation of suspended materials from rainfall. Therefore, more intensive monitoring is required to examine the magnitude and patterns of sediment accumulation which could influence overlying water quality.

Water Quality Similarity Evaluation in Geum River Using Water Quality Monitoring Network Data (물환경측정망 자료를 활용한 금강수계 수질 유사도 평가)

  • Kim, Jeehyun;Chae, Minhee;Yoon, Johee;Seok, Kwangseol
    • Journal of Environmental Impact Assessment
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    • v.30 no.2
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    • pp.75-88
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    • 2021
  • Six locations in the automated monitoring network at the Geum River Basin were selected forthis study. The water quality characteristics at two of the locations in the water quality monitoring network that were identical, or nearby, were examined, and their correlations were evaluated through statistical analysis. The results of the water quality analysis were converted to the water quality index and expressed in grades for comparison. For the data necessary for the study, public data from four years, from 2016-2019 were used and the evaluation parameters were water temperature, pH, EC, DO, TOC, TN, and TP. Results of the analysis showed that the water quality concentrations measured in the automated monitoring network and the water quality monitoring network differed in some measured values, but they tended to register variation in a specified ratio in most of the locations in the network. The analysis of the correlations of the parameters between the two monitoring networks found that water temperature, EC, and DO showed high correlations between the two monitoring networks. The TOC, TN, and TP showed high correlations, with a 0.7 or higher (correlation coefficient r), with the exception of some of the monitoring networks, although their correlations were lower than those of the basic parameters. The water quality index analysis showed that the water quality index values of the automated monitoring network and the water quality monitoring network were similar. The water quality index decreased and the pollution degree increased in the downstream direction, in both networks.

Influence of mixed liquor suspended solids on the removal efficiency of a hybrid membrane bioreactor

  • Palmarin, Matthew J.;Young, Stephanie
    • Membrane and Water Treatment
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    • v.7 no.1
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    • pp.11-22
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    • 2016
  • The characterization of treatment performance with respect to mixed liquor suspended solids (MLSS) concentration enables greater control over system performance and contaminant removal efficiency. Hybrid membrane bioreactors (HMBRs) have yet to be well characterized in this regard, particularly in the context of greywater treatment. The aim of this study, therefore, was to determine the optimal MLSS concentration for a decentralized HMBR greywater reclamation system under typical loading conditions. Treatment performance was measured at MLSS concentrations ranging from 1000 to 4000 mg/L. The treated effluent was characterized in terms of biochemical oxygen demand ($BOD_5$), chemical oxygen demand (COD), turbidity, ammonia ($NH_3$), total phosphorus (TP), total kjeldahl nitrogen (TKN), and total nitrogen (TN). An MLSS concentration ranging from 3000 to 4000 mg/L yielded optimal results, with $BOD_5$, COD, turbidity, $NH_3$, TP, TKN, and TN removals reaching 99.2%, 97.8%, 99.8%, 99.9%, 97.9%, 95.1%, and 44.8%, respectively. The corresponding food-to-microorganism ratio during these trials was approximately 0.23 to 0.28. Operation at an MLSS concentration of 1000 mg/L resulted in an irrecoverable loss of floc, and contaminant residuals exceeded typical guideline values for reuse in non-potable water applications. Therefore, it is suggested that operation at or below this threshold be avoided.

Effects of Physical Characteristics on a Nutrient-Chlorophyll Relationship in Korean Reservoirs

  • Hwang, Soon-Jin;Jeon, Ji-Hong;Ham, Jong-Hwa;Kim, Ho-Sub
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.44 no.7
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    • pp.64-73
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    • 2002
  • This study was performed to evaluate effects of physical characteristics of both watershed and reservoir on nutrient-chlorophyll relationship in Korean reservoirs. Simple linear models were developed with published data in Korea including 415 reservoirs and 11 multi-purpose dams, and physico-chemical parameters of reservoirs and characteristics relationship of models were analyzed. Theoretical residence time in Korean reservoirs was strongly correlated with the ratio of TA/ST (drainage area + surface area / storage volume) in the logarithmic function. As a result of monthly nutrients-chlorophyll-a regression analysis, significant Chl-a-TP relationship appeared during May~July. The high Chl-a yields per total phosphorus appeared during this time (R$\^$2/=0.51, p<0.001, N= 1088). Chlorophyll-a demonstrated much stronger relationship with TP. than TN. Seasonal algal-nutrient coupling were closely related with N:P ratio in the reservoir water, and it was, in turn, dependent on the monsoon climatic condition (precipitation). Based on the results of regression analysis and high N:P ratio, a major limiting factor of algal growth appeared to be phosphorus during this time. Unlikely TA/ST ratio, DA/SA ratio (drainage area f surface area) was likely to influence directly on the nutrient-Chl-a relationship, indicating that if storage volume and inflowing water volume were the same, algal biomass could be developed more in reservoirs with large surface area. Thus, DA/SA ratio seemed to be an important factor to affect the development of algal biomass in Korean reservoirs. With low determination coefficient of TP-Chl-a relationship, our findings indicated not only nutrient (phosphorus) but also other physical factors, such as DA/SA ratio, may affect algal biomass development in Korean reservoirs, where actual residence time appears to be more closely related to reservoir surface area rather than storage volume.

The Limnological Survey of a Coastal Lagoon in Korea (3): Lake Hwajinpo (동해안 석호의 육수학적 조사 (3): 화진포호)

  • Kwon, Sang-Yong;Lee, Jae-Il;Kim, Dong-Jin;Kim, Bom-Chul;Heo, Woo-Myung
    • Korean Journal of Ecology and Environment
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    • v.37 no.1 s.106
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    • pp.12-25
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    • 2004
  • Physicochemical parameters, plankton biomass, and sediment were surveyed from 1998 to 2000 at two months interval in a eutrophic coastal lagoon(Lake Hwajinpo, Korea). The lake is separated from the sea by a narrow sand dune. Littoral zone is well vegetated with leafing-leaved aquatic plants. The lake basin is divided into two subbasins by a shallow sill. It has intrusion of seawater by permeation and stormy waves. Stable chemoclines are formed by salinity difference at 1m depth all the year round. DO was often very low (< 1 mg$O_2\;L^{-1}$) at hypolimnion. Temperature inversions were observed in November. Nitrate and ammonium concentrations were very low(< (1.1 mgN $L^{-1}$), even though TN was usually 2.0 ${\sim}$ 3.5 mgN $L^{-1}$. TN/TP was generally lower than the Redfield ratio. Transparency was 0.2 ${\sim}$ 1.7 m, and COD, TP, and TN of sediment were 3.1 ${\sim}$ 40.3 mg$O_2\;g^{-1}$, 0.91 ${\sim}$ 1.39 mgP $g^{-1}$, and 0.34 ${\sim}$ 3.07 mgN $g^{-1}$, respectively. Phytoplankton chlorophyll- a concentrations were mostly over 40 mg $m^{-3}$. Two basins showed different phytoplankton communities with Oscillatoria so., Trachelomonas sp., Schizochlamys gelatinosa, and Anabaena spiroides dominant in South basin, and with Trachelomons sp., Schroederia so., schizochlamys gelatinosa, and Trachelomonas sp. dominant in the North basin. The seasonal succession of phytoplankton was very fast, possibly due to sudden changes in physical conditions, such as wind, turbidity, salinity and light.

Effects of Gumi City Sewage Treatment Effluent in the Downstream Nutrient Matter: Comparison of Daily Loading (구미시 하수처리 방류수가 하류 하천 영양염류에 미치는 영향: 부하량 비교)

  • Seong, Jin-Uk;Lee, Sang-Pal;Lee, Jae-Kyun;Park, Je-Chul
    • Journal of Environmental Science International
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    • v.22 no.12
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    • pp.1643-1650
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    • 2013
  • This study investigated water quality of effluents and stream from the sewage treatment plants located at Gumi Complex 4, Gumi, and Wonpyeong in Gumi. Downstream region was found to increase the concentration of nutrients for sewage treatment plant effluent. Both phosphorus and nitrogen were accounted most as soluble form. In particular, the high ratio of dissolved effluent of sewage treatment plants were investigated. In the streams, Phosphorus concentration was high during rainy season and nitrogen concentration was high in the dry season. Sewage treatment plant effluent was relatively less microbial activity and nutrient concentrations were higher in the winter. TN/TP ratio was the highest in the upstream region and the lowest in the sewage treatment plant effluent. The effect of the nutrient matter from a discharge of a sewage treatment plant on rivers varied depending on the size of the river and the treatment plant. However, the influence of the concentration was greater than that of flowrate. Sewage treatment plant effluent loads phosphorus, nitrogen accounted for 8% and 6% respectively at the point N3 of the Nakdong river.