• 제목/요약/키워드: TMA

검색결과 584건 처리시간 0.023초

SnO-P2O5계 유리에서 P2O5를 B2O3로 치환시 구조와 물성에 미치는 영향 (Effects of Substituting B2O3 for P2O5 on the Structure and Properties of SnO-P2O5 Glass Systems)

  • 김동환;황차원;김남진;임상혁;구동건;김태희;차재민;류봉기
    • 한국세라믹학회지
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    • 제48권1호
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    • pp.63-68
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    • 2011
  • The investigation is directed to lead free (Pb-free) frits that can be used for organic light emitting diode, plasma display screen devices and other sealing materials. $P_2O_5$-SnO system glasses have been prepared for Pb-free low temperature glass frit. Structure and properties of the glasses with the composition SnO-$xB_2O_3-(60-x)P_2O_5$ (x=0, 5, 10, 15, 20, 25, 30, 35, 40 mol%) were characterized by infrared spectra (IR), X-ray diffraction(XRD), Density, Molar volume, Thermo mechanical analysis(TMA) and weight loss after immersion test. Glass transition temperature($T_g$), dilatometric softening temperature($T_d$) and chemical durability increased, and coefficient of thermal expansion($\alpha$) decrease with the substitution of $B_2O_3$ for $P_2O_5$ in the range of 0~25 mol%.

원격 플라즈마 원자층 증착법을 이용한 Al2O3/GaN MIS 구조의 제작 및 전기적 특성 (Fabrication and Electrical Properties of Al2O3/GaN MIS Structures using Remote Plasma Atomic Layer Deposition)

  • 윤형선;김현준;이우석;곽노원;김가람;김광호
    • 한국전기전자재료학회논문지
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    • 제22권4호
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    • pp.350-354
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    • 2009
  • $Al_{2}O_{3}$ thin films were deposited on GaN(0001) by using a Remote Plasma Atomic Layer Deposition(RPALD) technique with a trimethylaluminum(TMA) precursor and oxygen radicals in the temperature range of $25{\sim}500^{\circ}C$. The growth rate per cycle was varied with the substrate temperature from $1.8{\AA}$/cycle at $25^{\circ}C$ to $0.8{\AA}$/cycle at $500^{\circ}C$. The chemical structure of the $Al_{2}O_{3}$ thin films was studied using X-ray photoelectron spectroscopy(XPS). The electrical properties of $Al_{2}O_{3}$/GaN Metal-Insulator-Semiconductor (MIS) capacitor grown at a $300^{\circ}C$ process temperature were excellent, a low electrical leakage current density(${\sim}10^{-10}A/cm^2$ at 1 MV) at room temperature and a high dielectric constant of about 7.2 with a thinner oxide thickness of 12 nm. The interface trap density($D_{it}$) was estimated using a high-frequency C-V method measured at $300^{\circ}C$. These results show that the RPALD technique is an excellent choice for depositing high-quality $Al_{2}O_{3}$ as a Sate dielectric in GaN-based devices.

가열조리가 복어 추출물 함질소화합물의 조성에 미치는 영향 (Changes of the Composition of Nitrogenous Compounds in Globefish Meat Extracts by the Cooking Method)

  • 양영;한영실;변재형
    • 한국식품조리과학회지
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    • 제6권2호
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    • pp.85-96
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    • 1990
  • Globefish, Fugu xanthopterus, known to have a severe toxin, is one of the favorite food in Korea and Japan when the toxic part is removed. In this paper, the effect of cooking on the composition of nitrogenous components in the extractives from globefish cooked investigated and the changes of the taste compounds originated from the nitrogenous components in the extractives were discussed. When the sample fish was analysed for general composition, drip amount and pH by the different methods of thawing, the method effective method was the running water thawing. Total nitrogen content in raw globefish and the frozen globefish was not different, and the nitrogen content was increased with the heat treatment. It seemed that the nitrogen content was higher in the extract from the boiled globefish than that of the steamed globefish. Taurine, lysine, glycine and alanine were occupied about 70% of the total free amino acids. Total free amino acid content was higher in the extracts from the frozen sample than those from the raw sample. The amount of free amino acids was increased when the globefish soup cooked under the direct-heat cooking than in the microwave oven-heat cooking. Among nucleotides in the extracts from the thawed and cooked fishes, IMP and inosine contents were increased, and the both components were decreased with the heating time and by the heating method. Tne content of total creatinine-nitrogen were 50% of the total nitrogen content of the extracts, but the concentration of glycinebetaine, TMA and TMAO were only a few amounts. It could be concluded that total creatinine components, including free amino acids such as taurine, lysine, glycine and alanine, and IMP might be the important components contributing to the taste of the cooked globefish.

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에폭시 수지에 따른 언더필의 특성에 관한 연구 (Characteristic of Underfill with Various Epoxy Resin)

  • 노보인;이종범;정승부
    • 마이크로전자및패키징학회지
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    • 제13권3호
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    • pp.39-45
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    • 2006
  • 다양한 에폭시 수지를 함유한 언더필의 열적 특성을 시차주사열량측정법, 열중량측정법, 동적-기계적 분석법, 열적-기계적 분석법과 같은 열 분석법을 이용하여 분석하였다. 또한, 언더필과 FR-4기판 사이의 접합 강도를 측정하였다. Cycolaliphatic 에폭시 수지를 함유한 언더필의 유리 전이 온도가 cycolaliphatic 에폭시 수지를 함유하지 않은 언더필의 유리 전이 온도보다 낮음을 확인할 수 있다. 대기로부터 유입된 산소와 열화된 폴리머 사이의 화학적 반응으로 인하여 언더필의 열적 감소 반응이 두 번 발생하는 것을 확인할 수 있다. Cycolaliphatic 에폭시 수지를 함유한 언더필의 열팽창 계수가 cycolaliphatic 에폭시 수지를 함유하지 않은 언더필의 열팽창 계수보다 높음을 확인할 수 있다. 과도한 경화 온도는 에폭시 수지의 경계면을 약하게 하여 에폭시 수지의 기계적 특성의 변화를 초래하게 되고 언더필과 FR-4 기판 사이의 접합 특성을 저하시키게 된다.

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Knowledge, Attitude and Practice Concerning Human Papilloma Virus Infection and its Health Effects among Rural Women, Karnataka, South India

  • Sabeena, Sasidharanpillai;Bhat, Parvati V;Kamath, Veena;Aswathyraj, Sushama;Arunkumar, Govindakarnavar
    • Asian Pacific Journal of Cancer Prevention
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    • 제16권12호
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    • pp.5053-5058
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    • 2015
  • Background: Cervical cancer is one of the commonest cancers among women all over the world. The association of cervical cancer with human papilloma virus (HPV) is well established. Knowledge about the causal relationship between HPV and cervical cancer is important to make appropriate, evidence-based health care choices. In this context we conducted a community based study among women about the knowledge, attitude and practice about HPV infections and their health effects. Materials and Methods: A cross sectional interview based house to house survey was conducted with a validated data collection tool covering sociodemographic factors, knowledge, attitude and practice about HPV and its health effects, among 1020 women from a rural village, Perdoor, in Udupi district, Karnataka, India in 2013-14. Results: The mean age of participants was 38.9 years (SD=12.6). Study participants showed a high literacy rate (85.7%). Only 2.4% of sexually exposed women had undergone Pap smear testing. Partners of 4.4%women had undergone circumcision and they belonged to the Muslim community. Male condom usage was reported by 26 women (2.6%). However, none of the participants had heard of HPV and its health effects. Conclusions: This community based study found complete ignorance about HPV among rural South Indian women in spite of a high literacy level.

현무암의 용융특성과 연속섬유 방사 연구 (Studies on the Melting Characterization of Basalt and its Continuous Fiber Spinning)

  • 박혜정;박선민;이재원;노광철;김재근
    • Composites Research
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    • 제23권3호
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    • pp.43-49
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    • 2010
  • 제주도 표선리 현무암 원광을 이용하여 연속 방사에 의해 현무암 섬유를 제조하였다. 먼저 현무암의 용융특성을 확인하기 위하여 현무암 원광을 백금도가니에 넣고 $1550^{\circ}C$로 용융시킨 후, 물속에서 급냉하였다. 냉각한 후 X-선 회절, 열팽창, 고온 점도, 고온 전기전도도와 고온 현미경을 측정 분석하여 연속방사 조건을 조사하였다. 연속 섬유를 제조하기 위한 최적의 방사 온도와 고온 점도는 각각 $1264^{\circ}C$$10^{2.8}$ poise이었다. 제조된 방사 섬유의 특성은 인장강도, 전자현미경 관찰, 내열시험 등으로 확인하였다. 부싱 온도 $1240^{\circ}C$와 와인더 속도 4600rpm의 방사 조건에서 제조된 섬유의 인장 강도는 3660MPa을 나타내었다.

배건담치의 정미성분에 관한 연구 (THE TASTE COMPOUNDS OF BROILED DRIED SEA MUSSELS)

  • 류병호;이응호
    • 한국수산과학회지
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    • 제11권2호
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    • pp.65-83
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    • 1978
  • This study was attempted to evaluate the taste of broiled-dried sea mussel which is a traditional dried Sea food in Korea. The contents of such compounds as free amino acids, nucleotides and their related compounds, TMAO, betaine, and nonvolatile organic acids were analysed. From the results of analysis of nucleotides, the contents of AMP and ADP in broiled-dried Mytilus coruscus and Mytilus edulis appeared higher than other nucleotides and tended to increase slightly after cooking, drying, and storage which might be due to both their stability and the addition of degradation of nucleic acids during cooking. In the free amino acid composition of fresh samples abundant amino were taurine, glycine, serine, glutamic acid, alanine, arginine, threonine, tyrosine, lysine and valine in order. Such amino acids as histidine, leucine, methionine and isoleucine were poor and both proline and phenylalanine were merely trace. The free amino acid composition in the extract of Mytilus corucus and Mytilus edulis after broil-drying was not changed. These amino acids, taurine, glycine, feline, glutamic acid, alanine and arginine were abundant in dried samples as well as in the fresh. The total free amino acid was greatly reduced after cooking and drying ranging from $76.3\%$ to $79.7\%$ loss to that of tile fresh. The content of betaine shelved the same tendency as in total free amino acid while TMA slightly increased relating to TMAO decrease during broil-frying. Such nonvolatile organic acids as succinic, lactic, malic and fumaric acid were abundant in both fresh and broiled-dried samples whereas oxalic and pyruvic acid were poor. It is found that the taste compounds of broiled-dried Mytilus coruscus and Mytilus edulis were composed of amino acids as glycine, serine, alanine, glutamic acid, arginine, and betaine, TMAO, ADP, AMP, and organic acids such as succinic acid, lactic acid, malic acid and fumaric acid. No significant differences in the taste compounds between male and female as well as between Mytilus coruscus and Mytilus edulis was not observed.

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E-beam 전조사에 의한 $NO_{3} ^{-}$ 선택 흡착용 아민화 PP-g-GMA 섬유 이온교환체의 합성과 그 특성에 관한 연구 (Studies on the Synthesis of Aminated PP-g-GMA Fibrous ion Exchanger by E-beam Pre-irradiation and Their Properties of Selective Adsorption for $NO_{3} ^{-}$)

  • 황택성;이선아;이면주
    • 폴리머
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    • 제26권2호
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    • pp.153-159
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    • 2002
  • 본 연구에서는 지하수 중의 NO$_{3}^{-}$ 이온을 선택적으로 흡착 제거시키기 위하여 E-beam 전조사법에 의해 GMA 단량체를 폴리프로필렌 섬유 기재에 그라프트 반응시켜 PP-g-GMA 공중합체를 제조한 후 아민화 반응을 통하여 강염기성 APP-g-GMA 음이온교환수지를 합성하였다. 공중합체의 그라프트율 및 TMA에 의한 아민화율은 반응온도가 증가할수록 증가하였으며, $60^{\circ}C$일 때 각각 133%, 88% 최대치를 나타내었고, 이때의 팽윤율과 이온교환용량은 각각 86%, 2.5 meq/g으로 IMAC HP555, Amberlite IRA 400와 같은 상용 이온교환수지 보다 높게 나타났다. $NO_3;^-$ 이온흡착의 최적 조건은 pH 5~6이었으며, trimethylammonium 기를 갖는 -Cl형의 APP-g-GMA 이온교환체가 가장 높은 선택 흡착성을 나타냈다.

단원자 증착법으로 증착한 $AlO_x/\;HfO_y$ 박막에서의 $AlO_x/$ 산화제에 따른 특성 변화 (Comparison of $AlO_x/$ barriers oxidized with $H_2O$, $O_2$ plasma or $O_3$ in Atomic Layer Deposited $AlO_x/\;HfO_y$ stacks)

  • 조문주;박홍배;박재후;이석우;황철성;정재학
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
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    • pp.275-277
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    • 2003
  • 최근 logic 소자의 gate oxide로 기존의 $SiO_2$, SiON보다 고유전, 작은 누설전류를 가지는 물질의 개발이 중요한 이슈가 되고 있다. 본 실험실에서는 Si 기판위에 $HfO_2$를 바로 증착하는 경우, 기판의 Si이 박막내로 확산하여 유전율이 저하되는 문제점을 인식하고, 기판과 $HfO_2$ 사이에 $AlO_x$를 방지막으로 사용하였다. 이 때, $AlO_x$의 Al precursor는 TMA로 고정하고, 산화제로는 $H_2O$, $O_2$-plasma, $O_3$를 각각 사용하였다. 모든 $AlO_x/\;HfO_y$ 박막에서 매우 우수한 누설전류특성을 얻을 수 있었는데, 특히 $O_3$를 산화제로 사용한 $AlO_x$방지막의 경우 가장 우수한 특성을 보였다. 또한 질소 분위기에서 $800^{\circ}C$ 10분간 열처리한 후, 방지막을 사용한 모든 경우에서 보다 향상된 열적 안정성을 관찰할 수 있었다.

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Selective Synthesis and Coating of ZnO Nanomaterials

  • Lee, Jong-Soo;Myungil Kang;Park, Kwangsue;Byungdon Min;Joowon Hwang;Kihyun Keem;Kim, Sangsig
    • KIEE International Transactions on Electrophysics and Applications
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    • 제2C권6호
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    • pp.314-320
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    • 2002
  • Three different ZnO nanomaterials (nanobelts, nanorods, and nanowires) were synthesized at 138$0^{\circ}C$ from ball-milled ZnO powders by a thermal evaporation procedure with an argon carrier gas without any catalysts. Transmission electron microscopy (TEM) revealed that the ZnO nanobelts are single crystalline with the growth direction perpendicular to the (010) lattice plane, and that the ZnO nanorods and nanowires are single crystalline with the growth directions perpendicular to the (001) and (110) lattice Planes, respectively. In cathodoluminescence (CL), the energy Position of the near band-edge (NBE) peak is 3.280 eV for the 100-, 250-, and 500-nm thick nanobelts, 3.262 eV for the 100- and 250-nm thick nanorods, and 3.237 eV for the 500-nm thick nanorods. The synthesized ZnO nanorods were coated conformally with aluminum oxide (Al$_2$O$_3$) material by atomic layer deposition (ALD). $Al_2$O$_3$films were then deposited on these ZnO nanorods by ALD at a substrate temperature of 300 $^{\circ}C$ using trimethylaluminum (TMA) and distilled water ($H_2O$). Transmission electron microscopy (TEM) images of the deposited ZnO nanorods revealed that 40nm-thick $Al_2$O$_3$ cylindrical shells surround the ZnO nanorods.