• Title/Summary/Keyword: TMA

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Retardation of Degradation in Accelerated Aging of Cotton Cellulose Using Borohydride Reduction

  • Kim, Hye-Kyung;Choi, Hyung-Min
    • International Journal of Human Ecology
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    • v.8 no.1
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    • pp.1-8
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    • 2007
  • Degradation of cellulose during prolonged exposure in atmospheric conditions has been recognized as one of main problems in preserving cellulose-made products. The purpose of this research was therefore to study effects of borohydride reduction in improving both the color and strength retention of cotton fabrics artificially aged at temperatures ranging from $100^{\circ}C$ to $150^{\circ}C$. Results indicated that the fabrics treated with either sodium or tetramethylammonium borohydrides (TMA) were degraded at rates about one-half that of water-washed cotton. These results were consistent over the temperature range. Calculation of the activation energy (Ea) by different methods showed $Ea\;=\;25.5{\pm}\;1.5\;Kcal$, in keeping with measurements made by others at lower temperatures. The TMA-treatment was effective in minimizing discoloration of the fabrics with pre-baking, but not of the un-prebaked fabrics.

A Study on the Characteristics of Aluminum Oxide Thin Films Prepared by ECR-PECVD (ECR-플라즈마 화학 증착된 알루미늄 산화막 연구)

  • 이재균;전병혁;이원종
    • Journal of the Korean Ceramic Society
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    • v.31 no.6
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    • pp.601-608
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    • 1994
  • Aluminum oxide thin films were deposited on p-type(100) silicon substrates by electron cyclotron resonance plasma enhanced CVD(ECR-PECVD) using TMA[Al(CH3)3] and oxygen as reactant gases at 16$0^{\circ}C$ or lower temperatures. The aluminum oxide films deposited by ECR-PECVD have the amorphous structure with the refractive index of 1.62~1.64 and the O/Al ratio of 1.6~1.7. Oxygen flow rate necessary for the stable deposition of the aluminum oxide films increases as the deposition temperature increases. It was found from the OES analysis that the ECR plasma had les cooling effect by introducing the TMA reactant gas in comparison with the RF plasma. The properties of aluminum oxide films prepared by ECR-PECVD were compared with those prepared by RF-PECVD. The ECR-PECVD aluminum oxide films have the higher refractive indices, the lower contents of impurities (H and C) and the stronger wet etch resistance than those deposited by RF-PECVD.

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Freshness Changes during Iced and Partial Freezing Storage of Sashimi (생선회용 어육의 냉장 및 Partial Freezing 저장중 선도의 변화)

  • 김복자
    • Journal of the Korean Home Economics Association
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    • v.18 no.4
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    • pp.87-94
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    • 1980
  • This study was carried out to make a comparison between iced and partial freezing of bastard, yellow tail, poragy, pomfret that were generally used for Sashimi and the results that measured k-value, VB-N, TMA-N were measured and the results are as follows : 1. Regardless of the kinds of fish, freshness is better preserved in partial freezing than in iced storage. 2. In Bastard, Yellow tail When iced its freshness estimation index its K-value rose above 20% after 4 days of storage. When stored partially frozen, its K-value reached 20% after 8 days. 3. Porgy when iced, its K-value reach 20% after 6 days of storage. But when stored partially frozen, its K-value could be prolonged until 9 days with same degree. Porge was preserved for the longest time among the four fishes. 4. Pomfret When iced during 4 days and stored partially frozen during 6 days, their K-value reached about 20% Pomfret was preserved for the shortest time among the four fishes. 5. According to the kinds of fish, the results that measured VB-N, TMA-N, total bacteria have some differences, but the method of partial freezing was superior to iced storage.

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AoA-Based Local Positioning System Using a Time-Modulated Array

  • Baik, Kyung-Jin;Lee, Sangjoon;Jang, Byung-Jun
    • Journal of electromagnetic engineering and science
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    • v.17 no.4
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    • pp.181-185
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    • 2017
  • In this paper, we propose an angle-of-arrival (AoA)-based local positioning system using a time-modulated array (TMA). The proposed system can determine a two-dimensional position using only two TMAs without any synchronization between the two receivers. The hardware for the proposed system consists of two commercial monopole antennas, a self-designed switch, and a well-known software-defined radio receiver. Furthermore, the location can be simply estimated in real time without the need for complicated positioning algorithms such as the MUSIC and ESPRIT algorithms. In order to evaluate the performance of our system, we estimated the position of the wireless node in an office environment. The position was estimated with a mean error of less than 0.1 m. We therefore believe that our system is appropriate for various wireless local positioning applications.

Properties of $Al_2O_3$ Insulating Film Using the ALD Method for Nonvolatile Memory Application (비휘발성 메모리 응용을 위한 ALD법을 이용한 $Al_2O_3$ 절연막의 특성)

  • Jung, Soon-Won;Lee, Ki-Sik;Koo, Kyung-Wan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.12
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    • pp.2420-2424
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    • 2009
  • We have successfully demonstrated of metal-insulator-semiconductor (MIS) capacitors with $Al_2O_3/p-Si$ structures. The $Al_2O_3$ film was grown at $200^{\circ}C$ on H-terminated Si wafer by atomic layer deposition (ALD) system. Trimethylaluminum [$Al(CH_3)_3$, TMA] and $H_2O$ were used as the aluminum and oxygen sources. A cycle of the deposition process consisted of 0.1 s of TMA pulse, 10 s of $N_2$ purge, 0.1 s of $H_2O$ pulse, and 60 s of $N_2$ purge. The 5 nm thick $Al_2O_3$ layer prepared on Si substrate by ALD exhibited excellent electrical properties, including low leakage currents, no mobile charges, and a good interface with Si.

Study on Hygrothermal Degradation and Corrosion Protection of Epoxy Coatings Cured by Different Amine Based Curing Agents

  • Shon, Min-Young;Kwon, Huck-Sang
    • Corrosion Science and Technology
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    • v.9 no.5
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    • pp.201-208
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    • 2010
  • Epoxy coatings cured by different amine based curing agents have been prepared. Atomic force microscopy (AFM) has been used to monitor the surface topology changes of epoxy coatings before and after hygrothermal cyclic test. The glass transition temperature ($T_g$) and coefficient of thermal expansion (CTE) of the epoxy coating were measured by Thermo-mechanical Analysis (TMA). The Electrochemical impedance spectroscopy (EIS) with hygrothermal cyclic test has been introduced to evaluate the corrosion protection of the epoxy coatings. In conclusion, thermal properties of epoxy coatings were in good agreement with the results of corrosion protection of epoxy coated carbon steel obtained result by EIS with hygrothermal cyclic test. The relationship between thermal properties, surface roughness changes and corrosion protection of epoxy coatings are discussed in this study.

Endovascular Closure Resolves Trimethylaminuria Caused by Congenital Portosystemic Shunts

  • Ponce-Dorrego, Mar?a Dolores;Garzon-Moll, Gonzalo
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.22 no.6
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    • pp.588-593
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    • 2019
  • This study aimed to report three new cases of an association between two rare conditions, congenital portosystemic shunts (CPSS) and trimethylaminuria (TMAU), and the efficacy of endovascular closure of the CPSS for resolving TMAU. Between November 2014 and April 2017, 15 patients with CPSS were enrolled in this prospective study to assess the efficacy of percutaneous endovascular shunt closure. Three patients presented with clinical symptoms of TMAU that were confirmed by urine analysis of trimethylamine (TMA) and TMA n-oxide. One year after endovascular closure of the congenital portosystemic shunt, the same parameters were evaluated were obtained and the values were compared to the pretreatment values. The results indicated the disappearance of clinical symptoms of TMAU and normalization of the urine test parameters in two patients and no changes in one patient, who developed new portosystemic communications.

The Effects of Additives on the Thermal Properties of a Clathrate Compound(I) -The Case of Ethanol- (포접화합물의 열물성에 미치는 첨가제의 효과(I) -TMA 물계 포접화합물에 Ethanol을 첨가한 경우-)

  • 김진흥;정낙규;김석현;김창오;강승현
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.3
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    • pp.258-264
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    • 2004
  • The ice thermal storage system is to use consolation latent heat of water. But, supercooling phenomenon of water during phase change is to increase the cooling capacity and to decrease COP of the refrigerator. Furthermore, this causes the operation cost of system to increase and the efficiency of energy to decrease. Therefore, the better thermal storage material than the water is required. The purpose of this study is to improve supercooling characteristics and thermal properties of TMA 30wt% clathrate by using Ethanol.