• Korean Chemical Engineering Research
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• v.48 no.4
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• pp.534-539
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• 2010

The adsorptive removal of organic sulfur compounds including tert-butylmercaptane(TBM), tetrahydrothiophene(THT) and dimethylsulfide(DMS) in methane was investigated over NaY and copper-exchanged NaY(CuNaY) zeolites at 303 K and atmospheric pressure. In the ternary adsorption system, the preferential adsorption of THT over other sulfur compounds on NaY and the concurrent adsorption of all sulfur compounds on CuNaY were achieved, which could be explained by the breakthrough curve, the temperature-programmed desorption, and the apparent activation energy for desorption. The sulfur uptake capacity of CuNaY(2.90~3.20 mmol/g) was much higher than that of NaY(0.70~0.90 mmol/g). A comparative study indicated that the $Cu^{1+}$ sites and acidity of CuNaY were probably responsible for the strong interaction with sulfur atom and high sulfur uptake abilities.

• Bulletin of the Korean Chemical Society
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• v.30 no.8
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• pp.1755-1759
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• 2009

Surface structure and molecular orientation of self-assembled monolayers (SAMs) formed by the spontaneous adsorption of tetrahydrothiophene (THT) and thiophene (TP) on Au(111) were investigated by means of scanning tunneling microscopy (STM) and carbon K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy. STM imaging revealed that THT SAMs have a commensurate (3 ${\times}\;2\sqrt[]{3}$) structure containing structural defects in ordered domains, whereas TP SAMs are composed of randomly adsorbed domains and paired molecular row domains that can be described as an incommensurate packing structure. The NEXAFS spectroscopy study showed that the average tilt angle of the aliphatic THT ring and $\pi$-conjugated TP ring in the SAMs were calculated to be about $30^o\;and\;40^o$, respectively, from the surface normal. It was also observed that the $\pi$* transition peak in the NEXAFS spectrum of the TP SAMs is very weak, suggesting that a strong interaction between $\pi$-electrons and the Au surface arises during the self-assembly of TP molecules. In this study, we have clearly demonstrated that the surface structure and adsorption orientation of organic SAMs on Au(111) are strongly influenced by whether the cyclic ring is saturated or unsaturated.

• The Korean Journal of Nuclear Medicine
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• v.36 no.2
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• pp.121-132
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• 2002

Purpose : Taxol(Paclitaxel), an antineoplastic agent, has been used in the treatment of ovarian and breast cancers. The determination of optimal Taxol concentrations in human serum was required for enhancing therapeutic effect and maintaining the appropriate Taxol level in blood. This study was aimed to synthesizeradiolabeled Taxol derivatives as radiotracer in competitive radioimmunoassay for monitoring Taxol concentrations in blood and to determine the usefulness of its derivatives. Materials and Methods : Hemisucdcinyltaxol(HT) was synthesized by esterification of Taxol with succinic anhydride. Tyraminehemisuccinyltaxol(THT) was synthesized by coupling of HT with tyramine using isobutylchlormate as coupling agent and purified by HPLC. By using chloramine-T($5.25mg/ml,\;10{\mu}{\ell}$) as oxidant agent, THT($4mg/ml,\;30{\mu}{\ell}$) was labeled wity $^{125}I\;(37MBq,\;1mCi)$. To estimate the stability of purified THT, $^{125}I-iodotyraminehemisuccinyltaxol(^125}ITHT)$ was dissolved in 80% acetonitrile aqueous solution, and the solution was incubated at $4^{\circ}C\;and\;37^{\circ}C$ for 7 days. At various time intervals, the stability of THT and $^{125}ITHT$ was monitored. The titer of Taxol monoclonal antibody, 3G5A7, was determined by competitive radioimmunoassay using $^{125}ITHT$ as a labeled antigen. A standard dose-response curve was demonstated by Taxol competitive radioimmunoassay. Resulls : HT and THT were synthesized with 79.9% and 19.5% yield, respectively. The labeling yield of $^{125}ITHT$ was 93%. After 7 days, the chemical purity of THT was 96.5% at $4^{\circ}C$, and 97.5% at $37^{\circ}C$. After 3 days, $^{125}ITHT$ was stable with 94.7% at $4^{\circ}C$ and 93.4% at $37^{\circ}C$. After 7 days, fadiochemical purity was diminished to 88.1% at $37^{\circ}C$. The titer of Taxol monoclonal antibody, 3G5A7, was determined to 1:256. A standard dose-response curve demonstated good collinearity ($R^2=0.971$) as Taxol concentration-dependent manner. Conclusion : Competitive radioimmunoassay using $^{125}I-iodotyraminehemisuccinytaxol$ as radiotracer could be used to monitor for concentration of Taxol in the human serum.

• Journal of Microbiology and Biotechnology
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• v.21 no.1
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• pp.62-70
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• 2011

The antibacterial effects of nine lactic acid bacteria (LAB) against Campylobacter jejuni were investigated by using agar gel diffusion and co-culture assays. Some differences were recorded between the inhibition effects measured with these two methods. Only two LAB, Lb. pentosus CWBI B78 and E. faecium THT, exhibited a clear anti- Campylobacter activity in co-culture assay with dehydrated poultry excreta mixed with ground straw (DPE/GS) as the only growth substrate source. It was observed that the supplementation of such medium with a cellulase A complex (Beldem S.A.) enhanced the antimicrobial effect of both LAB strains. The co-culture medium acidification and the C. jejuni were positively correlated with the cellulase A concentration. The antibacterial effect was characterized by the lactic acid production from the homofermentative E. faecium THT and the lactic and acetic acids production from the heterofermentative Lb. pentosus CWBI B78. The antagonistic properties of LAB strains and enzyme combination could be used in strategies aiming at the reduction of Campylobacter prevalence in the poultry production chain and consequently the risk of human infection.

• Korean Journal of Plant Resources
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• v.2 no.2
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• pp.291-297
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• 1989

It was indicated that natural fiber crops Ln Korea have been major crops, such as cotton, flax, ramie and Kenaf. The major varieties andagronomic characterics are summarized as follows. Cotton variety, Mokpo 6 is long fiber length and, is high lint yield, flax variety, Wiera is hiTh amount of dry stem and grains weiTht. On the other hand, kenaf variety, Suweon 2 is high dry fiber weight and fiher ratio.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.03a
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• pp.262-270
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• 2004

Basic experiments were carried out using the THT-IV low-power Hall thruster to examine the influences of magnetic field shape and strength, and acceleration channel length on thruster performance and to establish guidelines for design of high-performance Hall thrusters. Thrusts were measured with varying magnetic field and channel structure. Exhaust plasma diagnostic measurement was also made to evaluate plume divergent angles and voltage utilization efficiencies. Ion current spatial profiles were measured with a Faraday cup, and ion energy distribution functions were estimated from data with a retarding potential analyzer. The thruster was stably operated with a highest performance under an optimum acceleration channel length of 20 mm and an optimum magnetic field with a maximum strength of about 150 Gauss near the channel exit and with some shape considering ion acceleration directions. Accordingly, an optimum magnetic field and channel structure is considered to exist under an operational condition, related to inner physical phenomena of plasma production, ion acceleration and exhaust plasma feature. A new Hall thruster was designed with basic research data of the THT-IV thruster. With the thruster with many considerations, long stable operations were achieved. In all experiments at 200-400 V with 1.5-3 mg/s, the thrust and the specific impulse ranged from 15 to 70 mN and from 1100 to 2300 see, respectively, in a low electric power range of 300~1300 W. The thrust efficiency reached 55 %. Hence, a large map of the thruster performance was successfully made. The thermal characteristics were also examined with data of both measured and calculated temperatures in the thruster body. Thermally safe conditions were achieved with all input powers.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.21 no.1
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• pp.281-290
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• 1996

In this paper we suggest an OFDM star network based on carrier distribution and homodyne detection in which all optical carriers generated and stabilized in a specific node are distributed to each node. We studied ASK and PSK modulation schemes and calculated rspective SNRs and BERs for this network. We also discussed on the optical power requirement on the light sources for 200 Mb/s transmission speed. As a result, we found tht ASK and PSK respectively require 13 dBm and 10 dBm for 32 nodes and the nmber of nodes can be expanded to 73 with only 0 dBm of power and minimum insertion losses of components. The proposed network is more reliable than the conventional ones due to the centralized carrier maintenance andthe network is suitable for the adverse environment of the nodes.

• Journal of the Chungcheong Mathematical Society
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• v.4 no.1
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• pp.61-69
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• 1991

By $C^{(1)}$[0, 1] we denote the Banach algebra of complex valued continuously differentiable functions on [0, 1] with norm given by $${\parallel}f{\parallel}=\sup_{x{\in}[0,1]}({\mid}f(x){\mid}+{\mid}f^{\prime}(x){\mid})\text{ for }f{\in}C^{(1)}$$. By A we denote the sub algebra of $C^{(1)}$ defined by $$A=\{f{\in}C^{(1)}:f(0)=f(1)\text{ and }f^{\prime}(0)=f^{\prime}(1)\}$$. By an isometry of A we mean a norm-preserving linear map of A onto itself. The purpose of this article is to describe the isometries of A. More precisely, we show tht any isometry of A is induced by a point map of the interval [0, 1] onto itself.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.22 no.6
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• pp.1266-1272
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• 1997

Due to the price and performanceof uniprocessor workstations and off-the shelf networking, network of workstations(NOW) ae now a cost-effective parallel processing platform tht is competitive with supercomputers. Meanwhile, current network fiile system protocols rely heavily on a central server to coordinate file activity among client workstations. This central server can become a bottleneck that limits scalibility for environments with large numbers of clients. In this paper, we propsoe a highly reliable and effective software RAID file system on the network of workstation environment. We present results form a trace-driven simulation study that shows that the designed software RAID file system is more effective in the aspect of elapsed time when compared with client/server file systems.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.21 no.4
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• pp.807-821
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• 1996

In this paper, we proposed a nonlinear hierarchical mtion estimation method. Generally, the conventional hierarchical motion estimation methods have been proposed for fast convergence and detection of large motions. But they have a common drawback that large error in motion estimation is propapated across motion discontinuities. This artifiact is due to the constriaint of motion continuity and the linear interpolation of motion vectors between hierarchical levels. In this paper, we propose an effective hierarchical motion estimation mechod that is robust to motion discontinuities. The proposed algorithm is based on the decomposition of the functional domain for optimizing the intra-level motion estimation functional. Also, we propose an inter-level nonlinear motion estimation equation rather than using the conventional linearprojection scheme of motion field. computer simulations with several test sequences show tht the proposed algorithm performs better than several conventional methods.