• Title/Summary/Keyword: TCF4

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Dyeing of Cotton fabrics by Glycyrrhizae Radix Extract (감초추출물에 의한 면직물의 염색)

  • Lee, Young-Sook;Jang, Jeong-Dae
    • Textile Coloration and Finishing
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    • v.22 no.1
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    • pp.21-27
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    • 2010
  • The purpose of this research was to investigate the color characteristic and the dyeing properties of Glycyrrhizae Radix extract on cotton fabrics. The highest absorbance of Glycyrrhizae Radix extract was obtained in 75 v/v% of ethyl alcohol in water. Pre-mordanted cotton fabrics dyed at $30^{\circ}C$ and pH 3 for 80 minutes showed the highest K/S value. According to the dyeing conditions, the colors of the fabrics varied from yellow(Y) and yellowish red(YR) to greenish yellow(GY). The color fastness of the fabrics in dry-cleaning and water was 4~5 rating. The deodorization capacity and UV-cut effect of the dyed fabrics were higher than those of undyed ones.

Octadecane Fixation via Photocrosslinking of Polyethylene Film (폴리에틸렌 필름의 광가교에 의한 옥타데칸의 고정화)

  • Yun, Deuk-Won;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.22 no.3
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    • pp.214-219
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    • 2010
  • Polyethylene(PE) films were photocrosslinked by continuous UV irradiation. Benzophenone addition as low as 1wt% into the PE film increased the gel fraction up to 96%. The photocrosslinking was attributed to the recombination of PE radicals generated upon UV irradiation, which was enhanced by the hydrogen abstraction of the added benzophenone. Also the crossliked PE showed higher thermal stability and decreased crystallinity with increasing UV energy as shown by TGA, XRD and DSC analysis. It was also possible to fix 5.4% octadecane into PE by the photocrosslinking. The crosslinked PE film containing octadecane showed lower tensile strength and modulus coupled with higher extension compared to that without octadecane, which can be used as a new plasticizing method for the crosslinked PE film.

Synthesis and Application of Anthraquinoid Magenta Dyes for Pure Polypropylene Fibers (순수 폴리프로필렌 섬유용 안트라퀴논계 마젠타 염료의 합성과 응용)

  • Kim, Taekyeong;Chae, Yuri
    • Textile Coloration and Finishing
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    • v.25 no.2
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    • pp.102-109
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    • 2013
  • A new series of anthraquinoid magenta dyes having alkylphenyl substituents was synthesized and applied toward pure polypropylene fibers. The affinity of the dyes toward polypropylene fibers was increased gradually with the increase of the length of alkyl substituents. The optimum length of alkyl group was determined as heptyl substituents from the practical point of view. The color values of the dyes on polypropylene fabrics displayed slight bluish red, namely magenta which is more practical than primary red in color matching. The good fastness ratings to washing, rubbing and light were obtained for the dyes having longer alkyl groups than hexyl substituents. Expecially they exhibited ratings 4 of light fastness, which is higher than primary red dyes previously reported.

Anthraquinone and Indole based Chemosensor for Fluoride Anions Detection

  • Son, Young-A;Kim, Sung-Hoon
    • Textile Coloration and Finishing
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    • v.26 no.1
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    • pp.1-6
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    • 2014
  • We have designed and synthesized the colorimetric chemosensor through the reactions of 1,2-anthraquinone and indol-3-carboxaldehyde. Due to its well conjugated D-${\pi}$-A system and the existence of NH-fragment in indole moiety, we expected that the chemosensor can detect target anions with NH-fragment in indole part of the structure. In this regard, UV-Vis absorption spectra were measured to investigate sensing properties of the probe toward different anions in DMSO. This chemosensor shows to detect fluoride anions with absorption change in intensity. These properties are mainly related to the deprotonation effect. ICT system in this molecule was also observed by the computational approach using Material Studio 4.3 package.

Characteristics analysis and fabrication of SAW filter for micro-wave using Undoped-GaN thin film (Undoped-GaN 압전 박막을 이용한 RF용 SAW 필터의 제조 및 특성분석)

  • 장철영;박민정;정은자;고성용;최현철;이정희;이용현
    • Proceedings of the IEEK Conference
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    • 2002.06a
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    • pp.423-426
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    • 2002
  • Undoped-GaN thin film is deposited on Sapphire substrate by MOCVD. SAW velocity is measured with tile center frequency by HP8753C. Center frequency is 266.52 MHz and SAW velocity is 5330㎧ when wavelength was 20 Um. insertion loss, Q factor and side love attenuation is 41.265 dB, 257.41 and over 23 dB. k'i is calculated from tile measured data. k2'is from 1 % to 4 %. TCF is -61.817pp/m/$^{\circ}C$.

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Electrochemical Study on Energy Potential Levels with Pyrene Molecule

  • Kim, Hyungjoo;Li, Xiaochuan;Son, Young-A
    • Textile Coloration and Finishing
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    • v.25 no.3
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    • pp.159-164
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    • 2013
  • Pyrene based molecule has been synthesized through the reaction of pyrene-1-carboxaldehyde and 4- phenylthiosemicarbazide in this research. The pyrene based molecule showed specific optical properties such as absorption and emission changes after mixing with fluoride in DMSO. The phenomenon is induced by the interaction of the molecule and fluoride. This interaction may affect to electron distributions and potential energy levels. In this regard, synthesized pyrene based molecule has been investigated for its electron distributions and HOMO/LUMO energy levels depending on interaction with fluoride. The absorption measurement, cyclicvoltammograms and computational method were investigated to calculate and compare energy potential levels.

Dyeing of Ultra High Molecular Weight Polyethylene Fiber Using Anthraquinoid Super-hydrophobic Navy Dyes (안트라퀴논계 초소수성 네이비 염료를 이용한 초고분자량 폴리에틸렌 섬유의 염색)

  • Kim, Taekyeong;Ma, Heejung
    • Textile Coloration and Finishing
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    • v.31 no.2
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    • pp.98-106
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    • 2019
  • The dyeability and fastness properties of super-hydrophobic navy dyes having different length of alkyl groups were investigated on ultra high molecular weight polyethylene fabrics. Those dyes exhibited strong color strength in the wavelength of mainly 550~650nm, which meant that they were navy color. From the results accomplished under various dyeing conditions, it can be concluded that those dyes have higher affinity on the fibers at $130^{\circ}C$ than at the lower dyeing temperature. Considering processing time and thermal damage of the fibers, one hour is good enough to obtain full strength of color. Maximum color strength was obtained at 2~3%owf of pure dyes. Except for the rub fastness under dry condition, all fastness such as to washing and light showed as good as of 4~5 ratings.

Influence of Cotton Pre-Treatment on Dyeing with Rubia cordifolia extracts for Cotton (면의 전처리 방법이 Rubia cordifolia 추출물의 염색성에 미치는 영향)

  • Bum Hoon Lee
    • Textile Coloration and Finishing
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    • v.35 no.1
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    • pp.1-7
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    • 2023
  • In this study, the influence of pre-treatment(bleaching, mercerization by liquid ammonia and caustic soda) on cotton fabrics were investigated on dyeing Rubia cordifolia extracts. Aluminium Sulfate, Iron(Ⅱ) Sulfate Heptahydrate, Copper(Ⅱ) Sulfate Pentahydrate, Tin(Ⅱ) Sulfate, Manganese(Ⅱ) Chloride Tetrahydrate were used as mordanting agents. K/S value and washing fastnesses of the dyed cotton fabrics pretreated under different conditions were investigated. The K/S values were increased in the order of bleaching, liquid ammonia and mercerization pre-treatment. It was found that the pre-treatment conditions did not significantly affect the color change. The colorfastness to washing of most of all dyed fabrics were over grade 4 regardless of pre-treatment condition.

The Effect of Sodium dithionite in Dyeing with Indigo Pulverata Levis (청대 염색에서 sodium dithionite의 영향)

  • Cho, Kyung-Rae
    • Textile Coloration and Finishing
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    • v.27 no.2
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    • pp.155-163
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    • 2015
  • In dyeing cotton fabric with the Indigo Pulverata Levis, this research examined the effect of the sodium dithionite($Na_2S_2O_4$). For the separation of the Indigo-calcium hydroxide complex in the alkaline solution of the Indigo Pulverata Levis, the reduction with the $Na_2S_2O_4$ at $25^{\circ}C$ was more effective than the solution boiling. The concentration of Indigo in the cotton fabric increased with the increase of Indigo Pulverata Levis, but the concentration of indirubin did not increase particularly. The optimum temperature for the reduction was $60^{\circ}C$, and K/S value of dyed fabric decreased at over $60^{\circ}C$. The concentration of indigo and indirubin in the cotton fabric decreased as $Na_2S_2O_4$ concentration increased. In treating cotton fabric dyed with the Indigo Pulverata Levis by the $Na_2S_2O_4$, the concentration of indirubin decreased and the surface color of dyed cotton changed from purple blue to blue while the treatment temperature was getting higher.

Fluorescence-Quenched Sensor for Trinitophenol in Aqueous Solution Based on Sulfur Doped Graphitic Carbon Nitride

  • Min, Kyeong Su;Manivannan, Ramalingam;Satheshkumar, Angu;Son, Young-A
    • Textile Coloration and Finishing
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    • v.30 no.2
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    • pp.63-69
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    • 2018
  • In this study, we report on successful attempt towards the synthesis of sulfur self-doped $g-C_3N_4$ by directly heating thiourea in air. The synthesized materials were characterized using UV-vis spectral technique, FT-IR, XRD and TEM analysis. Further, the obtained material shows an excellent detection of carcinogenic TNP(Tri nitro phenol) in the presence of 10-fold excess of various other common interferences. The strong inner filter effect and molecular interactions(electrostatic, ${\pi}-{\pi}$, and hydrogen bonding interactions) between TNP and the $S-g-C_3N_4$ Nano sheets led to the fluorescence quenching of the $S-g-C_3N_4$ Nano sheets with an excellent selectivity and sensitivity towards TNP compared to that of other nitro aromatics under optimal conditions and the detection limit calculated was found to be 6.324 nM for TNP. The synthesized nanocomposite provides a promising platform for the development of sensors with improved reproducibility and stability for ultra-sensitive and selective sensing of TNP.