• Title/Summary/Keyword: T1CE

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Oxygen Permeability, Electronic and ionic Conductivities and Defect Chemistry of Ceria-Zirconia-Calcia

  • Kawamura, Ken-ichi;Watanabe, Kensuke;Nigara, Yutaka;Kaimai, Atsushi;Kawada, Tatsuya;Mizusaki, Junichiro
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.146-150
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    • 1998
  • The total conductivity and oxygen permeation in (Ce1-xZrxO2)0.9(CaO)0.1 solid solutions were measure das a function of temperature and oxygen partial pressure. Empirically, σ at given x and T was expressed essentially by σ=σo2+σeo Po2-1/4, where σo2 and σeo are constant. Applying a standard defect model in which major defects are Cace", Cece' and Vo in ideal solution, we can assign σo2 as the oxide ion conductivity decreases while the electronic conductivity increases with the increase in Zr content. Using the oxide ion and electronic conductivities thus determined, the oxygen permeation flux was calculated for respective Po2 and T conditions at which the measurements were made. The calculated values were found to agree with the observed ones.

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Production and Mechanical Properties of Mg-Zn-Ce Amorphous Alloys by Dispersion of Ultrafine hcp-Mg Paticles (hcp-Mg 입자분산형 Mg-Zn-Ce계 비정질합금의 제조와 기계적 성질)

  • Kim, Seong-Gyu;Park, Heung-Il;Kim, U-Yeol;Jo, Seong-Myeong;Kim, Yeong-Hwan;Inoue, A.;Masumoto, T.
    • Korean Journal of Materials Research
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    • v.4 no.8
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    • pp.847-854
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    • 1994
  • An amorphous single phase and coexistent amorphous and hcp-Mg phases in Mg-Zn-Ce system were found to form in the composition ranges of 20 to 40% Zn, 0 to 10% Ce and 5 to 20% Zn, 0 to 5% Ce, respectively. A $Mg_{85}Zn_{12}Ce_{3}$ amorphous alloy containing nanoscale hcp-Mg particles was found to form either by melt spinning or by heat treatment of melt -spun ribbon. The particle size of the hcp-Mg phase can be controlled in the range of 4 to 20 nm. The mixed phase alloy prepared thus has a good bending ductility and exhibits high ultimate tensile strength($\sigma_{B}$) ranging from 670 to 930 MPa and fracture elongation($\varepsilon_{f}$) of 5.2 to 2.0%. The highest specific strength($\sigma_{B}$/density =$\sigma_{s}$)$3.6 \times 10^5N \cdot m/kg$. It should be noted that the highest values of flB, US and ?1 are considerably higher than those (690MPa,$2.5 \times 10^5N \cdot m/kg$and 2.5%) for amorphous Mg-Zn-Ce alloys. The increase of the mechanical strengths by the formation of the mixed phase structure is presumably due to a dispersion hardening of the hcp supersaturated solution which has the hardness higher than that of the amorphous phase with the same composition.

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Changes of Hydrogen Storage Properties upon Hydrogen Absorption-Desorption Cycling in AB5-type Alloys (AB5계 합금에 있어서 수소 흡수-방출 cycling에 따른 수소 저장 특성 변화)

  • Noh, Hak;Choi, Jeon;Jung, So-Ri;Choi, Seung-Jun;Park, Choong-Nyeon
    • Journal of Hydrogen and New Energy
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    • v.12 no.3
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    • pp.177-189
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    • 2001
  • T hydrogen absorption-desorption behavior induced by thermal or hydrogen pressure cycling in a closed system was observed in hydrogen storage alloys, $(La-R-Mm)Ni_{4.5}Fe_{0.5}$, $MmNi_4Fe_{0.85}Cu_{0.15}$ and $(Ce-F-Mm)Ni_{4.7}Al_{0.2}Fe_{0.1}$. Thereby (La-R-Mm), Mm and (Ce-F-Mm) refer to La-rich mischmetal, mischmetal and Ce-free mischmetal respectively. As the results, it is found that the alloy stabilities during thermal cycling varies with alloy composition change. The highest stability occurs in $MmNi_4Fe_{0.85}Cu_{0.15}$ and the lowest stability in $(La-R-Mm)Ni_{4.5}Fe_{0.5}$. Comparing hydrogen pressure cycling with thermal cycling, pressure cycling causes severer degradation of the alloy $(Ce-F-Mm)Ni_{4.7}Al_{0.2}Fe_{0.1}$ than thermal cycling. When the 1500 times-cycled alloy is annealed at $400^{\circ}C$ for 3hrs under 1 atm of hydrogen pressure the hydrogen storage capacity is recovered only partially but not completely to the initial capacity. The amount of capacity loss after annealing is larger in the hydrogen pressure cycled samples than in the thermal cycled, suggesting an incoming of impure gas during hydrogen pressure cycling.

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Design of wideband microstrip monopole slot antenna (광대역 마이크로스트립 모노폴 슬롯안테나의 설계)

  • Lee, Young-Soon;Cho, Yun-Ki
    • Journal of Advanced Navigation Technology
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    • v.16 no.5
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    • pp.766-772
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    • 2012
  • In the present study, wideband microstrip monopole slot antennas which can be applied to the RF4CE Zigbee remote controller are designed. First I-shaped monopole slot antenna which has ${\lambda}g/4$ length at 2.45GHz is designed. In particular, a conducting via is used to connect the microstrip feed line and the ground plane surrounded with the etched slot for the bandwidth improvement. In order to reduce the antenna size, it is changed into L-shaped and T-shaped monopole slot antennas for which improve results of antenna performance are observed. In case of T-shaped monopole slot antenna, impedance bandwidth(VSWR<2) is about 3.32GHz, and also its radiation efficiency and gain is more than 90% and 2.1dBi respectively at whole operating frequency range. In particular, all of proposed monopole slot antennas have the end-fire radiations which has a maximum radiation power toward direction of open ends of monopole slots.

Fabrication of YBCO coated conductors using the nickel tapes textured in single crystalline qualities

  • Yoo, Ja-Eun;Jung, Kook-Chae;Lee, Jae-Seoung;Oh, Sang-Jun;Kim, Ho-Sup
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.86-91
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    • 2000
  • Ni tapes were textured by taking advantage of their secondary recrystallization. The obtained 18cm long tapes had textures of single crystalline qualities with their [001] axes tilted with respect to the surface and their [010] axes parallel to the rolling direction. YBCO/CeO$_2$/YSZ/CeO$_2$ films grown on the Ni tape had the same crystalline orientations. Magnetic field dependent I-V relations were measured on a 5cm section of the tape. Jc defined by 1mV criterion was 1.5 ${\times}$ 10$^5$A/cm$^2$ at 77K under zero field and was reduced by ${\sim}$50% under the applied magnetic field of 5T.

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Fabrications of YBCO Coated Conductors Using Tilted Single Crystalline Nickel Tapes

  • Kim, Ho-Sup;Yoo, Ja-Eun;Jung, Kook-Chae;Youn, Do-Jun
    • Progress in Superconductivity
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    • v.2 no.1
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    • pp.33-38
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    • 2000
  • Ni tapes were textured by taking advantage of their secondary recrystallization. The obtained 18cm long tapes had textures of single crystalline qualities with their [001] axes tilted with respect to the surface and their [010] axes parallel to the rolling direction. The reproducibility of this texturing was checked by taking statistics on the crystal orientations of 24 Ni tapes. $YBCO/CeO_2/YSZ/CeO_2$ films grown on the Ni tape had the same crystalline orientations. Magnetic field dependent I-V relations were measured on a 5cm section of the tape. $J_c$ defined by $20{\mu}V/mm$ criterion was $1.5\times10^5A/cm^2$ at 77K under zero field and was reduced by $\sim$50% under the applied magnetic field of 5T.

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Intrinsic and Extrinsic Defects and Their Itinerant Electronic Conductivity of Ceria (본성 및 외성 영역에서 Ceria 의 결함구조 및 자유전자 전도도)

  • Keu Hong Kim;Hyun Koen Suh;Young Sik Kwon;Jae Shi Choi
    • Journal of the Korean Chemical Society
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    • v.31 no.5
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    • pp.389-394
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    • 1987
  • The electrical conductivity of CeO$_2$ has been measured in the temperature range of 300 to 1000${\circ}$C under the oxygen pressures of 10$^{-5}$ to 10$^{-1}$ atm. Plots of log ${\sigma}$ vs. 1/T at constant PO$_2$ are found to be linear with an inflection, and the activation energy obtained from the slopes appears to be 2.16 eV for the intrinsic region. The conductivity dependences on PO$_2$ at the above temperature range are closely approximated by ${\sigma}$ ${\alpha}$PO$_2^{-1/4}$ for the intrinsic and ${\sigma}$ ${\alpha}$PO$_2^{-1/6.2}$ for the extrinsic, respectively. The dominant defects in this sample are believed to be Ce$^{3{\cdot}}$ interstitial for the intrinsic and the (Vo-2e') for the extrinsic range. The interpretations of conductivity dependences on temperature and $PO_2$ are presented, and conduction mechanisms are proposed to explain the data.

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Usefulness of the High B-value DWI in Brain Tumors (뇌종양 확산강조영상에서 High B-value의 유용성 평가)

  • Kim, Jin-tae;Byun, Jae-Hu;Park, Yong-Seong;Lee, Rae-Gon;Hwang, Seon-Kwang
    • Korean Journal of Digital Imaging in Medicine
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    • v.17 no.1
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    • pp.33-41
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    • 2015
  • This study attempts to examine the clinical usefulness of High b-value DWI (diffusion weighted imaging) for brain tumors with an edema. Subjects were seven patients selected from 65 patients who received an MRI scan for suspected encephalopathy and confirmed diagnosis at our hospital from February to July 2015 (male: 7, average age : 66 years old). As test equipment, 3.0T MR System (ACHIEVA Release, Philips, Best, The Netherlands) and 8Channel SENSE Head Coill were used. DWI checks on the use of the variable TR 5460ms, TE 132ms, Slice Thickness 4mm, gap 1mm, Slice number 29 is, 3D T1WI is TR 8.4ms, TE 3.9ms, matrix size $240{\times}240$, Slice can set 180 piecesIt was. b value of 0, 1,000, 2,000 s/mm2 with DWI acquisition and 3D T1WI enhancement five minutes after the Slice Thickness 3mm, gap 0mm to reconstruct the upper face axis (MPR TRA CE) was. As for the experiment, in b-value 1,000 and 2,000 images, SNR and the lesion at the lesion site and CNR in the normal site opposite to the lesion are measured. WW(window width) and WL(window level) are made equal in MRICro software, and the volume of the lesion is measured from each of b-value and MPR TRA CE image. Using SPSS ver. 1.8.0.0 Mann Whitney-test was analyzed for SNR and CNR, while Kruskal-Wallis test was analyzed for volume.

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A Study on the Solidification Characteristics of CV Graphite Cast Iron (CV흑연주철(黑鉛鑄鐵)의 응고특성(凝固特性)에 관한 연구(硏究))

  • Chun, C.C.;Kim, S.Y.;Lee, G.W.
    • Journal of Korea Foundry Society
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    • v.5 no.3
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    • pp.5-12
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    • 1985
  • Many researchers have studied the eutectic solidification of CV Graphite Cast Iron qualitatively. However quantative studies have not been done. The type of eutectic solidification of CV Graphite Cast Iron treated with CG Alloy (Fe-Si-Mg-5Ti-Ca-Ce) was studied quantitatively through M.D.E. value (Mushy Degree of Eutectic Solidification) = $t_2/t_1)$, where $t_1$ is the difference of the eutectic solidification starting time between surface and center part of the casting sample, and $t_2$ is the time of eutectic solidification of the center part. Following results were obtained. (1) The M.D.E. value of CV graphite cast iron lies between that of spheroidal graphite and that of flake graphite cast iron but is closer to that of Flake graphite cast iron. (2) The M.D.E. value of CV graphite cast iron depends upon CV ratio. (3) The time required for eutectic solidification increases as graphite form is changed from Flake, CV. to spheroidal graphite. (4) The M.D.E. value increases as cooling rate increases.

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Dating Sun's Locations at Equinoxes Inscribed on Cheonsang Yeolcha Bunyajido

  • Sang-Hyeon Ahn
    • Journal of The Korean Astronomical Society
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    • v.56 no.2
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    • pp.201-212
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    • 2023
  • The inscription of Cheonsang Yeolcha Bunyajido (天象列次分野之圖) has the sun's locations at the equinoxes, which must have been copied from the astronomical treatises in Chinese historical annals, Songshu (宋書) and Jinshu (晉書). According to the treatises, an astronomer Wang Fan (王蕃, 228-266 CE) referred those values from a calendrical system called Qianxiangli (乾象曆, 223 CE), from which it is confirmed that it adopted the sun's location at the winter solstice of the $(21{\frac{1}{4}})^{th}$ du of the 8th lunar lodge Dou (斗) as the reference direction for equatorial lodge angles. This indicates that the sun's locations at equinoxes and solstices in the calendrical system are the same as those in Jingchuli (景初曆, 237 CE). Hence, we propose that the sun's location at the autumnal equinox in Cheonsang Yeolcha Bunyajido should be corrected from 'wu du shao ruo' (五度少弱), meaning the $(5{\frac{1}{6}})^{th}$ du, to 'wu du ruo' (五度弱), meaning the $(4{\frac{11}{12}})^{th}$ du, of the first lunar lodge Jiao (角), as seen in Jingchuli. We reconstruct the polar coordinate system used in circular star charts, assuming that the mean motion rule was applied and its reference direction was the sun's location at the winter solstice. Considering the precession, we determined the observational epoch of the sun's location at the winter solstice to be to = -18.3 ± 43.0 adopting the observational error of the so-called archaic determinatives (古度). It is noteworthy that the sun's locations at equinoxes inscribed in Cheonsang Yeolcha Bunyajido originated from Houhan Sifenli (後漢 四分曆) of the Latter Han dynasty (85 CE), while the coordinate origin in the star chart is related to Taichuli (太初曆) of the Former Han dynasty (104 BCE).