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Investigation of Electronic Structures of TCr2O4 (T = Fe, Co, Ni) Spinel Oxides by Employing Soft X ray Synchrotron Radiation Spectroscopy (연 X선 방사광 분광법을 이용한 TCr2O4(T = Fe, Co, Ni) 스피넬 산화물의 전자구조 연구)

  • Kim, Hyun Woo;Hwang, Jihoon;Kim, D.H.;Lee, Eunsook;Kang, J.S.
    • Journal of the Korean Magnetics Society
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    • v.23 no.5
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    • pp.149-153
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    • 2013
  • The electronic structures of $TCr_2O_4$ (T = Fe, Co, Ni) spinel oxides have been investigated by employing synchrotron radiation-based soft X ray absorption spectroscopy (XAS). The measured 2p XAS spectra of transition-metal ions reveal that Cr ions are trivalent ($Cr^{3+}$), and all the T (T = Fe, Co, Ni) ions are divalent ($Fe^{2+}$, $Co^{2+}$, $Ni^{2+}$). It is also found that most of T (T = Fe, Co, Ni) ions occupy the A sites under the tetrahedral symmetry, while Cr ions occupy mainly the B sites under the octahedral symmetry. These findings show that the structures of $TCr_2O_4$ (T = Fe, Co, Ni) are very close to the normal spinel structures. Based on these findings, it is expected that Jahn-Teller (JT) effects are important in $FeCr_2O_4$ and $NiCr_2O_4$. In contrast, $CoCr_2O_4$ maintains the cubic structure without having the JT distortion since both $Cr^{3+}$ and $Co^{2+}$ ions are non-JT ions. This work suggests that the antiferromagnetic interaction between $Cr^{3+}$ and $T^{2+}$ ions plays an important role in determining the magnetic properties of $TCr_2O_4$ (T = Fe, Co, Ni).

The Effect of Pressure Support on Respiratory Mechanics in CPAP and SIMV (CPAP 및 SIMV Mode하에서 Pressure Support 사용이 호흡역학에 미치는 효과)

  • Lim, Chae-Man;Jang, Jae-Won;Choi, Kang-Hyun;Lee, Sang-Do;Koh, Youn-Suck;Kim, Woo-Sung;Kim, Dong-Soon;Kim, Won-Dong;Park, Pyung-Whan;Choi, Jong-Moo
    • Tuberculosis and Respiratory Diseases
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    • v.42 no.3
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    • pp.351-360
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    • 1995
  • Background: Pressure support(PS) is becomimg a widely accepted method of mechanical ventilation either for total unloading or for partial unloading of respiratory muscle. The aim of the study was to find out if PS exert different effects on respiratory mechanics in synchronized intermittent mandatory ventilation(SIMV) and continuous positive airway pressure (CPAP) modes. Methods: 5, 10 and 15 cm $H_2O$ of PS were sequentially applied in 14 patients($69{\pm}12$ yrs, M:F=9:5) and respiratory rate (RR), tidal volume($V_T$), work of breathing(WOB), pressure time product(PTP), $P_{0.1}$, and $T_1/T_{TOT}$ were measured using the CP-100 pulmonary monitor(Bicore, USA) in SIMV and CPAP modes respectively. Results: 1) Common effects of PS on respiratory mechanics in both CPAP and SIMV modes As the level of PS was increased(0, 5, 10, 15 cm $H_2O$), $V_T$ was increased in CPAP mode($0.28{\pm}0.09$, $0.29{\pm}0.09$, $0.31{\pm}0.11$, $0.34{\pm}0.12\;L$, respectively, p=0.001), and also in SIMV mode($0.31{\pm}0.15$, $0.32{\pm}0.09$, $0.34{\pm}0.16$, $0.36{\pm}0.15\;L$, respectively, p=0.0215). WOB was decreased in CPAP mode($1.40{\pm}1.02$, $1.01{\pm}0.80$, $0.80{\pm}0.85$, $0.68{\pm}0.76$ joule/L, respectively, p=0.0001), and in SIMV mode($0.97{\pm}0.77$, $0.76{\pm}0.64$, $0.57{\pm}0.55$, $0.49{\pm}0.49$ joule/L, respectively, p=0.0001). PTP was also decreased in CPAP mode($300{\pm}216$, $217{\pm}165$, $179{\pm}187$, $122{\pm}114cm$ $H_2O{\cdot}sec/min$, respectively, p=0.0001), and in SIMV mode($218{\pm}181$, $178{\pm}157$, $130{\pm}147$, $108{\pm}129cm$ $H_2O{\cdot}sec/min$, respectively, p=0.0017). 2) Different effects of PS on respiratory mechanics in CP AP and SIMV modes By application of PS (0, 5, 10, 15 cm $H_2O$), RR was not changed in CPAP mode($27.9{\pm}6.7$, $30.0{\pm}6.6$, $26.1{\pm}9.1$, $27.5{\pm}5.7/min$, respectively, p=0.505), but it was decreased in SIMV mode ($27.4{\pm}5.1$, $27.8{\pm}6.5$, $27.6{\pm}6.2$, $25.1{\pm}5.4/min$, respectively, p=0.0001). $P_{0.1}$ was reduced in CPAP mode($6.2{\pm}3.5$, $4.8{\pm}2.8$, $4.8{\pm}3.8$, $3.9{\pm}2.5\;cm$ $H_2O$, respectively, p=0.0061), but not in SIMV mode($4.3{\pm}2.1$, $4.0{\pm}1.8$, $3.5{\pm}1.6$, $3.5{\pm}1.9\;cm$ $H_2O$, respectively, p=0.054). $T_1/T_{TOT}$ was decreased in CPAP mode($0.40{\pm}0.05$, $0.39{\pm}0.04$, $0.37{\pm}0.04$, $0.35{\pm}0.04$, respectively, p=0.0004), but not in SIMV mode($0.40{\pm}0.08$, $0.35{\pm}0.07$, $0.38{\pm}0.10$, $0.37{\pm}0.10$, respectively, p=0.287). 3) Comparison of respiratory mechanics between CPAP+PS and SIMV alone at same tidal volume. The tidal volume in CPAP+PS 10 cm $H_2O$ was comparable to that of SIMV alone. Under this condition, the RR($26.1{\pm}9.1$, $27.4{\pm}5.1/min$, respectively, p=0.516), WOB($0.80{\pm}0.85$, 0.97+0.77 joule/L, respectively, p=0.485), $P_{0.1}$($3.9{\pm}2.5$, $4.3{\pm}2.1\;cm$ $H_2O$, respectively, p=0.481) were not different between the two methods, but PTP($179{\pm}187$, $218{\pm}181 cmH_2O{\cdot}sec/min$, respectively, p=0.042) and $T_1/T_{TOT}$($0.37{\pm}0.04$, $0.40{\pm}0.08$, respectively, p=0.026) were significantly lower in CPAP+PS than in SIMV alone. Conclusion: PS up to 15 cm $H_2O$ increased tidal volume, decreased work of breathing and pressure time product in both SIMV and CPAP modes. PS decreased respiration rate in SIMV mode but not in CPAP mode, while it reduced central respiratory drive($P_{0.1}$) and shortened duty cycle ($T_1/T_{TOT}$) in CPAP mode but not in SIMV mode. By 10 em $H_2O$ of PS in CPAP mode, same tidal volume was obtained as in SIMV mode, and both methods were comparable in respect to RR, WOB, $P_{0.1}$, but CPAP+PS was superior in respect to the efficiency of the respiratory muscle work (PTP) and duty cycle($T_1/T_{TOT}$).

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The Transmission Development with P.T.O Axle Design for Work Vehicle Including Multi-faculty (다기능 작업차를 위한 P.T.O 축 및 트랜스밋션의 최적설계 및 개발)

  • Kwac, Lee-Ku;Kim, Jae-Yeol
    • Journal of the Korean Society for Precision Engineering
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    • v.25 no.4
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    • pp.108-117
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    • 2008
  • A transmission designed with P.T.O(Power Take-Off) axle for agricultural work vehicles including multi-purpose vehicles has been developed. It is focused on the 4-wheel drive transmission of synchronous contact type for practical use in fruit tree households which is required for a large-sized agricultural vehicle. Concerning to the specification performed, the load capacity is from 500kg to 1,000kg and the safety should be secured for passengers. In addition, the driving condition should also be secured under bad situations of the topographic slope, swampy land and the rest. In order to carry out above tests, a prototype vehicle through strength analysis of transmission design has been manufactured. Consequently, optimal design conditions on the power transmission with multi-purpose vehicle for various jobs are proposed such as an indication of optimal RPM and torque at a certain work situation. The performance test through the prototype of multi-purpose work vehicle is performed and the related data base is achieved. Finally, it is improved on troubles by the analysis of the results of R&D and provided the solutions on problems occurring to mass production in the future.

On Lp(T2)-Convergence and Móricz (Lp(T2)-수렴성과 모리츠에 관하여)

  • LEE, Jung Oh
    • Journal for History of Mathematics
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    • v.28 no.6
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    • pp.321-332
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    • 2015
  • This paper is concerned with the convergence of double trigonometric series and Fourier series. Since the beginning of the 20th century, many authors have studied on those series. Also, Ferenc $M{\acute{o}}ricz$ has studied the convergence of double trigonometric series and double Fourier series so far. We consider $L^p(T^2)$-convergence results focused on the Ferenc $M{\acute{o}}ricz^{\prime}s$ studies from the second half of the 20th century up to now. In section 2, we reintroduce some of Ferenc $M{\acute{o}}ricz^{\prime}s$ remarkable theorems. Also we investigate his several important results. In conclusion, we investigate his research trends and the simple minor genealogy from J. B. Joseph Fourier to Ferenc $M{\acute{o}}ricz$. In addition, we present the research minor lineage of his study on $L^p(T^2)$-convergence.

Pattern Classification of Four Emotions using EEG (뇌파를 이용한 감정의 패턴 분류 기술)

  • Kim, Dong-Jun;Kim, Young-Soo
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.3 no.4
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    • pp.23-27
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    • 2010
  • This paper performs emotion classification test to find out the best parameter of electroencyphalogram(EEG) signal. Linear predictor coefficients, band cross-correlation coefficients of fast Fourier transform(FFT) and autoregressive model spectra are used as the parameters of 10-channel EEG signal. A multi-layer neural network is used as the pattern classifier. Four emotions for relaxation, joy, sadness, irritation are induced by four university students of an acting circle. Electrode positions are Fp1, Fp2, F3, F4, T3, T4, P3, P4, O1, O2. As a result, the Linear predictor coefficients showed the best performance.

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Development of Multistage Concentrating Solar Collector - I. Thermal performance of multistage cylindrical parabolique concentrating solar collector (다단이차원(多段二次元) 집광식(集光式) 태양열(太陽熱) 집열기(集熱器) 개발(開發)에 관(關)한 연구(硏究) - I. 다단이차원(多段二次元) 집광식(集光式) 태양열(太陽熱) 집열기(集熱器)의 열적(熱的) 성능분석(性能分析))

  • Song, Hyun-Kap
    • Solar Energy
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    • v.6 no.2
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    • pp.3-14
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    • 1986
  • It is desirable to collect the solar thermal energy at relatively high temperature in order to minimize the size of thermal storage system and to enlarge the scope of solar thermal energy utilization. In this study, to develop a solar collector that has both advantages of collecting solar thermal energy at high temperature and fixing conveniently the collector system for long term period, a cylindrical parabolique concentrating solar collector (M.C.P.C.S.C) was designed, which has several rows of parabolique reflectors and thin thickness such as the flat-plate solar collector, maintaining the optical form of concentrating solar collector. The thermal performance of the M.C.P.C.S.C. newly designed in this study was analysed theoretically and experimentally. The results are summarized as follows: 1) prediction equation for outlet temperature, $T_o$, of heat transfer fluid and for the thermal efficiency, ${\eta}$, of the collector were derived as; o $$T_o=[C+B1_n(\frac{I_c(t)}{pv^3})]T_i$$ o $${\eta}=\frac{A}{A_c}\dot{m}[(C-1)+B1_n(E{\cdot}di^6\frac{I_c(t)}{\dot{m}^3})]\frac{T_i}{I_c(t)}$$ 2) When the insolation on the tilted solar collector surface, $I_c$, was $900-950W/m^2$ and the heat transfer fluid was not circulated in tubular absorber, the maximum temperature on the absorber surface was $100-118^{\circ}C$, this result suggested that the heat transfer fluid could be heated up to $98-116^{\circ}C$. The maximum temperature on the absorber surface was decreased with the increase of the collector shape factor, $L_p/L_w$ 3) There was a good agreement between the experimental and theoretical value of solar collector efficiency, ${\eta}$, which was proportional to the collector shape factor, $L_p/L_w$ 4) It is desirable to continue the study on the relationship between the collector shape factor, $L_p/L_w$, and the thermal efficiency of solar collector.

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Analysis of Vegetation-Environment Telationships of Main Wild Vegetables on Short-term Income Forest Products, in Korea (단기소득임산물 자생지 주요 산채류 식생과 환경의 상관관계 분석)

  • Kim, Hyoun-Sook;Lee, Sang-Myong;Lee, Joongku
    • Korean Journal of Environment and Ecology
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    • v.33 no.4
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    • pp.447-452
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    • 2019
  • This study was conducted in 2016-2017 to provide the basic ecological data needed to establish environmental conditions for the cultivation of wild vegetables. It used TWINSPAN to classify the vegetation structure of natural habitats of wild vegetable nationwide and DCCA ordination to analyze the correlation between the by community structure and environmental factors. We performed TWINSPAN on 100 taxa with high importance values in 91 plots of major habitats of wild vegetables. The vegetation was classified into Cirsium setidens and Synurus deltoides group, Ligularia fischeri and Hemerocallis fulva group, Adenophora divaricata var. manshurica group, Platycodon grandiflorum and Aster scaber group, Aralia elata and Pteridium aquilinum group, and Pimpinella brachycarpa and Osmunda japonica group communities. We then performed DCCA ordination of 11 communities classified by TWINSPAN and 11 environmental factors. The results showed that the altitude had the strongest correlation with the vegetation. The Cirsium setidens, Synurus deltoids, and Lifularia fischeri communities were distributed in areas with similar environmental factors such as high altitude, gentle slope, and nutrient. The Aralia elata and Osmunda japonica communities were distributed in the location environment with low altitude, pH, O.M, T-N, $Ca^{2+}$, and C.E.C. The Hemerocallis fulva community was distributed in the location environment with moderate northeastern and northwestern slope, low altitude and pH, and high $P_2O_5$, whereas the Adenophora divaricata var. manshurica community was distributed in the location environment with gentle southeastern and southwestern slope, high altitude and pH, and low $P_2O_5$, which was the opposite tendency of the location environment from Hemerocallis fulva community. The Platycodon grandiflorum community was distributed in the location environment with gentle southwestern slope, low altitude, pH, O.M, T-N, $P_2O_5$, $Ca^{2+}$, and C.E.C., and high $Mg^{2+}$. The Pteridium aquilinum community was distributed in the location environment with southwestern slope, low altitude, O.M, T-N, C.E.C, $P_2O_5$, $Ca^{2+}$, and $K^+$. The Aster scaber and Pimpinella brachycarpa communities were widely distributed in many plots with various location environments.

NEW COMPLEXITY ANALYSIS OF PRIMAL-DUAL IMPS FOR P* LAPS BASED ON LARGE UPDATES

  • Cho, Gyeong-Mi;Kim, Min-Kyung
    • Bulletin of the Korean Mathematical Society
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    • v.46 no.3
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    • pp.521-534
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    • 2009
  • In this paper we present new large-update primal-dual interior point algorithms for $P_*$ linear complementarity problems(LAPS) based on a class of kernel functions, ${\psi}(t)={\frac{t^{p+1}-1}{p+1}}+{\frac{1}{\sigma}}(e^{{\sigma}(1-t)}-1)$, p $\in$ [0, 1], ${\sigma}{\geq}1$. It is the first to use this class of kernel functions in the complexity analysis of interior point method(IPM) for $P_*$ LAPS. We showed that if a strictly feasible starting point is available, then new large-update primal-dual interior point algorithms for $P_*$ LAPS have $O((1+2+\kappa)n^{{\frac{1}{p+1}}}lognlog{\frac{n}{\varepsilon}})$ complexity bound. When p = 1, we have $O((1+2\kappa)\sqrt{n}lognlog\frac{n}{\varepsilon})$ complexity which is so far the best known complexity for large-update methods.

Development of Flotation System for Utilization of Low Grade Lithium Ore (저품위 리튬운모광의 활용을 위한 부유선별 시스템 개발)

  • Lee, Kwang-Hoon;Jeon, Ho-Seok;Baek, Sang-Ho;Kim, Su-Gang
    • Mineral and Industry
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    • v.25
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    • pp.1-10
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    • 2012
  • In this present work, the froth flotation of lithium ore from Boam mine located in Wooljin, Kyungbuk has been carried out to produce high-grade lithium concentrate. The sample ore-Lepidolite mainly contained silicate mineral (quartz, muscovite) and calcite. In consequences of the experiment, it has been possible to obtain relatively high-grade lithium while using anionic acid (oleic acid) to remove calcite before the froth flotation for lithium concentrate. Among the amines collectors (Armac-T, Armac-C, Armafloat-18, Armafloat-1597), Armac-T has been relatively effective than another ones. Under the optimum condition (collector : Armac-T 100g/t, frother : AF65 50g/t, depressants : $Na_2SiO_3$ 600g/t and Lactic acid 100g/t, pulp density : 20%, pH 5.5, number of cleaning : 2), it has been obtained relatively high-grade lithium concentrate ($Li_2O$) with recovery of 80.3% and with grade of 4.33%.

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Effects of PbO on the Repassivation Kinetics of Alloy 690

  • Ahn, SeJin;Kwon, HyukSang;Lee, JaeHun;Park, YunWon;Kim, UhChul
    • Corrosion Science and Technology
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    • v.3 no.4
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    • pp.131-139
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    • 2004
  • Effects of PbO on the repassivation kinetics and characteristics of passive film of Alloy 690 were examined to elucidate the influences of PbO on the SCC resistance of that alloy. The repassivation kinetics of the alloy was analyzed in terms of the current density flowing from the scratch, i(t), as a function of the charge density that has flowed from the scratch, q(t). Repassivation on the scratched surface of the alloy occurred in two kinetically different processes; passive film initially nucleated and grew according to the place exchange model in which log i(t) is linearly proportional to q(t), and then grew according to the high field ion conduction model in which log i(t) is linearly proportional to 1/q(t) with a slope of cBV. The cBV is found to be a parameter representing repassivation rate and hence SCC susceptibility of the alloy. The lower the value of cBV, the faster the repassivation rate and the higher the SCC resistance of an alloy. Addition of PbO to pH 4 and 10 solutions increased the value of cBV of alloy 690, reflecting slower repassivation rate than without PbO. The change in the value of cBV was grater in pH 10 than in pH 4. The increase in SCC susceptibility of alloy 690 with the addition of PbO to solution was presumably due to the Cr-depletion in the outer parts of passive film of the alloy with an incorporation of Pb compounds in the film, which was revealed by Mott-Schottky, AES and XPS analyses.