• Title/Summary/Keyword: T.H.D.

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The ab Initio Quantum Mechanical Investigation for the Weakly Bound $H^+_{2n+1}$(n=1-6) Complexes (약한 결합을 갖는 $H^+_{2n+1}$(n=1-6) complex들에 대한 순 이론 양자역학적 연구)

  • In, Eun Jeong;Seo, Hyeon Il;Kim, Seung Jun
    • Journal of the Korean Chemical Society
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    • v.45 no.5
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    • pp.401-412
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    • 2001
  • The geometrical parameters, vibrational frequencies, and dissociation energies for $H_{2n+1}^+$ (n=1~6) clusters have been investigated using high level ab initio quantum mechanical techniques with large basis sets. The equilibrium geometries have been optimized at the self-consistent field (SCF), the single and double excitation configuration interaction (CISD), the coupled cluster with single and double excitation (CCSD), and the CCSD with connected triple excitations [CCSD(T)] levels of theory. The highest levels of theory employed in this study are TZ2P+d CCSD(T) up to $H^+_g$ and TZ2P CCSD(T) for $H_{11}^+$ and $H_{13}^+$. Harmonic vibrational frequencies are also determined at the SCF level of theory with various basis sets and confirm that all the optimized geometries are true minima. The dissociation energies, $D_e$, for $H_{2n+1}^+$ (n=26) have been predicted using energy differences at each optimized geometry and zero-point vibrational energies(ZPVEs) have been considered to compare with experimental dissociation energies, $D_0$.

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Tunnel Effects in the H + D$_2$ and D + H$_2$ Reactions

  • Jong-Baik Ree;Young-Seek Lee;In-Joon Oh;Tai-kyue Ree
    • Bulletin of the Korean Chemical Society
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    • v.4 no.1
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    • pp.28-36
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    • 1983
  • We considered the tunneling effect on the rate constants calculated from transition-state theory for the H + $D_2$ and D + $H_2$ reactions. A method for evaluating the important parameter Ec (potential barrier height) was proposed. A tunnel-effect correlation factor (TECF) ${\Gamma}_{t}exp{\theta}_t$ was estimated from experimental data, and compared with the corresponding values obtained from many theoretical methods. According to our results, the tunneling effect cannot be negligible around $800^{\circ}$K where the TECF value is ca. 0.8 whereas the factor approaches to unity at T > $2400^{\circ}$K where the tunneling completely disappears. In addition to the above fact, we also found that the TECF for the D + $H_2$ reaction is greater than that of the H + $D_2$ reaction in agreement with Garrett and Truhlar's result. In contrast to our result, however, Shavitt found that the order is reversed, i.e., TECF for (D + $H_2$) is greater than that for (H + $D_2$). We discussed about the Shavitt's result.

The Effects of Feeding Organic Feed on the Growth and Carcass Characteristics of Hanwoo Steers (유기사료 급여가 거세한우의 성장 및 도체특성에 미치는 영향)

  • Jeon, B.S.;Song, J.I.;Jeon, J.H.;Kwag, J.H.;Jang, S.S.;Kwon, E.G.;Cho, Y.M.;Cho, W.M.;Choi, H.C.;Park, K.H.;Yoo, Y.H.
    • Journal of Animal Environmental Science
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    • v.14 no.2
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    • pp.81-90
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    • 2008
  • This study was carried out to investigate the effects of the organic feed on weight gain, feed conversion rate, and carcass characteristics of Hanwoo steers. Three feeding treatments(T1 : rice straw and commercial concentrates, T2 : organic hay and concentrates, T3 : organic corn silage and concentrates) for 22 months (from 6 to 28 months) were used. As a result, weight gain was not significantly different among treatments throughout this study. Also T1 tended to improve weight gain and daily weight gain without significance. The percentage of meat quality grade over the first grads ($1,\;1^+,\;1^{++}$) were 50% in the carcass of Hanwoo steers fed T1 and T2, and 70% fed T3, respectively. T2 and T3 tended to improve marbling score and oleic acid content.

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Biomass and Net Primary Productivity in Natural Forests of Quercus mongolica and Quercus variabilis (신갈나무와 굴참나무 천연림(天然林) 생태계(生態系)의 현존량(現存量) 및 물질(物質) 생산성(生産性)에 관한 연구)

  • Song, Cheel Young;Lee, Soo Wook
    • Journal of Korean Society of Forest Science
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    • v.85 no.3
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    • pp.443-452
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    • 1996
  • A study has been made to estimate biomass and NPP based on equation form of $Wt=aD^bH^c$ for Quercus variabilis and Quercus mongolica natural stands(Mean age; 67, 62yrs old) in Chungju. Equation form of $Wt=aD^bH^c$ was more adequate than $Wt=a(D^2H)^b$ and $Wt=aD^b$ for the estimation of the biomass and NPP. Individual biomass was compared using a paired t-test by tree component which showed no significant differences. Total aboveground biomass of Quercus mongolica was 130.6 t/ha and that of Quercus variabilis was 137.4 t/ha. Biomass of Q. mongolica was composed of foliage 5.1 t/ha(3.9%), dead branch 3.5 t/ha(2.7%), live branch 29.7 t/ha(23.0%), bolebark 16.2 t/ha(12.5%), and bolewood 74.9 t/ha(58.0%), and that of Q. variabilis was composed of foliage 3.8 t/ha(2.9%), dead branch 2.9 t/ha(2.2%), live branch 24.3 t/ha(18.4%), bolebark 20.4 t/ha(15.5%), and bolewood 80.4 t/ha(61.0%). Net primary production was 10.0 t/ha/yr in the Q. mongolica stand and 8.6 t/ha/yr in the Q. variabilis stand, respectively. Net primary production of Quercus forest in Chungju was very close to the mean NPP of the broadleaved forest of temperate zone.

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Investigation of Proper Replacement Depth for the Reinforced Earth Wall on a Soft Ground by Finite Element Analysis (유한요소해석에 의한 연약지반 상 보강토 옹벽에 대한 적정 치환깊이 검토)

  • Lee, Byung-Sik
    • Journal of the Korean Geotechnical Society
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    • v.23 no.5
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    • pp.153-162
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    • 2007
  • For the reinforced earth wall constructed on a soft ground in parallel with replacing soft soils, the behavior of the wall according to variations of thickness and stiffness of soft layer, replacement depth, and wall height is investigated using a finite element method, in which incremental construction steps including consolidation of soft soil layer are considered. The behavior of wall is characterized by investigating displacements and settlements developing at the wall, and shear strains developing in a soil deposit. The stability of wall is, then, evaluated by comparing these values with the safety criteria determined on the basis of the literature. Based on the investigation, it is shown that the behavior of wall is influenced naturally from soft soil thickness(t), replacement depth(d) and wall height(h), but more significantly from d and h. In addition, it is also shown that the normalized replacement depth, d/h, required for the safety of wall is not influenced significantly by the variations of t and h. Consequently, it can be concluded that the proper replacement depth can be suggested in an equivalent value in terms of d/h, even for the cases where the wall height is varying with stations, but the variation is not significant.

Temperature Dependence of the Vibration-Vibration Energy Transfer for HF(v = n) + $H_2$(v = 0) and DF(v = n) + $D_2$(v = 0)

  • Lee, Chang-Soon;Kim, Yoo-Hang
    • Bulletin of the Korean Chemical Society
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    • v.13 no.1
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    • pp.11-17
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    • 1992
  • Vibration-to-vibration energy transfer probabilities for $HF(v=n)+H_2(v=0){\to}HF(v=n-1)+H_2(v=1)$ and $DF(v=n)+D_2(v=0){\to}DF(v=n-1)+D_2(v=1)$ including both the vibration-to-vibration and translation (V-V, T) and vibration-to-vibration and rotation (V-V, R) energy transfer paths have been calculated semiclassically using a simplified collision model and Morse-type intermolecular interaction potential. The calculated results are in reasonably good agreement with those obtained by experimental studies. They also show that the transition processes for $HF(v=1-3)+H_2(v=0){\to}HF(v=0-2)+H_2(v=1)$ and $DF(v=1,\;4)+D_2(v=0){\to}DF(v=0,\;3)+D_2(v=1)$ are strongly dependent on the V-V, T path at low temperature but occur predominantly via the V-V, R path with rising temperature. The vibration-to-vibration energy transfer for $HF(v=4)+H_2(v=0){\to}HF(v=3)+H_2(v=1)$ and $DF(v=2-3)+D_2(v=0){\to}DF(v=1-2)+D_2(v=1)$ occur predominantly via V-V, R path and V-V, T path through whole temperatures, respectively.

Development of On-tine Partial Discharge Monitoring System for High-Voltage Motor Stator Windings (고압 전동기 고정자 권선의 운전중 절연감시 시스템 개발)

  • Hwang, D.H.;Sim, W.Y.;Park, D.Y.;Gang, Dong-Sik;Kim, Y.J.;Song, S.O.;Kim, H.D.
    • Proceedings of the KIEE Conference
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    • 2001.11a
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    • pp.224-226
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    • 2001
  • In this paper, a novel high-voltage motor monitoring system (HVMMS) is proposed. This system monitors the insulation condition of the stator winding by on-line measurements of partial discharge (PD). Sensor, EMC (Epoxy-Mica Coupler) is used for PD measurement PD signals are continuously measured and digitized with a peak-hold A/D converter to build the database of the high-voltage motor's insulation condition. Also, this system can communicate with the central monitoring system via RS-485. This helps more efficient operation and maintenance of the generator.

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ON t-ALMOST DEDEKIND GRADED DOMAINS

  • Chang, Gyu Whan;Oh, Dong Yeol
    • Bulletin of the Korean Mathematical Society
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    • v.54 no.6
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    • pp.1969-1980
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    • 2017
  • Let ${\Gamma}$ be a nonzero torsionless commutative cancellative monoid with quotient group ${\langle}{\Gamma}{\rangle}$, $R={\bigoplus}_{{\alpha}{\in}{\Gamma}}R_{\alpha}$ be a graded integral domain graded by ${\Gamma}$ such that $R_{{\alpha}}{\neq}\{0\}$ for all ${\alpha}{\in}{\Gamma},H$ be the set of nonzero homogeneous elements of R, C(f) be the ideal of R generated by the homogeneous components of $f{\in}R$, and $N(H)=\{f{\in}R{\mid}C(f)_v=R\}$. In this paper, we introduce the notion of graded t-almost Dedekind domains. We then show that R is a t-almost Dedekind domain if and only if R is a graded t-almost Dedekind domain and RH is a t-almost Dedekind domains. We also show that if $R=D[{\Gamma}]$ is the monoid domain of ${\Gamma}$ over an integral domain D, then R is a graded t-almost Dedekind domain if and only if D and ${\Gamma}$ are t-almost Dedekind, if and only if $R_{N(H)}$ is an almost Dedekind domain. In particular, if ${\langle}{\Gamma}{\rangle}$ isatisfies the ascending chain condition on its cyclic subgroups, then $R=D[{\Gamma}]$ is a t-almost Dedekind domain if and only if R is a graded t-almost Dedekind domain.