• 천문학회보
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• 제36권2호
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• pp.156-156
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• 2011

VPH (Volume Phase Hologram) grating is one of the transmission gratings and is known as its remarkable efficiency (>90%). It has two different densities of gelatins causing interference patterns. The VPH grating is favored in many astronomical instruments these days and also IGRINS, which is up coming near infrared high-resolution spectroscope expected to see the first light next year, uses the VPH grating as its cross-disperser. The infrared astronomical instruments operate at cryogenic temperature (~100K) in order to cut down thermal noise and the optical components of IGIRNS will be operated at 130K. The VPH grating is sandwiched in between fused silica or glass and glued together using optical adhesive. IGRINS is expected to go through 50 times of thermal cycling in 10 years including the performance test and this research is to check whether the physical characteristic such as the adhesion or dichromatic gelatin does not break and change from the several cryogenic thermal cycling. The two identical test gratings provided from Kaiser Optical System, Inc. are used in this test. One VPH grating is cooled down to 100K for 2 hours with maximum dT/dt = 5 and warmed up to the room temperature and another grating is kept stored in the room temperature and used as a control sample. In order to check the change, we inspected the grating with eyes and checked its efficiency and transmission at the room temperature every 10 cycling. From the 40 times of cryogenic temperature cool down cycling, the VPH grating showed no signs of change within the error compared to the control sample. We concluded the VPH grating is durable through several cryogenic thermal cycling.

• 한국재료학회지
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• 제23권3호
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• pp.183-189
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• 2013

$Cu_2ZnSn(S,Se)_4$ material is receiving an increased amount of attention for solar cell applications as an absorber layer because it consists of inexpensive and abundant materials (Zn and Sn) instead of the expensive and rare materials (In and Ga) in $Cu(In,Ga)Se_2$ solar cells. We were able to achieve a cell conversion efficiency to 4.7% by the selenization of a stacked metal precursor with the Cu/(Zn + Sn)/Mo/glass structure. However, the selenization of the metal precursor results in large voids at the absorber/Mo interface because metals diffuse out through the top CZTSe layer. To avoid the voids at the absorber/Mo interface, binary selenide compounds of ZnSe and $SnSe_2$ were employed as a precursor instead of Zn and Sn metals. It was found that the precursor with Cu/$SnSe_2$/ZnSe stack provided a uniform film with larger grains compared to that with $Cu_2Se/SnSe_2$/ZnSe stack. Also, voids were not observed at the $Cu_2ZnSnSe_4$/Mo interface. A severe loss of Sn was observed after a high-temperature annealing process, suggesting that selenization in this case should be performed in a closed system with a uniform temperature in a $SnSe_2$ environment. However, in the experiments, Cu top-layer stack had more of an effect on reducing Sn loss compared to $Cu_2Se$ top-layer stack.

• 한국재료학회지
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• 제7권12호
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• pp.1089-1096
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• 1997

본 연구에서는 에폭시/산무수물계에 화학양론비(r=산무수물/에폭시)를 0.5, 0.7,0.9,1.1로 변화시켜 서로 다른 두종류의 경화촉진제 1-cyanoethy1-2-ethy1-4-methy1 imidazole(2E4MZ-CN)과 N,N-dimethy1 benzy1 amine(BDMZ)을 첨가한 시료에 대한 경화거동과 경화 후 물성을 관찰하였다. 이 시료의 등온 경화거동은 동역학 측정기(dynamic mechanical analyzer, DMA)와 시차주사 열량분석기(differential scanning calorimeter, DSC)를 이용하여 조사하였다. DMA로부터 구해진 결과를 보면 경화시 상대저장강성을 (relative storage rigidity, RSR)과 상대손실강성율(relative loss rigidity, RSR)과 상대손실강성율(relative loss rigidity, RLR)의 변화가 r값과 경화촉진제의 종류에 영향을 받았다. 그리고 DSC결과는 r값이 감소함에 따라 경화가 촉진되는 것으로 나타났다. 경화물의 성질을 조사하기 위하여 사용된 DMA로부터 얻어진 유리전이온도(glass transition temperature, T$_{g}$)와 가교결합간의 평균분자량(average molecular weigh between crosslinks, M$_{c}$은 사용한 두 경화촉진제에 대하여 r값의 영향이 다르게 나타났다. BDMA의 경우는 T$_{g}$가 1:1화학양론비인 r=0.9에서 최고치를 보였으나, 2E4MZ-CN은 r이 감소함에 따라 계속 증가하는 양상을 보였다. 이와 같은 경향은 2E4MZ-CN을 경화촉진제로 사용하였을 때 에폭시가 과량으로 될수록 잔류 에폭시기들간의 에케르반응이 추가적으로 일어나 M$_{c}$가 감소하기 때문이다.

• 대한조선학회논문집
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• 제57권4호
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• pp.241-253
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• 2020

The Small-Unit Riverine Craft (SURC) is a small high-speed vessel used by navies and marine corps in relatively shallow waterway environments, such as riverine areas or littoral coasts. In the past, SURCs have primarily been rigid-hulled inflatable boats constructed using composite materials such as glass fiber reinforced plastics. More recently, single-hull SURCs have been manufactured using aluminum for weight reduction. In this study, a Carbon Fiber Reinforced Polymer (CFRP) material was applied instead to examine its feasibility in the basic design of an SURC with a hull length of 10 m. The CFRP structural design was obtained using the properties of a marine CFRP laminate, determined in a previous study. Next, the designed CFRP SURC was modeled to confirm its functionality, then compared with existing aluminum SURCs, indicating that the CFRP SURC was 41.49 % lighter, reduced fuel consumption by 30 %, and could sail 50 NM further for every hour of engine operation. A method for reducing the high cost of carbon fiber was also proposed based on the adjustment of the carbon fiber content to provide the optimum strength where required. The data developed in this study can be used as a basis for further design of CFRP craft.

• 대한화학회지
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• 제31권1호
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• pp.110-117
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• 1987

선형저밀도폴리에틸렌(LLDPE)의 제조를 위해 여러가지 티탄알콕시드-알킬알루미늄 화합물을 촉매로 하여 에틸렌과 1-부텐을 슬러리 상태로 공중합하였다. 이때 촉매성분의 종류 및 농도, 숙성시간, 중합시간과 중합온도 등이 촉매활성과 공중합체 조성에 미치는 영향을 연구하였다. 그리고 공중합체의 성질과 1-부텐 함량과의 관계를 조사하였다. 그 결과 티탄사노르말부톡시드-염화디에틸알류미늄의 촉매를 사용하였을 때 가장 큰 촉매활성, 보다 많은 1-부텐 함량 및 가장 작은 가용성 부분의 LLDPE를 얻을 수 있었다. 얻은 공중합체의 밀도, 유리전이온도, 녹는점 및 녹음열 등은 1-부텐의 함량이 증가함에 따라 감소하였다.

• 한국정보통신학회논문지
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• 제15권3호
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• pp.551-560
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• 2011

최근 WLAN을 기반으로 하는 실내 위치추정 시스템에 대한 관심이 증가하고 있다. 대부분의 WLAN을 기반으로 하는 위치추정 시스템들은 fingerprinting 기법을 사용한다. fingerprinting 기법에서 이동객체의 위치정확도는 참조 점의 수에 비례한다. 하지만 참조 점의 수에 따라 training 단계에서 fingerprint 데이터베이스를 생성하기 위해 많은 시간과 노력을 요구한다. 이러한 문제점들을 해결하기 위해, 본 논문에서는 WLAN 기반 AP들의 주변 환경정보를 이용하여 AP와 이동 객체 간의 거리를 산출하여 위치를 추정하는 새로운 알고리즘을 제안하였으며, 이동 객체의 위치 정확도를 개선하기 위하여 제안 알고리즘에 파티클 필터를 적용하였다. 이 알고리즘을 구현하기 위하여 먼저 AP들의 주변에 존재하는 벽, 철문, 유리문, 파티션 등과 같은 환경 정보 데이터베이스를 구축하였고 위치 추정은 감쇠 모델과 경로 손실 모델을 이용하였다. 제안 알고리즘을 실험을 통하여 확인한 결과 위치 정확도는 낮았지만 fingerprinting의 문제점을 해결하였다.

• 대한기계학회논문집A
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• 제28권5호
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• pp.489-494
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• 2004

Long Period Gratings (LPG) is currently receiving considerable attention because of their consistent measuring results fur pressure, temperature, strain and flow. LPG is easier to prepare and has a high sensitivity compared with Fiber Bragg Gratings (FBG). In addition, this kind of optical fiber sensors could be used for implementations in various structures. In this paper, LPG was used to monitor in situ the resin flow and the curing process in VARTM (Vacuum Assisted Resin Transfer. Molding). In order to demonstrate the effectiveness of the method, FBG is inserted into the glass mat to monitor the resin flow using optical spectrum analyzer (OSA). The curing reactions in VARTM are also observed using the same method. From the results, the attenuation wavelength shift and the loss change of attenuation band can be obtained from the status of the RTM (Resin Transfer Molding) sample owing to the internal variations of the .effective index, temperature, and pressure. It is shown that the proposed LPG is more effective in monitoring the curing reaction than FBG.

• 폴리머
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• 제33권6호
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• pp.569-574
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• 2009

수분산 PUD 필름의 내스크래치 특성을 개선하기 위해서 카보네이트(PCD), 에스터(PCL), 실옥산(PDSBP)형의 폴리올을 혼성하여 유-무기 하이브리드 수분산 폴리우레탄(PUD)을 합성하였다. 선형구조(Linear type)의 PUD보다 그래프트형(graft type)의 PUD가 유화입경이 커지는 경향이며, 이는 소수성의 실옥산 그래프트 구조에 기인된다고 생각된다. 합성 PUD의 열적성질은 linear type의 PUD는 PCD의 함량이 증가할수록 유리전이온도($T_g$)는 증가하였으며, 열분해온도는 감소하였다. 반면에, graft type PUD는 PDSBP의 양이 증가할수록 $T_g$는 감소하였고, 열분해온도는 거의 유사하였다. Graft type PUD는 PDSBP의 함량이 증가할수록 내스크래치 특성 및 hardness는 향상되는 경향을 보였다. 9 wt%의 PDSBP 폴리올이 혼성된 경우, 3.3 N의 내스크래치 특성과 9 H 이상의 연필경도를 가지는 우수한 PUD 필름을 얻을 수 있었다.

• Restorative Dentistry and Endodontics
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• 제42권2호
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• pp.118-124
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• 2017

Objectives: This study aimed to evaluate the color stability of bulk-fill and nanohybrid resin-based composites polished with 3 different, multistep, aluminum-oxide impregnated finishing and polishing disks. Materials and Methods: Disk-shaped specimens (8 mm in diameter and 4 mm in thickness) were light-cured between two glass slabs using one nanohybid bulk-fill (Tetric EvoCeram, Ivoclar Vivadent), one micro-hybrid bulk-fill (Quixfil, Dentsply), and two nanohybrid incremental-fill (Filtek Ultimate, 3M ESPE; Herculite XRV Ultra, Kerr) resin-based composites, and aged by thermocycling (between $5-55^{\circ}C$, 3,000 cycles). Then, they were divided into subgroups according to the polishing procedure as SwissFlex ($Colt\grave{e}ne/Whaledent$), Optidisc (Kerr), and Praxis TDV (TDV Dental) (n = 12 per subgroup). One surface of each specimen was left unpolished. All specimens were immersed in coffee solution at $37^{\circ}C$. The color differences (${\Delta}E$) were measured after 1 and 7 days of storage using a colorimeter based on CIE Lab system. The data were analyzed by univariate ANOVA, Mann-Whitney U test, and Friedmann tests (${\alpha}=0.05$). Results: Univariate ANOVA detected significant interactions between polishing procedure and composite resin and polishing procedure and storage time (p < 0.05). Significant color changes were detected after 1 day storage in coffee solution (p < 0.05), except Quixfil/Optidisc which was color-stable after 7 days (p > 0.05). Polishing reduced the discoloration resistance of Tetric EvoCeram/SwissFlex, Tetric EvoCeram/Praxis TDV, Quixfil-SwissFlex, and all Herculite XRV Ultra groups after 7 days storage (p < 0.05). Conclusions: Discoloration resistance of bulk-fill resin-based composites can be significantly affected by the polishing procedures.

• Restorative Dentistry and Endodontics
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• 제41권2호
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• pp.114-120
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• 2016

Objectives: The aim of this study was to compare the push-out bond strength and dentinal tubule penetration of root canal sealers used with coated core materials and conventional gutta-percha. Materials and Methods: A total of 72 single-rooted human mandibular incisors were instrumented with NiTi rotary files with irrigation of 2.5% NaOCl. The smear layer was removed with 17% ethylenediaminetetraacetic acid (EDTA). Specimens were assigned into four groups according to the obturation system: Group 1, EndoRez (Ultradent Product Inc.); Group 2, Activ GP (Brasseler); Group 3, SmartSeal (DFRP Ltd. Villa Farm); Group 4, AH 26 (Dentsply de Trey)/gutta-percha (GP). For push-out bond strength measurement, two horizontal slices were obtained from each specimen (n = 20). To compare dentinal tubule penetration, remaining 32 roots assigned to 4 groups as above were obturated with 0.1% Rhodamine B labeled sealers. One horizontal slice was obtained from the middle third of each specimen (n = 8) and scanned under confocal laser scanning electron microscope. Tubule penetration area, depth, and percentage were measured. Kruskall-Wallis test was used for statistical analysis. Results: EndoRez showed significantly lower push-out bond strength than the others (p < 0.05). No significant difference was found amongst the groups in terms of percentage of sealer penetration. SmartSeal showed the least penetration than the others (p < 0.05). Conclusions: The bond strength and sealer penetration of resin-and glass ionomer-based sealers used with coated core was not superior to resin-based sealer used with conventional GP. Dentinal tubule penetration has limited effect on bond strength. The use of conventional GP with sealer seems to be sufficient in terms of push-out bond strength.