• Title/Summary/Keyword: Synthetic dyes

검색결과 114건 처리시간 0.025초

흰구름버섯에 의한 방향족 염료와 비스페놀 A의 분해 (Biodegradation of aromatic dyes and bisphenol A by Trametes hirsuta (Wulfen) Pilat)

  • 임경환;백승아;최재혁;이태수
    • 한국버섯학회지
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    • 제17권4호
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    • pp.247-254
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    • 2019
  • 흰구름버섯 (Trametes hirsuta)의 균사체는 CR, CV, RBBR 등 방향족 염료가 함유된 고체와 액체 배지에서 이들 염료를 효과적으로 탈색하였으나 MB의 탈색은 저조하였다. 각각 CR, MB, CV 및 RBBR 등 4종류의 염료가 함유된 액체배지에서 흰구름버섯의 균사체를 10일 간 배양했을 때 laccase, LiP, MnP 등 세 종류의 효소를 모두 생산하였으며 이들 효소 중 laccase의 활성도가 가장 높았으며 LiP와 MnP의 활성도laccase에 비해 낮았다. 따라서 흰구름버섯 균사체에 의한 방향족 염료의 탈색에는 laccase가 주로 사용되고 LiP나 MnP는 보조적인 역할을 하는 것으로 사료된다. 또한 비스페놀 A가 0, 25, 50, 100, 200 ppm의 농도로 함유된 PDA 배지에 균사체를 접종하여 배양한 결과 비스페놀 A의 농도가 증가함에 따라 균사체의 생장은 농도 의존적으로 저해되는 것으로 나타났다. 또한 비스페놀 A가 100 ppm 함유된 YMG 액체배지에 균사체를 접종하고 비스페놀 A의 분해율을 측정한 결과 배양 12시간 후 72.3%, 배양 24시간 후 95.3%, 그리고 배양 36시간 후에는 100% 분해된 것으로 나타났다. 따라서 본 연구 결과는 우리나라의 산업 활동 과정에서 생산되고 자연계로 배출되어 생물체에 큰 피해를 주는 합성염료와 내분비계 장애물질인 비스페놀 A를 친환경적으로 제거할 수 있는 기술의 개발에 도움이 될 수 있을 것으로 사료된다.

염료의 색도 제거를 위해 개발된 호알칼리성 미생물의 특성 (Charateristics of Akalophilic Microorganism Developed for Color Removal of Dye)

  • 이현욱;임동준
    • 한국염색가공학회지
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    • 제22권2호
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    • pp.145-154
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    • 2010
  • An alkalophilic microorganism capable of degrading dyes was developed for the treatment of alkaline dye solution. This strain was identified as Pseudomonas species. Using this microorganism, biological treatment of dye was studied in Erlenmeyer flasks. The characteristics of this microorganism were observed under various incubating-condition such as temperature, pH, nitrogen source, and macronutrients concentration. The removal effciencies of Disperse Red 60 from synthetic wastewater were 33.5 ~ 36.9% at the range of $30{\sim}40^{\circ}C$, and they were 31.1 ~ 36.7% at the range of initial pH 8 ~ pH 10, respectively. The optimal culture medium was found to be 0.25%(w/v) yeast extract, 0.25%(w/v) polypeptone, 0.1%(w/v) $KH_2PO_4$, 0.2%(w/v) $MgSO_4{\cdot}7H_2O$, and 1.0%(w/v) $Na_2CO_3$. In treatment of various dyes using Erlenmeyer flasks, the removal effciencies of Disperse Blue 87, Disperse Yellow 64, Disperse Red 60, Acid Blue 193, Acid Red 138, and Direct Yellow 23 were found to be 76%, 71%, 58%, 93%, 94%, and 90% respectively after 24hrs reaction of alkalophilic strain Pseudomonas sp. YBE-12.

코치닐을 활용한 우피의 천연염색 (Natural dyeing of cow leather with cochineal)

  • 김상률
    • 복식문화연구
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    • 제24권6호
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    • pp.817-824
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    • 2016
  • The introduction of natural dyes into modern dye houses is very promising green chemistry concept that should be popularized more to reduce the dependency of leather dyeing on some toxic and non-biodegradable synthetic dyes. In this study, the properties of dyeing of cochineal on cow leather were evaluated. The proper dyeing conditions were identified with dye uptake (K/S values) depending on the colorant concentration, dyeing duration, dyeing temperature, and dye bath pH. For the proper mordanting conditions, color changes for different mordants were observed as $La^{*}b^{*}$ and H V/C values. Color fastness (light, rubbing, and dry cleaning) was also examined. Additionally, antibacterial properties and UV protection were examined. The results were as follows: The optimized dyeing conditions were 300% o.w.f., $40^{\circ}C$, 40 min., and pH 5. The cow leather color was red in the absence of mordanting, while it was red purple after being mordanted with Al and Cu, and purple mordanted with Fe. The K/S value of cow leathers increased in the order of the dyeing using $AlK(SO_4)_2$ > $CuSO_4$ > $FeSO_4$. The colorfastness to light and rubbing were reduced compared to original (untreated) cow leather. However dry cleaning fastness was very satisfactory, with a 4~5 rating. The dyed and pre-mordanting dyed cow leather showed excellent antibacterial properties.

Swelling agent를 이용한 근적외선 흡수 유기색소의 polyester 흡착 (A Study on PET Adsorption Property of NIR Dye Using Swelling Agents)

  • 권수현;최재홍
    • 한국염색가공학회지
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    • 제30권1호
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    • pp.20-28
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    • 2018
  • The near infrared ray camouflage fabric has a near infrared ray reluctance similar to the surrounding environment and has a camouflage effect on the surrounding environment. Synthetic fibers used in military uniforms are difficult to have gastrointestinal function as general commercial dyes, unlike cellulose fibers, which use some commercial vat dyes to impart infrared gastrointestinal function. In this study, we optimized the adsorption pH, temperature and time for NIR dye application for polyester fabrics, and established the optimum concentration for the evaluation of adsorption build-up characteristics. In addition, it is difficult to adsorb it since the polyester material has a dense crystal structure and the NIR dye is bulky. Therefore, a swelling agent used for dyeing meta-aramid fibers with high Tg and high crystallinity was introduced as a separate preparation to increase the affinity to polyester, which is a hydrophobic fiber, to thereby obtain an excellent adsorption rate. As a result of comparing before and after using swelling agent, the adsorption rate difference was 10 times or more when compared with before.

매염제 처리에 의한 허브 염색직물의 염착 특성 - 세이지와 로즈마리 추출물 중심으로 - (Dyeing Characteristics of Herb Dyed Fabrics Treated with Mordants - Focused on Sage and Rosemary Extract -)

  • 구신애;배현숙
    • 한국의류산업학회지
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    • 제22권1호
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    • pp.119-129
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    • 2020
  • Unlike synthetic dyes, natural dyes do not affect the human body or create atmosphere pollution that are also mothproof, antibiotic and sterilized. This study examined the changes in dye adsorption properties according to mordant types and mordanting method to qualify trends using sage and rosemary extracts. Dyeability of sage extract is often similar to rosemary extract regardless of dyeing conditions. Dyeing properties of herb colorants on cotton, silk and wool fiber and effect of dyeing conditions on dye uptake were also compared. Dyed fabric showed a yellowish color and the dyeing affinity was somewhat good with rosemary extract. The surface color of the dyed fabrics was darkened by mordant treatment. The K/S value of herb colorants of protein fiber was higher than cellulose fiber. The concentration of mordant having the highest dyeing affinity was different from the mordant type. Regardless of the type of fiber, the K/S value of premordanting was the highest in mordanting method, and the K/S value of simultaneous mordanting indicated no noticeable mordant effect. The fastness of washing of silk fabric was reduced the most by mordant treatment. The lightfastness was reduced in Al mordant treatment regardless of the type of fiber. The lightfastness of wool increased somewhat by mordant treatment.

Development of Dye Natural Batik Based on Fiber Coconut Waste and Leaf Avocado through Extraction Method in Supporting Green Business

  • Agung UTAMA;Anita MUSTIKASARI;Nur KHOLIFAH
    • Asian Journal of Business Environment
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    • 제14권1호
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    • pp.15-22
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    • 2024
  • Purpose: The development of natural batik dyes based on a combination of coconut fiber waste and avocado leaves using the extraction method is important to support the green economy and reduce chemical waste in Indonesia. Research design, data and methodology: The research explores the use of coconut fiber and avocado leaf waste extraction as a natural batik dye and conducts market testing to assess consumer satisfaction. Results: Indonesian batik exports are growing, but synthetic dye practices are causing a decline in demand. To address this, natural dyes are being explored, including coconut fiber waste and avocado leaf waste. Conclusion: Test results from washing at 40 degrees Celsius in terms of color changes and color staining, from sweat in terms of changes in acid color and changes in base color, to sunlight in terms of color fastness value, to heat to iron in terms of color change and color staining shows a value of 3-4 (quite good) and 4-5 (good), meaning that coconut fiber and avocado leaves waste can be used as natural batik dye.

Trametes versicolor 의한 triphenyl methane계 염료의 분해 (Biodegradation of triphenyl methane dyes by white rot fungus, Trametes versicolor)

  • 백승아;최재혁;이태수;임경환
    • 한국버섯학회지
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    • 제13권1호
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    • pp.63-67
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    • 2015
  • 구름버섯(Trametes versicolor)은 phenolic compound인 CV와 MG를 효과적으로 탈색할 수 있었으며 고체와 액체배양 상태 모두에서 CV보다 MG를 더 효과적으로 탈색시켰다. 구름버섯에 의한 두 색소의 탈색 과정에서 phenolic compounds를 분해하는 것으로 알려진 세 가지 효소 중 laccase의 활성이 가장 높았다. MnP 역시 적은 수치지만 활성을 나타냈으며 LiP의 활성은 나타나지 않았다. 따라서 구름버섯에 의한 합성염료의 분해과정에서 laccase가 주로 사용되고 MnP는 탈색과정에서 보조적인 작용을 하는 것으로 추정된다. 그러나 CV의 경우 MnP가 활발하게 염료분해에 관여하는 것으로 판단된다. 또한 MG가 대부분 탈색되었을 때의 laccase 활성(0.16 U/mg)이 CV가 대부분 탈색되었을 때의 활성(0.23 U/mg)보다 현저하게 낮은 것으로 보아 구름버섯이 CV를 탈색시키는데 더 높은 활성의 laccase가 필요로 하는 것이 밝혀졌다. 본 실험에서 한국산 구름버섯 종의 CV와 MG 탈색능력이 확인되었으며 앞으로 한국산 구름버섯을 이용한 triphenyl methane계에 속하는 합성염료의 분해에 관한 친환경적 처리기술 개발에 도움이 될 것으로 기대된다.

絹과 Polyester合絲絹織物의 染色法改善에 關한 硏究 (A Study on Dyeing of Silk-Polyester Fabric)

  • 남중희;장병호
    • 한국잠사곤충학회지
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    • 제23권1호
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    • pp.56-64
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    • 1981
  • 絹과 polyester複合織物의 染色方法을 改善하기 위하여 浸染法과 捺染法에 對하여 染色條件을 檢討하였다. 本 實驗結果를 要約하면 다음과 같다. 1. P/S複合織物의 染色에 있어서는 azo系의 染科가 anthraquinone系의 染科보다 適合하다. 2. Carrier의 種類에 따라서는 使用濃度가 높으면 染斑이 나타난다. 3. Methylnapthalene系의 carrier (D.N)와 陰 Ion 性分散劑로 polyester織物을 染色한 경우에는 染科의 吸着度가 減少하였다. 4. Azo系의 分散染科가 非 Ion性의 carrier와 分散劑 사이에 親和性이 向上되었다. 5. 酸性染科에 의한 染科의 吸着度는 染色浴이 酸性側인 경우 增加되었고, 그 範圍는 pH 4~6이었다. 6. P/S複合織物을 捺染하는 경우에 있어서, 染科의 染着을 向上하기 위해서는 蒸熱溫度, 蒸熱時間 및 pH와의 關係를 適合하게 하여야 한다.

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선인장 열매의 색소 추출물에 의한 양모섬유의 염색 (Dyeing of Wool Fabric by the Pigment Extracted from Opuntia Ficus-indica)

  • 이세희;조용석;최순화
    • 한국염색가공학회지
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    • 제18권2호
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    • pp.8-14
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    • 2006
  • The pigment extraction of Opuntia ficus-indica has been conducted to develop useful natural dyes in place of synthetic dyes which are suspected to bring serious environmental pollutions. The dyeing ability on wool fabric by addition of ascorbic acid and several mordants were investigated by means of color measurement. In addition, the fastness of washing, perspiration, rubbing, light, dry cleaning, effect on bacterial reduction and UV-B protection were also investigated. From these investigation, it is suggested that the pigment extracted from Opuntia ficus-indica can be used as a source of natural dyes and the obtained result are as follows. 1. Maximum absorption band (${\lambda}max$) of Opuntia ficus-indica extract is 533nm. 2. The wool fabric dyed with Opuntia ficus-indica extract has stable color by the addition of ascorbic acid and is achieved with addition of 0.1% ascorbic acid, 0.5% several mordant, and three repeated dying at $50^{\circ}C$ for 1.5hr. 3. The wash fastness of the dyed wool fabric when it is washed with neutral detergent is more effective than alkaline detergent. The dry cleaning fastness of the dyed wool fabric is more excellent. In addition, the perspiration fastness of the dyed wool fabric is increased by mordanting method. And than the rubbing fastness of the dyed wool fabric is showed excellent under dryness and wetness. Light fastness of the dyed wool fabric, however is showed inferiority. 4. The wool fabric dyed with Opuntia ficus-indica extract is showed effective bacterial reduction and UV-B protection is increased remarkably.

Study on the Korean Traditional Dyeing:1) Unique features and understanding

  • Soh, Hwang Oak
    • International Journal of Costume and Fashion
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    • 제13권1호
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    • pp.35-47
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    • 2013
  • We know that humans are able to live comfortably when there is a balance between the living environment that surrounds us and us. Clothing, one of the necessities of life, serves a dual purpose of functioning as protection for the body as well as providing visual satisfaction, and so is the most effective bonding mechanism. A different type of comfort that has been provided through industrialization and advancements in technology has resulted in pollution problems in the environment, and it has reached a point of seriously thinking about its effects. The biggest problems in environmental pollution are air pollution and waste disposal, and something that cannot be ignored is that environmental hormones and harmful heavy metals have been discovered in the synthetic dyes used in the clothing product, and not only are they harmful to the body, but they also have adverse effects on skin allergies such as atopic dermatitis. Its effects on clothing, especially underwear and baby products, can become a serious issue. The use of natural vegetable dye can be considered the basis for the traditional Korean dyeing process, however not all natural dyeing process can be thought of as traditional Korean dyeing. This is because natural dyeing used to be the most common method of dyeing before synthetic dyes came along and became the dye of choice for most clothing. Natural dyes are beneficial to the body, and the nature colors, achieved from the natural materials, relieve eye strains as well as have a healing effect for people who are suffering from psychological instability such as stress. However, the use of mordant in order to increase the fastness and get better color effects can lead to even more damage to the environment, and it cannot be a dyeing method that is good for the body. Traditional natural dyeing is different from regular natural dyeing because it uses colors that the Korean people can identify with and applies specific methods in order to achieve those colors. Even though experimental study with dyestuff and practical use of the dyeing methods for traditional Korean dyeing has been started(Soh, H., 1983) and has been ongoing, it is still not easy for regular people to use the method on their own. At the present time, natural dye materials are getting made and sold more than ever, but there is a lot of confusion among consumers regarding the difference between traditional Korean dyeing and natural dyeing, as companies are using the two terms interchangeably to market their natural dye products. So getting a better understanding of the characteristics of traditional Korean dyeing and traditional colors should be considered first priority at this time. The purpose of this thesis is to study the traditional Korean view of color, which developed the culture of traditional dyeing in Korea, and the characteristics of traditional Korean dyeing, a method that pursued achieving Korea's color through natural dyeing.