• 제목/요약/키워드: Synthesizing

검색결과 1,032건 처리시간 0.026초

Synthesizing Dendronized Linear Polymers using "Click Chemistry"

  • Mynar Justin L.;Helms Brett;Hawker Craig J.;Frechet Jean M.J.
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.317-317
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    • 2006
  • Dendronized linear polymers have recently come forward as new materials for nanoscale applications. These "molecular cylinders" may be modified with specific chemical makeup, rigidity, surface decoration, and backbone properties much like their spherical analogs, dendrimers. There exist three main synthetic pathways to yield dendronized polymers: (i) graft-to; (ii) graft-from; and (iii) macromonomer. We present an efficient "graft-to" approach towards dendronized microstructures utilizing click chemistry. With the capacity to manipulate their chemical composition, these dendronized structures have already found broad use in site-isolation for catalysis, nanolithography and organic light emitting diodes. These and other potential applications of these materials will be also presented.

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Formation of Ti-0 Biomedical Film on Ti6A14V Alloy by DC Glow Plasma Oxidizing

  • Zheng, C.L.;Cui, F.Z.;Xu, Z.
    • Journal of Korean Vacuum Science & Technology
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    • 제6권1호
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    • pp.16-21
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    • 2002
  • Ti-0 film is a kind of biocompatible surface materials. In this paper, a new method, glow discharge plasma oxidizing, has been used in synthesizing Ti-O gradient films on Ti6A14V substrates. The effects of ion bombardment and process parameters on the structures of titanium oxide layers have been investigated. The results demonstrate that DC glow plasma oxidizing is more efficient in preparation of dense, hard, and high adhesive Ti-O biomedical films on titanium and its alloys. Samples treated by this method show higher hardness values than by others. Especially, in the condition of hollow cathode discharge, the ion bombardment enhances ionization of oxygen, promotes the oxygen permeation and facilitates the formation of the oxide of low valence states of titanium.

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First Principle Approach to Modeling of Primitive Quad Rotor

  • Sudiyanto, Tata;Muljowidodo, Muljowidodo;Budiyono, Agus
    • International Journal of Aeronautical and Space Sciences
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    • 제10권2호
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    • pp.148-160
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    • 2009
  • By the development of recent technology, a new variant of rotorcrafts having four rotors start drawing attention from aerial-robotics engineers more than before. Its potential spans from just being control device test bed to performing difficult task such as carrying surveillance device to unreachable places. In this regards, modeling a quad-rotor is significant in analyzing its dynamic behavior and in synthesizing control system for such a vehicle. This paper summarizes the modeling of a mini quad-rotor aerial vehicle. A first principle approach is considered for deriving the model based on Euler-Newton equations of motion. The result of the modeling is a simulation platform that is expected to acceptably predict the dynamic behavior of the quad-rotor in various flight conditions. Linear models associated with different flight condition can be extracted for the purpose of control synthesis.

Soft IP Compiler for a Reed-Solomon Decoder

  • Park, Jong-Kang;Kim, Jong-Tae
    • ETRI Journal
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    • 제25권5호
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    • pp.305-314
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    • 2003
  • In this paper, we present a soft IP compiler for the Reed-Solomon decoder that generates a fully synthesizable VHDL core exploiting characteristic parameters and design constraints that we newly classify for the soft IP. It produces a structural design with an estimable regular architecture based on a finite state machine with a datapath (FSMD). Since characteristic parameters provide different design points on the design space, using one of two simple procedures called the constructive search with area increment (CSAI) and constructive search with speed decrement (CSSD) for design space exploration, the core compiler makes it possible for an IP user to create the Reed-Solomon decoder with appropriate sub-architectures without synthesizing many models. Experimental results show that the IP compiler can apply to several industry standards.

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Fast Motion Synthesis of Quadrupedal Animals Using a Minimum Amount of Motion Capture Data

  • Sung, Mankyu
    • ETRI Journal
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    • 제35권6호
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    • pp.1029-1037
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    • 2013
  • This paper introduces a novel and fast synthesizing method for 3D motions of quadrupedal animals that uses only a small set of motion capture data. Unlike human motions, animal motions are relatively difficult to capture. Also, it is a challenge to synthesize continuously changing animal motions in real time because animals have various gait types according to their speed. The algorithm proposed herein, however, is able to synthesize continuously varying motions with proper limb configuration by using only one single cyclic animal motion per gait type based on the biologically driven Froude number. During the synthesis process, each gait type is automatically determined by its speed parameter, and the transition motions, which have not been entered as input, are synthesized accordingly by the optimized asynchronous motion blending technique. At the start time, given the user's control input, the motion path and spinal joints for turning are adjusted first and then the motion is stitched at any speed with proper transition motions to synthesize a long stream of motions.

QLQG/$H_{\infty}$ 제어를 이용한 다변수 하드비선형 제어기 설계 (Design of the multivariable hard nonlinear controller using QLQG/$H_{\infty}$ control)

  • 한성익;김종식
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1996년도 한국자동제어학술회의논문집(국내학술편); 포항공과대학교, 포항; 24-26 Oct. 1996
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    • pp.81-84
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    • 1996
  • We propose the robust nonlinear controller design methodology, the $H_{\infty}$ constrained quasi - linear quadratic Gaussian control (QLQG/ $H_{\infty}$), for the statistically-linearized multivariable system with hard nonlinearties such as Coulomb friction, deadzone, etc. The $H_{\infty}$ performance constraint is involved in the optimization process by replacing the covariance Lyapunov equation with the Riccati equation whose solution leads to an upper bound of the QLQG performance. Because of the system's nonlinearity, however, one equation among three Riccati equations contain the nonlinear correction terms that are very difficult to solve numerically. To treat this problem, we use simple algebraic techniques. With some analytic transformation for Riccati equations, the nonlinear correction terms can be so eliminated that the set of a linear controller to the different operating points are designed. Synthesizing these via inverse random input describing function (IRIDF) technique, the final nonlinear controller can be designed.

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MRM: 상징행렬을 이용한 다단계 리드뮬러회로의 합성 도구 (MRM : A synthesis Tool for Multi-level Reed Muller Circuits using Symbolic Matrix)

  • 이귀상;창준영
    • 전자공학회논문지A
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    • 제32A권10호
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    • pp.73-80
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    • 1995
  • In this paper, a synthesis tool using matrix operations for designing multi-level Reed Muller circuits is described which has been named as MRM (Multi-level Reed Muller Minimizer). The synthesis method which uses matrix operations has advantages in effectively minimizing chip area, delay optimization and fault detection capability. However, it uses only truth-table type maps for inputs, synthesizing only small circuits. To overcome the weakness, our method accepts two-level description of a logic function. Since the number of cubes in the two-level description is small, the input matrix becomes small and large circuits can be synthesized. To convert two-level representations into multi-level ones, different input patterns are extracted to make a map which can be fed to the matrix operation procedure. Experimental results show better performance than previous methods. The matrix operation method presented in this paper is new to the society of Reed Muller circuits synthesis and provides solid mathematical foundations.

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The Relationship between Mitochondria and NLRP3 Inflammasome

  • Lee, Hyun Ah;Na, Hee Sam;Chung, Jin
    • International Journal of Oral Biology
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    • 제42권3호
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    • pp.85-90
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    • 2017
  • Mitochondria participate in various intracellular metabolic pathways such as generating intracellular ATP, synthesizing several essential molecules, regulating calcium homeostasis, and producing the cell's reactive oxygen species (ROS). Emerging studies have demonstrated newly discovered roles of mitochondria, which participate in the regulation of innate immune responses by modulating NLRP3 inflammasomes. Here, we review the recently proposed pathways to be involved in mitochondria-mediated regulation of inflammasome activation and inflammation: 1) mitochondrial ROS, 2) calcium mobilization, 3) nicotinamide adenine dinucleotide ($NAD^+$) reduction, 4) cardiolipin, 5) mitofusin, 6) mitochondrial DNA, 7) mitochondrial antiviral signaling protein. Furthermore, we highlight the significance of mitophagy as a negative regulator of mitochondrial damage and NLRP3 inflammasome activation, as potentially helpful therapeutic approaches which could potentially address uncontrolled inflammation.

Tetramethyl-4,4'-diaminobenzophenone 合成에 關한 硏究 (The Studies on the Synthesis of a Tetramethyl-4,4'-diaminobenzophenone)

  • 전풍진;김진일
    • 대한화학회지
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    • 제4권1호
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    • pp.67-69
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    • 1957
  • The synthetic method of tetramethyl-4,4'-diaminobenzophenone accomplished by W. Michler is to pass gaseous carbonyl chloride in dimethylaniline until theoretical value of weight increases at room temperature and synthesize the ketone by heating it at above 120$^{\circ}C. In the result of the experiment to synthesize the ketone by Michler's method, it was observed that if gaseous phosgen was to be used at room temperature according to the method, the gas inhaling tube would be closed up by reaction products (gruel-like crystals) before the theoretical amount of gases passed in and causing difficulty for gas to be produce or inhaled With a view to remove the difficulty, the author examined an article published by W. Michler entitled. "The synthesis of organic acid with phosgen" and guessing that the use of liquid phosgen could overcome the difficulty, succeeded in synthesizing the substance in good yield easily by reacting dimethylaniline with phosgen that was condensed into liquid state.

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Applications of Tandem Mass Spectrometry in the Structure Determination of Permethylated Sialic Acid-containing Oligosaccharides

  • Yoo, Eun-Sun;Yoon, In-Mo
    • Bulletin of the Korean Chemical Society
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    • 제26권9호
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    • pp.1347-1353
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    • 2005
  • Sets of sialic acid-containing trisaccharides having different internal and terminal linkages have been synthesized to develop a sensitive method for analysis of the reducing terminal linkage positions. The trisaccharides, sialyl($\alpha$ 2-3)Gal($\beta$ 1-3)GalNAc and sialyl($\alpha$ 2-3)Gal($\beta$ 1-X)GlcNAc where X=3, 4 and 6, were synthesized and examined using electrospray ionization (ESI)-collision induced dissociation (CID) tandem mass spectrometry (MS/MS). The compounds chosen for this study are related to terminal groups likely to be found on polylactosamine-like glycoproteins and glycolipids which occur on the surface of mammalian cells. The purpose of this study is to develop tandem mass spectrometral methods to determine detailed carbohydrate structures on permethylated or partially methylated oligosaccharides for future applications on biologically active glycoconjugates and to exploit a faster method of synthesizing a series of structural isomeric oligosaccharides to be used for further mass spectrometry and instrumental analysis.