• Title/Summary/Keyword: Synthesis parameters

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Electrochemical Properties and Estimation on Active Material LiMnO2 Synthesis for Secondary

  • Wee, Sung-Dong;Kim, Jong-Uk;Gu, Hal-Bon
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.2
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    • pp.35-39
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    • 2003
  • This paper is contents on the orthorhombic crystalline calcined by the solid phase method with LiMnO$_2$ thin film structured as the result which an average pore diameter of power was 132.3${\AA}$ in porosity analysis. Voltage ranges are able to get the properties of charge and discharge for experimental results of LiMnO$_2$ thin film were 2.2V 4.3V. The current density and scan speed were 0. 1㎃/$\textrm{cm}^2$ and 0.2㎷/sec respectively. Properties of the charge and discharge are obtained by optimum experiment condition parameters. Li dense ratio of the LiMnO$_2$ thin film that discharged capacities were 87㎃h/g have been 96.9[ppm] at 670.784[nm] wavelength. The dense ratio of Mn analyzed to 837[ppm] at 257.610[nm] wavelength. It can be estimated the quality of the LiMnO$_2$ thin film as that the wrong LiMnO$_2$ thin film pulled up from cell of electrolyte and became dry it at 800$^{\circ}C$. The results of SEM and XRD were the same as that of original researchers.

Synthesis and Characterization of Trimetallic Rare Earth Orthoferrites, $La_xSm_{1-x}FeO_3$

  • Traversa, Enrico;Gusmano, Gualtiero;Allieri, Brigida;Depero, Laura E.;Sangaletti, Luigi;Aono, Hiromichi;Sadaoka, Yoshihiko
    • The Korean Journal of Ceramics
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    • v.6 no.1
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    • pp.21-26
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    • 2000
  • Nanosized powders of trimetallic orthoferrites containing La and Sm in different ratios were synthesised by the thermal decomposition at low temperatures of the corresponding hexacyanocomplexes. The precursors and their decomposition products were analyzed by simultaneous thermogravimetric and differential thermal analysis (TG/DTA), x-ray diffraction (XRD) and Raman spectroscopy. Single phase trimetallic precursors and oxides were obtained. The crystal structure of the perovskitic oxides was orthorhombic, and the lattice parameters were affected by the ionic size of the rare earth elements present in the oxides. Raman spectroscopy showed a disorder effect in the vibrational bands with increasing the La content.

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Surface hydrophilicity modification of PVDF membranes with an external electric field in the phase inversion process

  • Shi, Bao-Li;Su, Xing;He, Jing;Wang, Li-Li
    • Membrane and Water Treatment
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    • v.6 no.5
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    • pp.351-363
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    • 2015
  • To increase the surface hydrophilicity of PVDF membranes, in this paper, an electric enhancing method was adopted to treat PVDF nascent membranes during the phase inversion process. It was found that when PEG 600 was taken as the additive, the surface water contact angle of the PVDF membrane treated under 2 kV electric field was decreased from $84.0^{\circ}$ to $65.7^{\circ}$. The reason for the surface elements change of the PVDF membranes prepared under the electric field was analyzed in detail with the dielectric parameters of the polymer dope solutions. Results from BSA adsorption experiment showed that the antifouling ability of the external electric field-treated membranes was distinctly enhanced when compared with that of the untreated membranes. The amount of BSA adsorbed by the treated membranes was lower by 38-43%. Compared with the common chemical reaction methods to synthesize hydrophilic additives or membrane materials, the electric field-assisted processing method did not involve any additional chemical synthesis process and it was capable of realizing better hydrophilicity.

Morphologies of Aragonite Synthesized from Scallop Shells and Lime Stones by Successive Reaction

  • Keiko Sasaki;Hiroyuki Kobayashi;Yoo, Kyoung-Keun;Masami Tsunekawa
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.331-336
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    • 2001
  • Aragonite type of precipitated calcium carbonate was synthesized by the successive reaction with hybridization of waste scallop shells with limestone. In the first step, carbonation was performed by using calcined limestone with low brightness, followed by the additional carbonation using calcined-hydrous scallop shells with high brightness. The temperature and the amount ratio of calcined limestone to calcined-hydrous scallop shells were examined as parameters in the experimental conditions. The products were characterized by XRD, SEM. in addition to measurements of brightness index. the specific surface area, and bulk density. The amount ratio of limestone to scallop shell affected not only the brightness but also morphologies of products. The increase in relative amounts of limestone leads to decrease in brightness and bumpy surface of particles. High temperature reaction produces aragonite particles with longer sizes and higher bulk densities. This study has made an attempt to establish the synthesis of aragonite with high brightness and high strength by utilization of waste scallop shells.

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Effects of Piroxicam on Pharmacodynamics and Pharmacokinetics of Nifedipine in Spontaneously Hypertensive Rats (피록시캄이 니페디핀의 약력학 및 약동학에 미치는 영향)

  • 최기환;박인숙;김동섭;정혜주
    • YAKHAK HOEJI
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    • v.44 no.3
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    • pp.245-250
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    • 2000
  • Because nonsteroidal anti-inflammatory drugs are reported to cause fluid retention and hypertension by inhibition of prostaglandin synthesis, the effects of piroxicam on pharmacodynamics and pharmacokinetics of nifedipine were studied in male spontaneously hypertensive rats. They received nifedipine (0.5 mg/kg) alone or combined with piroxicam (5 mg/kg) intravenously. Plasma levels norepinephrine, an index of sympathetic stimulation, were measured prior to each treatment and 5 min after drug administration. Changes in blood pressure were examined serially and blood samples for analysis of nifedipine were also taken for 6 hr following drug administration. Plasma nifedipine concentration were assayed by HPLC and pharmacokinetic parameters were calculated. Blood pressure was reduced (p<0.01), but plasma norepinephrine level was increased (p<0.05) by nifedipine administration. Anti-hypertensive effect of nifedipine was potentiated (p<0.05) by piroxicam coadministration, but effect of nifedipine on plasma norepinephrine level was not affected. In case of rats received nifedipine and piroxicam, plasma nifedipine concentrations were higher (p<0.05) than those from rats received nifedipine alone at 2,3,4,5 and 6 hours following drug administration. The area under the plasma concentration vs. time curve was increased (p<0.05), while the elimination rate constant was decreased (p<0.01) by piroxicam coadministration. No significant differences were observed in the plasma clearance, apparent volume of distribution and elimination half-life. Thus, piroxicam not only potentiated antihypertensive effect of nifedipine, but also altered nifedipine pharmacokinetics in the rats. It is concluded that the potentiation of nifedipine antihypertensive effect might correlate with the increment of its plasma concentration by piroxicam coadministration.

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Tunable Q-factor 2-D Discrete Wavelet Transformation Filter Design And Performance Analysis (Q인자 조절 가능 2차원 이산 웨이브렛 변환 필터의 설계와 성능분석)

  • Shin, Jonghong
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.11 no.1
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    • pp.171-182
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    • 2015
  • The general wavelet transform has profitable property in non-stationary signal analysis specially. The tunable Q-factor wavelet transform is a fully-discrete wavelet transform for which the Q-factor Q and the asymptotic redundancy r, of the transform are easily and independently specified. In particular, the specified parameters Q and r can be real-valued. Therefore, by tuning Q, the oscillatory behavior of the wavelet can be chosen to match the oscillatory behavior of the signal of interest, so as to enhance the sparsity of a sparse signal representation. The TQWT is well suited to fast algorithms for sparsity-based inverse problems because it is a Parseval frame, easily invertible, and can be efficiently implemented. The transform is based on a real valued scaling factor and is implemented using a perfect reconstruction over-sampled filter bank with real-valued sampling factors. The transform is parameterized by its Q-factor and its over-sampling rate, with modest over-sampling rates being sufficient for the analysis/synthesis functions to be well localized. This paper describes filter design of 2D discrete-time wavelet transform for which the Q-factor is easily specified. With the advantage of this transform, perfect reconstruction filter design and implementation for performance improvement are focused in this paper. Hence, the 2D transform can be tuned according to the oscillatory behavior of the image signal to which it is applied. Therefore, application for performance improvement in multimedia communication field was evaluated.

Digital Image Processing Using Tunable Q-factor Discrete Wavelet Transformation (Q 인자의 조절이 가능한 이산 웨이브렛 변환을 이용한 디지털 영상처리)

  • Shin, Jong Hong
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.10 no.3
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    • pp.237-247
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    • 2014
  • This paper describes a 2D discrete-time wavelet transform for which the Q-factor is easily specified. Hence, the transform can be tuned according to the oscillatory behavior of the image signal to which it is applied. The tunable Q-factor wavelet transform (TQWT) is a fully-discrete wavelet transform for which the Q-factor, Q, of the underlying wavelet and the asymptotic redundancy (over-sampling rate), r, of the transform are easily and independently specified. In particular, the specified parameters Q and r can be real-valued. Therefore, by tuning Q, the oscillatory behavior of the wavelet can be chosen to match the oscillatory behavior of the signal of interest, so as to enhance the sparsity of a sparse signal representation. The TQWT is well suited to fast algorithms for sparsity-based inverse problems because it is a Parseval frame, easily invertible, and can be efficiently implemented. The TQWT can also be used as an easily-invertible discrete approximation of the continuous wavelet transform. The transform is based on a real valued scaling factor (dilation-factor) and is implemented using a perfect reconstruction over-sampled filter bank with real-valued sampling factors. The transform is parameterized by its Q-factor and its oversampling rate (redundancy), with modest oversampling rates (e. g. 3-4 times overcomplete) being sufficient for the analysis/synthesis functions to be well localized. Therefore, This method services good performance in image processing fields.

Parametric Study of Methanol Chemical Vapor Deposition Growth for Graphene

  • Cho, Hyunjin;Lee, Changhyup;Oh, In Seoup;Park, Sungchan;Kim, Hwan Chul;Kim, Myung Jong
    • Carbon letters
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    • v.13 no.4
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    • pp.205-211
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    • 2012
  • Methanol as a carbon source in chemical vapor deposition (CVD) graphene has an advantage over methane and hydrogen in that we can avoid optimizing an etching reagent condition. Since methanol itself can easily decompose into hydrocarbon and water (an etching reagent) at high temperatures [1], the pressure and the temperature of methanol are the only parameters we have to handle. In this study, synthetic conditions for highly crystalline and large area graphene have been optimized by adjusting pressure and temperature; the effect of each parameter was analyzed systematically by Raman, scanning electron microscope, transmission electron microscope, atomic force microscope, four-point-probe measurement, and UV-Vis. Defect density of graphene, represented by D/G ratio in Raman, decreased with increasing temperature and decreasing pressure; it negatively affected electrical conductivity. From our process and various analyses, methanol CVD growth for graphene has been found to be a safe, cheap, easy, and simple method to produce high quality, large area, and continuous graphene films.

Synthesis of High Purity Aluminum Nitride Nanopowder in Ammonia and Nitrogen Atmosphere by RF Induction Thermal Plasma (RF 유도결합 열 플라즈마를 이용한 암모니아와 질소분위기에서 고순도 AlN 나노 분말의 합성)

  • Kim, Kyung-In;Choi, Sung-Churl;Kim, Jin-Ho;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Journal of the Korean Ceramic Society
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    • v.51 no.3
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    • pp.201-207
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    • 2014
  • High-purity aluminum nitride nanopowders were synthesized using an RF induction thermal plasma instrument. Ammonia and nitrogen gases were used as sheath gas to control the reactor atmosphere. Synthesized AlN nanopowders were characterized by XRD, SEM, TEM, EDS, BET, FTIR, and N-O analyses. It was possible to synthesize high-purity AlN nanoparticles through control of the ammonia gas flow rate. However, additional process parameters such as plasma power and reactor pressure had to be controlled for the production of high-purity AlN nanopowders using nitrogen gas.

Multiobjective PI/PID Control Design Using an Iterative Linear Matrix Inequalities Algorithm

  • Bevrani, Hassan;Hiyama, Takashi
    • International Journal of Control, Automation, and Systems
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    • v.5 no.2
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    • pp.117-127
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    • 2007
  • Many real world control systems usually track several control objectives, simultaneously. At the moment, it is desirable to meet all specified goals using the controllers with simple structures like as proportional-integral (PI) and proportional-integral-derivative (PID) which are very useful in industry applications. Since in practice, these controllers are commonly tuned based on classical or trial-and-error approaches, they are incapable of obtaining good dynamical performance to capture all design objectives and specifications. This paper addresses a new method to bridge the gap between the power of optimal multiobjective control and PI/PID industrial controls. First the PI/PID control problem is reduced to a static output feedback control synthesis through the mixed $H_2/H_{\infty}$ control technique, and then the control parameters are easily carried out using an iterative linear matrix inequalities (ILMI) algorithm. Numerical examples on load-frequency control (LFC) and power system stabilizer (PSS) designs are given to illustrate the proposed methodology. The results are compared with genetic algorithm (GA) based multiobjective control and LMI based full order mixed $H_2/H_{\infty}$ control designs.