• Journal of Powder Materials
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• v.6 no.3
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• pp.238-245
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• 1999

The preparation of $n-TiO_2$ powder by the Chemical Vapor Synthesis process (CVS) was studied using the liquid metal organic precursor (TTIP). The residence time and the collection methods were considered as main processing variables through the experiments. The CVS equipment consisted of a micropump and a flashvaporizer, a tube furnace and a tubular collection device. The synthesis was performed at $1000^{\circ}C$ with various sets of collection zone. The residence time and the total system pressure were controlled in the range of 3~20 ms and 10 mbar, respectively. Nitrogen adsorption, X-ray diffraction and electron microscopy were used to determine particle size, specific surface area and crystallographic structure. The grain size of the as-prepared $n-TiO_2$ powder was in the range of 2~8 nm for all synthesis parameters and the powder exhibited only little agglomeration. The relationship between particle characteristics and the processing variables is reviewed based on simple growth model.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.3
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• pp.275-280
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• 2002

The peculiarities of using Self-propagating High-temperature Synthesis (SHS) and solid-stave chase synthesis for production of high temperature superconductor materials were discussed. Oxide superconductors with general formula of $ReBa_2Cu_3O_{7-x}$ (Re=Y, Sm) haute been made by using barium oxide initial powder instead of traditional barium carbonate. Phenomena observed during the grinding of the reactants mixture are presented. Mechano-chemical activation - as a pre-treatment of the reactants mixture - strongly influences the kinetic parameters, the reaction mechanism, and the composition and structure of the final product.

• Journal of Institute of Control, Robotics and Systems
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• v.8 no.8
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• pp.649-654
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• 2002

The essential philosophy of the QFT(Quantitative Feedback Theory) is that a suitable controller can be found by loop shaping a nominal loop transfer function such that the frequency response of this function does not violate the QFT bounds. The loop shaping synthesis involves the identification of a structure and its specialization by means of the parameter optimization. This paper presents an optimization algorithm to estimate the controller parameters from the frequency transfer function synthesis using the TLS(Total Least Squares) in the QFT loop shaping procedure. The proposed method identifies the parameter vector of the robust controller from an overdetermined linear system developed from rearranging the two dimensional system matrices and output vectors obtained from the QFT bounds. The feasibility of the suggested algorithm is illustrated with an example.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2000.11a
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• pp.445-450
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• 2000

In this paper, a numerical method is proposed for cam synthesis. kinematics of closed loop system with cam and follower is presented using relative coordinates. The system is transformed into an open loop system by cutting fictitiously higher-pair contact of cam and follower and envelope constraint equations are derived. Follower constraint equations are derived from the motion of the follower ends. The joint variables and follower profile parameters are calculated from the envelope constraint equations and follower constraint equations by using the Newton - Raphson iterative method. Algorithms for cam synthesis are presented and simulations are done to verify the effectiveness of the proposed method.

• Proceedings of the Materials Research Society of Korea Conference
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• 2010.05a
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• pp.11.1-11.1
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• 2010

As one of the non-vacuum, low temperature fabrication route, electrochemical synthesis has been focused for pursuing the cost-effective pathway to produce high efficiency photovoltaic devices. Especially the availability to form the thin film structure on flexible substrate would be the great advantage of electrochemical process. The successful synthesis of the most favorable absorber materials such as CdTe and CIGS has been reported by many researchers, however, the efficiency of electrochemically synthesized could not exceed that from vacuum process, because of microstructural controllability and compositional variation on devices. In this study, we represent the effect of process parameters on the microstructure and composition of compound semiconductor during the synthesis, and propose the photovoltaic characteristics of electrochemically synthesized solar cells.

• Proceedings of the KIEE Conference
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• 1997.07b
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• pp.587-589
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• 1997

In this paper we design the model following ${\mu}$-synthesis control system for optimal fuel-injection of diesel engine using genetic algorithms. To do this, we give gain and dynamics parameters to the weighting functions and apply genetic algorithms with reference model to the optimal determination of weighting functions that are given by D-K iteration method which can design ${\mu}$-synthesis controller in the state space. These weighting functions are optimized simultaneously in the search domain selected adequately. The effectiveness of this ${\mu}$-synthesis control system for fuel-injection is verified by computer simulation.

• Journal of the Korean Ceramic Society
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• v.32 no.9
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• pp.1085-1091
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• 1995

Molybdenum disilicide (MoSi2) was synthesized from Mo, MoO3, Si and Al powders by self-propagating high temperature synthesis (SHS). The effect of processing parameters such as Mo/MoO3 molar ratio, Ar gas pressure in the reactor and pressing pressure of compacts in synthesis of MoSi2 were investigated. h-MoSi2 was transformed into t-MoSi2 with increasing the Mo/MoO3 mole ratio, and only t-MoSi2 phase was identified above 3.5 : 1 (molar ratio). The synthesized phases did not change with the variation of Ar gas pressure and pressing pressure of compacts. It was found that the combustion temperature was above 2,50$0^{\circ}C$. The products were separated into MoSi2 (s) and $\alpha$-Al2O3 by the difference of their specific grativities. Bending strength, hardness and density of sintered specimen exhibited 82 MPa, 5.368 GPa and 5.43 g/㎤, respectively.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2000.11a
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• pp.201-206
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• 2000

In this work transfer function synthesis method based on FRF data of each substructure is investigated for a complex structure composed of many substructures. Though the transfer function synthesis method has superiority to analyze the characteristics of interfaces among substructures effectively, many problems arise in the computation process, especially matrix inversion process. Due to computational problems, the error between the data obtained by test and the predictions through computations is inevitable. So in this paper, computational aspects in the transfer function synthesis method are examined through a steering system problem of passenger car. For the FBS method, frequency response functions of 3 substructures are measured experimentally. Effects of several parameters such as matrix inversion method, connection conditions between substructures and off-diagonal terms on system response are studied numerically.

• Transactions of the Korean hydrogen and new energy society
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• v.20 no.5
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• pp.416-423
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• 2009

High-temperature steam electrolysis (HTSE) using solid oxide cell is a challenging method for highly efficient large-scale hydrogen production as a reversible process of solid oxide fuel cell (SOFC). The overall efficiency of the HTSE hydrogen and synthesis gas production system was analyzed thermo-electrochemically. A thermo-electrochemical model for the hydrogen and synthesis gas production system with solid oxide electrolysis cell (SOEC) and very high temperature gas-cooled reactor (VHTR) was established. Sensitivity analyses with regard to the system were performed to investigate the quantitative effects of key parameters on the overall efficiency of the production system. The overall efficiency with SOEC and VHTR was expected to reach a maximum of 58% for the hydrogen production system and to 62% for synthesis gas production system by improving electrical efficiency, steam utilization rate, waste heat recovery rate, electrolysis efficiency, and thermal efficiency. Therefore, overall efficiency of the synthesis production system has higher efficiency than that of the hydrogen production system.

• Textile Coloration and Finishing
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• v.27 no.4
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• pp.229-244
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• 2015

The effects of synthesis conditions on characteristics of the calcium-azo complex pigment, C.I. Pigment Red 57:1, were studied. It was mainly considered that the industrially required synthesis conditions for lowering electrical conductivity of the pigment solution keeping pigment quality such as particle size and color characteristics. Three parameters were chosen as control factors during the synthesis. The first was the amount of hydrochloric acid added to transform sodium nitrite into nitrous acid. The second was the amount of calcium chloride added to insolubilize the synthesized azo dye. The final factor was pH control during the coupling reaction. The electrical conductivity and pigment aggregate particle size were dependent on the amount of hydrochloric acid and calcium chloride. Higher HCl concentration gave brighter yellowish-red color because of smaller particle aggregate size and narrower size distribution. Amount of charged ions in the synthesis process might affect the "lake" formation resulting different particle aggregate size and color shade.