• Title/Summary/Keyword: Synthesis parameters

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Synthesis and analysis CdSe Quantum dot with a Microfluidic Reactor Using a Combinatorial Synthesis System (조합 합성 시스템의 미세유체반응기를 이용한 CdSe 양자점 합성 및 분석)

  • Hong, Myung Hwan;Lee, Duk-Hee;Kang, Lee-Seung;Lee, Chan Gi;Kim, Bum-Sung;Kim, Nam-Hoon
    • Journal of Powder Materials
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    • v.23 no.2
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    • pp.143-148
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    • 2016
  • A microfluidic reactor with computer-controlled programmable isocratic pumps and online detectors is employed as a combinatorial synthesis system to synthesize and analyze materials for fabricating CdSe quantum dots for various applications. Four reaction condition parameters, namely, the reaction temperature, reaction time, Cd/Se compositional ratio, and precursor concentration, are combined in synthesis condition sets, and the size of the synthesized CdSe quantum dots is determined for each condition. The average time corresponding to each reaction condition for obtaining the ultraviolet-visible absorbance and photoluminescence spectra is approximately 10 min. Using the data from the combinatorial synthesis system, the effects of the reaction conditions on the synthesized CdSe quantum dots are determined. Further, the data is used to determine the relationships between the reaction conditions and the CdSe particle size. This method should aid in determining and selecting the optimal conditions for synthesizing nanoparticles for diverse applications.

Prediction of Post-Treatment Outcome of Pathologic Voice Using Voice Synthesis (음성합성을 이용한 병적 음성의 치료 결과에 대한 예측)

  • 이주환;최홍식;김영호;김한수;최현승;김광문
    • Journal of the Korean Society of Laryngology, Phoniatrics and Logopedics
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    • v.14 no.1
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    • pp.30-39
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    • 2003
  • Background and Objectives : Patients with pathologic voice often concern about recovery of voice after surgery. In our investigation, we give controlled values of three parameters of voice synthesis program of Dr. Speech Science. such as jitter, shimmer, and NNE(normalized noise energy) which characterize someone's voice from others and deviced a method to synthesize the predicted voice after performing operation. Subjects and Method : Values of vocal jitter, vocal shimmer, and glottal noise were measured with voices of 10 vocal cord Paralysis and 10 vocal Polyp Patients 1 week Prior to and 1 month after the surgery. With Dr. Speech science voice synthesis program we synthesized 'ae' vowel which is closely identical to preoperative and post-operative voice of the patients by controlling the values of jitter, shimmer, and glottal noise. then we analyzed the synthesized voices and compared with pre and post-operative voice. Results : 1) After inputting the preoperative and corrected values of jitter, shimmer, and glottal noise into the voice synthesis Program, voices identical to vocal Polyp Patients' Pre- and Postoperative voices withiin statistical significance were synthesized 2) After elimination of synergistic effects between three paramenter, we were able to synthesize voice identical to vocal paralysis patients' preoperative voices. 3) After inputting only slightly increased jitter, shimmer into the synthesis program, we were able to synthesize voice identical to vocal cord paralysis patients' postoperative voices. Conclusion : Voices synthesized with Dr. Speech science program were identical to patients' actual pre and postoperative voice, and clinicians will be able to give the patients more information and thus increased patients cooperability can be expected.

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High purity C3A synthesis method and effect of CaCO3 on C3A initial hydration reaction (고순도 C3A 합성 방법 및 CaCO3가 C3A 초기 수화 반응에 미치는 영향)

  • Hye-Jin Yu;Woo Sung Yum
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.6
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    • pp.244-249
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    • 2023
  • In this study, various experimental parameters were investigated for high-purity C3A synthesis. As a results of experiment, it was verified that the calcined temperature was the most important parameter for the synthesis of high-purity C3A. In addition, more synthesis time was needed when large amount of C3A synthesis to achieve high-purity. Meanwhile, the C3A blended with CaCO3 showed different reaction products compared to normal cement because C15 and C30 had monocarbocaluminate as a reaction product at early stage of hydration. Furthermore, the production amount and formation rate of monocarboaluminate formation was different varying with the CaCO3 a mounts.

Singing Voice Synthesis Using HMM Based TTS and MusicXML (HMM 기반 TTS와 MusicXML을 이용한 노래음 합성)

  • Khan, Najeeb Ullah;Lee, Jung-Chul
    • Journal of the Korea Society of Computer and Information
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    • v.20 no.5
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    • pp.53-63
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    • 2015
  • Singing voice synthesis is the generation of a song using a computer given its lyrics and musical notes. Hidden Markov models (HMM) have been proved to be the models of choice for text to speech synthesis. HMMs have also been used for singing voice synthesis research, however, a huge database is needed for the training of HMMs for singing voice synthesis. And commercially available singing voice synthesis systems which use the piano roll music notation, needs to adopt the easy to read standard music notation which make it suitable for singing learning applications. To overcome this problem, we use a speech database for training context dependent HMMs, to be used for singing voice synthesis. Pitch and duration control methods have been devised to modify the parameters of the HMMs trained on speech, to be used as the synthesis units for the singing voice. This work describes a singing voice synthesis system which uses a MusicXML based music score editor as the front-end interface for entry of the notes and lyrics to be synthesized and a hidden Markov model based text to speech synthesis system as the back-end synthesizer. A perceptual test shows the feasibility of our proposed system.

Controlled Growth of Large-area Mono-, Bi-, and Few-layer Graphene by Chemical Vapor Deposition on Copper Substrate

  • Kim, Yooseok;Lee, Su-il;Jung, Dae Sung;Cha, Myoung-Jun;Kim, Ji Sun;Park, Seung-Ho;Park, Chong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.380.2-380.2
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    • 2014
  • Direct synthesis of graphene using a chemical vapor deposition (CVD) has been considered a facile way to produce large-area and uniform graphene film, which is an accessible method from an application standpoint. Hence, their fundamental understanding is highly required. Unfortunately, the CVD growth mechanism of graphene on Cu remains elusive and controversial. Here, we present the effect of graphene growth parameters on the number of graphene layers were systematically studied and growth mechanism on copper substrate was proposed. Parameters that could affect the thickness of graphene growth include the pressure in the system, gas flow rate, growth pressure, growth temperature, and cooling rate. We hypothesis that the partial pressure of both the carbon sources and hydrogen gas in the growth process, which is set by the total pressure and the mole fraction of the feedstock, could be the factor that controls the thickness of the graphene. The graphene on Cu was grown by the diffusion and precipitation mode not by the surface adsorption mode, because similar results were observed in graphene/Ni system. The carbon-diffused Cu layer was also observed after graphene growth under high CH4 pressure. Our findings may facilitate both the large-area synthesis of well-controlled graphene features and wide range of applications of graphene.

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Estimation of Camera Parameters for 3D-Based Synthesis from Uncalibrated Image Sequence (비 교정 영상에서의 영상합성을 위한 카메라 정보 복원에 관한 연구)

  • 오인환;윤용인;최종수
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.29 no.2C
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    • pp.229-237
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    • 2004
  • In this paper. we propose a new autocalibration algorithm. 3D-based image synthesis is roughly divided into two methods. One is using autocalibration method, and the other is using real 3D data like pattern information. The former is more progressive method. because there is no constraint or information about the scenes. Therefore autocalibration method has very difficult progress dealing with complicate non-lineal equations. Nowadays, constraints of camera intrinsic parameters are used in many researches. Therefore we solve the linear equations instead of complicate non-lineal equations. For example, to fix principal point of camera is a representative method.

Factored MLLR Adaptation for HMM-Based Speech Synthesis in Naval-IT Fusion Technology (인자화된 최대 공산선형회귀 적응기법을 적용한 해양IT융합기술을 위한 HMM기반 음성합성 시스템)

  • Sung, June Sig;Hong, Doo Hwa;Jeong, Min A;Lee, Yeonwoo;Lee, Seong Ro;Kim, Nam Soo
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.38C no.2
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    • pp.213-218
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    • 2013
  • One of the most popular approaches to parameter adaptation in hidden Markov model (HMM) based systems is the maximum likelihood linear regression (MLLR) technique. In our previous study, we proposed factored MLLR (FMLLR) where each MLLR parameter is defined as a function of a control vector. We presented a method to train the FMLLR parameters based on a general framework of the expectation-maximization (EM) algorithm. Using the proposed algorithm, supplementary information which cannot be included in the models is effectively reflected in the adaptation process. In this paper, we apply the FMLLR algorithm to a pitch sequence as well as spectrum parameters. In a series of experiments on artificial generation of expressive speech, we evaluate the performance of the FMLLR technique and also compare with other approaches to parameter adaptation in HMM-based speech synthesis.

A speed controller design for low speed marine diesel engine by the $\mu$-synthesis ($\mu$-설계법에 의한 저속 박용디젤기관의 속도제어기 설계)

  • 정병건;양주호;김창화
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.1
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    • pp.60-70
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    • 1995
  • In the field of marine transportation the energy saving is one of the most important factors for profit. In order to reduce the fuel oil consumption the ship's propulsion efficiency must be increased as much as possible. The propulsion efficiency depends upon a combination of an engine and a propeller. The propeller has better efficiency as lower rotational speed. This situation led the engine manufacturers to design the engine that has lower speed, longer stroke and a small number of cylinders. Consequently the variation of rotational torque became larger than before because of the longer delay-time in the fuel oil injection process and an increased output per cylinder. As this new trends the conventional mechanical-hydrualic governors for engine speed control have been replaced by digital speed controllers which adopted the PID control or the optimal control algorithm. But these control algorithms have not enough robustness to suppress the variation of the delay-time and the parameter pertubation. In this paper we consider the delay-time and the perturbation of engine parameters as the modeling uncetainties. Next we design the controller which has zero offset in steady state engine speed, based on the two-degree-of-freedom control theory and $\mu$-synthesis. Thd validity of the controller is investigated through the response simulation. We use a personal computer and an analog computer as the digital controller and the engine (plant) part respectively. And, we certify that the designed controller maintains its performance even though the engine parameters may vary.

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An Efficient Dynamic Optimization Method for Large Structures with Frequency Constraints (진동수 구속조건을 갖는 대형구조계의 효율적 동특성 최적화방법)

  • B.H. Kim;T.Y. Chung;K.C. Kim
    • Journal of the Society of Naval Architects of Korea
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    • v.31 no.2
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    • pp.91-98
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    • 1994
  • An efficient optimization procedure combining the frequency approximation technique and the component-mode synthesis method is proposed for the structural dynamic optimization of the large structures subject to prescribed natural frequency constraints. Frequency constraints are approximated by using the first-order sensitivities with respect to both design parameters and their reciprocals. The component-mode synthesis method proposed by the authors in Ref.[8] is used for the repetitive detail finite-element analysis and sensitivity analysis. The validity of the proposed optimization procedure is confirmed through the numerical implementation of some examples. The presented approximation technique requires much smaller number of repetitive analysis than that using the sensitivities with respect to design parameters only, and further improvement in the numerical efficiency is achieved by the adoption of the introduced component-mode synthesis.

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Empirical Data Analysis of a Social Network Name-Directory Service with Advertisements (광고를 동반한 소셜 네트워크 이름-디렉터리 서비스의 실험적 데이터 분석)

  • Kim, Yung Bok
    • Journal of Information Technology Services
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    • v.13 no.4
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    • pp.189-203
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    • 2014
  • With the evolution of Internet technologies and the increasing variety of Internet devices, advertisements in various web services have also expanded. Interactive web services often go hand in hand with effective advertisements for a business model. We estimated statistical parameters of the interactive web server for service monitoring and advertisement-effect. In the web pages, we integrated the plugins of social networking services (SNSs) (e.g. Facebook, Twitter) and an advertisement scheme (e.g. Google AdSense) that regards social name-directory contents. Empirical data analysis and statistical results are presented with the implementation of estimations of parameters (e.g. utilization-level and serviceability) and advertisements in a social networking name-directory service (http://ktrip.net or http://한국.net). We found that estimated parameters were applicable to service monitoring of web-server as well as to synthesis of advertisement-effect in our social-web name-directory service.