• 제목/요약/키워드: Synergetic

검색결과 150건 처리시간 0.033초

Preparation and Characterization and Visible Light Photocatalytic Activity of Fe-Treated AC/TiO2 Composites for Methylene Blue

  • Meng, Za-Da;Zhang, Kan;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제46권6호
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    • pp.621-626
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    • 2009
  • Fe-AC/Ti$O_2$ photocatalysts were prepared by a sol-gel method. The photocatalytic properties of Fe-AC/Ti$O_2$ photocatalysts for the purification of water have been investigated. The samples were characterized by scanning electron microscopy (SEM), specific surface area (BET), X-ray diffraction analysis (XRD), and energy dispersive X-ray spectroscopy (EDX). The photocatalytic activities were evaluated by the photocatalytic oxidation of methylene blue (MB) solution. It was found that the prepared Fe-AC/Ti$O_2$ composites have an excellent photocatalytic under visible light irradiation. A small amount of Fe ions in the AC/Ti$O_2$ composites could obviously enhance their photocatalytic activity. The high activities of the Fe-AC/Ti$O_2$ composites could be attributed to the results of the synergetic effects of the enhancement of the Fe element, the photocatalytic activity of Ti$O_2$, and the adsorption of AC.

치과용 티타늄 임플란트의 골융합 증진을 위한 체어사이드 친수성 표면처리방법 (Chair-side surface treatment method for inducing hydrophilicity in titanium dental implant)

  • 이정환;전수경;이해형
    • 대한치과의사협회지
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    • 제54권12호
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    • pp.985-995
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    • 2016
  • Titanium (Ti) has been widely used for dental implant due to great biocompatibility and bonding ability against natural alveolar bone. A lot of titanium surface modification has been introduced in dentistry and, among them, methods to introduce micro/nano-roughened surface were considered as clinically approved strategy for accelerating osseointegration of Ti dental implant. To have synergetic effect with topography oriented favors in cell attachment, chair-side surface treatment with reproducibility of micro/nano-topography is introduced as next strategy to further enhance cellular functionalities. Extensive research has been investigated to study the potential of micro/nano-topography preserved chair-side surface treatment for Ti dental implant. This review will discuss ultraviolet, low level of laser therapy and non-thermal atmospheric pressure plasma on Ti dental implant with micro/nano-topography as next generation of surface treatment due to its abilities to induce super-hydrophilicity or biofunctionality without change of topographical cues.

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The Effects of LMX and Feeling Trusted on Job Performance and Workplace Ostracism Among Salespeople

  • Xue, Yang;Moon, Jaeseung
    • 유통과학연구
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    • 제17권4호
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    • pp.41-50
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    • 2019
  • Purpose - The purpose of this study is to examine the impact of leader-member exchange (LMX) on employees' behaviors as well as to test the mediating roles of feeling trusted in the relationships. Research design, data, and methodology - Survey data were collected and analyzed from 285 sales people who work for various organizations in eastern China. The corresponding research models were verified using SPSS 22 and Amos 22. Results - The empirical results show that LMX plays a positive role in job performance and is positively related with subordinate's feelings of trust. However, the study was shown to have negative correlations between LMX and workplace ostracism. Feeling trusted by superiors mediated the relationship between LMX and job performance, resulting in employees being more motivated to do better, creating a positive synergetic effect. However, this relationship did not show to have significant mediating effects on the relationship between LMX and workplace ostracism. Conclusions - This study further enriches the relevant theory of LMX and has significance for management practices such as distribution sectors, guiding leaders to create a suitable team atmosphere. Leaders need to pay attention to build a high quality LMX with employees based on the empirical results of this study.

Novel Method to Confine Manganese Oxide Nanoparticles in Polyaniline Hollow Nanospheres and Its Supercapacitive Properties

  • Kwon, Hyemin;Lee, Jinho;Munkhbaatar, Naranchimeg;Yim, Sanggyu
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.196.2-196.2
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    • 2014
  • Nanostructuring the electrode surface is an emerging technology to improve the performance of supercapacitors since it can facilitate charge transfer, ion diffusion and electron propagation during electrochemical process. Fabrication of the electrode consisting of two or more materials together has also been focused on since it can provide synergetic effect such as broader working potential range and enhanced capacitance. In this work, we have used polyaniline (PANi) and manganese oxide (MnO2) as electrode materials. PANi is one of the promising electrode materials due to its high electrochemical activity, high doping level and stability. MnO2 is also widely studied material for supercapacitors since it is relatively cheap and environmentally friendly. Firstly, we synthesized polystyrene nanospheres on MnO2 nanoparticles. MnO2-incorporated PANi hollow nanospheres were then fabricated by polymerizing aniline monomers on these PS nanospheres and dissolving the inner PS spheres. The surface morphology, electronic absorption and electrical conductivity of the electrode were analyzed using field-emission scanning electron microscope (FE-SEM), UV-visible spectrometer, and sheet resistivity meter, respectively. The electrochemical properties such as capacitance of the supercapacitors were also estimated using cyclic voltammetry.

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Detection of Oxygen Species Generated from Ag2Se-Graphene Heterojunction Photocatalysts with Excellent Visible Light Driven Photocatalytic Performance

  • Meng, Ze-Da;Oh, Won-Chun
    • 한국재료학회지
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    • 제27권5호
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    • pp.255-262
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    • 2017
  • Reactive oxygen species (ROS) can be produced by interactions between sunlight and light-absorbing substances in natural water environments and can completely destroy various organic pollutants in waste water. In this study, we used graphene oxide modified $Ag_2Se$ nanoparticles to enhance photochemically generated oxygen (PGO) species activity. Surface area and pore volumes of the $Ag_2Se-graphene$ ($Ag_2Se-G$) samples showed catastrophic decrease due to deposition of $Ag_2Se$. The generation of reactive oxygen species was detected through the oxidation reaction of DPCI to DPCO. The photocurrent density and the PGO effect increase in the case of the use of modified graphene. The PGO effect of the graphene modified with $Ag_2Se$ composites increased significantly due to a synergetic effect between graphene and the $Ag_2Se$ nanoparticles. The photocatalytic activity of sample was evaluated by measuring the degradation of organic pollutants such as methylene blue (MB) and industrial dyes such as Texbrite BA-L (TBA) under visible light.

흰쥐에서 Cumambrin A의 대동맥 이완작용 (Effect of Cumambrin A on the Relaxation of Rat Aorta)

  • 홍용근;양민석;박윤배
    • 생약학회지
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    • 제36권1호통권140호
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    • pp.17-20
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    • 2005
  • We previously reported that the exogenous administration of cumambrin A, a sesquiterpene lactone from the dried flowers of Chrysanthemum boreale Makino has a pharmacological effect on normalization of blood pressure in the spontaneously hypertensive rats (SHR). In the present study, we further investigated the effect of cumambrin A on the relaxation of phenylephrine-induced precontracted rat aortic artery rings. The potency of cumambrin A was than compared to verapamil, a well known $Ca^{2+}-channel$ blocker. The results demonstrate that the isolated rat aortic arteries are relaxed to basal tension at a concentration of $5{\times}10^{-5}\;M$ cumambrin A treatment. The results also show that the phenylephrine-induced contraction is inhibited by a pretreatment of cumambrin A. Co-treatment of cumambrin A and verapamil showed a strong synergetic effect on the relaxation of rat aortic artery rings. Thus, these data demonstrate that cumambrin A is a potent relaxant of rat aortic smooth muscle and suggest that cumambrin A modulates intracellular or extracellular $Ca^{2+}$ mobilization.

3중분사가 HSDI 디젤엔진의 성능과 배기에 미치는 영향 (The Effect of Triple Injection on Engine Performance and Emissions in a HSDI Diesel Engine)

  • 최욱;박철웅;국상훈;배충식
    • 한국자동차공학회논문집
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    • 제12권5호
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    • pp.40-57
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    • 2004
  • The effects of triple (pilot, main and after) injection on combustion and emission characteristics in a HSDI (High-Speed Direct Injection) diesel engine were investigated using a single-cylinder optical diesel engine equipped with a common-rail injection system. The pilot injection affected the spray and combustion evolution of the following main injection. It was found that the pilot injection reduced the ignition delay, which led to lowered NOx (Nitric Oxides) level, and increased IMEP (Indicated Mean Effective Pressure) due to slow combustion pace during an expansion stroke. The after-injection was shown to be effective in reducing PM (Particulate Matter) even when a small amount of fuel was added. The results suggest that a proper combination of individual injection strategy could bring about a good synergetic effect on engine performance and emission.

A Study on Family Caregiver Support Programs in the U.S.A.: The Case of the State of Georgia

  • Cho, Kyungjin;Kim, Yun-Jung
    • International Journal of Human Ecology
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    • 제17권2호
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    • pp.1-15
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    • 2016
  • This is a descriptive study that introduces programs that support family caregivers looking after the elderly, by focusing on the case of Georgia, in the United States. The U.S. is one of the few countries that support family caregivers by law. In this study, we focus on the evidence-based interventions implemented through the Alzheimer's Disease Supportive Services Program (ADSSP), a federal policy that complements the National Family Caregiver Support Program (NFCSP). Our findings show that one-on-one evidence-based programs (EBPs) for family caregivers are both economical and effective in assisting caregivers. In our discussion, we highlight how the implementation of the latest EBPs can build an infrastructure to support family caregivers. ADSSP funding is useful as it constructs a caregiver support through the implementation of programs in the local community. The result is the creation of a well-coordinated division of labor among government agencies, academia and NGOs, which produces a synergetic effect in funding, research and development, translation and implementation of programs, and staff training. We conclude that the implementation of EBPs funded by the government is a useful reference for Korea and other rapidly aging countries, if we are to create an infrastructure for caregiver support, which can effectively prevent a crisis in caregiving.

Incorporation of Manganese Oxide Nanoparticles Into Polyaniline Hollow Nanospheres and Its Application to Supercapacitors

  • Kwon, Hyemin;Ryu, Ilhwan;Han, Jiyoung;Yim, Sanggyu
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.295-295
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    • 2013
  • Supercapacitors with higher energy and power density are attracting growing attention for their wide range of potential applications such as portable electronic equipments, hybrid vehicle and cellular devices. In various classes of materials for supercapacitors, the redox pseudocapacitive materials such as conducting polymers and metal oxides have been most widely studied recently. The nanostructuring of the electrode surface has also been focused on since it can provide large surface area and consequently easy diffusion of ions in the capacitors. Among the active materials, in this work, we have used polyaniline (PANi) and manganese oxide ($MnO_2$). PANi is one of the promising electrode and active materials due to its desirable properties such as high electrochemical activity, high doping level and stability. $MnO_2$ is also widely studied material for supercapacitors since it is relatively cheap and environmentally friendly. In this work, we fabricated PANi hollow nanospheres by polymerizing aniline monomers on the polystyrene (PS) nanospheres and then dissolving the inner PS spheres. This nanostructuring of the PANi surface can provide large surface area and hence easy diffusion of electrolyte ions. We also incorporated $MnO_2$ nanoparticles into the PANi hollow nanospheres and investigated its electrochemical properties. It is expected that the combination of these two active materials with slightly different working potential windows show synergetic effects such as broader working potential range and enhanced specific capacitance.

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CO-Tolerant PtMo/C Fuel Cell Catalyst for H2 Oxidation

  • Bang, Jin-Ho;Kim, Ha-Suck
    • Bulletin of the Korean Chemical Society
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    • 제32권10호
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    • pp.3660-3665
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    • 2011
  • CO-tolerant PtMo/C alloy electrocatalyst was prepared by a colloidal method, and its electrocatalytic activity toward CO oxidation was investigated. Electrochemical study revealed that the alloy catalyst significantly enhanced catalytic activity toward the electro-oxidation of CO compared to Pt/C counterpart. Cyclic voltammetry suggested that Mo plays an important role in promoting CO electro-oxidation by facilitating the formation of active oxygen species. The effect of Mo on the electronic structure of Pt was investigated using X-ray absorption spectroscopy to elucidate the synergetic effect of alloying. Our in-depth spectroscopic analysis revealed that CO is less strongly adsorbed on PtMo/C catalyst than on Pt/C catalyst due to the modulation of the electronic structure of Pt d-band. Our investigation shows that the enhanced CO electrooxidation in PtMo alloy electrocatalyst is originated from two factors; one comes from the facile formation of active oxygen species, and the other from the weak interaction between Pt and CO.