• Korean Journal of Agricultural Science
• /
• v.40 no.4
• /
• pp.367-375
• /
• 2013

The enzymatic interesterification was performed to produce structured lipids (SLs) with palm mid fraction (PMF) and stearic ethyl ester (STEE) for 1, 3, 6, 9, 12 and 15 hr at $80^{\circ}C$. The reaction was catalyzed by Lipozyme TLIM (immobilized lipase from Thermomyces lanuginosus, amount of 20% by weight of total substrates) in a shaking water bath set at 180 rpm. The optimum condition for synthesis of asymmetric SLs were: substrate molar ratio 1:0.5 (PMF:STEE, by weight), reaction time 6 hr, enzyme 20% (wt%, water activity=0.085) of total substrate and reaction temperature $80^{\circ}C$. After reaction at optimized condition, triacylglycerols (symmetrical and asymmetrical TAGs) from reactants were isolated. POP/PPO (1,3-palmitoyl-2-oleoyl glycerol or 1,2-palmitoyl-3-oleoyl glycerol), POS/PSO (palmitoyl-oleoyl-stearoyl glycerol or palmitoyl-stearoyl-oleoyl glycerol), SOS/SSO (1,3-stearoyl-2-oleoyl glycerol or 1,2-stearoyl-3-oleoyl glycerol) were obtained by solvent fractionation. Finally, refined SLs contained stearic acid of 16.91%. Solid fat index and thermogram of the refined SLs were obtained using differential scanning calorimetry. The degree of asymmetric triacylglycerol in the refined SLs was analyzed by Ag-HPLC equipped with evaporated light scattering detector (ELSD). The refined SLs consisted of symmetric TAG of 41.15 area% and asymmetric TAG of 58.85 area%.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.9 no.2
• /
• pp.143-155
• /
• 2007

The earth pressure acting on a circular shaft wall is smaller than that acting on the wall in plane strain condition due to the three dimensional axi-symmetric arching effect. Accurate estimation of the earth pressure is required for the design of the shaft wall. In this study, the stress model considering the decrease of earth pressure due to the horizontal and vertical arching effect and the influence of shape ratio (shaft height/radius) is proposed. In addition, model test on the sandy soil is conducted and a comparison is made between the stress model and the test results. The comparison shows that the proposed stress model is in agreement with test results; decrease of shape ratio (increase of radius) leads to stress state equal to the plane strain condition and approximate stress distribution is found between stress model and model test results.

• Bulletin of the Society of Naval Architects of Korea
• /
• v.27 no.4
• /
• pp.15-26
• /
• 1990

This paper describes a potential-baoed panel method formulated for the analysis cf a supercavitating two-dimensional symmetri strut. The method employs normal dipoles and sources distributed on the foil and cavity surfaces to represent the potential flow around the cavitating hydrofoil. The kinematic boundary condition on the wetted portion of the foil surface is satisfied by requiring that the total potential vanish in the fictitious inner flow region of the foil, and the dynamic boundary condition on the cavity surface is satisfied by requiring that the potential vary linearly, i.e., the tangential velocity be constant. Green's theorem then results in a potential-based integral equation rather than the usual velocity-based formulation of Hess & Smith type, With the singularities distributed on the exact hydrofoil surface, the pressure distributions are predicted with improved accuracy compared to those of the linearized lifting surface theory, especially near the leading edge. The theory then predicts the cavity shape and cavitation number for an assumed cavity length. To improve the accuracy, the sources and dipoles on the cavity surface are moved to the newly computed cavity surface, where the boundary conditions are satisfied again. This iteration process is repeated until the results are converged.

• Journal of Mechanical Science and Technology
• /
• v.15 no.4
• /
• pp.522-530
• /
• 2001

An experimental study of compressible jet flows has been undertaken in a small transonic wind tunnel. The aim of this investigation was to realize a jet simulator in the framework of wing/nacelle integration research and to characterize the jet flow behavior. First, free jet configuration, and subsequently jet flow in co-flowing air stream configuration were analyzed. Flow conditions were those encountered in a typical flight condition of a generic transport aircraft, i.e. fully expanded sonic jet flows interacting with a compressible external flowfield. Conventional experimental techniques were used to investigate the jet flows-Schlieren visualization and two-component Laser Doppler Velocimetry (LDV). The mean and fluctuating properties were measured along the jet centerline and in the symmetric plane at various downstream locations. The results of two configurations show remarkable differences in the mean and fluctuating components and agree well with the trend observed by other investigators. Moreover, these experiments enrich the database for such flow conditions and verify the feasibility of its application in future aerodynamic research of wing/nacelle interactions.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.7 no.3
• /
• pp.406-417
• /
• 1997

A numerical study was conducted on the optimum magnetic field intensity and asymmetric factor for uniform axial oxygen concentration in 8 inch silicon single crystal growing process by magnetic Czochralski method. For constant shape of cusp field, a change of coil and crucible position were compared. In case of symmetric cusp field, magnetic field intensity variation shows concave downward with crystal growing for uniform, axial oxygen concentration. A numerical results show similar value of standard deviation of average oxygen concentration for uniform oxygen concentration between coil and crucible position change. In case of asymmetric cusp field. asymmetric factor is increased with crystal growing to have uniform oxygen concentration.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.20 no.3
• /
• pp.968-977
• /
• 1996

The linear/nonlinear vibration response of the rotating hybrid cylindrical shell with simply supported boundary condition is studied. The Ritz-Galerkin method is applied to obtain the nonlinear frequency equation, which excludes in-plane and rotatory inertia but includes bending stretching coupling terms. The bifurcation phenomena for the linear frequency and the frequency ratio(nonlinear/linear frequency ratio) are presented. The hybrid cylindrical shells are composed of composite(GFRP, CFRP) metal(aluminium, steel) with symmetric and antisymmetric stacking sequence. The effects of the Coriolis and centrifugal force are considered The results also present the effects of length-to- radies ratio, radius-to-thickness ratio, the circumferential wave number, the stacking sequence, the material property, the initial excitation amplitude and the rotating speed. The present linear frequency results are compared with those of the available literature.

• Journal of the Korean Chemical Society
• /
• v.40 no.11
• /
• pp.686-691
• /
• 1996

Several kind of viologen derivatives were synthesized and the electrochromic property of these compounds was examined by cyclovoltametric and chronoamperometric method, relating to the mechanisum of coloring reaction. The electrochromic properties of 1,1'-diethyl-4,4'-bipyridinium dibromide(EV), 1,1'-dipropyl-4,4'-bipyridinium dibromide(PV), 1,1'-dibuthyl-4,4'-bipyridinium dibromide(BV) and 1-ethyl-1'-butyl-4,4'-bipyridinium dibromide(EBV) are studied by using an propylenecarbonate/methanol solution with $Bu_4NBF_4$ as supporting electrolyte. A monomer-dimer equilibrium was proposed to explain the related observation that EV and EBV cation radical solutions are violet at an applied voltage of 1.7∼3.0V but become blue in open-circuit condition.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.9
• /
• pp.2758-2764
• /
• 2014

We demonstrated the synthesis of organic carbonates using alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates and alcohol in the presence of aluminum chloride. Alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates were reacted with alcohol in the presence of $AlCl_3$ in toluene at room temperature to afford the corresponding unsymmetric and symmetric organic carbonates in good to excellent yields. These are efficient and convenient processes. Alkyl/aryl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylates are solid, stable and non-toxic $CO_2/CO_2R$(Ar) source. It is noteworthy that the reaction is carry out under an ambient and acidic conditions, the easy-to prepare and readily available starting materials and the quantitative isolation of reusable 4,5-dichloropyridazin-3(2H)-one.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.22 no.4
• /
• pp.731-742
• /
• 1998

Bolted opening structures is widely applied for class 1 machinery of nuclear plant with strict design requirement. As the shape of the bolted opening structure is non-axisymmetric due to the existence of stud bolts although it is almost axi-symmetric, 3D analysis is required to satisfy such kind of design requirements. Because as much as possible trial computations are need to get an optimal design condition in the limited period of basic design, an easy and fast analysis tool is useful in the design stage. In the paper, a transformation technique of non-axisymmetric problem into quasi-axisymmetric has been proposed based on the general purpose commercial code ANSYS. Both the pre-processor which incorporates the technique and prepares data and post-processor which prepares arranged results from the huge output of commercial code have been developed to help the design engineers.

• Journal of computational fluids engineering
• /
• v.11 no.3 s.34
• /
• pp.28-36
• /
• 2006

NSBT(No Slip Boundary Treatment) is a newly developed scheme for the treatment of a no slip condition on the solid wall of obstacle in a flow field. In our research, NSBT was used to perform LBM simulation of a flow over a circular cylinder to determine the flow feature and aerodynamics characteristic of the cylinder. To ascertain the applicability of NSBT on the complex shape of the obstacle, it was first simulated for the case of the flow over a circular and square cylinder in a channel and the results were compared against the solution of Navier-Stokes equation. The simulations were performed in a moderate range of Reynolds number at each cylinder position to identify the flow feature and aerodynamic characteristics of circular cylinder in a channel. The drag coefficients of the cylinder were calculated from the simulation results. We have numerically confirmed that the critical reynolds number for vortex shedding is in the range of 200$\sim$250. For the gap parameter $\gamma$ = 2 cases at Re > 240, the vortex shedding were symmetric and it resembled the Karmann vortex. As the cylinder approached to one wall, the vorticity significantly reduced in length while the vorticity on the other side elongated and the vorticity combined with the wall boundary-layer vorticity. The resultant $C_d$ by LBM concurred with the results of DNS simulation performed by previous researchers.